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At least 541 records · Page 30

Structure, Mobility, and Composition of Transition Metal Catalyst Surfaces. High-Pressure Scanning Tunneling Microscopy and Ambient-Pressure X-ray Photoelectron Spectroscopy Studies

Surface structure, mobility, and composition of transition metal catalysts were studied by high-pressure scanning tunneling microscopy (HP-STM) and ambient-pressure X-ray photoelectron spectroscopy (AP-XPS) at high gas pressures. HP-STM makes it possible to determine the atomic or molecular rearrangement at catalyst surfaces, particularly at the low-coordinated active surface sites. AP-XPS monitors changes in elemental composition and chemical states of catalysts in response to variations in gas environments. Stepped Pt and Cu single crystals, the hexagonally reconstructed Pt(100) single crystal, and Pt-based bimetallic nanoparticles with controlled size, shape and composition, were employed as the model catalysts for experiments in this thesis.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Overview of On-Line Optical Measurements at High Pressure for Flue Gases, Particulates and Acid-dew Point of Pressurized Oxy-Combustion

Optical flow cells are critical measurement interfaces, yet sampling under harsh conditions — high pressure, high temperature, particles, moisture, or corrosive gases — makes it difficult to maintain optical quality without perturbing the measurement. To address this challenge, a new flow cell was developed using a laminar coaxial flow field that separates the purge and sample flows. A dedicated test system was built to evaluate particle size distribution (PSD) measurements using a Malvern Panalytical Insitec analyzer. Results demonstrated that the sample flow alone defines the measurement zone, while the purge flow effectively shields the optical windows from deposition, eliminating sampling bias. The flow cell enables reliable PSD measurement under high pressure and temperature in moist, corrosive environments. As a key demonstration, the instrument was successfully deployed for on-line PSD measurement of flue gas from a 100 kWth pressurized oxy-coal combustor at 15 bara.

Cheng, Mao↗

High-pressure regulating system prevents pressure surges

Gas flow is controlled by means of a pressure regulating system which prevents pressure surges. A high-pressure fluid source, a spring-loaded fluid-damped regulator valve, an accumulator, a conventional normally closed command valve, and a control valve are the main components.

Keller, O. F.↗

Programmed-pressure air supply for positive-pressure breathing system

Motor-driven cam varies height of mercury column connected to loading diaphragm of pressure-regulating valve. Air supplied to open-loop, positive pressure breathing system is controlled so repetitive pressure--time profiles can be obtained during every insufflation--exhaust cycle.

Troutman, S. J., Jr.↗

A dynamic pressure generator for checking complete pressure sensing systems installed on an airplane

A portable dynamic pressure generator, how it operates, and a test setup on an airplane are described. The generator is capable of providing a sinusoidal pressure having a peak-to-peak amplitude of 3.5 N/sq cm (5 psi) at frequencies ranging from 100 hertz to 200 hertz. A typical power spectral density plot of data from actual dynamic pressure fluctuation tests within the air inlet of the YF-12 airplane is presented.

Demarco, D. M.↗

High-pressure cryogenic seals for pressure vessels

Problems associated with maintaining high pressures at cryogenic temperatures in pressure vessels are investigated. The goals were to identify the appropriate materials and design for a seal intended for cryogenic applications at pressures up to 4,080 bars (60,000 psi), and to examine the factors affecting the seal performance. The method employed and the apparatus used in a series of experimental seal system tests, and the test results are described in detail. It is concluded that the common seal designs and extrusion seal-ring materials such as Teflon, tin, and lead are not suitable. However, new seal systems developed using indium seal rings, brass or 304 stainless steel anvil rings, and two 0-rings of silicone rubber or Kel-F did prove suitable.

Buggle, A. E.↗

Low-pressure performance of annular, high-pressure (40 atm) high-temperature (2480 K) combustion system

Experimental tests were conducted to develop a combustion system for a 40 atmosphere pressure, 2480 K exhaust gas temperature, turbine cooling facility. The tests were conducted in an existing facility with a maximum pressure capability of 10 atmospheres and where inlet air temperatures as high as 894 K could be attained. Exhaust gas temperatures were as high as 2365 K. Combustion efficiences were about 100 percent over a fuel air ratio range of 0.016 to 0.056. Combustion efficiency decreased at leaner and richer ratios when the inlet air temperature was 589 K. Data are presented that show the effect of fuel air ratio and inlet air temperature on liner metal temperature. Isothermal system pressure loss as a function of diffuser inlet Mach number is also presented. Data included exhaust gas pattern factors; unburned hydrocarbon, carbon monoxide, and oxides of nitrogen emission index values; and smoke numbers.

