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At least 541 records · Page 30

Implementing Solar Technologies at Airports

Federal agencies, such as the Department of Defense and Department of Homeland Security, as well as numerous private entities are actively pursuing the installation of solar technologies to help reduce fossil fuel energy use and associated emissions, meet sustainability goals, and create more robust or reliable operations. One potential approach identified for siting solar technologies is the installation of solar energy technologies at airports and airfields, which present a significant opportunity for hosting solar technologies due to large amounts of open land. This report focuses largely on the Federal Aviation Administration's (FAA's) policies toward siting solar technologies at airports.

14 SOLAR ENERGY↗

AOI-2, A Novel Access Control Blockchain Paradigm for Cybersecure Sensor Infrastructure in Fossil Power Generation Systems

Fossil power generation systems are increasingly vulnerable to attack from both cybercriminals as well as internal threats. These vulnerabilities demand that emerging technologies such as blockchains be utilized to secure the data involved in the information flows within the Supervisory Control and Data Acquisition (SCADA) systems of the fossil power generation plants. The publicly accessible blockchain protocols, although secure, are visible to everyone. Even private blockchains currently are unable to support different levels of access to different participants, which is a critical requirement for the existing SCADA systems running the power plants. In light of the above, novel blockchain protocols that are specifically adapted to fossil power generation environments need to be developed in order to achieve the goal of cybersecure sensor networks. In this work, we address this question by creating a novel blockchain technology, namely smart private ledger, for cybersecure communication within the fossil power generation systems. A lab-scale sensor network consisting of strain and temperature sensors is constructed to develop the ledger. The technology has hierarchical access control which is compatible with the existing SCADA systems in fossil power plants. The sensor data is used with cryptographic digital signatures and secret sharing protocols within the nodes of the blockchain technology. The research results will lead to cybersecurity for machine-to-machine interactions, infrastructure for secure data logging for sensors, decentralized data storage, and second-layer technologies for high volume machine-to-machine interactions in the power plants. The work aims to largely address the concerns for the security of distributed sensor networks in such systems that can be compromised by insider threats and by cybercriminals. The research has led to the training of the next generation of engineers and scientists in the important areas of sensor engineering and blockchain technology.

01 COAL, LIGNITE, AND PEAT↗

Gap Analysis of Supply Chain Cybersecurity for Distributed Energy Resources

A supply chain is the combination of the ecosystem of resources needed to design, manufacture, and distribute a product. In the context of supply chain cybersecurity, the resources that directly influence this ecosystem include software, data, and/or other digital components. Compromised equipment or software in the supply chain may lead to attacks such as financial loss; denial of service; a breach of confidential or proprietary information from a company, its customers, or its suppliers; ransomware that denies operation of automated equipment for payment; and malicious control actions that could damage equipment and endanger personnel. Currently 60.8% of US energy comes from fossil fuels, 18.9% comes from nuclear energy, and the last 20.1% comes from renewable sources. Federal Energy Regulatory Commission order FERC 2222 and Executive Order 14017 on America's Supply Chains are important milestones for safely expanding generation from renewable energy and achieving the goal of a decarbonized U.S. energy sector by 2035. This report analyzes gaps and opportunities in the supply chain currently available to the renewable energy sector, to help stakeholders formulate a coordinated response.

24 POWER TRANSMISSION AND DISTRIBUTION↗

Integrated Radio Frequency and Ultrasonics with Conventional Processes for Efficient Water Removal in Pulp and Paper and Other Biomaterial Applications

Conventional drying processes used in the pulp and paper industry primarily involve lengthy, surface based, multi-cylinder conductive and convective drying with low thermal efficiencies and often use some fossil-based energy. Integration of cross cutting, electrically-powered, volumetric drying process intensification technologies based on Radio Frequency (RF) and acoustics (Ultrasonics) (US) will directly impart energy into the biomaterials resulting in improved energy efficiency and throughput. Integration of RFUS-based drying technology is expected to enable U.S. manufacturing industry to reduce capital and operating costs, energy consumption, and carbon emissions while increasing energy efficiency and throughput, improving product quality and sustainability, and helping preserve U.S. manufacturing jobs. The hybrid drying approach incorporates directed radio frequency (RF) and ultrasonic (US) energy with conventional conduction, diffusion and convective heat and mass transfer overcoming the limitations of the conventional drying processes and that meets/exceeds the minimum goals. We have shown the effective removal of free and bound water in the biomaterials by leveraging the synergies of RF and US technologies integrated with conventional manufacturing processes.

