Engineering Papers⌕ Search

SEARCH · Engineering Papers

Results for “Population Structure”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 541 records · Page 30
All sourcesNASA NTRSDOE OSTI
DOE OSTI2021

Catalytic CO Oxidation on MgAl 2 O 4 -Supported Iridium Single Atoms: Ligand Configuration and Site Geometry

Probing and understanding the local chemical environment of an active site is essential for designing high-performance single-atom catalysts (SACs). Density functional theory (DFT) calculations were performed to investigate the ligand configuration and site geometry of MgAl 2 O 4 -supported iridium single atoms (Ir-1) toward catalytic carbon monoxide (CO) oxidation. We employed MgAl 2 O 4 (111) and MgAl 2 O 4 (211) as the model substrates with adsorbed Ir single atoms of different site geometries. DFT calculations revealed that the Mg-site on MgAl 2 O 4 (111) and the step site on MgAl 2 O 4 (211) are the most stable adsorption sites for Ir single atoms. Irrespective of site choices, CO oxidation on supported Ir single atoms follows the Eley-Rideal (E-R) mechanism, in which the surface oxygen vacancies close to the Ir single atoms activate molecular O 2 with a negligible barrier and the rate-limiting step is the gas-phase CO directly attacking the O-Ir species that is modulated by a CO ligand. Furthermore, first-principles X-ray absorption near-edge spectra of reaction intermediates along with in situ/operando X-ray absorption spectroscopy (XAS) suggest that Ir single atoms adsorb primarily on the step sites of MgAl 2 O 4 . However, microkinetic modeling predicts that a higher activity can be attained on the equally stable Mg-site, maximizing the population of which in catalyst synthesis might prove fruitful in future studies. Electronic structure analysis indicates that the CO ligand increases the reactivity of adsorbed oxygen atoms bound to Ir single atoms by increasing the antibonding nature of the O-Ir bond.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2022

Entropy Stabilization Effects and Ion Migration in 3D “Hollow” Halide Perovskites

A recently discovered new family of 3D halide perovskites with the general formula (A) 1–x (en) x (Pb) 1–0.7x (X) 3–0.4x (A = MA, FA; X = Br, I; MA = methylammonium, FA = formamidinium, en = ethylenediammonium) is referred to as “hollow” perovskites owing to extensive Pb and X vacancies created on incorporation of en cations in the 3D network. The “hollow” motif allows fine tuning of optical, electronic, and transport properties and bestowing good environmental stability proportional to en loading. To shed light on the origin of the apparent stability of these materials, we performed detailed thermochemical studies, using room temperature solution calorimetry combined with density functional theory simulations on three different families of “hollow” perovskites namely en/FAPbI 3 , en/MAPbI 3 , and en/FAPbBr 3 . We found that the bromide perovskites are more energetically stable compared to iodide perovskites in the FA-based hollow compounds, as shown by the measured enthalpies of formation and the calculated formation energies. The least stable FAPbI 3 gains stability on incorporation of the en cation, whereas FAPbBr 3 becomes less stable with en loading. This behavior is attributed to the difference in the 3D cage size in the bromide and iodide perovskites. Configurational entropy, which arises from randomly distributed cation and anion vacancies, plays a significant role in stabilizing these “hollow” perovskite structures despite small differences in their formation enthalpies. With the increased vacancy defect population, we have also examined halide ion migration in the FA-based “hollow” perovskites and found that the migration energy barriers become smaller with the increasing en content.

36 MATERIALS SCIENCE↗
DOE OSTI2023

Antigen pressure from two founder viruses induces multiple insertions at a single antibody position to generate broadly neutralizing HIV antibodies

Vaccination strategies aimed at maturing broadly neutralizing antibodies (bnAbs) from naïve precursors are hindered by unusual features that characterize these Abs, including insertions and deletions (indels). Longitudinal studies of natural HIV infection cases shed light on the complex processes underlying bnAb development and have suggested a role for superinfection as a potential enhancer of neutralization breadth. Here we describe the development of a potent bnAb lineage that was elicited by two founder viruses to inform vaccine design. The V3-glycan targeting bnAb lineage (PC39-1) was isolated from subtype C-infected IAVI Protocol C elite neutralizer, donor PC39, and is defined by the presence of multiple independent insertions in CDRH1 that range from 1-11 amino acids in length. Memory B cell members of this lineage are predominantly atypical in phenotype yet also span the class-switched and antibody-secreting cell compartments. Development of neutralization breadth occurred concomitantly with extensive recombination between founder viruses before each virus separated into two distinct population “arms” that evolved independently to escape the PC39-1 lineage. Ab crystal structures show an extended CDRH1 that can help stabilize the CDRH3. Overall, these findings suggest that early exposure of the humoral system to multiple related Env molecules could promote the induction of bnAbs by focusing Ab responses to conserved epitopes.

