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At least 541 records · Page 30

Integrated reactor architecture of conductive network and catalytic nodes to accelerate polysulfide conversion for durable and high-loading Li-S batteries

The development of carbon-based heterogeneous framework host with synergistic catalytic and conductive effects for sulfur cathode is a promising strategy to realize high performance lithium sulfur batteries (LSBs). Here, an integrated reactor architecture with defective carbon nodes (IRA-DC) is designed for serving as high-loading (92.4 wt%) sulfur host. The hierarchical porous IRA-DC consists of untangled conductive carbon nanotube network and Co/N co-doped catalytic nodes with high dispersity. Therein the optimization of electric field distribution and homogenization of adsorption-catalysis sites offer the multi-electron conversion reaction of polysulfides with excellent kinetics and stability. The resultant IRA-DC/S cathode enables a high areal capacity of 8.86 mAh cm -2 under ultra-high sulfur loading (13.1 mg cm -2 ) and lean electrolyte (8 μL mg sulfur -1 ). It also displays a long-term cycling performance (1200 cycles at 1 C) and ultrahigh rate performance up to 20 C (with a capacity of 473.6 mAh g -1 ). In conclusion, this work provides an electrode building strategy by optimizing the environments of heterogeneous electrocatalysis and micro electric field to activate the polysulfide conversion efficiency and utilization of high-loading sulfur in monolithic sulfur-carbon cathodes.

25 ENERGY STORAGE↗

2022 Standard Scenarios Report: A U.S. Electricity Sector Outlook

This report documents the eighth edition of the annual Standard Scenarios. It summarizes 70 forward-looking scenarios of the U.S. electricity sector that have been designed to capture a wide range of possible futures. In August 2022, the United States Congress passed the Inflation Reduction Act (IRA), a law aimed at accelerating U.S. decarbonization, clean energy manufacturing, and deployment of new power and end-use technologies. This year’s scenarios include representations of the main electricity-sector provisions from IRA and the potential impact on electricity demand. The Standard Scenarios are simulated using the Regional Energy Deployment System (ReEDS) model, which projects utility-scale electricity sector evolution for the contiguous United States using a system-wide, least-cost approach subject to policy and operational constraints. A subset of the scenarios are simulated in the PLEXOS production cost model to obtain a broader suite of metrics at the hourly resolution, which are made available through the National Renewable Energy Laboratory’s (NREL’s) annual Cambium data sets. The scenarios can be viewed and downloaded from NREL’s Scenario Viewer. Annual results are available for the full suite of scenarios in the Standard Scenarios projects in the viewer, whereas the Cambium projects contain hourly data for a subset of scenarios. The Standard Scenarios includes a scenario called the Mid-case, which has central or median values for core inputs such as technology costs and fuel prices, moderately paced demand growth averaging 1.3% per year, and electricity sector policies as they existed in September 2022 (including IRA). The remaining 69 scenarios are created by varying inputs such as technology and fuel prices, resource availability, demand growth, whether nascent generation technologies are allowed, and by introducing national decarbonization constraints.

29 ENERGY PLANNING, POLICY, AND ECONOMY↗

Driving Investment in Wind Energy: An Introduction to Incentives and the Inflation Reduction Act [Slides]

In a webinar hosted by the U.S. Department of Energy's WINDExchange initiative, experts from the North Carolina Clean Energy Technology Center and the National Renewable Energy Laboratory introduce attendees to the key incentives supporting investment in wind energy deployment and manufacturing in the United States, as well as the role that the Inflation Reduction Act (IRA) plays in shaping those investments. Over the past few decades, incentives like the production tax credit and investment tax credit have supported the growth of wind energy deployment, while manufacturing-related incentives have helped scale up domestic manufacturing of wind energy components. With its passage in 2022, the IRA ushered in a new wave of investment in wind energy and other renewable technologies, as well as introducing new workforce requirements and equity provisions. This presentation explores the history and impact of major incentives, unpacks some of the complex provisions of the IRA, and highlights the ways federal incentives and policies will continue to shape the wind energy industry.

