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At least 541 records · Page 30

Effect of Cr Spacer on Structural and Magnetic Properties of Fe/Gd Multilayers

Here, we analyze the role of a thin Cr spacer between Fe and Gd layers on the structure and magnetic properties of a [Fe(35 Å)/Cr(t Cr )/Gd(50 Å)/Cr(t Cr )] 12 superlattice. Samples without the Cr spacer (t Cr = 0) and with a thin spacer (t Cr = 4 Å) are investigated using X-ray diffraction, polarized neutron and resonance X-ray magnetic reflectometry, static magnetometry, magneto-optical Kerr effect, and ferromagnetic resonance techniques. Magnetic properties are studied experimentally in a wide temperature range 4–300 K and analyzed theoretically using numerical simulation on the basis of the mean-field model. We show that a reasonable agreement with the experimental data can be obtained considering temperature dependence of the effective field parameter in gadolinium layers. In conclusion, the analysis of the experimental data shows that besides a strong reduction of the antiferromagnetic coupling between Fe and Gd, the introduction of Cr spacers into Fe/Gd superlattice leads to modification of both structural and magnetic characteristics of the ferromagnetic layers.

36 MATERIALS SCIENCE↗

Control of the third dimension in copper-based square-lattice antiferromagnets

Using a mixed-ligand synthetic scheme, we create a family of quasi-two-dimensional antiferromagnets, namely, [Cu(HF 2 )(pyz) 2 ]ClO 4 [pyz = pyrazine], [CuL 2 (pyz) 2 ](ClO 4 ) 2 [L = pyO = pyridine-N-oxide and 4-phpy-O = 4-phenylpyridine-N-oxide. These materials are shown to possess equivalent two-dimensional [Cu(pyz) 2 ] 2+ nearly square layers, but exhibit interlayer spacings that vary from 6.5713 to 16.777 Å, as dictated by the axial ligands. We present the structural and magnetic properties of this family as determined via x-ray diffraction, electron-spin resonance, pulsed- and quasistatic-field magnetometry and muon-spin rotation, and compare them to those of the prototypical two-dimensional magnetic polymer Cu(pyz) 2 (ClO 4 ) 2 . We find that, within the limits of the experimental error, the two-dimensional, intralayer exchange coupling in our family of materials remains largely unaffected by the axial ligand substitution, while the observed magnetic ordering temperature (1.91 K for the material with the HF 2 axial ligand, 1.70 K for the pyO and 1.63 K for the 4-phpy-O) decreases slowly with increasing layer separation. Despite the structural motifs common to this family and Cu(pyz) 2 (ClO 4 ) 2 , the latter has significantly stronger two-dimensional exchange interactions and hence a higher ordering temperature. Here, we discuss these results, as well as the mechanisms that might drive the long-range order in these materials, in terms of departures from the ideal S = 1/2 two-dimensional square-lattice Heisenberg antiferromagnet. In particular, we find that both spin-exchange anisotropy in the intralayer interaction and interlayer couplings (exchange, dipolar, or both) are needed to account for the observed ordering temperatures, with the intralayer anisotropy becoming more important as the layers are pulled further apart.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Spin-Orbit Coupling Controlled J = 3 / 2 Electronic Ground State in 5 d 3 Oxides

Spin-orbit entanglement in 5d-based transition metal oxides (TMOs) has been identified as a route to a host of unconventional physical states including quantum spin liquids, Weyl semimetals, and axion insulators. Yet despite intense interest, no clear rules have emerged for the treatment of spin-orbit coupling (SOC) in 5d TMOs outside of idealised LS or jj coupling paradigms. This is exemplified in 5d 3 oxides in which an orbitally-quenched singlet ground state is anticipated, yet SOC is manifest in the observed magnetic properties. Here we solve this long-outstanding puzzle by revealing that the electronic ground state of Os5+ 5d 3 ions is an unquenched J = 3/2 state. Resonant inelastic x-ray scattering (RIXS) in Ca3LiOsO6 and Ba 2 YOsO 6 exposes a SOC-controlled splitting of the t 2g manifold. The results are successfully described using an intermediate-coupling framework in which oxygen hybridisation promotes the breakdown of the orbital singlet. This framework opens the door to realistic treatment of SOC across a range of 5d TMOs beyond the 5d 3 case.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗

