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The charge transfer transition phenomenon and microstructure of Eu{sup 3+}-doped NaCaPO{sub 4} phosphors sintered with NH{sub 4}Cl flux via solid-state reaction

Graphical abstract: This paper describes: The charge transfer transition phenomenon and microstructure of Eu{sup 3+}-doped NaCaPO{sub 4} phosphors sintered with NH{sub 4}Cl flux via solid-state reaction. The emission intensity of NaCa{sub 0.95}PO{sub 4}:0.05Eu{sup 3+} phosphors with 2 wt.% NH{sub 4}Cl flux is enhanced as the sintering temperature was increased from 800 °C to 1000 °C and reveals the maximum value at 1000 °C. Photoluminescence emission spectra of NaCa{sub 0.95}PO{sub 4}:0.05Eu{sup 3+} phosphors with 2 wt.% NH{sub 4}Cl flux sintered at various sintering temperature for 3 h via solid state reaction method (λ{sub ex} = 270 nm). Highlights: ► NH{sub 4}Cl flux is helpful for enhancing the crystallization degree and decreasing surface defects. ► A single phase of NaCaPO{sub 4}:Eu{sup 3+} phosphor was observed as the sintering temperature was increased from 800 °C to 1000 °C. ► The intensity of the excitation peaks displays a maximum value at 1000 °C. ► The NaCaPO{sub 4} host added with NH{sub 4}Cl flux and sintered at the different temperature can affect the morphology. ► The NaCaPO{sub 4} host added with NH{sub 4}Cl flux and sintered at the different temperature can affect fluorescent properties. - Abstract: NaCa{sub 0.95}PO{sub 4}:0.05Eu{sup 3+} phosphors with 2 wt.% NH{sub 4}Cl flux sintered at various sintering temperature (800, 900, 1000, 1100 °C) for 3 h under air atmosphere were synthesized successfully via solid state reaction method. It is found that the addition of NH{sub 4}Cl flux and different sintering temperatures can affect the morphology and fluorescent properties of NaCa{sub 0.95}PO{sub 4}:0.05Eu{sup 3+} phosphor. The X-ray diffractions show a single phase and the microstructure observations show uniform morphologies for NaCa{sub 0.95}PO{sub 4}:0.05Eu{sup 3+} phosphors sintered at the range from 900 °C to 1000 °C, indicating that addition of 2 wt.% NH{sub 4}Cl flux is helpful for enhancing the crystallization, thus improving the luminescence intensity of the charge transfer transition. The intensity of the excitation peaks displayed a maximum value at 1000 °C. The chromaticity (x, y) is in the orange-red region (0.54, 0.39) and the lifetime value is about 2.1 ms, suitable for the remote phosphor packages.

36 MATERIALS SCIENCE↗

Changes in inundation drive carbon dioxide and methane fluxes in a temperate wetland

Wetlands cycle carbon by being net sinks for carbon dioxide (CO 2 ) and net sources of methane (CH 4 ). Daily and seasonal temporal patterns, dissolved oxygen (DO) availability, inundation status (flooded or dry/partially flooded), water depth, and vegetation can affect the magnitude of carbon uptake or emissions, but the extent and interactive effects of these variables on carbon gas fluxes are poorly understood. We characterized the linkages between carbon fluxes and these environmental and temporal drivers at the Old Woman Creek National Estuarine Research Reserve (OWC), OH. We measured diurnal gas flux patterns in an upstream side channel (called the cove) using chamber measurements at six sites (three vegetated and three non-vegetated). We sampled hourly from 7 AM to 7 PM and monthly from July to October 2022. DO concentrations and water levels were measured monthly. Water inundation status had the most influential effect on carbon fluxes with flooded conditions supporting higher CH 4 fluxes (0.39 μmol CH 4 m –2 s –1 ; –1.23 μmol CO 2 m –2 s –1 ) and drier conditions supporting higher CO 2 fluxes (0.03 μmol CH 4 m –2 s –1 ; 0.86 μmol CO 2 m –2 s –1 ). When flooded, the wetland was a net CO 2 sink; however, it became a source for both CH 4 and CO 2 when water levels were low. We compared chamber-based gas fluxes from the cove in flooded (July) and dry (August) months to fluxes measured with an eddy covariance tower whose footprint covers flooded portions of the wetland. The diurnal pattern of carbon fluxes at the tower did not vary with changing water levels but remained a CO 2 sink and a CH 4 source even when the cove where we performed the chamber measurements dried out. Furthermore, these results emphasize the role of inundation status on wetland carbon cycling and highlight the importance of fluctuating hydrologic patterns, especially hydrologic drawdowns, under changing climatic conditions.

