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At least 541 records · Page 30
All sourcesNASA NTRSDOE OSTI
NASA NTRS1987

Degradation mechanisms of materials for large space systems in low Earth orbit

Degradation was explored of various materials used in aerospace vehicles after severe loss of polymeric material coatings (Kapton) was observed on an early shuttle flight in low Earth orbit. Since atomic oxygen is the major component of the atmosphere at 300 km, and the shuttle's orbital velocity produced relative motion corresponding to approx. 5 eV of oxygen energy, it was natural to attribute much of this degradation to oxygen interaction. This assumption was tested using large volume vacuum systems and ion beam sources, in an exploratory effort to produce atomic oxygen of the appropriate energy, and to observe mass loss from various samples as well as optical radiation. Several investigations were initiated and the results of these investigations are presented in four papers. These papers are summarized. They are entitled: (1) The Space Shuttle Glow; (2) Laboratory Degradation of Kapton in a Low Energy Oxygen Ion Beam; (3) The Energy Dependence and Surface Morphology of Kapton Degradation Under Atomic Oxygen Bombardment; and (4) Surface Analysis of STS 8 Samples.

Gordon, William L.↗
NASA NTRS2012

The Evolution of Friction Stir Welding Theory at Marshall Space Flight Center

From 1995 to the present the friction stir welding (FSW) process has been under study at Marshall Space Flight Center (MSFC). This is an account of the progressive emergence of a set of conceptual tools beginning with the discovery of the shear surface, wiping metal transfer, and the invention of a kinematic model and making possible a treatment of both metallurgical structure formation and process dynamics in friction stir welding from a unified point of view. It is generally observed that the bulk of the deformation of weld metal around the FSW pin takes place in a very narrow, almost discontinuous zone with high deformation rates characteristic of metal cutting. By 1999 it was realized that this zone could be treated as a shear surface like that in simple metal cutting models. At the shear surface the seam is drawn out and compressed and pressure and flow conditions determine whether or not a sound weld is produced. The discovery of the shear surface was followed by the synthesis of a simple 3- flow kinematic model of the FSW process. Relative to the tool the flow components are: (1) an approaching translational flow at weld speed V, (2) a rotating cylindrical plug flow with the angular velocity of the tool , and (3) a relatively slow ring vortex flow (like a smoke ring) encircling the tool and driven by shoulder scrolls and pin threads. The rotating plug flow picks up an element of weld metal, rotates it around with the tool, and deposits it behind the tool ( wiping metal transfer ); it forms plan section loops in tracers cut through by the tool. Radially inward flow from the ring vortex component retains metal longer in the rotating plug and outward flow expels metal earlier; this interaction forms the looping weld seam trace and the tongue and groove bimetallic weld contour. The radial components of the translational and ring vortex flows introduce parent metal intrusions into the small grained nugget material close to the tool shoulder; if this feature is pronounced, nugget collapse may result. Certain weld features, in particular internal banding seen in transverse section as onion rings and associated surface ridges called tool marks , have long implied an oscillation flow component, but have only recently been attributed in the literature to tool eccentricity. Rotating plug shape, typically a hollow cylinder flared at the end where it sticks to the shoulder, varies as pressure distribution on the tool determines where sticking occurs. Simplified power input estimates balanced against heat loss estimates give reasonable temperature estimates, explain why the power requirement changes hardly at all over a wide range of RPM s, and yield isotherms that seem to fall along boundaries of parameter windows of operation.

Nunes, Arthur C.↗
NASA NTRSDate not supplied

New Phase Change Materials for Active Photonics

Phase change materials or PCMs are truly remarkable compounds whose unique switchable properties have fueled an explosion of emerging applications in electronics and photonics. Nonetheless, if we discount their use in optical discs, PCMs’ immense application potential in photonics beyond data recording has only begun to unfold in the past decade. While the material requirements for optical or electronic data storage have been succinctly summarized as five key elements “writability, archival storage, erasability, readability, and cyclability” decades ago, these requirements are not universally relevant to the diverse set of photonic applications now being explored. It also comes as no surprise that existing PCMs, which have been heavily vetted for data storage, are not necessarily the optimal compositions for different use cases in optics and photonics. PCMs with their attributes custom-tailored for specific applications are therefore in demand as phase-change photonics continue to expand. Here we discuss the PCM selection and design strategies specifically for photonic applications as well as our recent work developing active integrated photonic devices and metasurface optics based on new PCMs tailored for photonics.