Preface to Special Topic: Advances in Radio Frequency Physics in Fusion Plasmas

It has long been recognized that auxiliary plasma heating will be required to achieve the high temperature, high density conditions within a magnetically confined plasma in which a fusion “burn” may be sustained by copious fusion reactions. Consequently, the application of radio and microwave frequency electromagnetic waves to magnetically confined plasma, commonly referred to as RF, has been a major part of the program almost since its inception in the 1950s. These RF waves provide heating, current drive, plasma profile control, and Magnetohydrodynamics (MHD) stabilization. Fusion experiments employ electromagnetic radiation in a wide range of frequencies, from tens of MHz to hundreds of GHz. The fusion devices containing the plasma are typically tori, axisymmetric or non, in which the equilibrium magnetic fields are composed of a strong toroidal magnetic field generated by external coils, and a poloidal field created, at least in the symmetric configurations, by currents flowing in the plasma. The waves are excited in the peripheral regions of the plasma, by specially designed launching structures, and subsequently propagate into the core regions, where resonant wave-plasma interactions produce localized heating or other modification of the local equilibrium profiles. Experimental studies coupled with the development of theoretical models and advanced simulation codes over the past 40+ years have led to an unprecedented understanding of the physics of RF heating and current drive in the core of magnetic fusion devices. Nevertheless, there are serious gaps in our knowledge base that continue to have a negative impact on the success of ongoing experiments and that must be resolved as the program progresses to the next generation devices and ultimately to “demo” and “fusion power plant.” A serious gap, at least in the ion cyclotron (IC) range of frequencies and partially in the lower hybrid frequency ranges, is the difficulty in coupling large amount of power to the plasma while minimizing the interaction between the plasma and launching structures. These potentially harmful interactions between the plasma and the vessel and launching structures are challenging: (i) significant and variable loss of power in the edge regions of confined plasmas and surrounding vessel structures adversely affect the core plasma performance and lifetime of a device; (ii) the launcher design is partly “trial and error,” with the consequence that launchers may have to be reconfigured after initial tests in a given device, at an additional cost. Over the broader frequency range, another serious gap is a quantitative lack of understanding of the combined effects of nonlinear wave-plasma processes, energetic particle interactions and non-axisymmetric equilibrium effects on determining the overall efficiency of plasma equilibrium and stability profile control techniques using RF waves. This is complicated by a corresponding lack of predictive understanding of the time evolution of transport and stability processes in fusion plasmas.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Whispering-Gallery-Mode Tunable Narrow-Band-Pass Filter

An experimental tunable, narrow-band-pass electro-optical filter is based on a whispering-gallery resonator. This device is a prototype of tunable filters needed for the further development of reconfigurable networking wavelength-division multiplexers and communication systems that utilize radio-frequency (more specifically, microwave) subcarrier signals on optical carrier signals. The characteristics of whispering-gallery resonators that make them attractive for such applications include high tuning speed, compactness, wide tuning range, low power consumption, and compatibility with single-mode optical fibers. In addition, relative to Fabry-Perot resonators, these devices offer advantages of greater robustness and lower cost. As described in several prior NASA Tech Briefs articles, a whispering-gallery resonator is a spheroidal, disk-like, or toroidal body made of a highly transparent material. It is so named because it is designed to exploit whispering-gallery electromagnetic modes, which are waveguide modes that propagate circumferentially and are concentrated in a narrow toroidal region centered on the equatorial plane and located near the outermost edge. The experimental whispering-gallery tunable filter (see figure) is made from a disk of Z-cut LiNbO3 of 4.8-mm diameter and 0.17-mm thickness. The perimeter of the disk is rounded to a radius of curvature of 100 m. Metal coats on the flat faces of the disk serve as electrodes for exploiting the electro-optical effect in LiNbO3 for tuning. There is no metal coat on the rounded perimeter region, where the whispering-gallery modes propagate. Light is coupled from an input optical fiber into the whispering-gallery modes by means of a diamond prism. Another diamond prism is used to couple light from the whispering-gallery modes to an output optical fiber. This device is designed and operated to exploit transverse magnetic (TM) whispering- gallery modes, rather than transverse electric (TE) modes because the resonance quality factors (Q values) of the TM modes are higher. If Q values were not of major concern, it would be better to use the TE modes because the electro-optical shifts of the TE modes are 3 times those of the TM modes.

