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Sensing Techniques for Organochlorides through Intermolecular Interaction with Bicyclic Amidines

Toxic organochloride molecules are widely used in industry for various purposes. With their high volatility, the direct detection of organochlorides in environmental samples is challenging. Here, a new organochloride detection mechanism using 1,5-diazabicyclo[4.3.0]non-5-ene (DBN) is introduced to simplify a sensing method with higher detection sensitivity. Three types of organochloride compounds-trichloroethylene (TCE), dichloromethane (DCM), and dichlorodiphenyltrichloroethane (DDT)—were targeted to understand DCM conjugation chemistry by using nuclear magnetic resonance (NMR) and liquid chromatography with a mass spectrometer (LC-MS). 13C-NMR spectra and LC-MS data indicated that DBN can be labeled on these organochloride compounds by chlorine–nitrogen interaction. Furthermore, to demonstrate the organochloride sensing capability, the labeling yield and limit of detection were determined by a colorimetric assay as well as micellar electrokinetic chromatography (MEKC). The interaction with DBN was most appreciable for TCE, among other organochlorides. TCE was detected at picomolar levels, which is two orders of magnitude lower than the maximum contaminant level set by the United States Environmental Protection Agency. MEKC, in conjunction with this DBN-labeling method, enables us to develop a field-deployable sensing platform for detecting toxic organochlorides with high sensitivity.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Independent Orbiter Assessment (IOA): Analysis of the extravehicular mobility unit

The results of the Independent Orbiter Assessment (IOA) of the Failure Modes and Effects Analysis (FMEA) and Critical Items List (CIL) are presented. The IOA approach features a top-down analysis of the hardware to determine failure modes, criticality, and potential critical items (PCIs). To preserve independence, this analysis was accomplished without reliance upon the results contained within the NASA FMEA/CIL documentation. This report documents the independent analysis results corresponding to the Extravehicular Mobility Unit (EMU) hardware. The EMU is an independent anthropomorphic system that provides environmental protection, mobility, life support, and communications for the Shuttle crewmember to perform Extravehicular Activity (EVA) in Earth orbit. Two EMUs are included on each baseline Orbiter mission, and consumables are provided for three two-man EVAs. The EMU consists of the Life Support System (LSS), Caution and Warning System (CWS), and the Space Suit Assembly (SSA). Each level of hardware was evaluated and analyzed for possible failure modes and effects. The majority of these PCIs are resultant from failures which cause loss of one or more primary functions: pressurization, oxygen delivery, environmental maintenance, and thermal maintenance. It should also be noted that the quantity of PCIs would significantly increase if the SOP were to be treated as an emergency system rather than as an unlike redundant element.

Raffaelli, Gary G.↗

National Emission Standards for Hazardous Air Pollutants – Radionuclide Emissions Calendar Year 2017