phase change materials↗
NASA NTRS1977

What the exploration of Mars tells us about earth

Data obtained from the Viking missions to Mars have lead to comparisons between characteristics of that planet and certain aspects of earth. Topics discussed include: thermal and compositional evolution of the planets' interiors, the origin of their atmospheres, the history of their fluid environments, the evolution of organic material, and climatic changes. Examples of convective and magmatic activity on the crusts of the two planets are contrasted; outgassing evidenced in the crustal zones is related to the evolution of atmosphere. Analysis of experimental degassing of meteorites provides further insight into the origin and composition of planetary atmospheres. Attributes of the Martian surface, which is apparently an oxidizing rather than reducing medium, are reviewed, and explanations proposed to account for its lack of an organic richness comparable to that found on earth. Data on long-range climatic changes on earth, related to precession, obliquity, and eccentricity of the planet, may contribute to understanding of the Martian polar caps, and vice versa.

Rasool, S. I.↗
NASA NTRS1979

Albedo and color contrasts on asteroid surfaces

Asteroids in general display only small or negligible variations in spectrum or albedo during a rotational cycle. Color variations with rotation are described in the literature but are usually comparable to the noise in the measurements. Twenty-four asteroids have been systematically monitored for such color changes. Only 3 Juno, 4 Vesta, 6 Hebe, 71 Niobe, 349 Dembowska, and 944 Hidalgo display color variations larger than 0.03 mag. In each of these cases the asteroid appears redder near maximum brightness. Of seven asteroids monitored polarimetrically, only 4 Vesta shows a convincing variation, attributed to an albedo change with rotation. The lightcurve can be explained by albedo differences alone; Vesta apparently has a nearly spheroidal shape. Nothwithstanding the above results, the degree of uniformity of most asteroid surfaces is remarkable. If asteroids exist with large discrete domains of ferrosilicate, metallic, and/or carbonaceous material together on their surfaces, they have not yet been identified.

Degewij, J.↗
NASA NTRS1983

Space station needs, attributes, and architectural options. Volume 1. Executive summary

The initial space station should be manned, placed in 28.5 deg orbit, and provide substantial economic, performance, and social benefits. The most beneficial space station capabilities include: a space test facility; a transport harbor; satellite servicing and assembly; and an observatory. A space industrial park could be added once further development effort validates the cost and expanding commercial market for space processed materials. The potential accrued gross mission model benefit derived from these capabilities is $5.9B without the industrial park, and $9.3B with it. An unclassified overview of all phases of the study is presented.

Pritchard, E. B.↗
NASA NTRS1987

On the 9.25 minute X ray oscillations of V471 Tauri

The X-ray oscillations observed in the eclipsing spectroscopic binary V471 Tau by Exosat (Jensen, 1985) and attributed to rotational modulation of an X-ray-opaque pole due to He and metals accreted onto the DA2 white dwarf component (Jensen, 1986) are investigated theoretically. The observational data are summarized in a table and compared with the results of numerical simulations of the accretion of wind/flare material onto the white dwarf. The rotational modulation model is found to reproduce the observed line features only if the magnetic field is strong (about 10 kG), the accretion rate is about 10 to the -15th solar mass/yr, and the polar cap area is much larger than the theoretical lower limit of 5.7 x 10 to the 14th sq cm. It is recommended that nonradial g-mode oscillations of the white dwarf be investigated as an alternative explanation.

Sion, Edward M.↗
NASA NTRS1994

A survey of the core-congruential formulation for geometrically nonlinear TL finite elements

This article presents a survey of the core-congruential formulation (CCF) for geometrically nonlinear mechanical finite elements based on the total Lagrangian (TL) kinematic description. Although the key ideas behind the CCF can be traced back to Rajasekaran and Murray in 1973, it has not subsequently received serious attention. The CCF is distinguished by a two-phase development of the finite element stiffness equations. The initial phase developed equations for individual particles. These equations are expressed in terms of displacement gradients as degrees of freedom. The second phase involves congruential-type transformations that eventually binds the element particles of an individual element in terms of its node-displacement degrees of freedom. Two versions of the CCF, labeled direct and generalized, are distinguished. The direct CCF (DCCF) is first described in general form and then applied to the derivation of geometrically nonlinear bar, and plane stress elements using the Green-Lagrange strain measure. The more complex generalized CCF (GCCF) is described and applied to the derivation of 2D and 3D Timoshenko beam elements. Several advantages of the CCF, notably the physically clean separation of material and geometric stiffnesses, and its independence with respect to the ultimate choice of shape functions and element degrees of freedom, are noted. Application examples involving very large motions solved with the 3D beam element display the range of applicability of this formulation, which transcends the kinematic limitations commonly attributed to the TL description.