Savchenkov, Anatoliy↗

Low-energy electronic interactions in ferrimagnetic Sr 2 CrReO 6 thin films

We reveal in this study the fundamental low-energy landscape in the ferrimagnetic Sr 2 CrReO 6 double perovskite and describe the underlying mechanisms responsible for the three low-energy excitations below 1.4 eV. Here, based on resonant inelastic x-ray scattering and magnetic dynamics calculations, and experiments collected from both Sr 2 CrReO 6 powders and epitaxially strained thin films, we reveal a strong competition between spin-orbit coupling, Hund’s coupling, and the strain-induced tetragonal crystal field. Here, we also demonstrate that a spin-flip process is at the origin of the lowest excitation at 200 meV, and we bring insights into the predicted presence of orbital ordering in this material. We study the nature of the magnons through a combination of ab initio and spin-wave theory calculations, and show that two nondegenerate magnon bands exist and are dominated either by rhenium or chromium spins. The rhenium band is found to be flat at about 200 meV (±25 meV) through X-L-W-U high-symmetry points and is dispersive toward Γ.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Large resistance change on magnetic tunnel junction based molecular spintronics devices

Here, molecular bridges covalently bonded to two ferromagnetic electrodes can transform ferromagnetic materials and produce intriguing spin transport characteristics. This paper discusses the impact of molecule induced strong coupling on the spin transport. To study molecular coupling effect the octametallic molecular cluster (OMC) was bridged between two ferromagnetic electrodes of a magnetic tunnel junction (Ta/Co/NiFe/AlOx/NiFe/Ta) along the exposed side edges. OMCs induced strong inter-ferromagnetic electrode coupling to yield drastic changes in transport properties of the magnetic tunnel junction testbed at the room temperature. These OMCs also transformed the magnetic properties of magnetic tunnel junctions. SQUID and ferromagnetic resonance studies provided insightful data to explain transport studies on the magnetic tunnel junction based molecular spintronics devices.

36 MATERIALS SCIENCE↗

Exploring Highly Reversible 1.5-Electron Reactions (V 3+ /V 4+ /V 5+ ) in Na 3 VCr(PO 4 ) 3 Cathode for Sodium-Ion Batteries

The development of highly reversible multielectron reaction per redox center in sodium super ionic conductor-structured cathode materials is desired to improve the energy density of sodium-ion batteries. Here, we investigated more than one-electron storage of Na in Na 3 VCr(PO 4 ) 3 . Combining a series of advanced characterization techniques such as ex situ 51 V solid-state nuclear magnetic resonance, X-ray absorption near-edge structure, and in situ X-ray diffraction, we reveal that V 3+ /V 4+ and V 4+ /V 5+ redox couples in the materials can be accessed, leading to a 1.5-electron reaction. It is also found that a light change on the local electronic and structural states or phase change could be observed after the first cycle, resulting in the fast capacity fade at room temperature. As a result, we also showed that the irreversibility of the phase changes could be largely suppressed at low temperature, thus leading to a much improved electrochemical performance.

25 ENERGY STORAGE↗

Absolute NMR shielding scales and nuclear spin–rotation constants in {sup 175}LuX and {sup 197}AuX (X = {sup 19}F, {sup 35}Cl, {sup 79}Br and {sup 127}I)

