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A summary of the results from the field expeditions conducted within the framework of the Global Tropospheric Experiment (GTE) is presented. The missions reviewed include the Chemical Instrumentation Test and Evaluation missions and the Atmospheric Boundary Layer Experiment missions. Future GTE missions are also briefly reviewed.
New kinetic data yielding a slower formation rate and larger absorption cross sections of Cl2O2 are incorporated into a photochemical model to reassess the role of chlorine chemistry in accounting for the ozone reductions derived from TOMS observations in different regions of the Antarctic polar vortex during 1987. The model is further constrained by existing measurements from the Airborne Antarctic Ozone Experiment and the National Ozone Expedition II. Calculated concentrations of ClO based on the new kinetic data increase by almost a factor of two between the collar and core regions of the vortex during the second half of September. The calculated ozone reductions in the vortex core appear to be consistent with the TOMS observations in spite of the slower rate for the self-reaction of ClO.
Some proposed space exploration missions are examined. Consideration is given to requirements for human expeditions to Phobos and Mars and for establishing a lunar observatory and a permanent, self-sufficient facility on Mars. Earth-to-orbit transportation, propellant management, extraterrestrial construction and operations, life support technology, space transfer systems, and automation and robotics are examined in terms of proposed missions.
The Airborne Arctic Stratospheric Expedition (AASE) was conducted during January and February 1989. The polar stratosphere during this period was characterized by cold conditions from January to mid-February. A mid-February wave 2 major warming considerably warmed the polar stratosphere, but did not immediately lead to a lower stratospheric vortex breakup. As inferred from temperature data, January temperatures were sufficient for polar stratospheric cloud (PSC) formation. PSC regional extent was greater than the long-term average, but not significantly larger than in previous years.
Lower stratospheric temperatures during the Airborne Arctic Stratospheric Expedition are compared with temperatures available since January, 1964. January, 1989, was the coldest averaged January in the last 26 years at high latitude, lower stratospheric levels. There have been other months with temperatures almost as low as the level of January, 1989, and localized temperatures (e.g., minimum polar vortex temperatures) have been lower than that encountered in January 1989. February, 1989, was warmer than average and March, 1989, had some of the highest polar vortex temperatures in the last 26 years. Conditions were therefore not very favorable for Polar Stratospheric Cloud (PSC) formation into early spring.
Comparisons of temperatures from the research analysis STRATAN to radiosonde data, Meteorological Measurement System (MMS) data, and the National Meteorological Center (NMC) analyses are presented for the Airborne Arctic Stratospheric Expedition (AASE). The STRATAN analyses show consistent quality throughout AASE. The comparisons to MMS show that STRATAN more accurately represented low temperatures than NMC. This, coupled with forecast quality, show that STRATAN temperature fields are a valuable tool for diagnosing and forecasting polar stratospheric clouds.
Ice saturation at or just above the tropopause was frequently observed during the ER-2 vertical profiles over Stavanger (59 deg N) during the Airborne Arctic Stratospheric Expedition (AASE). On occasion, ice saturation extended as much as 500 m above the tropopause. Saturation was not observed over Punta Arenas (53 deg S) during the Airborne Antarctic Ozone Experiment. Saturation extending just above the tropopause was observed at Moffett Field (38 deg N) in winter but not in summer. The top of a thick cirrus layer at the tropopause will be very strongly cooled, and a thin cloud layer at the tropopause will either be strongly heated or cooled depending on the presence of lower level clouds. Some ER-2 data suggests removal of water and nitrogen species from the tropopause.
Airborne lidar measurements have been made of polar stratospheric clouds (PSCs) during the Airborne Arctic Stratospheric Expedition in January-February 1989. These show the existence of a systematic relationship between the backscatter depolarization ratio and the (aerosol + molecular)/molecular backscatter ratio. The data are consistent with a two population PSC particle model.
Lidar observations obtained from January 24 to February 2, 1989, during the Airborne Arctic Stratospheric expedition (AASE) mission further support the existence of two distinct classes (Types 1 and 2) of polar stratospheric clouds (PSCs). Most of the Type 1 PSCs observed were formed by rapid adiabatic cooling and exhibited very low depolarization ratios and low-to-intermediate scattering ratios. Type 2 PSCs were observed in regions of lowest temperature and showed much larger depolarization and scattering ratios, as would be expected from larger ice crystals. PSCs with low scattering ratios but moderate depolarization ratios were observed near the center of the vortex on one flight. These may have been either sparse Type 2 PSCs or Type 1 PSCs formed by less rapid cooling.
Polar stratospheric cloud (PSC) distributions in the wintertime Arctic stratosphere and their optical characteristics were measured with a multiwavelength airborne lidar system as part of the 1989 Airborne Arctic Stratospheric Expedition. PSCs were observed on 10 flights between January 6 and February 2, 1989, into the polar vortex. The PSCs were found in the 14-27 km altitude range in regions where the temperatures were less than 195 K. Two types of aerosols with different optical characteristics (Types 1a and 1b) were observed in PSCs thought to be composed of nitric acid trihydrate. Water ice PSCs (Type 2) were observed to have high scattering ratios (greater than 10) and high aerosol depolarizations (greater than 10 percent) at temperatures less than 190 K.
