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At least 541 records · Page 30

Mineralogy and petrology of the Abee enstatite chondrite breccia and its dark inclusions

A model is proposed for the petrogenesis of the Abee E4 enstatite chondrite breccia, which consists of clasts, dark inclusions and matrix, and whose dark inclusions are an unusual kind of enstatite chondritic material. When the maximum metamorphic temperature of the breccia parent material was greater than 840 C, euhedral enstatite crystals in metallic Fe, Ni, and sulfide-rich areas grew into pliable metal and sulfide. Breccia parent material was impact-excavated, admixed with dark inclusions, and rapidly cooled. During this cooling, the clast and matrix material acquired thermal remanent magnetization. A subsequent ambient magnetic field imparted a uniform net magnetic orientation to the matrix and caused the magnetic orientation of the clasts to be less random. The Abee breccia was later consolidated by shock or by shallow burial and long period, low temperature metamorphism.

Rubin, A. E.↗

Mineralogic information from a new airborne thermal infrared multispectral scanner

The thermal IR multispectral scanner (TIMS) has been developed for airborne geologic surveys. The resststrahlen band between 8-11 microns is exhibited by interatomic stretching vibrations of Si and oxygen bound up in the crystal lattice of silicate rocks. The crystal structure of the component minerals influence the depth and position of the detected band. The TIMS has six channels, an 80 deg field of view, and a sensitivity sufficient to detect a noise equivalent change in spectral emissivity of 0.002-0.006. The six bands measured are 8.2-8.6, 8.6-9.0, 9.4-10.2, 10.2-11.2, and 11.2-12.2 microns, using HgCdTe detectors. The data are analyzed with respect to emissivity variations as a function of wavelength, using the component transformation technique called a decorrelation stretch, with spectral differences being displayed as different colors. Sample scenes from Death Valley and the Nevada Cuprite mining district are compared with visible and near-IR color composites of the same areas, revealing the superior distinctions that are available with the TIMS.

Kahle, A. B.↗

Mineralogic and petrologic studies of meteorites and lunar samples

During a 13 year period beginning in 1971, the Extraterrestrial Petrology Group examined lunar soils from all 6 Apollo missions and those returned by the Soviet Luna 16, Luna 20, and Luna 24 missions. In addition, the properties and apparent origin of the carbonaceous chondrites were examined. Chondrules, calcium-aluminum-rich inclusions (CAI) and the fine grained matrix materials that accompany chondrules and CAI's in primitive meteorites were investigated. The effects of planetary hydrothermal alteration of matrix materials in the C1 chondrite was also investigated. Full length papers and extended abstracts published during the grant are listed chronologically.

Wood, J. A.↗

Mineralogy and petrology of chondrules and inclusions in the Mokoia CV3 chondrite

The inclusions and chondrules of the Mokoia CV3 chondrite are studied systematically and compared with those in the Allende meteorite. Five polished thin sections of Mokoia were examined by optical microscopy, backscattered scanning electron microscopy, and electronprobe microanalysis, and objects greater than about 100 microns in apparent diameter were measured and classified petrographically. Three major types of olivine chondrules are distinguished: igneous chondrules, which evidently crystallized from droplets of silicate melt; recrystallized chondrules, apparently metamorphosed at relatively high temperatures; and accretional aggregates, which are probably fragments of igneous chondrules. Refractory inclusions in Mokoia are generally similar to those found in Allende, although Mokoia inclusions include phyllosilicates rather than feldspathoids and melilite-rich Ca, Al-rich inclusions (CAIs) are more abundant in Allende. The small, fine-grained CAIs, which are more abundant than coarse-grained CAIs in both meteorites, are observed to represent aggregates of three distinct constituents: concentric objects, chaotic material and inclusion matrix. It is concluded that most of the CAIs probably formed during metamorphism, partial melting, and incomplete distillation of primitive dust aggregates heated in the solar nebula.

Cohen, R. E.↗

Comparison of Yamato and Victoria Land polymict eucrites - A view from mineralogical and isotopic studies

New interior samples of four Yamato polymict eucrites (Y74159, Y74450, Y75011, and Y75015) have been studied by electron microprobe, transmission electron microscope, and X-ray diffraction techniques, and compared with several samples of the Victoria Land polymict eucrites. These same samples have been analysed using Rb-Sr and Nd-Sm isotopic systematics. Several grains of inverted pigeonite, with blebby augite similar to those in Binda and Moama, have been identified in all four Yamato eucrites. Coarse-grained meso-stasis-rich subophitic basalts, which contain Mg-rich pigeonite (with Fe-rich olivine veinlets) zoned outward to a subcalcic ferroaugite rims, have also been found. These unique clasts were not found in ALH76005, 77302, 78040, 7858, and 78165 and EET eucrites. The tight grouping of Rb/Sr and Sm/Nd ratos, and similar modal compositions of the Yamato group indicate that they are most likely to be pieces from a single fall, and distinct from the ALH and EET groups. However, the Yamato, Allan Hills, and Elephant Moraine groups may sample a few distinct magmas or similar but different source regions on the same parent body.