Report submitted to regulators (State of Nevada and EPA Region IV). Required to document compliance with 40 CFR 61 Subpart H. The U.S. Department of Energy, National Nuclear Security Administration Nevada Field Office (NNSA/NFO) operates the Nevada National Security Site (NNSS) and the North Las Vegas Facility (NLVF). From 1951 through 1992, the NNSS was the continental testing location for U.S. nuclear weapons. The release of radionuclides from NNSS activities has been monitored since the initiation of atmospheric testing. After 1962, testing was limited to underground detonations, which greatly reduced radiation exposure to the public. Since nuclear testing ended in 1992, radiation monitoring focused on detecting airborne radionuclides from historically contaminated soils. These radionuclides are derived from re-suspension of soil (primarily by wind) and emission of tritium-contaminated soil moisture through evapotranspiration. Low amounts of legacy-related tritium are also emitted to air at the NLVF, an NNSS support complex in North Las Vegas. To protect the public from harmful levels of man-made radiation, the Clean Air Act, National Emission Standards for Hazardous Air Pollutants (NESHAP) (Title 40 Code of Federal Regulations [CFR] Part 61 Subpart H) (CFR 2010a) limits the release of radioactivity from a U.S. Department of Energy (DOE) facility to that which would cause 10 millirem per year (mrem/y) effective dose equivalent to any member of the public. This limit does not include radiation unrelated to NNSS activities. Unrelated doses could come from naturally occurring radioactive elements, from sources such as medically or commercially used radionuclides, or from sources outside of the United States, such as Japan’s Fukushima nuclear power plant, which was damaged in 2011. NNSA/NFO demonstrates compliance with the NESHAP limit by using environmental measurements of radionuclide air concentrations at critical receptor locations on the NNSS (U.S. Environmental Protection Agency [EPA] and DOE 1995). This method was approved by the EPA in 2001 (EPA 2001a) and has been the method used to demonstrate compliance with the 40 CFR 61.92 dose standard since 2005. Six locations on the NNSS have been established to act as critical receptor locations to demonstrate compliance with the NESHAP limit. These locations are actually pseudo-critical receptor stations because no member of the public resides at these onsite locations. Compliance is demonstrated if the measured annual average concentration is less than the NESHAP Concentration Level (CL) for Environmental Compliance listed in 40 CFR 61, Appendix E, Table 2 (CFR 2010a). For multiple radionuclides, compliance is demonstrated when the sum of the fractions (determined by dividing each radionuclide’s concentration by its CL and then adding the fractions together) is less than 1.0. In 2017, the potential dose from radiological emissions to air from both current and past NNSS activities was well below the 10 mrem/y dose limit. This is demonstrated by air sampling data collected at the critical receptor air monitoring stations which had average concentrations of radioactivity that were a fraction of the CL values. Concentrations ranged from 0.2% to a maximum of 5.7% of the allowed NESHAP limit. Clean Air Package 1988 (CAP88) was used to model dose to the offsite public from all 2017 NNSS radionuclide emissions. The model showed the maximally exposed individual to be on the adjacent U.S. Air Force Nevada Test and Training Range; this individual received a dose of 0.07 mrem/y. The potential dose to the public from NLVF emissions was also very low at 0.0000098 mrem/y, over six orders of magnitude lower than the 10 mrem/y limit.

07 ISOTOPE AND RADIATION SOURCES↗

Closure Report Central Nevada Test Area Subsurface Corrective Action Unit 443 January 2016

The U.S. Department of Energy (DOE) Office of Legacy Management (LM) prepared this Closure Report for the subsurface Corrective Action Unit (CAU) 443 at the Central Nevada Test Area (CNTA), Nevada, Site. CNTA was the site of a 0.2- to 1-megaton underground nuclear test in 1968. Responsibility for the site’s environmental restoration was transferred from the DOE, National Nuclear Security Administration, Nevada Field Office to LM on October 1, 2006. The environmental restoration process and corrective action strategy for CAU 443 are conducted in accordance with the Federal Facility Agreement and Consent Order (FFACO 1996, as amended 2011) and all applicable Nevada Division of Environmental Protection (NDEP) policies and regulations. This Closure Report provides justification for closure of CAU 443 and provides a summary of completed closure activities; describes the selected corrective action alternative; provides an implementation plan for long-term monitoring with well network maintenance and approaches/policies for institutional controls (ICs); and presents the contaminant, compliance, and use-restriction boundaries for the site.

54 ENVIRONMENTAL SCIENCES↗

Contaminant Attenuation and Transport Characterization of 200-UP-1 Operable Unit Sediment Samples

Contaminants disposed of at the land surface migrate through the vadose zone, forming plumes in groundwater. Processes that occur in the groundwater can attenuate contaminant concentrations during transport through the aquifer. For this reason, quantifying contaminant attenuation and contaminant transport processes in the aquifer, in support of the conceptual site model (CSM) and fate and transport modeling, are important for assessing the need for, and type of, remediation in the groundwater, including monitored natural attenuation (MNA). The framework to characterize attenuation and transport processes provided in U.S. Environmental Protection Agency (EPA) guidance documents was used to guide the laboratory effort reported herein.