Wear, J. D.↗

Generalization of low pressure, gas-liquid, metastable sound speed to high pressures

A theory is developed for isentropic metastable sound propagation in high pressure gas-liquid mixtures. Without simplification, it also correctly predicts the minimum speed for low pressure air-water measurements where other authors are forced to postulate isothermal propagation. This is accomplished by a mixture heat capacity ratio which automatically adjusts from its single phase values to approximately the isothermal value of unity needed for the minimum speed. Computations are made for the pure components parahydrogen and nitrogen, with emphasis on the latter. With simplifying assumptions, the theory reduces to a well known approximate formula limited to low pressure.

Bursik, J. W.↗

Dynamic-pressure measurements using an electronically scanned pressure module

Frequency response was measured for different lengths and diameters of tubing between a sinusoidal pressure source and a pressure sensing module from an electronically scanned pressure measuring system. Measurements were made for straight runs of both steel and vinyl tubing. For steel tubing, measured results are compared with results calculated by using equations developed by Tijdeman and Bergh. Measurements were also made with a bend in the vinyl tubing at the module. In addition, measurements were made with two coils placed in the tubing near the middle of the run.

Chapin, W. G.↗

An experimental study of the properties of surface pressure fluctuations in strong adverse pressure gradient turbulent boundary layers

Experimental data were obtained on blade self-noise generation by strong adverse-pressure-gradient attached boundary layers and by separated turbulent boundary layers that accompany stall. Two microphones were calibrated, placed in plastic housing, and installed in a wind tunnel where observations of acoustic and turbulent signals permitted decomposition of the surface pressure fluctuation signals into the propagated acoustic part and the turbulent-flow generated portion. To determine the convective wave speed of the turbulent contributions, the microphones were spaced a small distance apart in the streamwise direction and correlations were obtained. The turbulent surface pressure spectra upstream of detachment and downstream of the beginning of separation are discussed as well as measurements of turbulent velocity spectra and wavespeeds.

Simpson, R. L.↗

Pressure distribution data from tests of 2.29 M (7.5 feet) span EET high-lift transport aircraft model in the Ames 12-foot pressure tunnel

A high-lift transport aircraft model equipped with full-span leading-edge slat and part-span double-slotted trailing-edge flap was tested in the Ames 12-ft pressure tunnel to determine the low-speed performance characteristics of a representative high-aspect-ratio supercritical wing. These tests were performed in support of the Energy Efficient Transport (EET) program which is one element of the Aircraft Energy Efficiency (ACEE) project. Static longitudinal forces and moments and chordwise pressure distributions at three spanwise stations were measured for cruise, climb, two take-off flap, and two landing flap wing configurations. The tabulated and plotted pressure distribution data is presented without analysis or discussion.

Kjelgaard, S. O.↗

Description of a Pressure Measurement Technique for Obtaining Surface Static Pressures of a Radial Turbine

The aerodynamic performance of a solid uncooled version of a cooled radial turbine was evaluated in the Small Engine Components Test Facility Turbine rig at the NASA Lewis Research Center. Specifically, an experiment was conducted to rotor surface static pressures. This was the first time surface static pressures had been measured on a radial turbine at NASA Lewis. These pressures were measured by a modified Rotating Data Package (RDP), a standard product manufactured by Scanivalve, Inc. Described here are the RDP, and the modifications that were made, as well as the checkout, installation, and testing procedures. The data presented are compared to analytical results obtained from NASA's MERIDL TSONIC BLAYER (MTSB) code.

Dicicco, L. Danielle↗

Description of a pressure measurement technique for obtaining surface static pressures of a radial turbine

The aerodynamic performance of a solid uncooled version of a cooled radial turbine was evaluated in the Small Engine Components Test Facility Turbine rig at the NASA Lewis Research Center. Specifically, an experiment was conducted to rotor surface static pressures. This was the first time surface static pressures had been measured on a radial turbine at NASA Lewis. These pressures were measured by a modified Rotating Data Package (RDP), a standard product manufactured by Scanivalve, Inc. Described here are the RDP, and the modifications that were made, as well as the checkout, installation, and testing procedures. The data presented are compared to analytical results obtained from NASA's MERIDL TSONIC BLAYER (MTSB) code.

Dicicco, L. D.↗

A Balanced-pressure Sliding Seal for Transfer of Pressurized Air Between Stationary and Rotating Parts

A combination sliding-ring and pressure-balancing seal capable of transferring pressurize air from stationary to rotating parts was developed and experimentally investigated at sliding velocities and cooling-air pressures up to 10,000 feet per minute and 38.3 pounds per square inch absolute, respectively. Leakage of cooling air was completely eliminated with an expenditure of balance air less than one-fourth the leakage loss of air from labyrinth seals under the same conditions. Additional cooling of the carbon-base seal rings was required, and the maximum wear rate on the rings was about 0.0005 inch per hour.

Curren, Arthur N↗