Takeda, H.↗

Mineralogical investigations of lunar samples and meteorites

Electron microprobe analysis was employed to study north ray crater breccia 67015 from the Moon. The melting history of lunar troctolite 130-9 was investigated, along with the presence of Mg-26 in anorthite grains recovered from the Vaca Meurta mesosiderite. Geographic distributions of meteorites in Antarctica were plotted. The Allende meteorite was analyzed with the electron microprobe method.

Marvin, U. B.↗

Mineralogical studies of lunar meteorites and their lunar analogs

The minerology and textural properties of three lunar meteorites (Yamato 791197, ALH81005, and Yamato 82192) were analyzed and compared with lunar surface rock samples. The chemical composition and textures of pyroxene and the occurrance of glass matrices were specifically addressed. The study of glass in the lunar meteorites suggests that the glass was not produced by a meteorite impact which excavated the mass into orbit towards the Earth. The glass had been devitrified on the lunar surface before the excavation, and new glass was not produced by the last impact.

Takeda, H.↗

Mineralogy and chemistry of the Earth

The Earth is the prototype if not typical terrestrial planet. Ideas about the origin, evolution, structure and chemistry of the planets can be tested most thoroughly on the Earth. Similarly, the study of the other planets has generated new ideas which may be applicable to the Earth. For example the concepts of magma oceans, large polar wander, global stress fields, buoyant lithosphere, deep cumulate reservoirs, multiple tectonic styles and crust generation may also apply to the Earth, present or past. It is no longer valid to think of the mantle as an essentially homogeneous undifferentiated shell of olivine with pockes of basalt providing melts to midocean ridges and oceanic islands. It appears to be a well differentiated, outgassed body with both radial and lateral chemical variations. The lower mantle is close to chondritic in its major element chemistry. The transition region is garnet and clinopyroxene rich and may be a major basalt reservoir. This would explain the thin crust paradox. Chemical stratification of the Earth probably occurred during accretion.

Anderson, D. L.↗

Mineralogical comparison and cooling history of lunar and chondritic vesicular melt breccias

Lunar sample 77135, an impact melt breccia full of vesicles, has been reinvestigated by electron microprobe and X-ray diffraction techniques and compared with a vesicular melt LL chondrite, Yamato 790964, in an attempt to understand their impact heating processes and subsequent cooling history. Notable similarities between the lunar and chondritic melt breccias include: abundant vesicles, similar pyroxene chemical zoning trends, the presence of variable amounts of clastic material, and similar chemical compositions except for K and Na contents of glass and mesostasis. Some constraints on the cooling history are estimated from Mg-Fe diffusion profiles in olivine and pyroxene. The burial depth of lunar sample 77135 during cooling was 0.2-100 m; the depth for the chondrite was probably smaller. Impact melts were probably produced and a layer of regolith retained on the parent body sufficiently thick to allow the olivines to homogenize during slow cooling.

Miyamoto, M.↗

Martian dust particles as condensation nuclei - A preliminary assessment of mineralogical factors

Experiments were performed to determine the factors influencing ice nucleation detected in Viking Lander data from the Mars surface. The study focused on the relationship between mineral properties and condensate formation under Mars conditions. Pulverized particles of the primary phases of basaltic rocks and their alteration products, expandable clay minerals and a nonexpandable clay mineral, and petrologically well-characterized regolith materials ranging from 10-60 microns in size, were studied. The powders were individually or in combinations mixed with water in a flowing CO2 atmosphere while calorimetry data was taken on the ice nucleation threshold. The ice-forming characteristics of the mixes were found to be a function of the crystallographic disregistry, chemical bonding, and active-site properties of the individual minerals. The crystalline materials were better nucleators of condensates than were the cryptocrystalline mineral specimens, while nonexpandable clay materials, particularly zeolite, were the more effective nucleators among the weathering product materials.

Gooding, J. L.↗

Iron oxide and hydroxide precipitation from ferrous solutions and its relevance to Martian surface mineralogy

Experiments were performed to examine if the ubiquitousness of a weak magnetic component in all Martian surface fines tested with the Viking Landers can be attributed to ferric iron precipitation in aqueous solution under oxidizing conditions at neutral pH. Ferrous solutions were mixed in deionized water and various minerals were added to separate liquid samples. The iron-bearing additives included hematite, goethite, magnetite, maghemite, lepidocrocite and potassium bromide blank at varying concentrations. IR spectroscopic scans were made to identify any precipitates resulting from bubbling oxygen throughout the solutions; the magnetic properties of the precipitates were also examined. The data indicated that the lepidocrocite may have been preferentially precipitated, then aged to maghemite. The process would account for the presumed thin residue of maghemite on the present Martian surface, long after abundant liquid water on the Martian surface vanished.

