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At least 541 records · Page 30

A general diagram for estimating pore size of ultrafiltration and reverse osmosis membranes

A slit sieve model has been used to develop a general correlation between the average pore size of the upstream surface of a membrane and the molecular weight of the solute which it retains by better than 80%. The pore size is determined by means of the correlation using the high retention data from an ultrafiltration (UF) or a reverse osmosis (RO) experiment. The pore population density can also be calculated from the flux data via appropriate equations.

Sarbolouki, M. N.↗

Single-pulse gas thermometry at low temperatures using two-photon laser-induced fluorescence in NO-N2 mixtures

A technique suitable for measuring fluctuating temperatures in supersonic turbulent flows of N2 seeded with NO has been demonstrated in a nonflowing cell. The method relies on the two photon excitation of two selected ro-vibronic transitions in the NO gamma (alpha 2 sigma+, v prime = 0 yields ch1zp1, v double prime = 0). Previously announced in STAR as N83-20079

Gross, K. P.↗

Geostrophic adjustment in a shallow-water numerical model as it relates to thermospheric dynamics

The theory of geostrophic adjustment and its application to the dynamics of the high latitude thermosphere have been discussed in previous papers based on a linearized treatment of the fluid dynamical equations. However, a linearized treatment is only valid for small Rossby numbers given by Ro = V/fL, where V is the wind speed, f is the local value of the Coriolis parameter, and L is a characteristic horizontal scale for the flow. For typical values in the auroral zone, the approximation is not reasonable for wind speeds greater than 25 m/s or so. A shallow-water (one layer) model was developed that includes the spherical geometry and full nonlinear dynamics in the momentum equations in order to isolate the effects of the nonlinearities on the adjustment process. A belt of accelerated winds between 60 deg and 70 deg latitude was used as the initial condition. The adjustment process was found to proceed as expected from the linear formulation, but that an asymmetry between the response for an eastward and westward flow results from the nonlineawr curvature (centrifugal) terms. In general, the amplitude of an eastward flowing wind will be less after adjustment than a westward wind. For instance, if the initial wind velocity is 300 m/s, the linearized theory predicts a final wind speed of 240 m/s, regardless of the flow direction. However, the nonlinear curvature terms modify the response and produce a final wind speed of only 200 m/s for an initial eastward wind and a final wind speed of almost 300 m/s for an initial westward flow direction. Also, less gravity wave energy is produced by the adjustment of the westward flow than by the adjustment of the eastward flow. The implications are that the response of the thermosphere should be significantly different on the dawn and dusk sides of the auroral oval. Larger flow velocities would be expected on the dusk side since the plasma will accelerate the flow in a westward direction in that sector.

Larsen, M. F.↗

Multispecies CARS measurements in turbulent combustion

A coherent anti-Stokes Raman scattering (CARS) instrument was upgraded to more accurately measure the number density of oxygen molecules. This instrument is designed to simultaneously measure nitrogen number density, oxygen number density, and the ro-vibrational temperature of nitrogen. The CARS is a nonintrusive diagnostic technique which utilizes a pulsed Nd:YAG laser, broadband dye lasers, a complex optical system, and an intensified photodiode array detector to sample hostile combustion environments. Measurements were made in a flame produced by a coaxial subsonic diffusion hydrogen-air burner. These data were used as a data base for comparison with the results of two separate computational fluid dynamics calculations. Complications which had arisen in previous studies with regard to interpretation of the oxygen data were eliminated.

Antcliff, Richard R.↗

The decay of isotropic turbulence in a rapidly rotating frame

A direct numerical simulation of the decay of initially isotropic turbulence in a rapidly rotating frame was conducted. This 128 x 128 x 128 simulation was completed for a Reynolds number Re sub lambda = 15.3 and a Rossby number Ro sub lambda = 0.07 based on the initial turbulent kinetic energy and Taylor microscale. The numerical results indicate that the turbulence remains essentially isotropic during the major part of the decay (i.e., beyond the point where the turbulent kinetic energy has decayed to less than 10 percent of its initial value). The rapid rotation has the primary effect of shutting off the energy transfer so that the turbulence dissipation (and hence the rate of decay of the turbulent kinetic energy) is substantially reduced. Consequently, the anisotropy tensor remains essentially unchanged while the energy spectrum undergoes a nearly linear viscous decay (the same results that are predicted by Rapid Distortion Theory which is only formally valid for much shorter elapsed times. Surprisingly, no Taylor-Proudman reorganization of the flow to a two-dimensional state is observed. The implications that these results have on turbulence modeling are discussed briefly along with prospective future research.