59 BASIC BIOLOGICAL SCIENCES↗
DOE OSTI2021

The Resilience Planning Landscape for Communities and Electric Utilities

Synapse Energy Economics has conducted structured interviews to better characterize the current landscape of resilience planning within and across jurisdictions. Synapse interviewed representatives of a diverse group of communities and their electric utilities. The resulting case studies span geographies and utility regulatory structures and represent a range of threats. They also vary in terms of population density and size. This report summarizes our approach and the findings gleaned from these conversations. All the communities and utilities we interviewed see increased interest in and commitment of resources for energy-related resilience. The risks and consequences these communities and utilities faced in the past, face now, and will face in the future drove them to improve engagement, advance processes, further decision-making, and in many cases invest in projects. While no process used by communities and utilities was the same, the different processes used by communities and utilities allowed each one to make progress in its own way. Several approaches are emerging that can provide good models for other communities and utilities with an interest in improving resilience.

29 ENERGY PLANNING, POLICY, AND ECONOMY↗
DOE OSTI2023

Range wide genetic differentiation in the bull kelp Nereocystis luetkeana with a seascape genetic focus on the Salish Sea

Introduction: In temperate regions, one of the most critical determinants of present range-wide genetic diversity was the Pleistocene climate oscillations, the most recent one created by the last glacial maximum (LGM). This study aimed to describe N. luetkeana genetic structure across its entire range (Alaska to California) and test different models of population connectivity within the Salish Sea. This region was colonized after the LGM and has been under increased disturbance in recent decades. Methods: We utilized microsatellite markers to study N. luetkeana genetic diversity at 53 sites across its range. Using higher sampling density in the Salish Sea, we employed a seascape genetics approach and tested isolation by hydrodynamic transport and environment models. Results: At the species distribution scale, we found four main groups of genetic co-ancestry, Alaska; Washington with Vancouver Island’s outer coast and Juan de Fuca Strait; Washington’s inner Salish Sea; and Oregon with California. The highest allelic richness (AR) levels were found in California, near the trailing range edge, although AR was also high in Alaska. The inner Salish Sea region had the poorest diversity across the species distribution. Nevertheless, a pattern of isolation by hydrodynamic transport and environment was supported in this region. Discussion: The levels of allelic, private allele richness and genetic differentiation suggest that during the LGM, bull kelp had both northern and southern glacial refugia in the Prince of Wales Island-Haida Gwaii region and Central California, respectively. Genetic diversity in Northern California sites seems resilient to recent disturbances, whereas the low levels of genetic diversity in the inner Salish Sea are concerning.

59 BASIC BIOLOGICAL SCIENCES↗
NASA NTRS1975

Some comparisons of impact craters on Mercury and the moon

Although the general morphologies of fresh mercurian and lunar craters are remarkably similar, comparisons of ejecta deposits, interior structures, and changes in morphology with size reveal important differences between the two populations of craters. The differences are attributable to the different gravity fields in which the craters were formed and have significant implications for the interpretation of cratering processes and their effects on all planetary bodies.

Gault, D. E.↗
NASA NTRS1979

Automated Array Assembly, Phase 2

The solar cell module process development activities in the areas of surface preparation are presented. The process step development was carried out on texture etching including the evolution of a conceptual process model for the texturing process; plasma etching; and diffusion studies that focused on doped polymer diffusion sources. Cell processing was carried out to test process steps and a simplified diode solar cell process was developed. Cell processing was also run to fabricate square cells to populate sample minimodules. Module fabrication featured the demonstration of a porcelainized steel glass structure that should exceed the 20 year life goal of the low cost silicon array program. High efficiency cell development was carried out in the development of the tandem junction cell and a modification of the TJC called the front surface field cell. Cell efficiencies in excess of 16 percent at AM1 have been attained with only modest fill factors. The transistor-like model was proposed that fits the cell performance and provides a guideline for future improvements in cell performance.

Carbajal, B. G.↗
NASA NTRS1985

Orbit on demand - In this century if pushed

Performance requirements and design features of the next generation of manned launch vehicles are discussed. The vehicles will launch within minutes of demand and will have a several-day turnaround time. Launch and landing sites will have minimal facilities. Baseline requirements comprise carriage and return of a 5000 lb, 7 ft diam, 15 ft long payload, a 160 n. mi. polar orbit, a 200 fps on-orbit delt-V capability, provisions for two men for 24 hr, an 1100 n. mi. cross range option, 500 flights/vehicle, land on 10,000 ft runways, and be acceptable passing over populated areas. Significant advances are needed in propulsion and fuel systems, lightweight durable structures and airbreathing acceleration engines. Trade-offs have yet to be fully explored among the number of stages and horizontal or vertical take-off.