42 ENGINEERING↗

Revisiting “Additional Carbon”: Tracking Atmosphere–Ecosystem Carbon Exchange to Establish Mitigation and Negative Emissions From Bio-Based Systems

Climate stabilization plans rely heavily on advanced bioenergy and bioproducts for substitution of fossil-based energy sources and materials, and increasingly, for negative emissions via the direct sequestration of biogenic carbon. Yet, there remain persistent, largely unresolved critiques of bioenergy assessment methodology, particularly in the areas of land use and biogenic carbon accounting. The concept of “additional carbon” calls for evaluating the climate performance of bio-based systems by whether feedstock production creates measurable new local agro-ecosystem uptake of carbon from the atmosphere. This concept is challenging to operationalize for first-generation biofuels, and has largely been advanced as a negative critique. However, carbon additionality is more straightforward to establish—and less critical to overall system mitigation performance—in advanced bioenergy systems. In this Perspective, I review the additional carbon critique, and why it is analytically challenging to address in first-generation biofuel systems based on conventional food crops with large existing markets. Next, I make a case that carbon additionality (1) is more readily achievable with cellulosic feedstocks, (2) is more directly observable for dedicated biomass crops, and (3) is not a strict requirement for achieving net mitigation in carbon-negative bio-based systems. I end by discussing how centering atmosphere–ecosystem carbon exchanges in bio-based system assessment could create new opportunities for enterprise-scale performance monitoring and verification, augmenting and diversifying the current reliance on model-based life-cycle assessment approaches.

54 ENVIRONMENTAL SCIENCES↗

Current Developments of Carbon Capture Storage and/or Utilization–Looking for Net-Zero Emissions Defined in the Paris Agreement

An essential line of worldwide research towards a sustainable energy future is the materials and processes for carbon dioxide capture and storage. Energy from fossil fuels combustion always generates carbon dioxide, leading to a considerable environmental concern with the values of CO2 produced in the world. The increase in emissions leads to a significant challenge in reducing the quantity of this gas in the atmosphere. Many research areas are involved solving this problem, such as process engineering, materials science, chemistry, waste management, and politics and public engagement. To decrease this problem, green and efficient solutions have been extensively studied, such as Carbon Capture Utilization and Storage (CCUS) processes. In 2015, the Paris Agreement was established, wherein the global temperature increase limit of 1.5 °C above pre-industrial levels was defined as maximum. To achieve this goal, a global balance between anthropogenic emissions and capture of greenhouse gases in the second half of the 21st century is imperative, i.e., net-zero emissions. Several projects and strategies have been implemented in the existing systems and facilities for greenhouse gas reduction, and new processes have been studied. This review starts with the current data of CO2 emissions to understand the need for drastic reduction. After that, the study reviews the recent progress of CCUS facilities and the implementation of climate-positive solutions, such as Bioenergy with Carbon Capture and Storage and Direct Air Capture. Future changes in industrial processes are also discussed.

Regufe, Maria João (ORCID:0000000327748302)↗

Gold Nanoparticle Mesoporous Carbon Composite as Catalyst for Hydrogen Evolution Reaction

Increased environmental pollution and the shortage of the current fossil fuel energy supply has increased the demand for eco-friendly energy sources. Hydrogen energy has become a potential solution due to its availability and green combustion byproduct. Hydrogen feedstock materials like sodium borohydride (NaBH 4 ) are promising sources of hydrogen; however, the rate at which the hydrogen is released during its reaction with water is slow and requires a stable catalyst. In this study, gold nanoparticles were deposited onto mesoporous carbon to form a nano-composite catalyst (AuNP-MCM), which was then characterized via transmission electron microscopy (TEM), powder X-ray diffraction (P-XRD), and scanning electron microscopy/energy dispersive X-ray spectroscopy (SEM/EDS). The composite’s catalytic ability in a hydrogen evolution reaction was tested under varying conditions, including NaBH 4 concentration, pH, and temperature, and it showed an activation of energy of 30.0 kJ mol -1 . It was determined that the optimal reaction conditions include high NaBH 4 concentrations, lower pH, and higher temperatures. This catalyst, with its stability and competitively low activation energy, makes it a promising material for hydrogen generation.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

System-of-Systems Considerations in the Notional Development of a Metropolitan Aerial Transportation System