54 ENVIRONMENTAL SCIENCES↗

Consideration of Decabromodiphenyl Ether Flame Retardant in Thermal and Radiation Aging of Crosslinked Polyethylene Cable Insulation

Decabromodiphenyl ether (decaBDE) has been used as a flame-retardant additive in nuclear-grade electrical cable insulation. However, decaBDE has been identified as a persistent, bioaccumulative and toxic (PBT) substance, leading to regulatory scrutiny. On January 6, 2021, the Environmental Protection Agency (EPA) published a final rule to phase out decaBDE. The 2021 rule set a two-year compliance deadline for “processing and distribution in commerce of decaBDE for use in wire and cable insulation in nuclear power generation facilities.” In recognition of industry concerns following a sudden discontinuation of decaBDE-containing Class 1E wire and cable essential for nuclear power operations and the time needed for qualifying the individual components using the alternative insulation technology, an extended compliance deadline was set in the finalized amendments to the 2021 rule as published by the Environmental Appeals Board on November 12, 2024. The 2024 rule set the compliance deadline for processing and distributing decaBDE-containing wire and cable insulation until the end of the service life of these materials. Since decaBDE has long been relied upon as the flame retardant in one of the most common cross-linked polyethylene (XLPE) nuclear cable insulation formulations, RSCC Firewall III insulation, questions have naturally arisen regarding whether changes in cable performance might be expected for XLPE containing a decaBDE alternative, especially for safety-related cables that must perform their safety function in a design basis event such as a loss of coolant accident.

22 GENERAL STUDIES OF NUCLEAR REACTORS↗

Gridded National Inventory of U.S. Methane Emissions

We present a gridded inventory of US anthropogenic methane emissions with 0.1 deg x 0.1 deg spatial resolution, monthly temporal resolution, and detailed scale dependent error characterization. The inventory is designed to be onsistent with the 2016 US Environmental Protection Agency (EPA) Inventory of US Greenhouse Gas Emissionsand Sinks (GHGI) for 2012. The EPA inventory is available only as national totals for different source types. We use a widerange of databases at the state, county, local, and point source level to disaggregate the inventory and allocate the spatial and temporal distribution of emissions for individual source types. Results show large differences with the EDGAR v4.2 global gridded inventory commonly used as a priori estimate in inversions of atmospheric methane observations. We derive grid-dependent error statistics for individual source types from comparison with the Environmental Defense Fund (EDF) regional inventory for Northeast Texas. These error statistics are independently verified by comparison with the California Greenhouse Gas Emissions Measurement (CALGEM) grid-resolved emission inventory. Our gridded, time-resolved inventory provides an improved basis for inversion of atmospheric methane observations to estimate US methane emissions and interpret the results in terms of the underlying processes.

Methane↗

Great Lakes Water Resources II: A Google Earth Engine Tool to Automate Wetland Extent Mapping Using Optical and Radar Satellite Sensors in the Great Lakes Basin for Wetland Management and Monitoring

The Great Lakes Basin is one of the world’s largest freshwater ecosystems. The Basin harbors over 200,000 acres of wetlands that provide a variety of environmental, ecological, and recreational functions to over 30 million people in the region. Some of these functions include improving water quality, mitigating flood impacts, providing wildlife habitat, and housing recreational activities. However, due to anthropogenic activities, habitat conversion and degradation threaten to disrupt or destroy remaining wetland ecosystems. Maps of wetland distribution based on ground surveys are costly and labor-intensive, prohibiting timely evaluations of wetland loss and gain. The Great Lakes Water Resources II team at the NASA Jet Propulsion Laboratory developed the Wetlands Extent Tool 2.0 (WET 2.0) in Google Earth Engine to automate mapping of wetland distribution in the Great Lakes Basin. The team partnered with the US Fish and Wildlife Service, Environmental Protection Agency, Minnesota Department of Natural Resources, the National Oceanic and Atmospheric Administration, and Ducks Unlimited. WET 2.0 incorporates Landsat 8 Operational Land Imager (OLI), Sentinel-1 C-band Synthetic Aperture Radar (C-SAR), and Sentinel-2 Multispectral Instrument (MSI) data. Utilizing a Random Forest classifier, WET 2.0 is capable of automatically mapping wetland extent in the entire Great Lakes Basin, achieving a mean overall accuracy of 80.12% when tested in Michigan.Findings and maps produced by WET 2.0 will enable our partners to identify areas of ecosystem degradation and wetland destruction in order to enact environmental practices and policy initiatives to maintain environmental and economic health in the area.