Posey-Dowty, J.↗

Aqueous alteration in carbonaceous chondrites - Mass balance constraints on matrix mineralogy

Bulk chemical compositions of matrix material were determined in eleven Antarctic CM chondrites and five non-Antarctic CM and CI chondrites, using microprobe defocused-beam technique. The results, along with previously published data, are used to provide mass balance constraints on the relative proportions of intergrown and intermixed phyllosilicate phases in carbonaceous chondrite matrices. In terms of Fe, Si, and Mg, the CM matrix bulk compositions plot within a triangle defined by the compositions of PCP (a mixture of 25 percent tochilinite and 75 percent cronstedtite), Mg-rich serpentine, and Fe-rich serpentine. Results indicate differing amounts of PCP and serpentines in individual CM matrices. The discrepancies found between predicted and measured S and Ni values require additional sulfide phases. CI matrices were found to contain little, if any, PCP; they consist mostly of serpentine and montmorillonite.

Mcsween, Harry Y., Jr.↗

Remote mineralogical and vegetation mapping using imaging spectrometry

Two airborne flight systems were developed for geological studies: the airborne imaging spectrometer (AIS) and the advanced visible and infrared imaging spectrometer. A satellite imaging spectrometer system, the high resolution imaging spectrometer, is currently being developed and is planned for flight on the proposed NASA Earth Orbiting System. Examples of the application of these instruments in mineral and vegetation studies are described. Experiments conducted with AIS over the Cuprite Mining District (Nevada) and the Owens Valley (California) demonstrate the power of this new approach to remote sensing.

King, James, Jr.↗

Mineralogical studies of sulfide samples and volatile concentrations of basalt glasses from the southern Juan de Fuca Ridge

Sulfide samples obtained from Alvin dives on the southern Juan de Fuca Ridge were examined, showing the presence of two previously undiscovered minerals, both formed at low temperatures. The first detection of lizardite, starkeyite, and anatase in such an environment is also reported. Sulfide geothermometry involving the Cu-Fe-S system shows a vent temperature of less than 328 C for one sample. Ice-melting temperatures on inclusions from this sample are about -2.8 C, and fluid inclusion studies on crystals near this sample show pressure-corrected homogenization temperatures of 268 and 285 C. Volatile concentrations from vesicle-free basalt glass from the vent field are found to be about 0.0013 wt pct CO2 and 0.16 wt pct H2O.

Brett, Robin↗

Mineralogy and phase-chemistry of the Cretaceous/Tertiary section in the Lattengebirge, Bavarian Alps

The Lattengebirge K/T section reveals three distinct Ir spikes. Two of them are contained in the K/T transition zone sensu-strictu termed clayey interval, with 4.4 ppb Ir at the actual K/T boundary, and 2.8 ppb Ir 10 cm above the boundary. The highest Ir enrichment of 9 ppb, however, was detected in semi-cleaned organic material from a thin sandstone layer of Upper Maastrichtian age at 16 cm below the boundary. In this layer various discernible phases are preserved, contrasting with the worldwide observed K/T transition zones which are generally entirely composed of diagenetically altered materials. Given that, important clues to understanding the Cretaceous terminal events may be provided. The phases of the Cretaceous Ir bearing layer at Lattengebirge consist of: sandstone fragmental minerals in a carbonate matrix, coal which is partly burnt, melt glasses presumably of combustion-metamorphic origin, and sulfides, mainly chalcopyrite, contained in the coal. Like many known K/T sections and the Lattengebirge boundary sensu-strictu, the Cretaceous horizon is enriched in Ir and chalcophile elements as well. Although the Lattengebirge section offers the freshest materials, including melt glasses, of all K/T localities investigated, no unequivocal evidence of formation by impact has been found there.

Graup, G.↗

A remote mineralogic perspective on gabbroic units in the lunar highlands

Three lunar highland regions containing abundant high-Ca pyroxene are investigated in order to constrain the chemistry of the pyroxene assemblage of gabbroic regions and determine the state of gabbroic materials in the highland crust. The compositional gap between orthopyroxenes and clinopyroxenes noted in remote sensing observations corresponds to that found in lunar rock samples. It is found that Mg-gabbronorite or KREEP basalt with abundant high-Ca pyroxene are the most likely rock types of those thus far identified that may be responsible for gabbroic areas in the highlands. The western lunar highlands are shown to be distinct from the east in minerology.

Lucey, Paul G.↗