Felippa, Carlos A.↗
NASA NTRS2003

Instrument for Measuring Temperature of Water

A pseudo-Brewster-angle infrared radiometer has been proposed for use in noncontact measurement of the surface temperature of a large body of water (e.g., a lake or ocean). This radiometer could be situated on a waterborne, airborne, or spaceborne platform. The design of the pseudo-Brewster-angle radiometer would exploit the spectral-emissivity and polarization characteristics of water to minimize errors attributable to the emissivity of water and to the reflection of downwelling (e.g., Solar and cloud-reflected) infrared radiation. The relevant emissivity and polarization characteristics are the following: . The Brewster angle is the angle at which light polarized parallel to the plane of incidence on a purely dielectric material is not reflected. The pseudo-Brewster angle, defined for a lossy dielectric (somewhat electrically conductive) material, is the angle for which the reflectivity for parallel-polarized light is minimized. For pure water, the reflectivity for parallel-polarized light is only 2.2 x 10(exp -4) at its pseudo- Brewster angle of 51deg. The reflectivity remains near zero, several degrees off from the 51deg optimum, allowing this angle of incidence requirement to be easily achieved. . The wavelength range of interest for measuring water temperatures is 8 to 12 microns. The emissivity of water for parallel- polarized light at the pseudo-Brewster angle is greater than 0.999 in this wavelength range. The radiometer would be sensitive in the wavelength range of 8 to 12 microns, would be equipped with a polarizer to discriminate against infrared light polarized perpendicular to the plane of incidence, and would be aimed toward a body of water at the pseudo- Brewster angle (see figure). Because the infrared radiation entering the radiometer would be polarized parallel to the plane of incidence and because very little downwelling parallel-polarized radiation would be reflected into the radiometer on account of the pseudo-Brewster arrangement, the radiation received by the radiometer would consist almost entirely of thermal emission from the surface of the water. Because the emissivity of the water would be very close to 1, the water could be regarded as a close approximation of a blackbody for the purpose of computing its surface temperature from the radiometer measurements by use of the Planck radiation law.

Ryan, Robert↗
NASA NTRS1971

Search for exoelectrons in Apollo 12 materials.

The search for exoelectron emission from Apollo 12 materials usually produced negative results, suggesting that the concentration of naturally occurring traps is very low. Weak exoelectron activity was found scattered inhomogeneously within a pigeonite basalt rock and in a deep core tube sample. Its erratic appearance and intensity makes any interpretation of radiation history most difficult and is attributed to the activity being carried by only a few scattered crystals. The thermally stimulated emission of exoelectrons is judged an unsuitable technique for tracing the radiation histories of these samples.

Gammage, R. B.↗
NASA NTRS1973

Multidimensional analysis of fast-spectrum material replacement measurements for systematic estimation of cross section uncertainties

A series of central core and core-reflector interface sample replacement experiments for 16 materials performed in the NASA heavy-metal-reflected, fast spectrum critical assembly (NCA) were analyzed in four and 13 groups using the GAM 2 cross-section set. The individual worths obtained by TDSN and DOT multidimensional transport theory calculations showed significant differences from the experimental results. These were attributed to cross-section uncertainties in the GAM 2 cross sections. Simultaneous analysis of the measured and calculated sample worths permitted separation of the worths into capture and scattering components which systematically provided fast spectrum averaged correction factors to the magnitudes of the GAM 2 absorption and scattering cross sections. Several Los Alamos clean critical assemblies containing Oy, Ta, and Mo as well as one of the NCA compositions were reanalyzed using the corrected cross sections. In all cases the eigenvalues were significantly improved and were recomputed to within 1 percent of the experimental eigenvalue. A comparable procedure may be used for ENDF cross sections when these are available.

Klann, P. G.↗
NASA NTRS1981

Two-dimensiosnal electron beam charging model for polymer films

A two dimensional model was developed to describe the charging of thin polymer films exposed to a uniform mon-energetic electron beam. The study was motivated by observed anomalous behavior of geosynchronous satellites which was attributed to electrical discharges associated with the differential charging of satellite surfaces of magnetospheric electrons. Electric fields both internal and external to the irradiated specimen were calculated at steady state in order to identify regions of high electrical stress. Particular emphasis was placed on evaluating the charging characteristics near the material's edge. The model was used to identify and quantify the effects of some of the experimental parameters notably: beam energy; beam angle of incidence; beam current density; material thickness; and material width. Simulations of the following situations were also conducted: positive or negative precharging over part of the surface; a central gap in the material; and a discontinuity in the material's thickness.