54 ENVIRONMENTAL SCIENCES↗

Monitoring autophagic flux using p62/SQSTM1 based luciferase reporters in glioma cells

Highlights: • A luciferase based autophagic flux detection system, Luc2p-p62 vs. Luc2p-p62ΔU, was developed. • This system can be used to detect TMZ-induced autophagic flux changes in U87MG cells. • This system can assay the effect of autophagy modulators in different types of tumor cells. Autophagy is a highly dynamic process characterized with the term of autophagic flux. In the present study, we developed a quantifiable luciferase reporter system to measure the capacity as well as the dynamics of autophagic flux. Briefly, a luciferase variant of Luc2p was fused with p62/SQSTM1 or its UBA domain deletion mutant (p62ΔU) and transfected into cells. The expressed Luc2p-p62 fusion protein was primarily degraded via autophagy, while Luc2p-p62ΔU was employed as a normalization control due to its resistance to autophagic degradation. The luciferase activity of the lysates from two parallel populations of glioma cells expressing either Luc2p-p62 or Luc2p-p62ΔU was determined and the ratio of Luc2p-p62ΔU/Luc2p-p62 was used to assay the autophagic flux. By this approach, the induction of autophagy was manifested as an increased Luc2p-p62ΔU/Luc2p-p62 ratio, which could be neutralized by autophagy inhibitors or knockdown of ATG5. The performance of our autophagic flux detection system was comparable to a recently reported GFP-LC3-RFP-LC3ΔG probe. We tested the system in TMZ treated glioma cells, and found that coadministration of chloroquine to attenuate cellular autophagic flux significantly improved the TMZ efficacy by triggering more early apoptosis. Collectively, our luciferase-based autophagic flux assay may serve as a useful alternative yet sensitive method for autophagic flux detection in tumor cells.

60 APPLIED LIFE SCIENCES↗

Large Eddies Regulate Turbulent Flux Gradients in Coupled Stable Boundary Layers

Due to strong mean wind shear, the stable boundary layer (SBL) becomes vertically coupled. In a coupled SBL, large turbulent eddies enhance cross-layer mixing and vertically mix turbulent kinetic energy. However, large gradients in momentum and heat fluxes are frequently observed, degrading the performance of Monin-Obukhov similarity theory. It is shown that increased vertical gradients of mean variables (i.e., wind speed and potential temperature) can cause flux gradients. This process is operated upon by downward penetrating large eddies with altered phase difference, contributing unevenly to fluxes and thus causing flux gradients. In the coupled SBL with small gradients in mean variables, large eddies are vertically synchronized, contributing evenly to fluxes across layers and thus causing small flux gradients. As turbulent production becomes weak and the cross-layer difference in turbulent flux transport increases, large eddies become less vertically synchronized, contributing unevenly to fluxes across layers and thus causing large flux gradients.

58 GEOSCIENCES↗

Joint CO 2 Mole Fraction and Flux Analysis Confirms Missing Processes in CASA Terrestrial Carbon Uptake Over North America