There are substantial future challenges related to sustaining and improving efficient, cost-effective, and environmentally friendly transportation options for urban regions. Over the past several decades there has been a worldwide trend towards increasing urbanization of society. Accompanying this urbanization are increasing surface transportation infrastructure costs and, despite public infrastructure investments, increasing surface transportation "gridlock." In addition to this global urbanization trend, there has been a substantial increase in concern regarding energy sustainability, fossil fuel emissions, and the potential implications of global climate change. A recently completed study investigated the feasibility of an aviation solution for future urban transportation (refs. 1, 2). Such an aerial transportation system could ideally address some of the above noted concerns related to urbanization, transportation gridlock, and fossil fuel emissions (ref. 3). A metro/regional aerial transportation system could also provide enhanced transportation flexibility to accommodate extraordinary events such as surface (rail/road) transportation network disruptions and emergency/disaster relief responses.

Alonso, Juan J.↗

NETL - Supercomputing: NETL Simulation Based Engineering User Center (SBEUC)

NETL's Simulation-Based Engineering User Center, or SBEUC, integrates one of the world's largest high-performance computers with an advanced visualization center. The SBEUC offers a collaborative environment among researchers at NETL sites and those working through the NETL-Regional University Alliance.

42 ENGINEERING↗

NETL - Chemical Looping Reactor

NETL's Chemical Looping Reactor unit is a high-temperature integrated CLC process with extensive instrumentation to improve computational simulations. A non-reacting test unit is also used to study solids flow at ambient temperature. The CLR unit circulates approximately 1,000 pounds per hour at temperatures around 1,800 degrees Fahrenheit.

20 FOSSIL-FUELED POWER PLANTS↗

Carbon Sequestration

Carbon Sequestration- the process of capturing the CO2 released by the burning of fossil fuels and storing it deep withing the Earth, trapped by a non-porous layer of rock.

01 COAL, LIGNITE, AND PEAT↗

Syngas Conversion to Hydrocarbon Fuels through Mixed Alcohol Intermediates

Synthesis gas (syngas) can be used to synthesize a variety of fuels and chemicals. Domestic transportation and military operational interests have driven continued focus on domestic syngas-based fuels production. Liquid transportation fuels may be made from syngas via four basic processes: 1) higher alcohols, 2) Fischer-Tropsch (FT), 3) methanol-to-gasoline (MTG), and 4) methanol-to-olefins (MTO) and olefins-to-gasoline/distillate (MOGD). Compared to FT and higher alcohols, MTG and MTO-MOGD have received less attention in recent years. Due to the high capital cost of these synthetic fuel plants, the production cost of the finished fuel cannot compete with petroleum-derived fuel. Pacific Northwest National Laboratory has recently evaluated one way to potentially reduce capital cost and overall production cost for MTG by combining the methanol and MTG syntheses in a single reactor. The concept consists of mixing the conventional MTG catalyst (i.e. HZSM-5) with an alcohol synthesis catalyst. It was found that a methanol synthesis catalyst, stable at high temperature (i.e. Pd/ZnO/Al2O3) [1], when mixed with ZSM-5, was active for syngas conversion. Relatively high syngas conversion can be achieved as the equilibrium-driven conversion limitations for methanol and dimethyl ether are removed as they are intermediates to the final hydrocarbon product. However, selectivity control was difficult to achieve as formation of undesirable durene and light hydrocarbons was problematic [2]. The objective of the present study was thus to evaluate other potential composite catalyst systems and optimize the reactions conditions for the conversion of syngas to hydrocarbon fuels, through the use of mixed alcohol intermediates. Mixed alcohols are of interest as they have recently been reported to produce higher yields of gasoline compared to methanol [3]. 1. Lebarbier, V.M., Dagle, R.A., Kovarik, L., Lizarazo-Adarme, J.A., King, D.L., Palo, D.R., Catalyst Science & Technology, 2012, 2, 2116-2127. 2. Zhu, Y., Jones, S.B., Biddy, M.J., Dagle, R.A., Palo, D.P., Bioresource Technology, 2012, 117, 341-351. 3. Gujar, A.C., Guda, V.K., Nolan, M., Yan W., Toghiani, H., White, M.G., Applied Catalysis A: General, 2009, 363, 115-121.