Speziale, C. G.↗

An assessment of potential degradation products in the gas-phase reactions of alternative fluorocarbons in the troposphere

Tropospheric chemical transformations of alternative hydrofluorocarbons (HCF's) and hydrochlorofluorocarbons (HCFC's) are governed by hydroxyl radical initiated oxidation processes, which are likely to be analogous to those known for alkanes and chloroalkanes. A schematic diagram is used to illustrate plausible reaction mechanisms for their atmospheric degradation, where R, R', and R'' denote the F- and/or Cl-substituted alkyl groups derived from HCF's and HCFC's subsequent th the initial H atom abstraction by HO radicals. At present, virtually no kinetic data exist for the majority of these reactions, particularly for those involving RO. Potential degradation intermediates and final products include a large variety of fluorine- and/or chlorine-containing carbonyls, acids, peroxy acids, alcohols, hydrogen peroxides, nitrates and peroxy nitrates, as summarized in the attached table. Probably atmospheric lifetimes of these compounds were also estimated. For some carbonyl and nitrate products shown in this table, there seem to be no significant gas-phase removal mechanisms. Further chemical kinetics and photochemical data are needed to quantitatively assess the atmospheric fate of HCF's and HCFC's, and of the degradation products postulated in this report.

Niki, Hiromi↗

Reactant conversion in homogeneous turbulence: Mathematical modeling, computational validations and practical applications

Closed form analytical expressions are obtained for predicting the limited rate of reactant conversion in a binary reaction of the type F + rO yields (1 + r) Product in unpremixed homogeneous turbulence. These relations are obtained by means of a single point Probability Density Function (PDF) method based on the Amplitude Mapping Closure. It is demonstrated that with this model, the maximum rate of the reactants' decay can be conveniently expressed in terms of definite integrals of the Parabolic Cylinder Functions. For the cases with complete initial segregation, it is shown that the results agree very closely with those predicted by employing a Beta density of the first kind for an appropriately defined Shvab-Zeldovich scalar variable. With this assumption, the final results can also be expressed in terms of closed form analytical expressions which are based on the Incomplete Beta Functions. With both models, the dependence of the results on the stoichiometric coefficient and the equivalence ratio can be expressed in an explicit manner. For a stoichiometric mixture, the analytical results simplify significantly. In the mapping closure, these results are expressed in terms of simple trigonometric functions. For the Beta density model, they are in the form of Gamma Functions. In all the cases considered, the results are shown to agree well with data generated by Direct Numerical Simulations (DNS). Due to the simplicity of these expressions and because of nice mathematical features of the Parabolic Cylinder and the Incomplete Beta Functions, these models are recommended for estimating the limiting rate of reactant conversion in homogeneous reacting flows. These results also provide useful insights in assessing the extent of validity of turbulence closures in the modeling of unpremixed reacting flows. Some discussions are provided on the extension of the model for treating more complicated reacting systems including realistic kinetics schemes and multi-scalar mixing with finite rate chemical reactions in more complex configurations.

Madnia, C. K.↗

Coronal mass ejections and the injection profiles of solar energetic particle events

Previous studies using Skylab and Solwind coronagraph observations have shown that almost all E greater than 10 MeV solar energetic proton (SEP) events are associated with the occurrence of a coronal mass ejection (CME). These earlier studies did not address the relationship between the position of the associated CME and the timing of the injection of particles into the interplanetary medium. Ten cases are selected in which a SEP event observed with the GSFC detectors on the IMP 8 or ISEE 3 spacecraft was correlated to a CME well observed by the Solwind coronagraph. The height of the leading edge of the CME is compared with the particle injection profiles for several energy ranges using the solar release times for the particles. The derived injection profiles are found to be increasing and sometimes reaching maximum while the associated CMEs are at heights of 2-10 Ro.

Kahler, S. W.↗

The anomalous extinction curve in the direction of Rho Ophiuchi from 950 to 1180 A

We report the interstellar extinction from 950 to 1180 A in the direction of Rho Oph. These data were obtained with a moderate-resolution sounding rocket observation of Ro Oph, and two lightly reddened B stars of identical spectral type. Unlike Voyager observations in this wavelength region, our spectral resolution is sufficient to directly measure the contribution of molecular hydrogen along the line of sight and unambiguously identify the dust contribution. The derived curves compare favorably with the extrapolation of functional fits to the Rho Oph derived from longer wavelengths. In addition, we have fitted a model of dust extinction to the derived curve and find that the best fits indicate that the line of sight exhibits a larger than average grain size and a preferential concentration of graphite relative to silicates. The sharp rise seen at the shortest wavelengths (below 1000 A) cannot be explained by standard silicate-graphite dust models and may be indicative of a nonstandard grain shape or a missing component in the extinction models.