Terrestrial biosphere models (TBMs) play a key role in the detection and attribution of carbon cycle processes at local to global scales and in projections of the coupled carbon-climate system. TBM evaluation commonly involves direct comparison to eddy-covariance flux measurements. This study uses atmospheric CO 2 mole fraction ([CO 2 ]) measured in situ from aircraft and tower, in addition to flux-measurements from summer 2016 to evaluate the CASA TBM. WRF-Chem is used to simulate [CO 2 ] using biogenic CO 2 fluxes from a CASA parameter-based ensemble and CarbonTracker version 2017 (CT2017) in addition to transport and CO 2 boundary condition ensembles. The resulting “super ensemble” of modeled [CO 2 ] demonstrates that the biosphere introduces the majority of uncertainty to the simulations. Both aircraft and tower [CO 2 ] data show that the CASA ensemble net ecosystem exchange (NEE) of CO 2 is biased high (NEE too positive) and identify the maximum light use efficiency E max a key parameter that drives the spread of the CASA ensemble in summer 2016. These findings are verified with flux-measurements. The direct comparison of the CASA flux ensemble with flux-measurements confirms missing sink processes in CASA. Separating the daytime and nighttime flux, we discover that the underestimated net uptake results from missing sink processes that result in overestimation of respiration. NEE biases are smaller in the CT2017 posterior biogenic fluxes, which assimilates observed [CO 2 ]. Flux tower analyses, however, reveal an unrealistic overestimation of nighttime respiration in CT2017 due to the limitation of inversion strategy.

54 ENVIRONMENTAL SCIENCES↗

New two-dimensional space-resolving flux detection technique for measurement of hohlraum inner radiation in Shenguang-III prototype

The space-resolving measurement of X-ray flux from a specific area (laser spot, re-emitting wall, or capsule) inside the hohlraum is an ongoing and critical problem in indirectly driven inertial-confinement fusion experiments. In this work, we developed a new two-dimensional space-resolving flux detection technique to measure the X-ray flux from specific areas inside the hohlraum by using the time- and space-resolving flux detector (SRFD). In two typical hohlraum experiments conducted at the Shenguang-III prototype laser facility, the X-ray flux and radiation temperature from an area 0.2 mm in diameter inside the hohlraum were measured through the laser entrance hole (LEH). The different flux intensities and radiation temperatures detected using the SRFD from the inner area of the LEH were compared with the result measured using the flat-response X-ray detector from the entire LEH. This comparison was also analyzed theoretically. The inner area detected using the SRFD was found to be the re-emitting wall area alone. This important improvement in space-resolving X-ray flux measurement will enhance the current X-ray flux space characterization techniques, thereby furthering the quantitative understanding of X-ray flux space behavior in the hohlraum.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

MAGNETIC HELICITY FLUX IN THE PRESENCE OF SHEAR

Magnetic helicity has risen to be a major player in dynamo theory, with the helicity of the small-scale field being linked to the dynamo saturation process for the large-scale field. It is a nearly conserved quantity, which allows its evolution equation to be written in terms of production and flux terms. The flux term can be decomposed in a variety of fashions. One particular contribution that has been expected to play a significant role in dynamos in the presence of mean shear was isolated by Vishniac and Cho. Magnetic helicity fluxes are explicitly gauge dependent however, and the correlations that have come to be called the Vishniac-Cho flux were determined in the Coulomb gauge, which turns out to be fraught with complications in shearing systems. While the fluxes of small-scale helicity are explicitly gauge dependent, their divergences can be gauge independent. We use this property to investigate magnetic helicity fluxes of the small-scale field through direct numerical simulations in a shearing-box system and find that in a numerically usable gauge the divergence of the small-scale helicity flux vanishes, while the divergence of the Vishniac-Cho flux remains finite. We attribute this seeming contradiction to the existence of horizontal fluxes of small-scale magnetic helicity with finite divergences.

79 ASTRONOMY AND ASTROPHYSICS↗

SEPARATION OF THE INTERSTELLAR BOUNDARY EXPLORER RIBBON FROM GLOBALLY DISTRIBUTED ENERGETIC NEUTRAL ATOM FLUX

The Interstellar Boundary Explorer (IBEX) observes a remarkable feature, the IBEX ribbon, which has energetic neutral atom (ENA) flux over a narrow region {approx}20{sup 0} wide, a factor of 2-3 higher than the more globally distributed ENA flux. Here, we separate ENA emissions in the ribbon from the distributed flux by applying a transparency mask over the ribbon and regions of high emissions, and then solve for the distributed flux using an interpolation scheme. Our analysis shows that the energy spectrum and spatial distribution of the ribbon are distinct from the surrounding globally distributed flux. The ribbon energy spectrum shows a knee between {approx}1 and 4 keV, and the angular distribution is approximately independent of energy. In contrast, the distributed flux does not show a clear knee and more closely conforms to a power law over much of the sky. Consistent with previous analyses, the slope of the power law steepens from the nose to tail, suggesting a weaker termination shock toward the tail as compared to the nose. The knee in the energy spectrum of the ribbon suggests that its source plasma population is generated via a distinct physical process. Both the slope in the energy distribution of the distributed flux and the knee in the energy distribution of the ribbon are ordered by latitude. The heliotail may be identified in maps of globally distributed flux as a broad region of low flux centered {approx}44{sup 0}W of the interstellar downwind direction, suggesting heliotail deflection by the interstellar magnetic field.

