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At least 541 records · Page 30
All sourcesNASA NTRSDOE OSTI
NASA NTRS1989

Denitrification in the Antarctic stratosphere

Rapid loss of ozone over Antarctica in spring requires that the abundance of gaseous nitric acid be very low. Precipitation of particulate nitric acid has been assumed to occur in association with large ice crystals, requiring significant removal of H2O and temperatures well below the frost point. However, stratospheric clouds exhibit a bimodal size distribution in the Antarctic atmosphere, with most of the nitrate concentrated in particles with radii of 1 micron or greater. It is argued here that the bimodal size distribution sets the stage for efficient denitrification, with nitrate particles either falling on their own or serving as nuclei for the condensation of ice. Denitrification can therefore occur without significant dehydration, and it is unnecessary for temperatures to drop significantly below the frost point.

Salawitch, R. J.↗
NASA NTRS1990

Small-scale disequilibrium in a magmatic inclusion and its more silicic host

An investigation of small-scale isotopic, compositional, and mineralogical variation across the interface of a basaltic-andesite inclusion and its dacitic host from Cerro-Chascon, a Holocene dome in northern Chile, is discussed. Serial sectioning across the interface of the inclusion and its host dacite, complemented by microdrill sampling and detailed microprobe work, has enabled an examination of the scale of mixing and chemical disequilibrium. The composition of the inclusion is found to be relatively homogeneous; the dacite host is heterogeneous on a small scale; the isotopic composition in the marginal zone shows the highest Sr-87/Sr-86 and lowest Nd-143/Nd-144; the large plagioclase crystals in the inclusions and host are xenocrystic. These differences are reconciled with a model of magma evolution in a crustal magma chamber.

Davidson, Jon P.↗
NASA NTRS1994

D/H ratios and H2O contents of mantle-derived amphibole megacrysts from Dish Hill, California

D/H ratios are, in principle, useful in characterizing reservoirs of mantle hydrogen and as tracers of volatile transfer processes in Earth's interior. In practice, however, interpretation of isotopic measurements on mantle derived H is complicated by surface processes such as contamination and degassing which may alter the primary D/H ratio. Although there are indications that water associated with subduction zones and certain chemically enriched basalts is enriched in D relative to 'typical' upper mantle water, the extent of isotopic heterogeneity of mantle H remains uncertain. Kaersutitic amphibole megacrysts in alkaline basalts are one of the most widespread sources of mantle water and are therefore potentially useful for large-scale regional studies of D/H variation. However, D/H ratios of these amphiboles vary widely (from plus 8 to minus 113 percent), even in samples from the same locality, so that this potential has yet to be realized. In order to investigate the origin of this variability, and to explore the possibility that primary mantle D/H ratios may be deduced from these amphiboles, we analyzed the D/H ratios and chemical compositions of a suite of 17 kaersutitic amphiboles from Dish Hill, California. This work contrasts with previous studies in which sampling is widespread, but representatives from any given locality are few. Samples were collected from a restricted area on the southern flank of the volcanic center and are associated with the basal volcanic breccia. Fourteen of the samples were large single crystals or crystal fragments (megacrysts, 0.4 to 30 grams), believed to derive from pegmatitic veins crystallized from melts in the mantle. Two were coarse-grained intergrowths of amphibole with olivine and spinel, and one was a thin (2 mm) selvage on a peridotite xenolith.

Bell, David R.↗
NASA NTRS1994

Diffusive modification of primary zoning in olivine cores in Angrite LEW 87051

Angrite LEW 87051 consists of large olivine crystals set in a fine-grained groundmass that clearly represents a crystallized melt. A few olivines contain Ca-poor, Cr-rich cores that crystallized from a very different melt than the outer part of the crystals constituting the majority of olivine in LEW 87051. We evaluate a model in which the cores formed through fractional crystallization of one melt, then were incorporated into a different melt as xenocrysts, whereupon the original zoning patterns were modified by diffusion. Using a similar approach, we calculate zoning patterns for the cores that would result from perfect fractional crystallization, compare them with the observed zoning, and determine whether the differences could result from diffusive modification consistent with known diffusion rates for Ca, Mn, and Cr. Using distribution coefficients from the 1400 C, IW + 1 experiments, we computed CaO, Cr2O3, and MnO abundances in the hypothetical parent melt by inverting the olivine at the centers of the cores. We further assumed that the primary zoning profile for CaO is essentially unmodified, because the diffusion rate of Ca in olivine is slow. We carried out the fractional crystallization calculation until the calculated Ca content was that observed at break in zoning profiles at the outer edge of the core. We then normalized the distance of this calculated profile to the length of the observed profile in the olivine core and calculated profiles for MnO and Cr2O3. The CaO zoning profile agrees well with the observed profile. The observed MnO profile is slightly higher than the calculated profile near the edge. Diffusion calculations indicate that reversal of the general trend of primary zoning through diffusion would require that diffusion of Cr is 5-10x faster than that of Mn.

