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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 541 records · Page 30

5-2428: Fracture Permeability Impact on Seismic Slip Behavior

Our goal is to develop, apply and validate a holistic thermal, hydrologic, mechanical, and chemical (THMC) workflow that includes evaluation of induced seismic slip in EGS reservoirs. We will integrate experimental and modeling approaches to reduce parameter uncertainty and better predict/mitigate seismic hazard at EGS sites. Our novel approach couples 3D physics-based earthquake simulations with THMC models (THMc+E). This capability will enable improve engineering decisions at Utah-FORGE and move EGS operations toward repeatable, robust, economically viable, and socially accepted development. For example, our THMC+E models will predict circulation scenarios and related seismic hazard for a suite of flow rates and under uncertainty, thus enabling evaluation of optimal circulation strategy. Laboratory experiments will be performed to constrain key model parameters and Bayesian techniques will provide a probabilistic evaluation of parameters used in models. THMC+E simulations will enable exploration various circumstances that may hinder EGS success and develop mitigation strategies.

58 GEOSCIENCES↗

IER 516: Zirconium Test Assembly CED Phase-1: Preliminary Experiment Design

IER-516, Zirconium Test Assembly (ZTA), is a campaign to design, execute, and document a series of high-fidelity critical benchmark experiments to validate current and future zirconium (Zr) and zirconium hydride (ZrH x ) nuclear data evaluations. ZTA is a collaborative project between Los Alamos National Laboratory and the French Autoritè de Sûretè Nuclèaire et de Radioprotection. The experiments will be fueled with highly enriched uranium (HEU), and utilize the Comet critical assembly machine at the National Criticality Experiments Research Center. A total of ten preliminary critical experiments were designed and optimized for Zr and ZrHx nuclear data sensitivities using the MCNP-Particle Swarm Optimization methodology in the thermal, epithermal, intermediate, and fast neutron energy regions.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

AI-Optimized Polarization at Jefferson Lab

The AI-Optimized Polarization project seeks to develop experimental control applications for polarized targets and beams at Jefferson Lab using AI/ML. This paper will focus on two ongoing efforts involving a cryogenic polarized target and a linearly-polarized photon beam. Firstly, cryogenic targets, such as those used in Halls B and C (and approved for Hall D), are complex systems that are sensitive to a number of factors, including the temperature, beam currents, and the microwave and NMR apparatus. Secondly, the Hall D photon beam polarization depends on the optimal orientation of a diamond radiator, which produces coherent bremsstrahlung radiation from the electron beam incident upon it. Manual operation of both systems is tedious and error prone; implementing well-designed, interpretable control systems that incorporate AI is expected to lead to improved real-time polarization. AI optimization of nuclear physics experiments will lead, not just to cost-savings, but also to more efficient and higher-quality data, and this project will help to lay the foundation for future autonomous experiments.

Moran, Patrick [College of William and Mary, Willi↗

Promoted Ru/PrOx Catalysts for Mild Ammonia Synthesis

Ammonia synthesis is one of the most important chemical reactions. Due to thermodynamic restrictions and the reaction requirements of the current commercial iron catalysts, it is also one of the worst reactions for carbon dioxide emissions and energy usage. Ruthenium-based catalysts can substantially improve the environmental impact as they operate at lower pressures and temperatures. In this work, we provide a screening of more than 40 metals as possible promoter options based on a Ru/Pr2O3 catalyst. Cesium was the best alkali promoter and was held constant for the series of double-promoted catalysts. Ten formulations outperformed the Ru-Cs/PrOx benchmark, with barium being the best second promoter studied and the most cost-effective option. Designs of experiments were utilized to optimize both the pretreatment conditions and the promoter weight loadings of the doubly promoted catalyst. As a result, optimization led to a more than five-fold increase in activity compared to the unpromoted catalyst, therefore creating the possibility for low-ruthenium ammonia synthesis catalysts to be used at scale. Further, we have explored the roles of promoters using kinetic analysis, X-ray Photoelectron Spectroscopy (XPS), and in situ infrared spectroscopy. Here, we have shown that the role of barium is to act as a hydrogen scavenger and donor, which may permit new active sites for the catalyst, and have demonstrated that the associative reaction mechanism is likely used for the unpromoted Ru/PrOx catalyst with hydrogenation of the triple bond of the dinitrogen occurring before any dinitrogen bond breakage.