Water Resources↗

2016 Annual Site Environmental Report

This report provides the U.S. Department of Energy (DOE) and the public with information on the level of radioactive and non-radioactive pollutants (if any) that are added to the environment as a result of Princeton Plasma Physics Laboratory’s (PPPL) operations. The results of the 2016 environmental surveillance and monitoring program for PPPL’s are presented and discussed. The report also summarizes environmental initiatives, assessments, and community involvement programs that were undertaken in 2016. PPPL has engaged in fusion energy research since 1951. The vision of the Laboratory is to create innovations to make fusion power a practical reality – a clean, alternative energy source. 2016 marked the eighteenth year of National Spherical Torus Experiment and the first year of NSTX-U (Upgrade) operations. The NSTX-U Project is a collaboration among national laboratories, universities, and national and international research institutions and is a major element in the US Fusion Energy Sciences Program. Its design tests the physics principles of spherical torus (ST) plasmas, playing an important role in the development of smaller, more economical fusion reactors. NSTX-U began operations after its first upgrade that installed the new center stack magnets and second neutral beam, which would allow for hotter plasmas and greater field strength to maintain the fusion reaction longer. Due to operational issues with a poloidal coil, NSTX-U operated briefly in 2016. In 2016, PPPL’s radiological environmental monitoring program measured tritium in the air at the NSTX-U Stack and at on -site sampling stations. Using highly sensitive monitors, PPPL is capable of detecting small changes in the ambient levels of tritium. The operation of an in- stack monitor located on D-site is used to demonstrate compliance with the National Emission Standard for Hazardous Air Pollutants (NESHAPs) regulations. Also included in PPPL’s radiological environmental monitoring program, are water monitoring – ground and surface, and waste waters. PPPL’s radiological monitoring program characterized the background levels of tritium in the environment; the data are presented in this report. Ground water monitoring continued under the New Jersey Department of Environmental Protection’s Site Remediation Program. PPPL monitored for non-radiological contaminants, mainly volatile organic compounds (components of chlorinated degreasing solvents). In 2016, PPPL was in compliance with its permit limits for surface and sanitary discharges, excepting two elevated chlorine-produced oxidant concentration. PPPL was honored with awards for its waste reduction and recycling program, and its “EPEAT” electronics purchasing for the third consecutive year.