Martin, J. A.↗
NASA NTRS1986

Methodology of design and analysis of external walls of space station for hypervelocity impacts by meteoroids and space debris

The development of criteria and methodology for the design and analysis of Space Station wall elements for collisions with meteoroids and space debris at hypervelocities is discussed. These collisions will occur at velocities of 10 km/s or more and can be damaging to the external wall elements of the Space Station. The wall elements need to be designed to protect the pressurized modules of the Space Station from functional or structural failure due to these collisions at hypervelocities for a given environment and population of meteoroids and space debris. The design and analysis approach and the associated computer program presented is to achieve this objective, including the optimization of the design for a required overall probability of no penetration. The approach is based on the presently available experimental and actual data on meteoroids and space debris flux and damage assessments and the empirical relationships resulting from the hypervelocity impact studies in laboratories.

Batla, F. A.↗
NASA NTRS1989

Evolution of radio quasars for z of less than 2

A sample of 72 radio quasars is used to study the cosmic and individual evolution of quasars in the 1-2 redshift range. It is shown that the most luminous sources at all redshifts are unresolved, and that one-sided and two-sided structures correspond to progressively lower core (and total) luminosities. The sizes and fractional population of triple sources are found to fall steadily with increasing redshift to z of about 1.7. A correlation over many orders of magnitude is noted between the optical and maximum radio-core luminosity.

Neff, S. G.↗
NASA NTRS1991

A non-local thermodynamic equilibrium, line-blanketed synthetic spectrum of Iota Herculis - C, Al, and Si lines

A non-LTE line-blanketed model stellar atmosphere is used to compute a model of I Herculis (B3 IV) with a Teff of 17,500 K and a log g of 3.75, following the conclusions of Peters and Polidan (1985). Detailed profiles of a number of lines of C, Al, and Si in the 1200-2000-A region are computed, including the resonance lines of C II, Al II, and Al III. These profiles are compared to observations obtained from the coaddition of eight IUE SWP images, using a technique developed by Leckrone and Adelman (1989). Comparison of carbon lines with a model that is underabundant in carbon by a factor of 2 relative to the sun indicates that the C abundance of Iota Her is at most one-half solar. Non-LTE effects are examined by comparing an LTE model possessing identical atmospheric parameters with the non-LTE model. Substantial differences in the populations of the model atomic states are found, but differences in the temperature structure of the two models often mask the non-LTE effects in the synthetic spectra.

Grigsby, James A.↗
NASA NTRS1993

Origin of the Apollo 15 very low Ti green glass. A perspective from the compositional diversity in the very low Ti glasses

The very low Ti green glasses from the Apollo 15 site have intrigued scientists for over 20 years. Their primitive composition has been used to understand magmatic processes and the structure of the moon. The compositional variability observed in the Apollo 15 glass population has long been a point of debate. Initial studies did not recognize the compositional diversity in the glasses. Stolper et al. documented the major element variability and concluded it could not be produced by magmatic processes and therefore concluded that these glasses must be of impact origin. Subsequent studies confirmed a volcanic origin for the glass population and attempted to elucidate magmatic processes to account for its compositional variability. Models that have been proposed for these glasses include the following: (1) the crystallization of single or multiple phases (olivine, pyroxene, Fe metal, immiscible sulfide); (2) the incompatible behavior of Ni and Co during multiple phase crystallization at extremely low fO2; and (3) magma or source mixing. All of these models have problems. Type (1) models appear not to be consistent with recent trace element studies on the glasses; model (2) is dependent on the debatable incompatible behavior of Ni and Co, and, in models of type (3), the origin and nature of mixing models are somewhat unconstrained. This study compares the Apollo 15 green glasses with the very low Ti picritic glasses from other landing sites.