79 ASTRONOMY AND ASTROPHYSICS↗

VARIATIONS OF SOLAR ELECTRON AND PROTON FLUX IN MAGNETIC CLOUD BOUNDARY LAYERS AND COMPARISONS WITH THOSE ACROSS THE SHOCKS AND IN THE RECONNECTION EXHAUSTS

The magnetic cloud boundary layer (BL) is a dynamic region formed by the interaction of the magnetic cloud (MC) and the ambient solar wind. In the present study, we comparatively investigate the proton and electron mean flux variations in the BL, in the interplanetary reconnection exhaust (RE), and across the MC-driven shock by using the Wind data from 1995 to 2006. In general, the proton flux has higher increments at lower energy bands compared with the ambient solar wind. Inside the BL, the core electron flux increases quasi-isotropically and the increments decrease monotonously with energy from {approx}30% (at 18 eV) to {approx}10% (at 70 eV); the suprathermal electron flux usually increases in either parallel or antiparallel direction; the correlation coefficient of electron flux variations in parallel and antiparallel directions changes sharply from {approx}0.8 below 70 eV to {approx}0 above 70 eV. Similar results are also found for RE. However, different phenomena are found across the shock where the electron flux variations first increase and then decrease with a peak increment (>200%) near 100 eV. The correlation coefficient of electron flux variations in parallel and antiparallel directions is always around 0.8. The similar behavior of flux variations in BL and RE suggests that reconnection may commonly occur in BL. Our work also implies that the strong energy dependence and direction selectivity of electron flux variations, which were previously thought to have not enough relevance to magnetic reconnection, could be considered as an important signature of solar wind reconnection in the statistical point of view.

79 ASTRONOMY AND ASTROPHYSICS↗

Formation of a compound flux rope by the merging of two filament channels, the associated dynamics, and its stability

We present observations of compound flux rope formation, which occurred on 2014 January 1, via merging of two nearby filament channels, the associated dynamics, and its stability using multiwavelength data. We also discuss the dynamics of cool and hot plasma moving along the newly formed compound flux rope. The merging started after the interaction between the southern leg of the northward filament and the northern leg of the southward filament at ≈01:21 UT and continued until a compound flux rope formed at ≈01:33 UT. During the merging, the cool filament plasma heated up and started to move along both sides of the compound flux rope, i.e., toward the north (≈265 km s{sup –1}) and south (≈118 km s{sup –1}) from the point of merging. After traveling a distance of ≈150 Mm toward the north, the plasma cooled down and started to return back to the south (≈14 km s{sup –1}) after ≈02:00 UT. The observations provide a clear example of compound flux rope formation via merging of two different flux ropes and the occurrence of a flare through tether cutting reconnection. However, the compound flux rope remained stable in the corona and had a confined eruption. The coronal magnetic field decay index measurements revealed that both the filaments and the compound flux rope axis lie within the stability domain (decay index <1.5), which may be the possible cause for their stability. The present study also deals with the relationship between the filament's chirality (sinistral) and the helicity (positive) of the surrounding flux rope.

