Engineering Papers⌕ Search

SEARCH · Engineering Papers

Results for “Field stability”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 541 records · Page 30
All sourcesNASA NTRSDOE OSTI
DOE OSTI2025

Spin-State and Reorganization Energy Considerations for Metal-Centered Photoredox Catalysis

Transition-metal complexes featuring metal-centered excited states have recently emerged as mechanistically distinct platforms for selective photochemistry, including photoredox catalysis. Among these, Co(III) complexes have demonstrated productive photoinduced electron transfer via the 3 T 1 metal-centered state. In contrast, photoreactivity from the 5 T 2 metal-centered state in Fe(II) polypyridyl complexes remains limited. Building on our prior report concerning reactivity associated with the 5 T 2 state in [Fe(tren(py) 3 )] 2+ (tren(py) 3 = tris(2-pyridylmethyliminoethyl)-amine), we introduced stronger-field ligands in an effort to increase excited-state energies of Fe(II) polypyridyl complexes and enhance reactivity. Despite achieving nanosecond-scale excited-state lifetimes and favorable thermodynamic driving forces, no photoreactivity was observed. Reinvestigation of the observations previously reported for [Fe(tren(py) 3 )] 2+ revealed interactions between the metal complex and the substrate in their respective ground states that mimicked dynamic quenching of the chromophore, prompting a reassessment of mechanistic considerations inherent in leveraging reductive chemistry from the 5 T 2 excited state of Fe(II). Our analysis indicates that electron transfer from the 5 T 2 excited state of a low-spin d6 metal is subject to significant barriers both in terms of reorganization energies and spin conservation that undermines its ability to act as an electron donor for photoredox catalysis. In contrast, ligand fields that are sufficient to stabilize the 3 T 1 excited state have available to them numerous spin-allowed and, in certain cases, near-barrierless pathways to engage in excited-state electron transfer (both oxidative and reductive depending on the identity of the metal). These results highlight the critical role of spin-state changes and their associated reorganization energy requirements in metal-centered photoredox catalysis.

charge transfer↗
DOE OSTI2023

Formation of turing patterns in strongly magnetized electric discharges

Abstract Pattern formation and self-organization in many biological and non-biological systems can be explained through Turing’s activator-inhibitor model. Here we show how this model can be employed to describe the formation of filamentary structures in a low-pressure electric discharge exposed to a strong magnetic field. Theoretical investigation reveals that the fluid equations describing a magnetized plasma can be rearranged to take the mathematical form of Turing’s activator-inhibitor model. Numerical simulations based on the equations derived from this approach could reproduce the various patterns observed in the experiments. Also, it is shown that a density imbalance between electrons and ions exists in the bulk of the magnetized plasma that generates an electric field structure transverse to the applied magnetic field. This electric field is responsible for the stability of the filamentary patterns in the magnetized plasma over time scales much longer than the characteristic time scales of the electric discharge.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
DOE OSTI2020

DFT modelling of explicit solid–solid interfaces in batteries: methods and challenges

Density Functional Theory (DFT) calculations of electrode material properties in high energy density storage devices like lithium batteries have been standard practice for decades. By contrast, DFT modelling of explicit interfaces in batteries arguably lacks universally adopted methodology and needs further conceptual development. In this paper, we focus on solid–solid interfaces, which are ubiquitous not just in all-solid state batteries; liquid-electrolyte-based batteries often rely on thin, solid passivating films on electrode surfaces to function. We use metal anode calculations to illustrate that explicit interface models are critical for elucidating contact potentials, electric fields at interfaces, and kinetic stability with respect to parasitic reactions. The examples emphasize three key challenges: (1) the “dirty” nature of most battery electrode surfaces; (2) voltage calibration and control; and (3) the fact that interfacial structures are governed by kinetics, not thermodynamics. To meet these challenges, developing new computational techniques and importing insights from other electrochemical disciplines will be beneficial.