17 WIND ENERGY↗

Development of the first infrared satellite observatory

A development history is given for the Infrared Astronomical Satelite (IRAS), whose primary mission objective is an unbiased, all-sky survey in the 8-120 micron wavelength range. A point source catalog of more than 200,000 IR sources, to be published later this year, represents the accomplishment of this objective. IRAS has also conducted 10,000 pointed observations of specific objects. Attention is given to the cost increases and schedule slips which resulted from the substantial technical challenges of IRAS hardware and software development, and to the management techniques which had to be employed in this major international project.

Smith, G. M.↗

SIRTF: The next step

The scientific and technical background and prospects for the space infrared telescope facility (SIRTF) are described. This facility is a superfluid-helium-cooled, 0.85-meter infrared telescope to be placed in orbit in 1993. It is designed to carry out photometry over the wavelength range 2 to 700 micrometers, and diffraction-limited imagery in either broad or narrow spectral bands over the range 1.8 to 200 micrometers. It is proposed that SIRTF measure spectra in the range 2.5 to 200 micrometers with resolving power between 50 and 1000 and that the focal plane contain about 20,000 detector elements, both discrete and in arrays. The SIRTF observatory is designed to be a long-lived facility providing opportunities for general investigations by the entire scientific community. For following up the all-sky survey carried out by the Infrared Astronomical Satellite (IRAS), SIRTF is ideal. It can do a deep survey to flux levels 5000 times fainer than IRAS and can obtain spectra of even the faintest IRAS sources.

Gillett, F. C.↗

Design of the superfluid helium dewar for the Cosmic Background Explorer (COBE)

Design features of the 664-liter superfluid helium dewar to be used for the Cosmic Background Explorer (COBE) are described, with emphasis on the similarities and differences vis a vis the Infrared Astronomical Satellite (IRAS) dewar. The dewar (23 percent larger than the IRAS dewar) is intended to provide a 14-month operating lifetime (vs. 10 months for IRAS). A far infrared absolute spectrophotometer (FIRAS) and diffuse infrared background experiment (DIRBE) will conduct full sky surveys over the wavelength region from 1 micron to 1 centimeter. Launch into a 900-km sun-synchronous polar orbit is scheduled for the autumn of 1987.

Hopkins, R. A.↗

Science operations management

The operation teams engaged in the IR Astronomical Satellite (IRAS) project included scientists from the IRAS International Science Team. The detailed involvement of these scientists in the design, testing, validation, and operations phases of the IRAS mission contributed to the success of this project. The Project Management Group spent a substantial amount of time discussing science-related issues, because science team coleaders were members from the outset. A single scientific point-of-contact for the Management Group enhanced the depth and continuity of agreement reached in decision-making.

Squibb, G. F.↗

Infrared spectra of WC10 planetary nebulae nuclei

The 5.2 to 8.0 micron spectra are presented for two planetary nebulae nuclei Hen1044 (He2-113) and CPD-56 8032. The unidentified infrared (UIR) emission bands at 6.2 microns, 6.9 microns, 7.7 microns are present in the spectra of Hen1044 and in CPD-56 8032, and the 8.6 micron band is present in the long wavelength shoulder of the 7.7 micron band in the spectrum of CPD-56 8032. The 8 to 13 micron spectra of these two stars by Aitken et. al. clearly show the presence of the 8.6 micron band in He2-113 while weakly resolving this feature in the spectra of CPD-56 8032. In their spectra the 11.3 micron band is also clearly detected in both objects. The 6.2 micron and 7.7 micron bands are characteristic of the infrared active C-C stretching modes in polycyclic aromatic hydrocarbons (PAHs); the 3.3 micron, 8.6 micron, and 11.3 micron bands are respectively assigned to the in-plane stretching mode, the in-plane bending mode, and the out-of-plane bending mode of the aromatic CH bond. The weak 6.9 micron emission feature is attributed to the UIR spectrum by Bregman et. al. The IRAS LRS spectra of He2-113 (IRAS 14562-5406) and CPD-56 8032 (IRAS 17047-5650) are presented. Cohen et. al. identify the broad plateau from 11.3 to 13.0 microns in the spectrum of He2-113 with increased hydrogenation of PAHs. This broad plateau is not seen in the LRS spectrum of CPD-56 8032. Also, He2-113 has greater infrared excess emission in the 17-22 micron region than does CPD-56 8032.