54 ENVIRONMENTAL SCIENCES↗

Metallurgical Evaluations of Depainting Processes on Aluminum Substrate

In December 1993, the Environmental Protection Agency (EPA) Emission Standards Division and the National Aeronautics and Space Administration's (NASA's) Marshall Space Flight Center (MSFC) signed an Interagency Agreement (IA) initiating a task force for the technical assessment of alternative technologies for aerospace depainting operations. The United States Air Force (USAF) joined the task force in 1994. The mandates of the task force were: (1) To identify available alternative depainting systems that do not rely on methylene chloride or other ozone-depleting, chlorinated, and volatile organic carbon solvents. (2) To determine the viability, applicability, and pollution prevention potential of each identified alternative. (3) To address issues of safety, environmental impact, reliability, and maintainability. Through a Technical Implementation Committee (TIC), the task force selected and evaluated eight alternative paint stripping technologies: chemical stripping, carbon dioxide (CO2) blasting, xenon flashlamp and CO2 coatings removal (FLASHJET(R)), CO2 laser stripping, plastic media blasting (PMB), sodium bicarbonate wet stripping, high-pressure water blasting (WaterJet), and wheat starch abrasive blasting (Enviro-Strip(R)). (The CO2 blasting study was discontinued after the first depainting sequence.) This final report presents the results of the Joint EPA/NASA/USAF Interagency Depainting Study. Significant topics include: (1) Final depainting sequence data for the chemical stripping, PMB, sodium bicarbonate wet stripping, and WaterJet processes. (2) Strip rates for all eight technologies. (3) Sequential comparisons of surface roughness measurements for the seven viable depainting technologies. (4) Chronological reviews of and lessons learned in the conduct of all eight technologies. (5) An analysis of the surface roughness trends for each of the seven technologies. (6) Metallurgic evaluations of panels Summaries of corrosion and hydrogen embrittlement evaluations of chemical stripping panels, detailed descriptions of which appear in previous reports. Because the requirements for alternative systems are diverse, as are initial setup, training, and on-going operational considerations, this study does not recommend a particular product or process. Users of this study will draw their own conclusions from the data presented herein.

McGill, Preston↗

Stormwater Pollution Prevention Plan, TA-60-01 Heavy Equipment Shop, Revision 4: LANS Archived 2019

This Storm Water Pollution Prevention Plan (SWPPP) was developed in accordance with the provisions of the Clean Water Act (33 U.S.C. §§1251 et seq., as amended), and the Multi-Sector General Permit for Storm Water Discharges Associated with Industrial Activity (U.S. EPA, June 2015) issued by the U.S. Environmental Protection Agency (EPA) for the National Pollutant Discharge Elimination System (NPDES) and using the industry specific permit requirements for Sector P-Land Transportation and Warehousing as a guide. This SWPPP applies to discharges of stormwater from the operational areas of the TA-60-01 Heavy Equipment Shop at Los Alamos National Laboratory. This is the archived and final revision of the SWPPP for LANS.

42 ENGINEERING↗

National Council on Radiation Protection (NCRP) 2024 annual meeting: advanced and small modular nuclear power reactors

On 25–26 March 2023, the U.S. National Council on Radiation Protection and Measurements (NCRP) held its 2024 annual meeting in Bethesda, Maryland, USA. The NCRP dates from 1929, and this meeting celebrated the 60th anniversary of receiving a U.S. Congressional Charter. For this annual meeting the NCRP felt it was essential to provide a briefing about advanced and small modular nuclear reactors (SMRs). The Journal of Radiological Protection is delighted to publish the following synopsis of material presented at the U.S. NCRP meeting. This synopsis is divided into five sections. The first section provides an overview of the whole meeting together with summaries of two context setting overview papers. The following four sessions of this synopsis are specific to advanced and small modular nuclear power reactors. The meeting also included keynote presentations by three of NCRP annual award recipients. The meeting topical areas were Technology Overview and Critical Issues. The individual papers laid the groundwork to understanding reactor technologies, terminology, and the fundamental concepts and processes for electrical generation. The perspectives of the U.S. Environmental Protection Agency and states, through the Conference of Radiation Control Program Directors were provided. The papers included a discussion of diverse topics including potential emergency preparedness considerations, radiological survey requirements, an evaluation of the future of nuclear power, the economics of reactors (both large and small), and the critical issues identified by the recent National Academies of Sciences’ study on advanced reactors. Here, the summary papers were developed to briefly document the major points and concepts presented during the oral papers presented at the 2024 NCRP Annual Meeting. The meeting heralded the dawn of a new era for commercial nuclear power.