Shearer, C. K.↗
NASA NTRS2011

Drought and Heat Waves: The Role of SST and Land Surface Feedbacks

Drought occurs on a wide range of time scales, and within a variety of different types of regional climates. At the shortest time scales it is often associated with heat waves that last only several weeks to a few months but nevertheless can have profound detrimental impacts on society (e.g., heat-related impacts on human health, desiccation of croplands, increased fire hazard), while at the longest time scales it can extend over decades and can lead to long term structural changes in many aspects of society (e.g., agriculture, water resources, wetlands, tourism, population shifts). There is now considerable evidence that sea surface temperatures (SSTs) play a leading role in the development of drought world-wide, especially at seasonal and longer time scales, though land-atmosphere feedbacks can also play an important role. At shorter (subseasonal) time scales, SSTs are less important, but land feedbacks can play a critical role in maintaining and amplifying the atmospheric conditions associated with heat waves and short-term droughts. This talk reviews our current understanding of the physical mechanisms that drive precipitation and temperature variations on subseasonal to centennial time scales. This includes an assessment of predictability, prediction skill, and user needs at all time scales.

Schubert, Siegfried↗
NASA NTRSDate not supplied

Analysis of Darkened Fragments Resulting from Laboratory Hypervelocity Experiments

NASA’s Orbital Debris Program Office (ODPO) relies on measurements from optical, radar, and in situ measurements to facilitate the development of data-driven orbital debris environmental engineering models such as the NASA Orbital Debris Engineering Model (ORDEM). For optical measurements, the ODPO relies on ground-based optical telescopes to statistically assess objects in geosynchronous orbit and, in the future, low Earth orbit (LEO). The data collected include the detected object’s orbital parameters, time of observation, and optical magnitude. The latter parameter can be converted to a size using NASA’s optical Size Estimation Model (oSEM). It is well known that the observed magnitude of orbital debris can vary based on an object's material constituents, observational geometry, and the effects of space weathering. To assess these magnitude variations, the ODPO uses the Optical Measurement Center (OMC) at NASA Johnson Space Center to characterize a variety of materials and fragments from laboratory impact tests representative of fragments that constitute the orbital debris population. One experiment was DebriSat: a 56 kg spacecraft was built to incorporate structural elements of a modern LEO spacecraft and was subjected to a hypervelocity impact test at the U.S. Air Force’s Arnold Engineering Development Complex using test parameters that may be encountered in LEO. The DebriSat project has provided an abundance of information for assessing fragmentation debris in terms of material, color, shape, size, density, mass, and other derived parameters. Prior to the impact test, the ODPO collected spectral measurements on a subset of the materials used to construct DebriSat for a “ground-truth” of their optical properties. After the successful hypervelocity impact test, the DebriSat team observed a fine, dark dust coating all the fragments. Prior research has suggested that this came from ablated material deposited on the fragments during the impact test, causing a change in the reflective properties [1]. Given that this lower reflectivity on the DebriSat fragments will influence the laboratory-acquired magnitudes used to calculate size and inform potential updates to the oSEM, it is critical to assess if this darkening effect on the DebriSat fragments is a laboratory bias or something that could occur in on-orbit breakup events. This paper will provide a brief overview of the OMC and DebriSat experiment, focused on the optical characterization of a subset of materials using broadband photometric measurements and spectroscopic measurements. In addition, elemental analysis of various DebriSat fragments and the soft-catch foam used in the hypervelocity experiment compared with pristine foam will be examined to further evaluate the source of the dark material coating all fragments. Finally, the authors will present a twofold plan 1) for assessing potential biases in laboratory impact experiments that could affect laboratory optical characterization and 2) for mitigating biases when compared with ground-based optical telescopic measurements of the orbital debris environment.

Heather Cowardin↗
NASA NTRSDate not supplied

Analysis of Darkened Fragments Resulting from Laboratory Hypervelocity Experiments