25 ENERGY STORAGE↗
DOE OSTI2020

Bioavailable soil Pb minimized by in situ transformation to plumbojarosite

Exposure to lead (Pb) during early life has persistent adverse health effects. During childhood, ingestion of bioavailable Pb in contaminated soils can be a major route of Pb absorption. Remediation to alter physiochemical properties of soil-borne Pb can reduce Pb bioavailability. Our laboratory-based approach for soil Pb remediation uses addition of iron (Fe) sulfate and application of heat to promote formation of plumbojarosite (PLJ), a sparingly soluble Pb-Fe hydroxysulfate mineral. We treated two soils with anthropogenic Pb contamination and samples of clean topsoil spiked with various Pb compounds (i.e., carbonate, chloride, phosphate [P], or sulfate) to convert native Pb species to PLJ and used a mouse assay to assess relative bioavailability (RBA) of Pb in untreated (U) and remediated soils. Bone and blood Pb levels were significantly lower (P < 0.001, Student's t test) in mice that consumed diets amended with remediated soils than with U soils. Estimated RBA for Pb in both remediated natural soils and Pb-mineral spiked soils were reduced by >90% relative to Pb RBA for U soils, which is substantially more effective than other soil amendments, including P. X-ray absorption spectroscopy showed that >90% of all Pb species in remediated soils were converted to PLJ, and ingested PLJ was not chemically transformed during gastrointestinal tract transit. Post treatment neutralization of soil pH did not affect PLJ stability, indicating the feasibility in field conditions. These results suggest that formation of PLJ in contaminated soils can reduce the RBA of Pb and minimize this medium’s role as a source of Pb exposure for young children.

59 BASIC BIOLOGICAL SCIENCES↗
DOE OSTI2026

Measuring dynamics of differentially rotating, unmagnetized, free-boundary plasma produced by soft x-ray irradiation

We present results from a new experiment, fielded on the MAGPIE pulsed power generator, producing a rotating, boundary-free plasma with no pre-imposed magnetic field. Angular momentum is introduced to the rotating system by the oblique collision of multiple plasma flows, which are driven by x-ray ablation of solid targets using the soft x-rays emitted from the implosion of wire array z-pinches. This produces a hydrodynamically stable plasma which undergoes ~2-3 rotations over the duration of the experiment, significantly more than previous pulsed-power platforms. Estimating the angular frequency from the electron density profile in the inner part of the rotating plasma shows that it has a quasi-Keplerian rotation profile. The system also allows for the addition of a controllable magnetic field. This, combined with the sufficiently large Reynolds (~10 5 ) and magnetic Reynolds (~10) numbers, will enable investigation of the effect of magnetic field on the structure and stability of the rotating plasma.

Physics - Plasma physics↗
DOE OSTI2020

Spinodal electronic phase separation during insulator-metal transitions

Electronic phase transitions such as insulator-metal transitions are common in strongly correlated systems. Here, using a combination of thermodynamic linear-stability analysis and phase-field simulations and employing VO 2 as a prototypical example, we predict that an insulator-metal transition driven by photoexcitation may involve an intermediate, modulated charge density state with a temperature-dependent characteristic wavelength. It is shown that such an intermediate two-phase electronic state is formed through a spinodal mechanism and that its formation can be generic for insulator-metal transitions driven by fast stimuli. This transient electronic phase separation is expected to stimulate future experimental and computational efforts.

36 MATERIALS SCIENCE↗
DOE OSTI2021

Noncollinear Ground State from a Four-Spin Chiral Exchange in a Tetrahedral Magnet

We propose a quartic chiral term m x m y m z ∇ • m for the energy density of a cubic ferromagnet with broken parity symmetry (point group T d ). We demonstrate that this interaction causes a phase transition from a collinear ferromagnetic state to a noncollinear magnetic cone ground state provided its strength exceeds the geometric mean of magnetic exchange and cubic anisotropy. The corresponding noncollinear ground state may also be additionally stabilized by an external magnetic field pointing along certain crystallographic directions. Here, the four-spin chiral exchange does also manifest itself in peculiar magnon spectra and favors spin waves with the wave vector that is perpendicular to the average magnetization direction.

36 MATERIALS SCIENCE↗
DOE OSTI2021

Analyzing Custom Proof Masses and Quantum Limits of a Manufacturable Cavity Optical Levitation Solution

This report details results of a one-year LDRD to understand the dynamics, figures of merit, and fabrication possibilities for levitating a micro-scale, disk-shaped dielectric in an optical field. Important metrics are the stability, positional uncertainty, and required optical power to maintain levitation. Much of the results are contained in a publication written by our academic alliance collaborators. Initial structures were grown at Sandia labs and a test fabrication flow was executed. Owing to our strength in VCSEL lasers, we were particularly interested in calculations and fabrication flows that could be compatible with a VCSEL light source.