Mikouchi, T.↗
NASA NTRS1994

Effusive silicic volcanism in the Central Andes: The Chao dacite and other young lavas of the Altiplano-Puna Volcanic Complex

The largest known Quaternary silicic lava body in the world is Cerro Chao in north Chile, a 14-km-long coulee with a volume of at least 26 cu km. It is the largest of a group of several closely similar dacitic lavas erupted during a recent (less than 100,000 year old) magmatic episode in the Altiplano-Puna Volcanic Complex (APVC; 21-24 deg S) of the Centra; Andean Volcanic Zone. The eruption of Chao proceeded in three phases. Phase 1 was explosive and produced approximately 1 cu km of coarse, nonwelded dacitic pumice deposits and later block and ash flows that form an apron in front of the main lava body. Phase 2 was dominantly effusive and erupted approximately 22.5 cu km of magma in the form of a composite coulee covering approximately 53 sq km with a 400-m-high flow front and a small cone of poorly expanded pumice around the vent. The lava is homogeneous with rare flow banding and vesicular tops and selvages. Ogives (flow ridges) reaching heights of 30 m form prominent features on its surface. Phase 3 produced a 6-km-long, 3-km-wide flow that emanated from a collapsed dome. Ogives are subdued, and the lava is glassier than that produced in previous phases. All the Chao products are crystal-rich high-K dacites and rhyodacites with phenocrysts of plagioclase, quartz, hornblende, biotite, sphene, rare snidine, and oxides. Phenocryst contents reach 40-60 vol % (vesicle free) in the main phase 2 lavas but are lower in the phase 1 (20-25%) and phase 3 (approximately 40%) lavas. Ovoid andesitic inclusions with vesicular interiors and chilled margins up to 10 cm are found in the later stages of phase 2 and compose up to 5% of the phase 3 lava. There is little evidence for preeruptive zonation of the magma body in composition, temperature (approximately 840 C), fO2 (19(exp -11), or water content, so we propose that eruption of the Chao complex was driven by intrusion of fresh, hot andesitic magma into a crystallizing and largely homogeneous body of dacitic magma. Morphological measurements suggest that the Chao lavas had internal plastic viscosities of 10(exp 10) to 10(exp 12) Pa s, apparent viscosities of 10(exp 9) Pa s, surface viscosities of 10(exp 15) to 10(exp 24) Pa s, and a yield strength of 8 x 10(exp 5) Pa. These estimates indicate that Chao would have exhibited largely similar rheological properties to other silicic lava extrusions, notwithstanding its high phenocryst content. We suggest that Chao's anomalous size is a function of both the relatively steep local slope (20 deg to 3 deg) and the available volume of magma. The eruption duration for Chao's emplacement is thought to have been about 100 to 150 years, with maximum effusion rates of about 25 cu m/s for short periods. Four other lavas in the vicinity with volumes of approximately 5 cu km closely resemble Chao and are probably comagnetic. The suite as a whole shares a petrologic and chemical similarity with the voluminous regional Tertiary to Pleistocene ignimbrites of the APVC and may be derived from a zone of silicic magmatism that is thought to have been active since the late Tertiary. Chao and the other young lavas may represent either the waning of this system or a new episode fueled by intrusions of mafic magma.

De Silva, S. L.↗
NASA NTRS1998

The Effect of Solution Conditions on the Nucleation Kinetics of Tetragonal Lysozyme Crystals

An understanding of protein crystal nucleation rates and the effect of solution conditions upon them, is fundamental to the preparation of protein crystals of the desired size and shape for X-ray diffraction analysis. The ability to predict the effect of supersaturation, temperature, pH and precipitant concentration on the number and size of crystals formed is of great benefit in the pursuit of protein structure analysis. In this study we experimentally examine the effect of supersaturation, temperature, pH and sodium chloride concentration on the nucleation rate of tetragonal chicken egg white lysozyme crystals. In order to do this batch crystallization plates were prepared at given solution concentrations and incubated at three different temperatures over the period of one week. The number of crystals per well with their size and dimensions were recorded and correlated against solution conditions. Duplicate experiments indicate the reproducibility of the technique. Although it is well known that crystal numbers increase with increasing supersaturation, large changes in crystal number were also correlated against solution conditions of temperature, pH and salt concentration over the same supersaturation ranges. Analysis of these results enhance our understanding of the effect of solution conditions such as the dramatic effect that small changes in charge and ionic strength can have on the number of tetragonal lysozyme crystals that form and grow in solution.