61 RADIATION PROTECTION AND DOSIMETRY↗

Discharge Permit-1845 Quarterly Status Report (Jul-Sep 2017)

Trichloroethene (TCE) and nitrate have been identified as constituents of concern in groundwater at the Sandia National Laboratories, New Mexico (SNL/NM) Technical Area (TA)-V Groundwater (TAVG) Area of Concern (AOC) based on detections above the U.S. Environmental Protection Agency (EPA) maximum contaminant level (MCL) in samples collected from monitoring wells. The EPA MCLs and the State of New Mexico drinking water standards for TCE and nitrate are 5 micrograms per liter and 10 milligrams per liter (as nitrogen), respectively. A phased Treatability Study/Interim Measure (TS/IM) of in-situ bioremediation (ISB) will be implemented to evaluate the effectiveness of ISB as a potential technology to treat the groundwater contamination at TAVG AOC (New Mexico Environment Department [NMED] April 2016). The NMED Hazardous Waste Bureau (HWB) approved the Revised Treatability Study Work Plan (TSWP) (SNL/NM March 2016) in May 2016 (NMED May 2016). The SNL/NM Environmental Restoration Operations (ER) personnel are responsible for implementing the TS/IM of ISB at TAVG AOC in accordance with the Revised TSWP.

54 ENVIRONMENTAL SCIENCES↗

Transfer and Transition: Interagency Coordination for Managing Public Lands at UMTRCA Title II Sites in Wyoming – 16614

By the end of fiscal year 2025, the U.S. Department of Energy (DOE) Office of Legacy Management (LM) is anticipating adding 17 sites remediated under Title II of the Uranium Mill Tailings Radiation Control Act (UMTRCA) to the current inventory of 90 sites that it manages. Among the new sites are ones where federal public lands occur within the proposed long-term care boundary, the boundary determined by the Nuclear Regulatory Commission and LM as necessary to maintain site protectiveness for the entombed uranium mill tailings and residual groundwater contamination. For these sites, public land withdrawals for land and minerals will need to be established. LM’s primary mission at UMTRCA sites is to protect the public and the environment from exposure to contamination at the sites. For the sites with public lands or federally controlled minerals that will be transferring to LM, the Office will apply to the Department of the Interior (DOI) Bureau of Land Management (BLM) for new, public land and mineral withdrawals. At most current LM UMTRCA sites that involved public lands and minerals, DOI granted DOE “full administrative jurisdiction” and permanent withdrawals. Hence, these withdrawals are, permanently, no longer subject to public land, mining, and mineral-leasing laws and regulations. LM is coordinating with DOI/BLM in Wyoming to permanently withdraw full and partial jurisdiction at future UMTRCA Title II sites in that state. This approach would allow LM to fully administer surface lands and minerals, where necessary, and DOI and LM to administer surface lands and leasable minerals where it would not jeopardize sites’ radiological safety and long-term public and environmental protection. This “shared-jurisdiction approach” will meet LM’s strategic goal of protecting human health and the environment but also allow BLM to fulfill their mission to “manage and conserve the lands under the mandate of multiple-use and sustained yield.” In addition, LM could also fulfill the fourth goal of its Strategic Plan, to optimize land use and assets.