We present nuclear spin–rotation constants, absolute nuclear magnetic resonance (NMR) shielding constants, and shielding spans of all the nuclei in {sup 175}LuX and {sup 197}AuX (X = {sup 19}F, {sup 35}Cl, {sup 79}Br, {sup 127}I), calculated using coupled-cluster singles-and-doubles with a perturbative triples (CCSD(T)) correction theory, four-component relativistic density functional theory (relativistic DFT), and non-relativistic DFT. The total nuclear spin–rotation constants determined by adding the relativistic corrections obtained from DFT calculations to the CCSD(T) values are in general in agreement with available experimental data, indicating that the computational approach followed in this study allows us to predict reliable results for the unknown spin–rotation constants in these molecules. The total NMR absolute shielding constants are determined for all the nuclei following the same approach as that applied for the nuclear spin–rotation constants. In most of the molecules, relativistic effects significantly change the computed shielding constants, demonstrating that straightforward application of the non-relativistic formula relating the electronic contribution to the nuclear spin–rotation constants and the paramagnetic contribution to the shielding constants does not yield correct results. We also analyze the origin of the unusually large absolute shielding constant and its relativistic correction of gold in AuF compared to the other gold monohalides.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Helicon Wave Physics Impacts on Electrodeless Thruster Design

Effective generation of helicon waves for high density plasma sources is determined by the dispersion relation and plasma power balance. Helicon wave plasma sources inherently require an applied magnetic field of .01-0.1 T, an antenna properly designed to couple to the helicon wave in the plasma, and an rf power source in the 10-100 s of MHz, depending on propellant choice. For a plasma thruster, particularly one with a high specific impulse (>2000 s), the physics of the discharge would also have to address the use of electron cyclotron resonance (ECR) heating and magnetic expansion. In all cases the system design includes an optimized magnetic field coil, plasma source chamber, and antenna. A preliminary analysis of such a system, calling on experimental data where applicable and calculations where required, has been initiated at Glenn Research Center. Analysis results showing the mass scaling of various components as well as thruster performance projections and their impact on thruster size are discussed.

Gilland, James↗

Helicon Wave Physics Impacts on Electrodeless Thruster Design

Effective generation of helicon waves for high density plasma sources is determined by the dispersion relation and plasma power balance. Helicon wave plasma sources inherently require an applied magnetic field of .01-0.1 T, an antenna properly designed to couple to the helicon wave in the plasma, and an rf power source in the 10-100 s of MHz, depending on propellant choice. For a plasma thruster, particularly one with a high specific impulse (>2000 s), the physics of the discharge would also have to address the use of electron cyclotron resonance (ECR) heating and magnetic expansion. In all cases the system design includes an optimized magnetic field coil, plasma source chamber, and antenna. A preliminary analysis of such a system, calling on experimental data where applicable and calculations where required, has been initiated at Glenn Research Center. Analysis results showing the mass scaling of various components as well as thruster performance projections and their impact on thruster size are discussed.

Gilland, James H.↗

Scalar Atomic Defect-Based Solid-State Self-calibrating Magnetometer (3SM) for Space Plasma Analysis