Judge, Russell A.↗
NASA NTRS2001

High-Resolution Large-Field-of-View Three-Dimensional Hologram Display System and Method Thereof

A real-time, dynamic, free space-virtual reality, 3-D image display system is enabled by using a unique form of Aerogel as the primary display media. A preferred embodiment of this system comprises a 3-D mosaic topographic map which is displayed by fusing four projected hologram images. In this embodiment, four holographic images are projected from four separate holograms. Each holographic image subtends a quadrant of the 4(pi) solid angle. By fusing these four holographic images, a static 3-D image such as a featured terrain map would be visible for 360 deg in the horizontal plane and 180 deg in the vertical plane. An input, either acquired by 3-D image sensor or generated by computer animation, is first converted into a 2-D computer generated hologram (CGH). This CGH is then downloaded into large liquid crystal (LC) panel. A laser projector illuminates the CGH-filled LC panel and generates and displays a real 3-D image in the Aerogel matrix.

Chao, Tien-Hsin↗
NASA NTRS2001

Constraints on PSC Particle Microphysics Derived From Lidar Observations

Based on extensive T-matrix computations of light scattering by polydispersions of randomly oriented, rotationally symmetric nonspherical particles, we analyze existing lidar observations of polar stratospheric clouds (PSCs) and derive several constraints on PSC particle microphysical properties. We show that sharp-edged nonspherical particles (finite circular cylinders) exhibit less variability of lidar backscattering characteristics with particle size and aspect ratio than particles with smooth surfaces (spheroids). For PSC particles significantly smaller than the wavelength, the backscatter color index Alpha and the depolarization color index Beta are essentially shape-independent. Observations for type Ia PSCs can be reproduced by spheroids with aspect ratios larger than 1.2, oblate cylinders with diameter-to-length ratios greater than 1.6, and prolate cylinders with length-to-diameter ratios greater than 1.4. The effective equal-volume-sphere radius for type la PSCs is about 0.8 microns or larger. Type Ib PSCs are likely to be composed of spheres or nearly spherical particles with effective radii smaller than 0.8 microns. Observations for type II PSCs are consistent with large ice crystals (effective radius greater than 1 micron modeled as cylinders or prolate spheroids.

Liu, Li↗
NASA NTRS1993

(abstract) Cometary Particles as a Tracer of Jupiter's Stratospheric Circulation

The impact of fragments of comet Shoemaker-Levy 9 on Jupiter's atmosphere in July 1994 may provide an unprecedented opportunity to study Jupiter's stratospheric circulation. Recent calculations by Z. Sekanina predict that much of the comet material will be deposited in Jupiter's stratosphere. If so, and if the material is deposited in a confined region (10 000 km or less, horizontally) we can expect a situation analogous to an El Chichon or Pinatubo event for the terrestrial stratosphere. Initially the volatile material will be vaporized and will rapidly recondense. The large ice crystals and dust particles will rain out and be lost to the troposphere. The cloud of small particles which remain may have settling times of more than a year. These submicron to micron particles would probably be easily seen in methane filter images in the near-IR, and possibly in the ultraviolet. An observational program to monitor the dispersal of this cloud or clouds would reveal much about the nature of the circulation. Some predictions about the meridional evolution of the clouds can be made already, based on the meridional circulation model of West et al. unless the impact itself significantly disrupts the annual average circulation well after the initial transients die away.

comet Shoemaker-Levy 9 impact Jupiter stratosphere↗
NASA NTRS2010

Fabrication of an Absorber-Coupled MKID Detector and Readout for Sub-Millimeter and Far-Infrared Astronomy

We have fabricated absorber-coupled microwave kinetic inductance detector (MKID) arrays for sub-millimeter and far-infrared astronomy. Each detector array is comprised of lambda/2 stepped impedance resonators, a 1.5 micrometer thick silicon membrane, and 380 micrometer thick silicon walls. The resonators consist of parallel plate aluminum transmission lines coupled to low impedance Nb microstrip traces of variable length, which set the resonant frequency of each resonator. This allows for multiplexed microwave readout and, consequently, good spatial discrimination between pixels in the array. The Al transmission lines simultaneously act to absorb optical power and are designed to have a surface impedance and filling fraction so as to match the impedance of free space. Our novel fabrication techniques demonstrate high fabrication yield of MKID arrays on large single crystal membranes and sub-micron front-to-back alignment of the microstrip circuit.