Wooden, D. H.↗

Star formation rates as a function of galaxy mass

Correlations were found between the colors and absolute magnitudes of spiral galaxies. Using optical and/or near IR (1.6 micron) colors, it was found that lower luminosity spirals are systematically bluer than higher luminosity spirals. Infrared Astronomy Satellite (IRAS) far IR luminosities were used to investigate the suggestion that one prime cause of these color-absolute magnitude correlations is a systematic variation with galaxy mass of the current star formation rate (SFR) per unit mass. To the extent that the IRAS fluxes actually measure disk SFR, no correlation of SFR/unit mass and galaxy mass was found. Other possible explanations of the color-absolute magnitude correlations are discussed, as well as caveats on the use of IRAS fluxes as a means of comparing SFRs in galaxies of differing mass.

Romanishin, W.↗

Starburst galaxies

The infrared properties of star-forming galaxies, primarily as determined by the Infrared Astronomy Satellite (IRAS), are compared to X-ray, optical, and radio properties. Luminosity functions are reviewed and combined with those derived from optically discovered samples using 487 Markarian galaxies with redshifts and published IRAS 60 micron fluxes, and 1074 such galaxies in the Center for Astrophysics redshift survey. It is found that the majority of infrared galaxies which could be detected are low luminosity sources already known from the optical samples, but non-infrared surveys have found only a very small fraction of the highest luminosity sources. Distributions of infrared to optical fluxes and available spectra indicate that the majority of IRAS-selected galaxies are starburst galaxies. Having a census of starburst galaxies and associated dust allow severl important global calculations. The source counts are predicted as a function of flux limits for both infrared and radio fluxes. These galaxies are found to be important radio sources at faint flux limits. Taking the integrated flux to z = 3 indicates that such galaxies are a significant component of the diffuse X-ray background, and could be the the dominant component depending on the nature of the X-ray spectra and source evolution.

Weedman, Daniel W.↗

Properties of the unusual galaxy PSC 09104+4109

The IRAS source PSC 09104+4109 is tentatively identified with a faint emission line galaxy having z = 0.442. Assuming this identification is correct, the total infrared luminosity of this galaxy is estimated to be 5 x 10 to the 12th power L sub 0, among the highest for galaxies detected by IRAS. This energy is concentrated at wavelengths less than 30 micrometers, and is approx. 50 times greater than the estimated optical luminosity. The serendipitous way in which this source was found in the PSC catalog suggests that many more similar objects may be found at the lowest levels of the IRAS survey.

Kleinmann, S. G.↗

Circumnuclear starbursts in Seyfert galaxies

Observational diagnostics for the recognition of circumnuclear star formation in Seyfert galaxies are described and illustrated. These methods include: (1) spatially resolved optical spectroscopy, which allows the emission lines for HII regions to be separated from those originating in gas ionized by the Seyfert nucleus; (2) radio continuum mapping, where the linear radio sources characteristic of the nuclear activity may be distinguished from the diffuse morphology of multiple supernova remnants generated in a starburst; (3) infrared spectroscopic searches for emission features of dust, which are seen in starbursts but not in Seyfert nuclei; (4) the shape of the IRAS spectrum. These various diagnostics agree well as to the presence or absence of ongoing star formation. The IRAS spectra of a significant fraction of Seyferts are dominated by emission from dust heated by stars, not the Seyfert nucleus itself. In these cases, the spectrum is curved, being steep between 25 and 60 microns and flatter between 60 and 100 microns. When the Seyfert nucleus dominates, the 25 to 100 micron spectrum is much flatter. It is suggested that the location of a Seyfert galaxy in the IRAS color-color diagram reflects primarily the relative contributions of the active nucleus and dust heated by stars to the infrared fluxes.