Reeves, R. D.↗
NASA NTRS1996

Observations of Dynamic Strain Aging in Polycrystalline NiAl

Dynamic strain aging has been investigated at temperatures between 77 and 1100 K in eight polycrystalline NiAl alloys. The 0.2% offset yield stress and work hardening rates for these alloys generally decreased with increasing temperature. However, local plateaus or maxima were observed in conventional purity and carbon doped alloys at intermediate temperatures (600-900 K). This anomalous behavior was not observed in low interstitial high-purity, nitrogen doped, or in titanium doped materials. Low or negative strain rate sensitivities (SRS) were also observed in all eight alloys in this intermediate temperature range. Coincident with the occurrence of negative SRS was the occurrence of serrated flow in conventional purity alloys containing high concentrations of Si in addition to C. These phenomena have been attributed to dynamic strain aging (DSA). Chemical analysis of the alloys used in this study suggests that the main species causing strain aging in polycrystalline NiAl is C but indicate that residual Si impurities can enhance the strain aging effect.

Weaver, M. L.↗
NASA NTRS1997

Spectrophotometry of Dust in Comet Hale-Bopp

Comets, such as Hale-Bopp (C/1995 O1), are frozen reservoirs of primitive solar nebula dust grains and ices. Analysis of the composition of cometary dust grains from infrared spectroscopic techniques permits an estimation of the types of organic and inorganic materials that constituted the early primitive solar nebula. In addition, the cometary bombardment of the Earth (approximately 3.5 Gy ago) supplied the water for the oceans and brought organic materials to Earth which may have been biogenic. Spectroscopic observations of comet Hale-Bopp suggest the possible presence of organic hydrocarbon species, silicate and olivine dust grains, and water ice. Spectroscopy near 3 microns obtained in Nov 1996 r=2.393 AU, delta=3.034 AU) shows a feature which we attribute to PAH emission. The spatial morphology of the 3.28 microns PAH feature is also presented. Optical and infrared spectrophotometric observations of comets convey valuable information about the spatial distribution and properties of dust and gas within the inner coma. In the optical and NIR shortward of 2 microns, the observed light is primarily scattered sunlight from the dust grains. At longer wavelengths, particularly in the 10 gm window, thermal emission from these grains dominates the radiation allowing an accurate estimate of grain sizes and chemical composition. Here we present an initial analysis of spectra taken with the NASA HIFOGS at 7-14 microns as part of a multiwavelength temporal study of the "comet of the century".

Witteborn, Fred C.↗
NASA NTRS2004

Epoxy Crosslinked Silica Aerogels (X-Aerogels)

NASA is interested in the development of strong lightweight materials for the dual role of thermal insulator and structural component for space vehicles; freeing more weight for useful payloads. Aerogels are very-low density materials (0.010 to 0.5 g/cc) that, due to high porosity (meso- and microporosity), can be, depending on the chemical nature of the network, ideal thermal insulators (thermal conductivity approx. 15 mW/mK). However, aerogels are extremely fragile. For practical application of aerogels, one must increase strength without compromising the physical properties attributed to low density. This has been achieved by templated growth of an epoxy polymer layer that crosslinks the "pearl necklace" network of nanoparticles: the framework of a typical silica aerogel. The requirement for conformal accumulation of the epoxy crosslinker is reaction both with the surface of silica and with itself. After cross-linking, the strength of a typical aerogel monolith increases by a factor of 200, in the expense of only a 2-fold increase in density. Strength is increased further by coupling residual unreacted epoxides with diamine.