42 ENGINEERING↗
DOE OSTI2024

Test and Validate Distributed Coaxial Cable Sensors for in situ Condition Monitoring of Coal-Fired Boiler Tubes

This project aims to test, validate, and advance the technology readiness level (from TRL5 to TRL7) of a novel low-cost distributed stainless-steel/ceramic coaxial cable sensing (SSC-CCS) technology for in situ monitoring of the boiler tube temperature in existing coal-fired power plants. The novel SSC-CCS sensing technology and associated condition-based monitoring (CBM) software to be demonstrated in this project will lead to an improved understanding of the boiler tube failure mechanisms and a prognostic system to improve the overall performance, reliability, and flexibility of the nation’s coal-fired power plant fleet. A boiler tube monitoring system with distributed coaxial cable temperature sensors and a sensor acquisition system was constructed. The high-temperature coaxial cable sensor with a length of 1.3m was made by using a quartz tube (1mm inner diameter (ID) and 6mm outer diameter (OD)) to concentrically separate a 304 stainless-steel (SS) rod (1mm OD) and SS tube (7.94mm OD and 6.16mm ID). The sensor acquisition system includes a vector network analyzer (VNA), a radio frequency (RF) power amplifier, multiple switches and a USB hub. The distributed stainless-steel quartz coaxial cable sensor (SSQ-CCS) had a linear response to temperature with a resolution uncertainty of σ = 0.77℃. To withstand the harsh conditions of 3,300 steam pressures and 800℃ high temperatures, the sensor was shielded by a protective tube made of the same material as the boiler tube. The protection tube had an OD of 1.5 inches and a thickness of 0.25 inches. In the laboratory tests, the sensor showed good sensitivity and fast response. The drift was bounded between +0.33% and -0.67% during a test at 600℃ for 350 hours, indicating good stability of the sensor. A field test was conducted where four sensors were welded on four superheat tubes (SH-Ts) at a coal-fired power station over 400 days. Conventional thermocouples were welded to the superheater tubes alongside the coaxial cable sensors for the purpose of comparison. Two sensors were capable of distributed sensing, with three multiplexed sensing sections. The other two sensors were single section. During the 400-day test period, the power plant experienced startups and shutdowns. At the steady state operations, the temperature of the boiler tube is about 600℃ (1112°F). The sensors recorded the entire coal-firing processes (start-up, steady state, and shut-down) and the glitch event. A GSM modem and a Watchdog were added to the system to ensure reliable data recording. The GSM modem sent daily messages to plant managers and Clemson team to inform the status of the sensor system. If the system was not normally working, the Watchdog would reboot the system automatically. The new coaxial cable based distributed sensing technology has been proven to be successful in both laboratory and field tests. A comprehensive four-stage multi-physics computational framework has been developed to assist the design, optimization, installation, and operation of SSQ-CCS. With the consideration of various operation conditions, we predict the distributions of flue gas temperatures within coal-fired boilers, the temperature correlation between the boiler tube and SSQ-CCS, and the safety of SSQ-CCS. A conditional-based monitoring system is implemented as well. The computational framework developed in this work can guide the future operation of coal-fired plants and other power plants for the safety prediction of boiler operations.

01 COAL, LIGNITE, AND PEAT↗
NASA NTRS1975

Connective stability of competitive equilibrium

The purpose of this paper is to derive necessary and sufficient conditions for the connective stability of nonlinear matrix systems described by the equation x-dot = A(t, x) x, where the matrix A(t, x) has time-varying nonlinear elements. The results obtained can be used to study the stability of competitive equilibrium in fields as diverse as economics and engineering, model ecosystems, and the arms race.-

Siljak, D. D.↗
NASA NTRS1980

Field verification of lateral-torsional coupling effects on rotor instabilities in centrifugal compressors

Lateral and torsional vibration data obtained on a centrifugal compressor train which had shaft instabilities and gear failures is examined. The field data verifies that the stability of centrifugal compressors can be adversely affected by coincidence of torsional natural frequencies with lateral instability frequencies. The data also indicates that excitation energy from gear boxes can reduce stability margins if energy is transmitted either laterally or torsionally to the compressors. The lateral and torsional coupling mechanisms of shaft systems is discussed. The coupling mechanisms in a large industrial compressor train are documented and the potential effect on rotor stability is demonstrated. Guidelines are set forth to eliminate these potential problems by minimizing the interaction of torsional and lateral responses and their effect on rotor stability.