Wilson, Andrew S.↗

Infrared-ultraviolet spectra of active galactic nuclei

Data from IRAS and IUE were combined with ground based optical and infrared spectrophotometry to derive emission line free spectral energy distributions (SEDs) for 29 active galactic nuclei (AGNs) between 0.1 and 100 microns. The IRAS data were scaled down to account for extended emission. These correction factors, determined by comparing small aperture ground based 10.6 micron data with large aperture IRAS 12 micron fluxes, were usually less than 25%. These corrected SEDs are shown.

Malkan, M. A.↗

Observations of gaseous circumstellar disks. III

Echelle spectra obtained at the Ca II K line and the Na I D lines are reported for seven stars which show excess fluxes in at least one of the IRAS bands at 25, 60, and 100 microns. Detectable circumstellar absorption lines arising from the gaseous components of the presumed circumstellar dust disks are found in none of these cases, in contrast to the previously reported case of Beta Pic. Conversely, six A or F stars which were known before the launch of IRAS to show gaseous circumstellar disks do not show excess fluxes in any of the IRAS bands. Similar echelle spectra of these stars show Ca II circumstellar absorption lines comparable in four cases to that of Beta Pic.

Hobbs, L. M.↗

Bolometric luminosity evolution

The observations made by IRAS are capable of detecting evolution in the OB star formation rates of galaxies at cosmologically interesting redshifts if that evolution takes the form of star formation rates ten or more times higher than seen in nearby galaxies. Spectroscopic follow-up observations of IRAS-selected galaxies, and IRAS source counts, indicate that there may indeed exist a rare population of galaxies with such high star formation rates. The most luminous found so far approach quasars in luminosity.

Lonsdale, Carol J.↗

The enhancement of infrared emission in interacting galaxies

Selected infrared properties, based on IRAS observations, of two categories of interacting galaxy pairs from the Arp-Madore Catalogue of Southern Peculiar Galaxies and Associations are examined. For pairs of comparably sized galaxies, a strong tendency exists for pairs with the highest far-IR color temperatures to have the smallest separation. This finding implies that galaxy interactions significantly enhance the intensity or the efficiency of star formation. No trend of far-IR color temperature varying with pair separation is found for pairs consisting of a galaxy with a small companion. There are 10 times as many pairs in the sample that contain one IRAS far-IR galaxy as there are pairs for which both galaxies were detected by IRAS, thus strengthening previous conclusions that the effect of a perturbation depends strongly on the detailed geometry of the interaction.

Telesco, C. M.↗

An infrared view of the universe

Results from IRAS and the technical details of the IRAS satellite are reviewed. The IRAS telescope operation is briefly described. The observation of the Vega phenomenon, or the orbiting clouds of dust which encircle main sequence stars, is discussed. Also, the discovery that a large number of solar-type stars have excess IR radiation due to orbiting shells or disks of solid material is examined. In addition, the prospects for future telescopes are considered.

Soifer, Baruch T.↗

Further spectroscopic studies of the Bootes region - Two more galaxies in the void

Redshifts are reported for 40 galaxies in the direction of the Bootes void identified in the Case Low-Dispersion Northern Sky Survey, List IV. Two new emission-line galaxies have been discovered in the void. The density of bright emission-line galaxies in the void is estimated to be a factor of 3 + or - 2 lower than the density of similar galaxies in the field. The galaxies are distributed uniformly with distance from the void center. A previously reported correlation between Case IV redshift estimates and measured redshifts is confirmed. Data for previously observed IRAS galaxies are combined with the present results to compared the luminosity distribution of IRAS galaxies to that for emission-line galaxies. The IRAS luminosity distribution contains a greater fraction of intrinsically bright galaxies than the emission-line galaxy distribution.

Weistrop, Donna↗