Green, James C.↗

Planar imaging of OH density distributions in a supersonic combustion tunnel

Images of absolute OH number density were obtained using planar laser-induced fluorescence (PLIF) in a supersonic H2-air combustion tunnel. A tunable KrF excimer laser was used to excite the Q2(11) ro-vibronic line. Calibration of the PLIF images was obtained by referencing the signal measured in the flame to that obtained by the excitation of OH produced by thermal dissociation of H2O in an atmospheric furnace. Measurement errors due to uncertainty in internal furnace atmospheric conditions and image temperature correction are estimated.

Quagliaroli, T. M.↗

The dependence of the dissipation on rotation

A form of the evolution equation for the dissipation showing the effects of rotation is derived directly from the Navier-Stokes equations. Rotation affects the dissipation if the flow is inhomogeneous or compressible. This is due to the fact that pressure scales with inverse Rossby number and certain pressure correlations usually neglected have to be retained when Re Ro is approximately equal to 1. The term reflecting the effects of rotation on the dissipation is a volume integral of the two-point velocity correlation similar in structure to the 'rapid-pressure' correlation appearing in the second-moment equations. Some of its properties are indicated.

Ristorcelli, J. R.↗

Flame quenching by a variable-width rectangular-slot burner as a function of pressure for various propane-oxygen-nitrogen mixtures

Flame quenching by a variable-width rectangular-slot burner as a function of pressure for various propane-oxygen-nitrogen mixtures was investigated. It was found that for cold gas temperatures of 27 degrees C, pressures of 0.1 ro 1.0 atmosphere, and volumetric oxygen reactions of the oxidant of 0.17, 0.21, 0.30, 0.50, and 0.70, the relation between pressure p and quenching distance d is approximately given by d (unity) p (superscript -r) with r = 1, for equivalence ratios approximately equal to one. The quenching equation of Simon and Belles was tested. For equivalence ratios less than or equal to unity, this equation may by used, together with one empirical constant, to predict the observed quenching distance within 4.2 percent. The equation in it's present form does not appear to be suitable for values of the equivalence ratio greater than unity. A quantitative theoretical investigation has also been made of the error implicit in the assumption that flame quenching by plane parallel plates of infinite extent is equivalent to that of a rectangular burner. A curve is presented which relates the magnitude of this error to the length-to-width ratio of the rectangular burner.

COMBUSTION RESEARCH↗

Surface-pressure Distributions on a Systematic Group of NACA 1-series Cowlings with and Without Spinners

A method for calculating the flow fields of axially symmetric bodies from their pressure distributions is reported in NACA RM No. L8I17. In order to facilitate application of this method to the important case of the cowling-spinner combination, for use in the design of propellers, the present paper presents static-pressure distributions on the tops of 79 high-critical-speed NACA 1-series cowling-spinner combinations over wide ranges of inlet-velocity ratio at angles of attack of 0 degrees, 2 degrees, 4 degrees, and 6 degrees. Static-pressure distributions around the nose sections of several cowlings are given in greater detail to aid in estimating the pressures near the stagnation points and to show the effect of changes in the internal lip shape. The effects of the operation of a typical propeller on the surface pressures on the cowling are shown for one configuration. The pressure distributions over the nine NACA 1-series nose inlets used as the basic components of these combinations are also presented ro supplement the existing open-nose-cowling data of NACA ACR No. L5F30a which are applicable to the case of the rotating cowling.

Boswinkle, Robert W JR↗

Measurement of atmospheric OH by titration of near-IR fluorescent dyes

Recent research has shown that certain polymethine dyes can be detected at ultratrace levels (greater than or equal to 6x10(exp -14) M) in solution by fluorimetry. These detection limits are possible because of the inherent sensitivity of fluorescence techniques, because the dyes fluoresce in the near infrared region where background interference is negligible, and because powerful infrared diode lasers are now available to improve the signal to noise ratio. Other work has shown that the hydroxyl radical destroys the ability of polymethine dyes to fluoresce. These observations form the basis for a new hydroxyl radical detector that is essentially a fluorometric titrator. Theoretically, the detector should show an acceptable sensitivity and response time. Assuming that the atmospheric HO concentration is about 10(exp -11) moles m(exp -3) (i.e. 10(exp 6) molecules cm(exp -3)), then 10 L of air 'titrated' with 20 mL of 10(exp -11) M dye solution (an easily detected concentration) should result in a drop in the fluorescent signal of 50 percent - a readily detectable change. At a flow rate of 3 L min(exp -1) the sampling time would be 3 minutes. The biggest potential problem is selectivity: other oxidants may also cause the fluorescence signal to be lost. The chemistry of polymethine dyes has not been studied in detail and so no quantitative data are available. However, a survey of the literature suggests that in general HO should react up to six orders of magnitude faster than HO2 and other radicals such as RO2 and RO. It should also react much more rapidly than H2O2 and O3. Thus it may be possible to discriminate kinetically against potential interfering substances. It was shown in the laboratory that 10(exp -4) M H2O2 has little effect on the absorption spectrum of the dye IR125 over a period of hours but that the band at 780 nm is slowly lost in water over a period of days even under argon in the dark. By contrast, DMSO solutions of IR125 are stable.