79 ASTRONOMY AND ASTROPHYSICS↗

FORMATION AND ERUPTION OF A SMALL FLUX ROPE IN THE CHROMOSPHERE OBSERVED BY NST, IRIS, AND SDO

Using high-resolution images from the 1.6 m New Solar Telescope at Big Bear Solar Observatory, we report the direct evidence of chromospheric reconnection at the polarity inversion line between two small opposite polarity sunspots. Small jetlike structures (with velocities of ∼20–55 km s{sup −1}) were observed at the reconnection site before the onset of the first M1.0 flare. The slow rise of untwisting jets was followed by the onset of cool plasma inflow (∼10 km s{sup −1}) at the reconnection site, causing the onset of a two-ribbon flare. The reconnection between two sheared J-shaped cool Hα loops causes the formation of a small twisted (S-shaped) flux rope in the chromosphere. In addition, Helioseismic and Magnetic Imager magnetograms show the flux cancellation (both positive and negative) during the first M1.0 flare. The emergence of negative flux and the cancellation of positive flux (with shear flows) continue until the successful eruption of the flux rope. The newly formed chromospheric flux rope becomes unstable and rises slowly with a speed of ∼108 km s{sup −1} during a second C8.5 flare that occurred after ∼3 hr of the first M1.0 flare. The flux rope was destroyed by repeated magnetic reconnection induced by its interaction with the ambient field (fan–spine topology) and looks like an untwisting surge (∼170 km s{sup −1}) in the coronal images recorded by the Solar Dynamics Observatory/Atmospheric Imaging Assembly. These observations suggest the formation of a chromospheric flux rope (by magnetic reconnection associated with flux cancellation) during the first M1.0 flare and its subsequent eruption/disruption during the second C8.5 flare.

79 ASTRONOMY AND ASTROPHYSICS↗

ELM and inter-ELM heat and particle flux to a secondary divertor in the DIII-D tokamak

DIII-D ELMing discharges with a secondary X-point (XPT) inside the vessel were used to evaluate the power distribution between the primary and secondary divertors. The magnetic balance, defined by the distance between the primary and secondary separatrices at the outer midplane (dRsep), was varied from -5 mm (lower-single-null, LSN) to +16 mm (upper-single-null, USN). In this work, we find that the secondary divertor receives up to 1/3 of the total heat flux (primary + secondary divertors), and it is dominated by the ELM-driven flux. Both the radially-integrated and the peak heat flux to the secondary divertor decay below ~50% of the maximum as dRsep is varied from -5 to +6mm, but the integrated heat flux decay flattens out and it would take dRsep above ~25mm to reduce the ELM heat flux to the secondary divertor below 10% of the one deposited to a well-defined SN. Both the secondary inner and outer strike points receive heat flux during ELMs. The peak heat flux is comparable in both strike points for dRsep < 10mm, but the inner strike point receives less than 15% of the total flux. Furthermore, this is experimental evidence that the secondary inner divertor region receives significant ELM flux which should be taken into account for the design of future generation tokamaks.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

THE ROLE OF A FLUX ROPE EJECTION IN A THREE-DIMENSIONAL MAGNETOHYDRODYNAMIC SIMULATION OF A SOLAR FLARE

We investigated the dynamic evolution of a three-dimensional (3D) flux rope eruption and magnetic reconnection process in a solar flare by simply extending the two-dimensional (2D) resistive magnetohydrodynamic simulation model of solar flares with low β plasma to a 3D model. We succeeded in reproducing a current sheet and bi-directional reconnection outflows just below the flux rope during the eruption in our 3D simulations. We calculated four cases of a strongly twisted flux rope and a weakly twisted flux rope in 2D and 3D simulations. The time evolution of a weakly twisted flux rope in the 3D simulation shows behaviors similar to those of the 2D simulation, while a strongly twisted flux rope in the 3D simulation clearly shows a different time evolution from the 2D simulation except for the initial phase evolution. The ejection speeds of both strongly and weakly twisted flux ropes in 3D simulations are larger than in the 2D simulations, and the reconnection rates in 3D cases are also larger than in the 2D cases. This indicates positive feedback between the ejection speed of a flux rope and the reconnection rate even in the 3D simulation, and we conclude that the plasmoid-induced reconnection model can be applied to 3D. We also found that small-scale plasmoids are formed inside a current sheet and make it turbulent. These small-scale plasmoid ejections have a role in locally increasing the reconnection rate intermittently as observed in solar flares, coupled with a global eruption of a flux rope.