The Earth’s magnetosphere is a system of multiple, co-located particle populations interacting via plasma waves. Things to understand are driving processes, radiation belt and ring current issues, auroral physics, internal plasma processes, and magnetosphere-ionosphere mapping issues. These plasma-physics processes enable the Earth’s magnetosphere to evolve in response to temporal changes in the solar wind and they underlie the phenomena of space weather, which impacts spacecraft systems, astronauts, radio communications, and ground based electric-power grids. The objective of 3SM is to measure magnetic field strength and to calibrate the Vector Magnetometer (VM) device to maintain absolute accuracy during a mission. The 3SM features make the instrument preferably suited not only for the traditional role of scalar magnetometers as absolute references for the calibration of the on-board vector instruments, but also for extended operational capacities, such as higher frequency scalar measurements (of potential interest for magnetosphere studies for the low frequency part of the spectrum) or autonomous scalar / vector operations. Diamond has been the solid-state platform of choice for quantum device technologies for some time, however, it suffers from difficulties such as scalability, integration, and cost. While the diamond platform is very useful for quantum technologies, further development is needed to make it viable. The material platform of choice for NASA Glenn’s Quantum Sensing And Spin Physics (Q-SASP) is silicon carbide (SiC). This is due to the much higher industry development of the SiC material platform for high-power and high-temperature electronics. It leverages both the decades-long SiC development expertise and infrastructure at NASA Glenn and its growing capabilities in quantum metrology. To make SiC devices usable for quantum technologies such as quantum sources, a much deeper understanding of defects is needed. Q-SASP is developing quantum metrology capabilities to evaluate the energy structure, defect formation energy, band structure augmentation, generation/recombination rates, and limits of dipole-dipole coupling in non-metal implanted SiC devices. This can be achieved by analysis of zero-field splitting, low-field resonance, and singlet-triplet mixing through various forms of Electrically Detectable Magnetic Resonance (EDMR) and Near-Zero Field Magnetic Resonance (NZFMR) spectroscopy. This work will discuss recent system developments, device developments, computational modeling, and spectroscopy results and analysis of defects created by non-metal implantations in SiC devices. The defect formation energies of V Si ,V C , V C V Si , N C V Si , N Si , N C in 4H-SiC are previously reported values in other research [2]-[3]. The defect formation energies of PSi and PC were calculated in GPAW [fig 1A]. The basic underlying mechanism of the zero-field phenomenon is the mixing of singlet and triplet states [4]-[5]. In most spin-dependent transport, two electron spins are involved, and thus one must consider each of their interactions with the field. We investigated the electronic and magnetic properties of 4H-SiC and 6H-SiC. The defect formation energy helps us determine what types of defects we are observing in the SiC EDMR experiment. They have very low formation energy (it is negative). The phosphorus substitution in 4H-SiC is a very stable defect. The band diagrams provide us with vital information about how the electronic properties of SiC (such as band gap) change as we add non-metal defects. The zero-field splitting parameters allow us to study the inflection point in the NZFMR [fig 1B]. We clearly observed zero-field splitting. We also noted that the zero-field splitting remained constant with changing bias. We aspect it zero-field splitting to remain constant while the hyperfine and exchange interaction perturbations shift under the influence of an external magnetic field. This is the essence of quantum magnetometry and self-calibration.

space plasma↗

Wave excitation by nonlinear coupling among shear Alfvén waves in a mirror-confined plasma

A shear Alfvén wave at slightly below the ion-cyclotron frequency overcomes the ion-cyclotron damping and grows because of the strong anisotropy of the ion temperature in the magnetic mirror configuration, and is called the Alfvén ion-cyclotron (AIC) wave. Density fluctuations caused by the AIC waves and the ion-cyclotron range of frequencies (ICRF) waves used for ion heating have been detected using a reflectometer in a wide radial region of the GAMMA 10 tandem mirror plasma. Various wave-wave couplings are clearly observed in the density fluctuations in the interior of the plasma, but these couplings are not so clear in the magnetic fluctuations at the plasma edge when measured using a pick-up coil. A radial dependence of the nonlinearity is found, particularly in waves with the difference frequencies of the AIC waves; bispectral analysis shows that such wave-wave coupling is significant near the core, but is not so evident at the periphery. In contrast, nonlinear coupling with the low-frequency background turbulence is quite distinct at the periphery. Nonlinear coupling associated with the AIC waves may play a significant role in the beta- and anisotropy-limits of a mirror-confined plasma through decay of the ICRF heating power and degradation of the plasma confinement by nonlinearly generated waves.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Local site behavior of the 5$d$ and 4$f$ ions in the frustrated pyrochlore Ho 2 Os 2 O 7

The pyrochlore osmate Ho 2 Os 2 O 7 is a candidate material for a fragile J=0 local singlet ground state, however little is known regarding the single-ion behavior of either the Os or Ho ions. To address this we present polarized neutron powder diffraction (PNPD) and resonant inelastic x-ray scattering (RIXS) measurements that separately probe the local site behavior of the Os and Ho ions. The PNPD results are dominated by Ho 3+ scattering and the analysis reveals local site susceptibility behavior consistent with spin ice materials. Complimentary unpolarized neutron powder diffraction show an ordered spin ice ground state in an applied magnetic field. To isolate the Os 4+ single-ion behavior we present resonant inelastic x-ray scattering (RIXS) measurements at the osmium L-edge. Analysis of the RIXS spectra parameterize the spin-orbit coupling (0.35 eV), Hund’s coupling (0.27 eV) and trigonal distortion (-0.17 eV). Here, the results are considered within the context of a J=0 model and possible departures from this through structural distortions, excitonic interactions and 5d-4f interactions between the Os ion and the surrounding Ho lattice. The experimental methodology employed highlights the complimentary information available in rare earth based 5d pyrochlores from distinct neutron and x-ray scattering techniques that allow for the isolation and determination of the behavior of the different ions.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Long-range exchange interaction between magnetic impurities in graphene