NASA’s Orbital Debris Program Office (ODPO) relies on measurements from optical, radar, and in situ measurements to facilitate the development of data-driven orbital debris environmental engineering models such as the NASA Orbital Debris Engineering Model (ORDEM). For optical measurements, the ODPO relies on ground-based optical telescopes to statistically assess objects in geosynchronous orbit and, in the future, low Earth orbit (LEO). The data collected include the detected object’s orbital parameters, time of observation, and optical magnitude. The latter parameter can be converted to a size using NASA’s optical Size Estimation Model (oSEM). It is well known that the observed magnitude of orbital debris can vary based on an object's material constituents, observational geometry, and the effects of space weathering. To assess these magnitude variations, the ODPO uses the Optical Measurement Center (OMC) at NASA Johnson Space Center to characterize a variety of materials and fragments from laboratory impact tests representative of fragments that constitute the orbital debris population. One experiment was DebriSat: a 56 kg spacecraft was built to incorporate structural elements of a modern LEO spacecraft and was subjected to a hypervelocity impact test at the U.S. Air Force’s Arnold Engineering Development Complex using test parameters that may be encountered in LEO. The DebriSat project has provided an abundance of information for assessing fragmentation debris in terms of material, color, shape, size, density, mass, and other derived parameters. Prior to the impact test, the ODPO collected spectral measurements on a subset of the materials used to construct DebriSat for a “ground-truth” of their optical properties. After the successful hypervelocity impact test, the DebriSat team observed a fine, dark dust coating all the fragments. Prior research has suggested that this came from ablated material deposited on the fragments during the impact test, causing a change in the reflective properties [1]. Given that this lower reflectivity on the DebriSat fragments will influence the laboratory-acquired magnitudes used to calculate size and inform potential updates to the oSEM, it is critical to assess if this darkening effect on the DebriSat fragments is a laboratory bias or something that could occur in on-orbit breakup events. This presentation will provide a brief overview of the OMC and DebriSat experiment, focused on the optical characterization of a subset of materials using broadband photometric measurements and spectroscopic measurements. In addition, elemental analysis of various DebriSat fragments and the soft-catch foam used in the hypervelocity experiment compared with pristine foam will be examined to further evaluate the source of the dark material coating all fragments. Finally, the authors will present a twofold plan 1) for assessing potential biases in laboratory impact experiments that could affect laboratory optical characterization and 2) for mitigating biases when compared with ground-based optical telescopic measurements of the orbital debris environment.

Heather Cowardin↗
DOE OSTI2020

Determining Cs-137 Background body burdens for Wild Pigs At Savannah River Site

Savannah River Site (SRS) is a unique U.S. Department of Energy facility in that most of the 310-square miles of land has not be industrialized since operations began in 1953. This has allowed abundant, undisturbed vegetation structure to exists as well as an increase in herd sizes among wildlife populations onsite. Cs-137 is widespread across SRS due to the production of nuclear materials, but is mostly from global atmospheric fallout from nuclear weapons testing. Due to most of SRS being undisturbed land, the concentrations of Cs-137 are higher on site than off site. The SRS began conducting annual deer harvests that were open to the public beginning in 1965. All animals harvested during these hunts are monitored for Cs-137, which is measured using a Sodium Iodide detector. There has been an effective method for calculating the background Cs-137 body burden for the deer population at the SRS, developed by Gaines and Novak using data collected during hunts and gamma overflight data to determine the areas contaminated by site activities. For animals that have a Cs-137 concentration above the established background level, a dose is assigned to the hunter. By applying the same method for wild pigs using data collected from hunts, gamma overflight, and developing a site-specific home range of wild pigs, we were able to calculate the Cs-137 background body burden concentrations of wild pigs on site. Objectives: Develop site-specific home range for wild pigs at SRS; Determine the average concentrations of Cs-137 in wild pigs from background; Use Gaines and Novak method for determining background Cs-137 body burdens wild pigs on SRS. Methods and Materials: Development of site-specific home range of wild pigs was determined to be 2.5 miles using: Four studies conducted between 1969 and 1992 for the SRS wild pig population. (Mayer and Brisbin) The background compartments were determined using: Gamma overflight data showing contaminated areas; Site-specific home range of the wild pigs. Results and Conclusion: All data were generated through the JMP software to provide a histogram and summary statistics. The estimate of an upper tolerance limit for the background contamination with 95% confidence is 1.965 pCi/g for the wild pigs. This means that for wild pigs on SRS from the background compartments are expected to have Cs-137 concentrations of less than 1.965 pCi/g. The current background for the deer is 2.59 pCi/g. For the background compartments Cs-137 concentrations from 2012-2018: Mean: 0.815 pCi/g, Maximum: 2.341 pCi/g, Minimum: -0.704 pCi/g.

07 ISOTOPE AND RADIATION SOURCES↗
NASA NTRS1990

Molecular clouds and the large-scale structure of the galaxy

The application of molecular radio astronomy to the study of the large-scale structure of the Galaxy is reviewed and the distribution and characteristic properties of the Galactic population of Giant Molecular Clouds (GMCs), derived primarily from analysis of the Columbia CO survey, and their relation to tracers of Population 1 and major spiral features are described. The properties of the local molecular interstellar gas are summarized. The CO observing programs currently underway with the Center for Astrophysics 1.2 m radio telescope are described, with an emphasis on projects relevant to future comparison with high-energy gamma-ray observations. Several areas are discussed in which high-energy gamma-ray observations by the EGRET (Energetic Gamma-Ray Experiment Telescope) experiment aboard the Gamma Ray Observatory will directly complement radio studies of the Milky Way, with the prospect of significant progress on fundamental issues related to the structure and content of the Galaxy.

Thaddeus, Patrick↗