79 ASTRONOMY AND ASTROPHYSICS↗

Characteristics of the Diffuse Astrophysical Electron and Tau Neutrino Flux with Six Years of IceCube High Energy Cascade Data

In this work, we report on the first measurement of the astrophysical neutrino flux using particle showers (cascades) in IceCube data from 2010-2015. Assuming standard oscillations, the astrophysical neutrinos in this dedicated cascade sample are dominated (~90%) by electron and tau flavors. The flux, observed in the sensitive energy range from 16 TeV to 2.6 PeV, is consistent with a single power-law model as expected from Fermi-type acceleration of high energy particles at astrophysical sources. We find the flux spectral index to be γ=2.53±0.07 and a flux normalization for each neutrino flavor of $\phi$ astro =1.66$_{-0.27}^{+0.25}$ at E 0 =100 TeV, in agreement with IceCube's complementary muon neutrino results and with all-neutrino flavor fit results. In the measured energy range we reject spectral indices γ≤2.28 at ≥3σ significance level. Because of high neutrino energy resolution and low atmospheric neutrino backgrounds, this analysis provides the most detailed characterization of the neutrino flux at energies below ~100 TeV compared to previous IceCube results. Results from fits assuming more complex neutrino flux models suggest a flux softening at high energies and a flux hardening at low energies (p value ≥0.06). The sizable and smooth flux measured below ~100 TeV remains a puzzle. In order to not violate the isotropic diffuse gamma-ray background as measured by the Fermi Large Area Telescope, it suggests the existence of astrophysical neutrino sources characterized by dense environments which are opaque to gamma rays.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Stochastic Parameterization of Subgrid-Scale Velocity Enhancement of Sea Surface Fluxes

Abstract Subgrid-scale (SGS) velocity variations result in gridscale sea surface flux enhancements that must be parameterized in weather and climate models. Traditional parameterizations are deterministic in that they assign a unique value of the SGS velocity flux enhancement to any given configuration of the resolved state. In this study, we assess the statistics of SGS velocity flux enhancement over a range of averaging scales (as a proxy for varying model resolution) through systematic coarse-graining of a convection-permitting atmospheric model simulation over the Indian Ocean and west Pacific warm pool. Conditioning the statistics of the SGS velocity flux enhancement on 1) the fluxes associated with the resolved winds and 2) the precipitation rate, we find that the lack of a separation between “resolved” and “unresolved” scales results in a distribution of flux enhancements for each configuration of the resolved state. That is, the SGS velocity flux enhancement should be represented stochastically rather than deterministically. The spatial and temporal statistics of the SGS velocity flux enhancement are investigated by using basic descriptive statistics and through a fit to an anisotropic space–time covariance structure. Potential spatial inhomogeneities of the statistics of the SGS velocity flux enhancement are investigated through regional analysis, although because of the relatively short duration of the simulation (9 days) distinguishing true inhomogeneity from sampling variability is difficult. Perspectives for the implementation of such a stochastic parameterization in weather and climate models are discussed.

54 ENVIRONMENTAL SCIENCES↗

Prediction of Critical Heat Flux in Water-Cooled Plasma Facing Components Using Computational Fluid Dynamics

Several commercial computational fluid dynamics (CFD) codes now have the capability to analyze Eulerian two-phase flow using the Rohsenow nucleate boiling model. Analysis of boiling due to one-sided heating in plasma facing components (pfcs) is now receiving attention during the design of water-cooled first wall panels for ITER that may encounter heat fluxes as high as 5 MW/m2. Empirical thermalhydraulic design correlations developed for long fission reactor channels are not reliable when applied to pfcs because fully developed flow conditions seldom exist. Star-CCM+ is one of the commercial CFD codes that can model two-phase flows. Like others, it implements the RPI model for nucleate boiling, but it also seamlessly transitions to a volume-of-fluid model for film boiling. By benchmarking the results of our 3d models against recent experiments on critical heat flux for both smooth rectangular channels and hypervapotrons, we determined the six unique input parameters that accurately characterize the boiling physics for ITER flow conditions under a wide range of absorbed heat flux. We can now exploit this capability to predict the onset of critical heat flux in these components. In addition, the results clearly illustrate the production and transport of vapor and its effect on heat transfer in pfcs from nucleate boiling through transition to film boiling. This article describes the boiling physics implemented in CCM+ and compares the computational results to the benchmark experiments carried out independently in the United States and Russia. Temperature distributions agreed to within 10 °C for a wide range of heat fluxes from 3 MW/m 2 to 10 MW/m 2 and flow velocities from 1 m/s to 10 m/s in these devices. Although the analysis is incapable of capturing the stochastic nature of critical heat flux (i.e., time and location may depend on a local materials defect or turbulence phenomenon), it is highly reliable in determining the heat flux where boiling instabilities begin to dominate. Beyond this threshold, higher heat fluxes lead to the boiling crisis and eventual burnout. This predictive capability is essential in determining the critical heat flux margin for the design of complex 3d components.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Materials compatibility and aging for flux and cleaner combinations