The effective spin exchange RKKY coupling between impurities (adatoms) on graphene mediated by conduction electrons is studied as a function of the strength of the potential part of the on-site energy U of the electron-adatom interaction. With increasing U, the exchange coupling becomes long range, determined largely by the impurity levels with energies close to the Dirac points. Finally, when adatoms reside on opposite sublattices, their exchange coupling, normally antiferromagnetic, becomes ferromagnetic and resonantly enhanced at a specific distance where an impurity level crosses the Dirac point.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Axion-mediated Transport of Fast Radio Bursts Originating in Inner Magnetospheres of Magnetars

Abstract Among magnetar models of fast radio bursts (FRBs), there is ongoing debate about whether the site of coherent radio emission lies within or beyond the light cylinder. We propose a mechanism by which FRBs produced near the magnetar surface are transported out of the magnetosphere by axions, which are hypothetical particles that couple to photons. If the emission site hosts strong accelerating electric fields, a considerable fraction of the FRB energy budget is converted to an axion burst. Once produced, the axion burst free streams out of the magnetosphere due to the rapidly decreasing magnetic field. The burst may escape through either the open or closed magnetosphere while retaining the temporal signature of the original FRB. In the wind region, axions resonantly excite ordinary (O) modes that escape as the plasma density decreases. The radio efficiency of this mechanism satisfies energetics constraints from FRB 121102 for axion−photon coupling strengths that have not been excluded by other astrophysical probes.

Prabhu, Anirudh (ORCID:0000000191157844)↗

Using magnetic dynamics to measure the spin gap in a candidate Kitaev material

Spin-orbit entangled materials have attracted widespread interest due to the novel magnetic phenomena arising from the interplay between spin-orbit coupling and electronic correlations. However, the intricate nature of spin interactions within Kiteav materials complicates the precise measurement of low-energy spin excitations. Using Na 2 Co 2 TeO 6 as an example, we study these low-energy spin excitations using the time-resolved resonant elastic x-ray scattering (tr-REXS). Our observations unveil remarkably slow spin dynamics at the magnetic peak, whose recovery timescale is several nanoseconds. This timescale aligns with the extrapolated spin gap of ~1 μeV, obtained by density matrix renormalization group (DMRG) simulations in the thermodynamic limit. The consistency demonstrates the efficacy of tr-REXS in discerning low-energy spin gaps inaccessible to conventional spectroscopic techniques.

36 MATERIALS SCIENCE↗

Thin-film lithium niobate on diamond as a platform for efficient spin-phonon coupling

Negatively charged silicon vacancy (SiV − ) centers in diamond are leading candidates for solid-state quantum memory that can be controlled using electromagnetic or acoustic waves. The latter are particularly promising due to the strong strain response of SiV − , enabling large spin-phonon interaction strengths. Indeed, coherent spin control via surface acoustic waves (SAWs) has been demonstrated and is essential for developing on-chip phononic quantum networks. However, the absence of piezoelectricity in diamond requires an interface with a piezoelectric material for efficient transduction and delivery of acoustic waves to spins in diamonds. Here, we demonstrate a heterogeneously integrated phononic platform that combines thin-film lithium niobate with diamond to enable acoustic control of single SiV − spins. Additionally, leveraging large SAW-induced strain at the location of SiV − , we achieve coherent acoustic control of an electron spin with more than twofold improvement in Rabi frequency compared to state-of-the-art devices based on aluminum nitride on diamond. Furthermore, this work represents a crucial step towards realizing phonon-based quantum information processing systems.

Optically detected magnetic resonance↗