Betterton, Eric A.↗

The radical amplifier

The radical amplifier as a method for measuring radical concentrations in the atmosphere has received renewed attention lately. In principle, it can measure the total concentration of HO(x) and RO(x) radicals by reacting ambient air with high concentrations of CO (3-10 percent) and NO (2-6 ppmv), and measuring the NO2 produced.

Hastie, D. R.↗

ROSAT observations of four unidentified EMSS sources

We present an analysis of four unidentified Einstein Observatory Extended Medium Sensitivity Survey sources detected in two pointed ROSAT/Position Sensitive Proportional Counter (PSPC) observations. One source (MS0420.0-3838) is resolved in two sources denoted with N (North) and S (South) in the ROSAT image. Only for one source (MS0420.6-3839) we have enough counts to allow a spectral analysis. For the other sources we have limited ourselves to the calculation of the x-ray hardness ratio and then, assuming a galactic value for the hydrogen column density, we have derived an energy index alpha (sub epsilon). We find a wide range of alpha(sub epsilon) (1 equal to or less than alpha(sub epsilon) equal to or less than 3). Thanks to a significantly improved x-ray positional accuracy, generally only one or two objects down to approx. 22 mag are present in the error circle. We have spectroscopically identified three sources with AGN: two are radio-quiet Quasi-Stellar Object (QSO) at z = 0.831 and z = 0.482, the third one is a Narrow Emission Line Galaxy at z = 0.572. For the remaining sources no optical spectroscopy is available; however, the values of alpha(sub ox) and alpha(sub ro) show that also these sources are probably AGN.

Ciliegi, Paolo↗

The Advanced Communication Technology Satellite and ISDN

This paper depicts the Advanced Communication Technology Satellite (ACTS) system as a global central office switch. The ground portion of the system is the collection of earth stations or T1-VSAT's (T1 very small aperture terminals). The control software for the T1-VSAT's resides in a single CPU. The software consists of two modules, the modem manager and the call manager. The modem manager (MM) controls the RF modem portion of the T1-VSAT. It processes the orderwires from the satellite or from signaling generated by the call manager (CM). The CM controls the Recom Laboratories MSPs by receiving signaling messages from the stacked MSP shelves ro units and sending appropriate setup commands to them. There are two methods used to setup and process calls in the CM; first by dialing up a circuit using a standard telephone handset or, secondly by using an external processor connected to the CPU's second COM port, by sending and receiving signaling orderwires. It is the use of the external processor which permits the ISDN (Integrated Services Digital Network) Signaling Processor to implement ISDN calls. In August 1993, the initial testing of the ISDN Signaling Processor was carried out at ACTS System Test at Lockheed Marietta, Princeton, NJ using the spacecraft in its test configuration on the ground.

Lowry, Peter A.↗

The 27-28 October 1986 FIRE IFO Cirrus Case Study: Cloud Optical Properties Determined by High Spectral Resolution Lidar

During the First ISCCP Region Experiment (FIRE) cirrus intensive field observation (IFO) the High Spectral Resolution Lidar was operated from a roof top site on the University of Wisconsin-Madison campus. Because the HSRL technique separately measures the molecular and cloud particle backscatter components of the lidar return, the optical thickness is determined independent of particle backscatter. This is accomplished by comparing the known molecular density distribution to the observed decrease in molecular backscatter signal with altitude. The particle to molecular backscatter ratio yields calibrated measurements of backscatter cross sections that can be plotted ro reveal cloud morphology without distortion due to attenuation. Changes in cloud particle size, shape, and phase affect the backscatter to extinction ratio (backscatter-phase function). The HSRL independently measures cloud particle backscatter phase function. This paper presents a quantitative analysis of the HSRL cirrus cloud data acquired over an approximate 33 hour period of continuous near zenith observations. Correlations between small scale wind structure and cirrus cloud morphology have been observed. These correlations can bias the range averaging inherent in wind profiling lidars of modest vertical resolution, leading to increased measurement errors at cirrus altitudes. Extended periods of low intensity backscatter were noted between more strongly organized cirrus cloud activity. Optical thicknesses ranging from 0.01-1.4, backscatter phase functions between 0.02-0.065 sr (exp -1) and backscatter cross sections spanning 4 orders of magnitude were observed. the altitude relationship between cloud top and bottom boundaries and the cloud optical center altitude was dependent on the type of formation observed Cirrus features were observed with characteristic wind drift estimated horizontal sizes of 5-400 km. The clouds frequently exhibited cellular structure with vertical to horizontal dimension ratios of 1:5-1:1.

Grund, C. J.↗