A materials study of high reliability electronics cleaning is presented here. In Phase 1, mixed type substrates underwent a condensed contaminants application to view a worst- case scenario for unremoved flux with cleaning agent residue for parts in a silicone oil filled environment. In Phase 2, fluxes applied to copper coupons and to printed wiring boards underwent gentle cleaning then accelerated aging in air at 65% humidity and 30 O C. Both sets were aged for 4 weeks. Contaminants were no-clean (ORL0), water soluble (ORH1 liquid and ORH0 paste), and rosin (RMA; ROL0) fluxes. Defluxing agents were water, solvents, and engineered aqueous defluxers. In the first phase, coupons had flux applied and heated, then were placed in vials of oil with a small amount of cleaning agent and additional coupons. In the second phase, pairs of copper coupons and PWB were hand soldered by application of each flux, using tin-lead solder in a strip across the coupon or a set of test components on the PWB. One of each pair was cleaned in each cleaning agent, the first with a typical clean, and the second with a brief clean. Ionic contamination residue was measured before accelerated aging. After aging, substrates were removed and a visual record of coupon damage made, from which a subjective rank was applied for comparison between the various flux and defluxer combinations; more corrosion equated to higher rank. The ORH1 water soluble flux resulted in the highest ranking in both phases, the RMA flux the least. For the first phase, in which flux and defluxer remained on coupons, the aqueous defluxers led to worse corrosion. The vapor phase cleaning agents resulted in the highest ranking in the second phase, in which there was no physical cleaning. Further study of cleaning and rinsing parameters will be required.

36 MATERIALS SCIENCE↗

The QCECOR Value-Added Product: Quality-Controlled Eddy Correlation Flux Measurements

Eddy correlation flux (ECOR) measurement system stations are used by the U.S. Department of Energy Atmospheric Radiation Measurement (ARM) user facility to provide surface turbulence flux measurements. In recent years, ARM has significantly enhanced its ECOR systems and made them available at all its primary research observatories and mobile facilities. However, the original ECOR data were not corrected through common eddy correlation corrections and still contain suspicious data due to instrument and measurement uncertainties. Such uncertainties in the ECOR surface turbulence fluxes hampered their uses by the user community. To improve the ECOR data, we develop a value-added product (VAP) —the Quality-Controlled Eddy Correlation Flux (QCECOR) — by applying the following necessary corrections and quality control (QC) procedures: Eddy correlation corrections. Determination of the quality-controlled energy fluxes from the corrected ECOR fluxes. Stringent QC checks. Flagging possible incorrect fluxes due to hydrometeor impacts using the collocated surface energy balance system (SEBS) wetness measurements. The QCECOR VAP currently contains two variables: surface latent heat flux (LH) and sensible heat flux (SH), together with their QC flags. When SEBS are collocated with ECOR, the wetness measurements from SEBS are used to flag the LH that may be incorrect due to hydrometeors such as precipitation, dew, or frost. An indeterminate flag is given to those that fail the wetness test. The QCECOR data are currently available at the Southern Great Plains (SGP) atmospheric observatory for the ARM extended facilities of E1, E3, E5, E6, E10, E14, E16, E21, E24, E31, E33, E37, E38, E39, and E41 updated to 2018. The data are also available at the following AMF sites: PYE (Point Reyes, 2005), NIM (Niamey, Niger, 2006), FKB (Black Forest, Germany, 2007), HFE (Shouxian, China, 2008), GRW (Azores, 2009 to 2010), and MAO (Manacapuru, Brazil, 2014-2015). The algorithm is now in the process of moving to production mode. After that, QCECOR will run automatically for all available ARM sites.

47 OTHER INSTRUMENTATION↗