Brown, Ari-David↗
NASA NTRS2007

Condensed-Phase Nitric Acid in a Tropical Subvisible Cirrus Cloud

In situ observations in a tropical subvisible cirrus cloud during the Costa Rica Aura Validation Experiment on 2 February 2006 show the presence of condensed-phase nitric acid. The cloud was observed near the tropopause at altitudes of 16.3-17.7 km in an extremely cold (183-191 K) and dry 5 ppm H2O) air mass. Relative humidities with respect to ice ranged from 150-250% throughout most of the cloud. Optical particle measurements indicate the presence of ice crystals as large as 90 microns in diameter. Condensed RN031H20 molar ratios observed in the cloud particles were 1-2 orders of magnitude greater than ratios observed previously in cirrus clouds at similar RN03 partial pressures. Nitric acid trihydrate saturation ratios were 10 or greater during much of the cloud encounter, indicating that RN03 may be present in the cloud particles as a stable condensate and not simply physically adsorbed on or trapped in the particles.

Popp, P. J.↗
NASA NTRS2012

An Experimental Investigation of the Shergottite NWA 6162

The Martian meteorite North West Africa 6162 (NWA 6162) is a shergottite found in Morocco in 2010. The meteorite has large olivine crystals with Mg-depleted rims as low as FO(sub 65) and Mg-rich cores of up to FO(sub 74). It is similar both in appearance and composition to another shergottite, SaU 005. Our objective is to determine if NWA 6162 represents a liquid or if it is a product of olivine accumulation. Olivine accumulation would leave the parent melt Mg-depleted and the complementary olivine cumulates would be Mg-enriched. Therefore, if NWA 6162 is a partial cumulate we would expect that liquidus olivines grown from this bulk composition would be more magnesium than olivines in the natural sample.

Barnett, R. Gaylen↗
NASA NTRS2010

Fabrication of an Absorber-Coupled MKID Detector and Readout for Sub-Millimeter and Far-Infrared Astronomy

We have fabricated absorber-coupled microwave kinetic inductance detector (MKID) arrays for sub-millimeter and farinfrared astronomy. Each detector array is comprised of lambda/2 stepped impedance resonators, a 1.5μm thick silicon membrane, and 380μm thick silicon walls. The resonators consist of parallel plate aluminum transmission lines coupled to low impedance Nb microstrip traces of variable length, which set the resonant frequency of each resonator. This allows for multiplexed microwave readout and, consequently, good spatial discrimination between pixels in the array. The Al transmission lines simultaneously act to absorb optical power and are designed to have a surface impedance and filling fraction so as to match the impedance of free space. Our novel fabrication techniques demonstrate high fabrication yield of MKID arrays on large single crystal membranes and sub-micron front-to-back alignment of the microstrip circuit.

far-infrared↗
DOE OSTI2011

DETERMINATION OF STOKES SHAPE FACTOR FOR SINGLE PARTICLES AND AGGLOMERATES

The large octahedral crystals of spinel can precipitate from glass during the high-level waste vitrification process and potentially block the glass discharge riser of electrically heated ceramic melters. To help predict the settling behavior of spinel in the riser, the settling of single particles and agglomerates was studied in stagnant and transparent viscosity oils at room temperature with developed optical particle-dynamics-analyzer. Determined dimensions and terminal settling velocities of particles were used for calculation of their Stokes shape factors. Calculated shape factor for the glass beads was almost identical with the theoretical shape factor of 2/9 for a perfect sphere. The shape factor for single spinel crystal was about 7.6 % higher compare to the theoretically predicted value for octahedron. Stokes shape factor of irregularly shaped multi-particle agglomerates was lower than that of the glass beads and individual spinel crystals because of the higher surface drag caused by the larger surface area to volume ratio.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗
DOE OSTI2016

Microstructural creep, fatigue and creep-fatigue modeling of Nickel-based superalloy Inconel 617 at high temperature - 18506

Inconel 617 is a solution strengthened nickel-based alloy which has been considered as one of the leading structural material for the intermediate heat exchangers (IHX) in very high temperature reactor (VHTR). In order to gain understanding of the creep and fatigue deformation mechanisms and their interactions in alloy 617 operating in the VHTR environment, a computational model that operates at the microstructural scale has been developed for creep, fatigue and creep-fatigue modeling of alloy 617. This model is based on an isothermal, large deformation crystal plasticity finite element (CPFE) formulation and idealizes the deformation in the crystal lattice as collective glide and climb of dislocations. A recently developed glide resistance evolution equation by the authors that can capture the intermediate softening observed in both fatigue and creep-fatigue cycles of Inconel 617 at high temperature is adopted for the dislocation glide formulation. Dislocation climb is incorporated to account for the interactions between dislocations and local point defects at high temperature. The CP equations are solved incrementally as the constitutive relationship in the context of FE analysis on fully resolved microstructure reconstructed from experiment data. Model parameters are calibrated and verified using experimental tests. (authors)

21 SPECIFIC NUCLEAR REACTORS AND ASSOCIATED PLANTS↗