Chemistry↗

Fiber-Coupled Multipass NIR Sensor for In Situ, Real-Time Water Vapor Outgassing Monitoring

This work presents the recent development of a fiber-coupled multipass near-infrared (NIR) gas sensor used to monitor water vapor desorption of small material coupons. The gas sensor design employs a White cell topology to maximize the optical path length over a compact, hand-size footprint. Water vapor concentrations are quantified over a large dynamic range by simultaneously applying wavelength modulation and tunable diode laser absorption spectroscopy techniques. A custom headspace optimized for material desorption experiments is assembled using commercially available vacuum chamber components. We provide in situ measurements of water vapor desorption from two geometries of the industrially important silicone elastomer Sylgard-184 as a case study for sensor viability. To corroborate the results, the gas sensor data are compared to numerical simulations based on a triple-mode diffusion–sorption model, consisting of Henry, Langmuir, and Pooling modes.

gas sensor↗

Seismic investigations - The Viking Mars Lander.

A lightweight three-component short period seismometer has been developed for preliminary seismic investigations of Mars. Because of weight and data-rate constraints the Viking seismic experiment is far from optimal but it should, at a minimum, provide information about the microseismic level and an upper bound on the seismicity of the planet. If Mars is tectonically active a start can be made on the problem of the internal structure, dynamics, and composition of the planet. A good distribution of modest sized Marsquakes will make it possible to determine if Mars has a core. The size of the core is related to the conditions of planetary formation.

Anderson, D. L.↗

Space processing of chalcogenide glasses

Manufacture of chalcogenide glasses in space will eliminate many of the causes of optical non-homogeneity and contamination that are inherent in earth-bound manufacture. A program is outlined to demonstrate the feasibility of various techniques and processes that will be utilized to manufacture chalcogenide glasses in space. Amorphous character, purity, and homogeneity parameters are being investigated at various stages of the glass forming process. These parameters in merit index form will serve to provide guidelines for the design of the actual melting experiment in space, and for the optimization of the exact chalcogenide composition to be included in the space experiments.

Larsen, D. C.↗

Human controller modeling in environments that include non-control tasks

In complex environments where the human operator is a supervisor, he must allocate his attention between different kinds of tasks for optimum overall performance. When a portion of the future reference trajectory for the control task is available for preview, scheduling various activities is possible. A model has been developed for this situation using dynamic programming to solve an optimal control problem. An experiment was conducted where subjects controlled an airplane symbol over a map, shown a fixed distance into the future. Discrete, non-control tasks were introduced as number entry tasks. Results from the model are compared with experimental results.

Govindaraj, T.↗

Modeling the human controller in environments that include continuous and discrete tasks

In complex environments where the human operator is a supervisor, he must allocate his attention between different kinds of tasks for satisfactory overall performance. When a portion of the future reference trajectory for a continuous control task is available for preview, scheduling various other discrete activities is possible. A model has been developed for this situation using dynamic programming to solve an optimal control problem. An experiment was conducted where subjects controlled an airplane symbol over a map, shown a fixed distance into the future. Discrete tasks were introduced as data entry tasks. Results showed that the model compared favorably with experimental results.

Govindaraj, T.↗

High density circuit technology

Acquisition of polyimide materials for inter-metal dielectrics was obtained from three vendors, with considerable evaluation conducted on the Dupont PI2550 material. Experimental results indicate this material can be patterned using contact printing to line width far below 0.1 mils. Optimum line width is acquired using plasma etch equipment. Metal lift-off experiments on thermal evaporated films were optimized for application to sputtered deposited films. Alternate metal-lift-off experiments are proposed for future investigation. Dry processing equipment studies and future trends in VLSI fabrication techniques are on-going.