Dual-polarization 0.532 micron lidar data show systematic polar stratospheric cloud (PSC) evolution along a portion of the Airborne Arctic Stratospheric Expedition DC-8 flight of January 31, 1989. This flight leg was roughly aligned with air parcel motion on isentropic surfaces from 400-500 K, where the local adiabatic cooling rate was about 20 K/day. Type 1 PSCs show low depolarization ratios and scattering ratios which approach intermediate limiting values as ambient temperature decreases. These data suggest that Type 1 particles formed by rapid cooling may be nearly spherical and are restricted in size by partitioning of a limited HNO3 vapor supply among many competing growth sites. Type 2 PSCs appear at temperatures below estimated local frost points with increases in depolarization and scattering typical of larger ice crystals.
The Stratospheric Aerosol Measurement II (SAM II) satellite experiment measures 14 daily 1.0-micron aerosol extinction profiles in the high northern latitudes. These SAM II data were used to spot the locations of polar stratospheric clouds (PSCs) and provide an overview of the vertical structure of the upper tropospheric and stratospheric aerosols during the 1989 Airborne Arctic Stratospheric Expedition (AASE). Although SAM II measured a higher than average number of PSCs in January 1989 as compared to the previous 10 years, the number of PSCs sighted during the entire 1989 winter season is only slightly above average. Also discussed is the vertical gradient in aerosol extinction which occurs as the SAM II measurement locations cross the polar vortex.
The NASA Langley Research Center aerosol lidar system was one of several instruments that flew aboard a DC-8 during the Airborne Arctic Stratospheric Expedition. Several of the Stratospheric Aerosol Measurement II (SAM II) altitude profiles of aerosol extinction were close enough in time and space to allow for intercomparison with the lidar measurements of aerosol backscatter. Comparisons between three SAM II 1.0 micron aerosol extinction profiles and analogous profiles inferred from nearly simultaneous airborne lidar measurements are discussed. The other two comparisons show the first near-simultaneous SAM II/lidar measurements of a polar stratospheric cloud (PSC). The comparison made well within the edge of a relatively homogeneous PSC layer was also good, especially using an extinction-to-backscatter model derived from in situ PSC particle size measurements.
A new instrument, the Forward Scattering Spectrometer Probe (FSSP) 300, was used on the NASA ER-2 during the Airborne Arctic Stratospheric Expedition (AASE) to count and size particles in the size range 0.4-24 microns in diameter. A brief description of the instrument is presented, and observations for each ER-2 flight are summarized. Measurements were made in both type I and type II polar stratospheric clouds as well as in the background sulfuric-acid particles. Total particle concentrations up to 16/cu cm with total particle volumes up to 10 cubic micron/cu cm were observed in some of the polar-stratospheric-cloud events.
As shown independently by two different techniques, nitric acid aerosols and polar stratospheric clouds (PSCs) both form below similar threshold temperatures. This supports the idea that the PSC particles involved in chlorine activation and ozone depletion in the winter polar stratosphere are composed of nitric acid. One technique used to show this is the inertial impaction of nitric acid aerosols using an Er-2 aircraft; the other method is remote sensing of PSCs by the Stratospheric Aerosol Measurement (SAM II) satellite borne optical sensor. Both procedures were in operation during the Arctic Airborne Stratospheric Expedition in 1989, and the Airborne Antarctic Ozone Experiment in 1987. Analysis of Arctic particles gathered in situ indicates the presence of nitric acid below a 'first appearance' temperature Tfa = 202 K. This is the same highest temperature at which PSCs are seen by the SAM II satellite. In comparison, a 'first appearance' temperature Tfa = 198 K as found for the Antarctic samples.
In-situ measurements of total reactive odd nitrogen NO(y), were made from the NASA DC-8 aircraft in the lower arctic stratosphere during the 1989 Airborne Arctic Stratospheric Expedition. Throughout January and February, NO(y) mixing ratios were typically between 0.5 and 3 parts per billion by volume (ppbv) at altitudes between 10 and 12.5 km. During several flights late in the mission, events of unusually light NO(y) occurred with mixing ratios up to 12 ppbv at these altitudes. Simultaneous measurements of N2O, O3, and H2O during these events suggest that large changes in NO(y) are not expected. The elevated NO(y) values are interpreted as a vertical redistribution of NO(y) in the lower stratosphere resulting from gravitational sedimentation of aerosol particles containing HNO3. No evidence of the redistribution of H2O is noted, consistent with observations of denitrification without dehydration higher in the stratosphere.
It is argued that the reaction COF2 + H2O - 2HF + CO2 should proceed on surfaces of polar stratospheric clouds, based on laboratory evidence for this reaction in condensed phase and on analysis of column observations of HF during the Airborne Arctic Stratospheric Expedition. If the hypothesis is confirmed, observations of COF2 and HF could provide unambiguous indication of heterogeneous processing of polar air, and could help elucidate the influence of heterogeneous chemistry on concentrations of HCl, ClNO3, and chlorine oxide radicals.
Trend analysis of the Airborne Arctic Stratospheric Expedition's ER-2 profile data reveals an average decrease in N2O on potential temperature isentropes which can be attributed to diabatic cooling of inner vortex air. This conclusion is independently supported by radiative transfer computations. Trends in ozone and water vapor over the same period are not consistent with the magnitude of the diabatic descent. After accounting for the diabatic motion (estimated from N2O), an additional 0.44 + or - 0.3 percent/day average anomalous O3 decrease above 440 K (about 20 km) is needed to balance the continuity equation. This ozone decrease suggests additional photochemical destruction of ozone in the presence of the high amounts of ClO observed during the mission. A 0.4 + or - 0.3 percent/day average anomalous increase in H2O is also observed near 420 K (about 18 km) which may be due to the evaporation of ice crystals falling from higher, colder stratospheric layers.