fabrizio, Eve↗
NASA NTRS2010

Advances in Solid State Joining of Haynes 230 High Temperature Alloy

The J-2X engine is being designed for NASA s new class of crew and launch vehicles, the Ares I and Ares V. The J-2X is a LOX/Hydrogen upper stage engine with 294,000 lbs of thrust and a minimum Isp of 448 seconds. As part of the design criteria to meet the performance requirements a large film-cooled nozzle extension is being designed to further expand the hot gases and increases the specific impulse. The nozzle extension is designed using Haynes 230, a nickel-chromium-tungsten-molybdenum superalloy. The alloy was selected for its high strength at elevated temperatures and resistance to hydrogen embrittlement. The nozzle extension is manufactured from Haynes 230 plate spun-forged to form the contour and chemically-milled pockets for weight reduction. Currently fusion welding is being evaluated for joining the panels which are then mechanically etched and thinned to required dimensions for the nozzle extension blank. This blank is then spun formed into the parabolic geometry required for the nozzle. After forming the nozzle extension, weight reduction pockets are chemically milled into the nozzle. Fusion welding of Haynes results in columnar grains which are prone to hot cracking during forming processes. This restricts the ability to use spin forging to produce the nozzle contour. Solid state joining processes are being pursued as an alternative process to produce a structure more amenable to spin forming. Solid state processes have been shown to produce a refined grain structure within the joint regions as illustrated in Figure 1. Solid state joining processes include friction stir welding (FSW) and a patented modification termed thermal stir welding (TSW). The configuration of TSWing utilizes an induction coil to preheat the material minimizing the burden on the weld tool extending its life. This provides the ability to precisely select and control the temperature. The work presented in this presentation investigates the feasibility of joining the Haynes 230 alloy using the solid state welding processes of FSW and TSW. Process descriptions and attributes of each weld process will be presented. Weld process set-up and welding techniques will be discussed leading to the challenges experienced in joining the superalloy. Mechanical property data will also be presented.

Ding, R. Jeffrey↗
NASA NTRS2016

Cometary Origin of Atmospheric Methane Variations on Mars Unlikely

The detection of methane in the atmosphere of Mars was first reported in 2004. Since then a number of independent observations of methane have been reported, all showing temporal variability. Up until recently, the origin of methane was attributed to sources either indigenous to Mars or exogenous, where methane is a UV degradation byproduct of organics falling on to the surface. Most recently, a new hypothesis has been proposed that argues that the appearance and variation of methane are correlated with specific meteor events at Mars. Indeed, extraplanetary material can be brought to a planet when it passes through a meteoroid stream left behind by cometary bodies orbiting the Sun. This occurs repeatedly at specific times in a planet's year as streams tend to be fairly stable in space. In this paper, we revisit this latest hypothesis by carrying out a complete analysis of all available data on Mars atmospheric methane, including the very recent data not previously published, together with all published predicted meteor events for Mars. Whether we consider the collection of individual data points and predicted meteor events, whether we apply statistical analysis, or whether we consider different time spans between high methane measurements and the occurrence of meteor events, we find no compelling evidence for any correlation between atmospheric methane and predicted meteor events.

methane↗
NASA NTRS1996

The infrared spectrum of the Galactic center and the composition of interstellar dust

We have obtained 5-8 micrometers spectra of the Galactic center from the Kuiper Airborne Observatory at resolving powers of approximately 50, approximately 150, and approximately 300. These spectra show absorption features at 5.5, 5.8, 6.1, and 6.8 micrometers. Together with previously observed features in the 3 micrometers region, these features are compared with laboratory spectra of candidate materials. The 3.0 and 6.1 micrometers features are due to the OH stretching and bending variations of H2O and are well fitted by water of hydration in silicates (e.g., talc). The 3.0 micrometer band is equally well fitted by ice mixtures containing 30% H2O, but such mixtures do not provide a good fit to the observed 6.1 micrometer band. The 3.4 and 6.8 micrometers features are identified with the CH stretching and deformation modes in CH2 and CH3 groups in saturated aliphatic hydrocarbons. The 6.1 micrometer band shows a short wavelength shoulder centered on 5.8 micrometer, attributed to carbonyl (C double bond O) groups in this interstellar hydrocarbon dust component. Finally, the narrow 5.5 micrometer feature is also attributed to carbonyl groups, but in the form of metal carbonyls [e.g., Fe(CO)4]. We have derived column densities and abundances along the line of sight toward the Galactic center for the various identified dust components. This analysis shows that hydrocarbon grains contain only 0.08 of the elemental abundance of C and contribute only a relatively minor fraction (0.1) of the total dust volume. Most of the interstellar dust volume is made up of silicates (approximately 0.6). Small graphite grains, responsible for the 2200 angstroms bump, account for 0.07 of the total dust volume. The remaining one-quarter of the interstellar dust volume consists of a material(s) without strong IR absorption features. Likely candidates include large graphite grains, diamonds, or amorphous carbon grains, which all have weak or no IR active modes. Finally, various models for the origin of the hydrocarbon dust component of the interstellar dust are discussed. All of them face some problems in explaining the observations, in particular, the absence of the spectroscopic signature of hydrocrbon grains in sources associated with molecular clouds.

NASA Discipline Exobiology↗