Wade, T. E.↗

Spacelab experiment integration

The capabilities and characteristics of Spacelab are discussed, and a process is described for the integration of a large number of experiments into the vehicle. Spacelab payload services and experiment integration functions are examined. The latter include science management; mission definition, documentation, and control requirements and interfaces; analytical integration; ground processing; flight operations; and postflight activities. It is concluded that the major factors involved in Spacelab experiment integration have been optimized to a great extent with respect to maximum science return for minimum cost.

Lester, R. C.↗

Convective-diffusive transport in vapor growth ampoules

Theoretical and experimental work on heat and mass transport in crystal growth by closed ampoule vapor transport is reviewed. It is shown that double-diffusive phenomena, together with the three-dimensional boundary conditions of real systems lead to a complexity of the transport modes that are beyond the reach of the simplifying models currently used in the materials preparation literature. Consequences of the new insights for earth-bound vapor transport and for optimization of future space experiments are discussed.

Rosenberger, F.↗

Hydrovolcanism

Hydrovolcanism is a common phenomena produced by the interaction of magma or magmatic heat with an external source of water, such as a surface body, an aquifer, or a glacier. The effects include hydrofracture of existing rock units in the subsurface and the formation of hyaloclastites in a subaqueous environment. Hydroexplosions originate within a few kilometers of the surface. They may be relatively small, phreatic events or devastating complex blasts. Large-scale experiments determined that the optimal mixing ratio of water to basaltic melt (thermite plus silicates) for efficient conversion of thermal energy into mechanical energy is in the range of 0.1 to 0.3. Based on experimental results, eruptions can be classified as dominantly magmatic if the ratio of external water to magma is less than 0.2. Eruptions with water/melt ratios in the range of 0.2 to 1.0 are highly explosive and carry tephra in a hot vapor that contains dominantly superheated (dry) steam.

Sheridan, M. F.↗

Approximate solutions to minimax optimal control problems for aeroassisted orbital transfer

The maneuver considered in the present investigation involves the coplanar transfer of a spacecraft from a high earth orbit (HEO) to a low earth orbit (LEO). HEO can be a geosynchronous earth orbit (GEO). The basic concept utilized involves the hybrid combination of propulsive maneuvers in space and aerodynamic maneuvers in the sensible atmosphere. The considered type of flight is also called synergetic space flight. With respect to the atmospheric part of the maneuver, trajectory control is achieved by means of lift modulation. The Bolza problem of optimal control is stated, and the first-order optimality conditions for this problem are given. The one-arc approach, the two-arc approach, and the three-subarc approach are discussed. Attention is given to the Chebyshev problem of optimal control, details concerning aeroassisted orbital transfer (AOT), AOT optimization problems, and numerical experiments.

Miele, A.↗

Development of a versatile laser light scattering instrument

A versatile laser light scattering (LLS) instrument is developed for use in microgravity to measure microscopic particles of 30 A to above 3 microns. Since it is an optical technique, LLS does not affect the sample being studied. A LLS instrument built from modules allows several configurations, each optimized for a particular experiment. The multiangle LLS instrument can be mounted in the rack in the Space Shuttle and on Space Station Freedom. It is possible that a Space Shuttle glove-box and a lap-top computer containing a correlator card can be used to perform a number of experiments and to demonstrate the technology needed for more elaborate investigations. This offers simple means of flying a great number of experiments without the additional requirements of full-scale flight hardware experiments.

Meyer, William V.↗

A preview of a microgravity laser light scattering instrument

The development of a versatile, miniature, modular light scattering instrument to be used in microgravity is described. The instrument will measure microscopic particles in the size range of thirty angstroms to above three microns. This modular instrument permits several configurations, each optimized for a particular experiment. In particular, a multiangle instrument will probably be mounted in a rack in the Space Shuttle and on the Space Station. It is possible that a Space Shuttle glove-box and a lap-top computer containing a correlator card can be used to perform a number of experiments and to demonstrate the technology needed for more elaborate investigations.

Meyer, W. V.↗