Wachel, J. C.↗
NASA NTRS1981

A test and instrumentation system for the investigation of degradation of electrical insulating materials

A comprehensive test apparatus has been developed for the evaluation of the effects of thermal cycling, high temperatures and high electric fields on the quality and stability of electrical insulating materials used in spacecraft systems. The system includes a test chamber in which the specimen can be subjected to thermal and electrical stresses encountered in the space environment (temperatures from -50 to 200 C and voltages from 0 to 10 kV rms, respectively) simultaneously. The system instrumentation includes provisions for the measurement of the change in capacitance, the thermal dissipation factor of the material, and complex dielectric constants with changes in temperature, corona intensity and voltages at frequencies from 22 kHz to 70 MHz, as well as the volume and surface resistivities of the materials.

Doreswamy, C. V.↗
NASA NTRS1983

X-ray emission and spin-up evolution of the 6.1-ms pulsar

An upper bound is calculated for the X ray luminosity of the binary pulsar PSR1953+29 and discussed in terms of effects on theretical models for the pulsar's formation and spin-up. The upper limit was obtained by summing the detected counts measured by the Einstein Observatory within a circle of radius 150 arcsec and subtracting local background fluxes. A flux upper bound of less than 4 x 10 to the 32 erg/sec, a neutron star radius of 15 km, a temperature less than 1,000,000 K, and a pulsar age of at least 3000 year are obtained. The neutron star could be much older than 10,000,000 yr, the spin-down rate is up to 10 to the minus 17 str/sec, and formation occurred by accretion when the companion was in a red giant phase. The pulsar has a mass of about 0.3 solar mass, travels an orbit of about 10 to the 13 cm, and evolved from a white dwarf near its Chandrasekhar limit. It is suggested that the magnetic surface field of the pulsar has stabilized near 1 billion G.

Helfand, D. J.↗
NASA NTRS1984

Tearing instability in an anisotropic neutral sheet

A study is made of the collisionless tearing-mode stability properties of a field-reversed plasma layer whose temperature distribution is anisotropic. The plasma is confined by its self magnetic field with no external field. A kinetic description is used for both ions and electrons. The effects of the axis-crossing and nonaxis-crossing orbits are discussed. It is found that the conventional technique of matching the inner and outer asymptotic solutions at the electron inner-region is inadequate for the anisotropic case. An intermediate region in which the axis-crossing ion orbits are important is identified. The eigenvalue equation is solved using both analytic approximations and numerical methods to obtain the eigenmode structure and the linear dispersion relation. Previously announced in STAR as N84-14920

Chen, J.↗
NASA NTRS1986

Low-frequency electromagnetic waves driven by gyrotropic gyrating ion beams

The origin of left- and right-hand-polarized low-frequency waves in space plasmas is analyzed. It has been shown that a gyrotropic gyrating ion beam, a ring in velocity space, can excite electromagnetic modes in the plasma near the beam gyrofrequency. It excites left-hand-polarized shear Alfven waves and their harmonics via the coupling of Alfven modes with the beam modes. It can also excite right-hand-polarized fast-mode magnetosonic waves and their harmonics as well. The excitation is possible for beam ions heavier than the plasma ions. The growth rate varies as one-third power of the beam density and decreases with the angle of wave propagation with respect to the ambient magnetic field. The nonlocality has a stabilizing effect on the instability. The predicted values of the wave frequencies compare reasonably well with those observed in satellite data.

Sharma, O. P.↗
NASA NTRS1987

A numerical study of flare stabilized projectiles at Mach 7.0

The effect of nose shape on two flare stabilized projectiles was studied using a Parabolized Navier-Stokes code. Pressure coefficients, forces and moments, skin friction coefficients, and Stanton number calculations are presented for the hemisphere-cylinder-flare and the cone-cylinder-flare configurations. Pitching moment and static margin plots versus flare angles and flare lengths are presented in a parametric study to show aerodynamic stability effects. Distinctly different flow field values of pressure, local Mach number, and dynamic pressure were generated by the two different nose configurations. These flow field values just upstream of the flare will be examined. The code demonstrated its value as a design tool by making a clear distinction between aerodynamically stable characteristics for this variety of nose shapes, flare angles, and flare lengths.

Hughson, Montgomery C.↗
NASA NTRS1988

A mirror instability associated with newly created ions in a moving plasma

Using a plasma model in which the ambient magnetic field is parallel to the z axis and the wave vector, an instability that resembles the usual hydromagnetic mirror instability is demonstrated. The instability is caused by freshly created ions in a moving plasma; the source of its free energy is associated with the ring distribution of the newly created ions, resulting in a high ion kinetic temperature in the direction transverse to the ambient magnetic field. The results of a stability analysis indicate that this instability can lead to the amplification of magnetosonic waves.

Wu, C. S.↗