syngas, catalysis, mixed alchohols, biomass, fossi↗

PERFORMANCE IMPROVEMENT OF CREEP-RESISTANT FERRITIC STEEL WELDMENTS THROUGH THERMO-MECHANICAL TREATMENT AND ALLOY DESIGN

Two different approaches have been proposed for improvement of cross-weld creep properties of the high temperature ferrous structural materials for fossil-fired energy applications. The traditional creep strength-enhanced ferritic (CSEF) steel weldments suffer from Type IV failures which occur at the fine-grained heat affected zone (FGHAZ). In order to minimize the premature failure at FGHAZ in the existing CSEF steels, such as modified 9Cr-1Mo ferritic-martensitic steels (Grade 91), a thermo-mechanical treatment consisting of aus-forging/rolling and subsequent aus-aging is proposed which promotes the formation of stable MX carbonitrides prior to martensitic transformation. Such MX remains undissolved during welding process, even in FGHAZ, which successfully improves the cross-weld creep properties. Another approach is to develop a new fully ferrtic, creep-resistant FeCrAl alloy which is essentially free from Type IV failure issues. Fe-30Cr-3Al base alloys with minor alloying additions were developed which achieved a combination of good oxidation/corrosion resistance and improved tensile and creep performance comparable or superior to Grade 92 steel.

Yamamoto, Yukinori↗

HEAT AND MASS TRANSFER IN HUMIDIFYING REGENERATOR FOR A SUB-ATMOSPHERIC HYBRID HEAT ENGINE

Heat and mass transfer processes in advanced modular sub-atmospheric hybrid heat engine have been evaluated for technical and economic feasibility. The presented concept combines fossil fuel energy conversion in a sub-atmospheric air turbine coupled with a reciprocating internal combustion engine to create a hybrid system for power generation. This system can achieve over 65% of net electrical or mechanical power conversion efficiency. The uniqueness of the advanced modular sub-atmospheric hybrid heat engine is in the operating conditions of the air turbine which operates at sub-atmospheric pressure and low temperature and produces power at high efficiency. This is possible due to a unique combination of the system components such as sub-atmospheric air turbine, humidifying air regenerator, and compressor inlet air cooling system. The humidifying air regenerator is the core component of the advanced sub-atmospheric turbine, which makes the turbine ultra-high efficient. It is a regenerative heat-mass exchanger to increase the working fluid (humid air) mass flow rate before the turbine and decrease the mass flow rate after the turbine. It is found that increased heat and mass transfer rate or increased air humidification in humidifying air regenerator would allow the turbine operating at lower temperature and increased efficiency. Optimal heat and mass transfer rates were found for higher efficiency, lower costs, and smaller footprint of the hybrid engine. The results of feasibility study of heat and mass transfer processes in the humidifying air regenerator are presented in this paper.

Heat Engine, Sub-atmospheric Turbine, Humidifying ↗

Techno-Economic Analysis of Integrated Gasification Fuel Cell Systems

This is a presentation that was delivered virtually at the 2020 International Pittsburgh Coal Conference. In the presentation, details of the cost and performance parameter improvement due to incremental changes made in gasification and fuel cell operation and system configurations were presented. High level results indicate that SOFC fueled by coal-derived synthesis gas can be competitive with other fossil-based energy generation technologies when significant improvement to gasification technology is made and carbon capture is included. The cost of carbon capture of this system is very low due to the high efficiency of the SOFC and the high system fuel utilization due to the vent gas recirculation concept which recirculates hydrogen in the effluent back to the cell.

Noring, Alex↗

Nanoporous Catalysts for Biomass Conversion

Transforming plant biomass to biofuel and chemicals has become a global effort as results of increasing fuel demand but diminishing fossil-based energy preservation and rising concerns of climate and environmental impact. Various conversion routes involving thermochemical and biological conversions have been established and well-studied. Heterogeneous catalysis is playing a critical role in the biomass conversion and, with some unique catalytic properties, nanoporous catalysts have been extensively utilized in catalytic process of biomass conversion and exhibited exciting catalytic performance. This chapter will be devoted to nanoporous catalysts used in biomass conversion. It will start with a brief introduction of current biomass conversion technologies and then a detailed review of the application of various nanoporous materials in a large diversity of catalytic reactions in biomass conversion. The nanoporous materials include zeolites and zeotypes, metal-organic frameworks (MOFs), nanoporous carbons and carbon nitrides, nanoporous oxides, hydroxides and complex oxide forms, porous organic polymers (POPs), and porous metals.

Shi, Hui↗