54 ENVIRONMENTAL SCIENCES↗

Discharge Permit-1845 Quarterly Status Report October 2018

Trichloroethene (TCE) and nitrate have been identified as constituents of concern in groundwater at the Sandia National Laboratories, New Mexico (SNL/NM) Technical Area (TA)-V Groundwater (TAVG) Area of Concern (AOC) based on detections above the U.S. Environmental Protection Agency (EPA) maximum contaminant level (MCL) in samples collected from monitoring wells. The EPA MCLs and the State of New Mexico drinking water standards for TCE and nitrate are 5 micrograms per liter and 10 milligrams per liter (as nitrogen), respectively. A phased Treatability Study/Interim Measure (TS/IM) of in-situ bioremediation (ISB) is being implemented to evaluate the effectiveness of ISB as a potential technology to treat the groundwater contamination at the TAVG AOC (New Mexico Environment Department [NMED] April 2016). The NMED Hazardous Waste Bureau (HWB) approved the Revised Treatability Study Work Plan (TSWP) (SNL/NM March 2016) in May 2016 (NMED May 2016). The SNL/NM Environmental Restoration Operations personnel are responsible for implementing the TS/IM of ISB at TAVG AOC in accordance with the Revised TSWP. Per the Revised TSWP, up to three injection wells (TAV-INJ1, TAV-INJ2, and TAV-INJ3) would be installed at TA-V in the vicinity of the highest contaminant concentrations detected in groundwater at monitoring wells LWDS-MW1, TAV-MW6, and TAV-MW10. The injection wells would be used to gravity-inject substrate solution and biodegradation bacteria to groundwater. The substrate solution consists of an inert tracer as well as essential food and nutrients for biostimulation. The substrate solution would be prepared in aboveground tanks. The TS/IM would be conducted in two phases: Phase I includes a pilot test followed by full-scale injection at the first injection well (TAV-INJ1); Phase II includes full-scale injections at the second and third injection wells (TAV-INJ2 and TAV-INJ3). The NMED Ground Water Quality Bureau (GWQB) requires a groundwater Discharge Permit (DP) for the operation of injection wells. NMED GWQB issued the DP-1845 to the U.S. Department of Energy/National Nuclear Security Administration (DOE/NNSA) for the SNL/NM TA-V Treatability Study injection wells on May 26, 2017 (NMED May 2017). The DP-1845 term started on May 30, 2017 and ends on May 30, 2022. Attachment A provides a copy of DP-1845. This quarterly report provides responses to DP-1845 Operating Conditions Terms and Conditions #3 through #8 and Monitoring and Reporting Terms and Conditions #10 through #17 for the April 1 to June 30, 2018 reporting period. The other Terms and Conditions are NMED statements of fact and do not require a response.

54 ENVIRONMENTAL SCIENCES↗

Finding Pennsylvania's Solar Future (Final Technical Report)

Finding Pennsylvania’s Solar Future (Project) was a project of the Pennsylvania Department of Environmental Protection (DEP) Energy Program’s Office (EPO) with funding from the U.S. Department of Energy Solar Energy Technologies Office. DEP brought together a project team that included Citizens for Pennsylvania’s Future (PennFuture), the Vermont Energy Investment Corporation (VEIC), and Pennsylvania-based solar subject matter experts (“Facilitators”) Sharon Pillar, Dr. Jeffrey Brownson, Ron Celentano, and Maureen Mulligan. The goals of the project were to explore whether Pennsylvania has sufficient technical and economic potential to increase in-state solar generation to provide 10 percent of its electricity consumption by 2030 and to identify potential pathways to achieve this target, as well as to explore the associated economic, environmental, and health impacts of achieving the goal. The project had four essential activities: stakeholder engagement, scenario modeling and analysis, strategy development, and dissemination and outreach.

14 SOLAR ENERGY↗

Ecological objectives can be achieved with wood-derived bioenergy

Renewable, biomass-based energy options can reduce the climate impacts of fossil fuels. However, calculating the effects of wood-derived bioenergy on greenhouse gases (GHGs), and thus on climate, is complicated (Miner et al. 2015). To clarify concerns and options about bioenergy, in November 2014, the US Environmental Protection Agency (EPA) produced a second draft of its Framework for Assessing Biogenic CO 2 Emissions fromStationary Sources (http://1.usa.gov/1dikgHq), which considers the latest scientific information and input from stakeholders. Furthermore, the EPA is expected to make decisions soon about the use of woody biomass under the Clean Power Plan, which sets targets for carbon pollution from power plants.

09 BIOMASS FUELS↗

Geochemical, Microbial, and Physical Characterization of 200-DV-1 Operable Unit B-Complex Cores from Boreholes C9552, C9487, and C9488 on the Hanford Site Central Plateau

The 200-DV-1 Operable Unit (OU) is in the process of characterizing the vadose zone to support a remedial investigation and feasibility study. Contaminants disposed of at the land surface must migrate through the vadose zone before entering groundwater. Quantifying contaminant attenuation and contaminant transport processes in the vadose zone, in support of the conceptual site model (CSM) and fate and transport modeling, are important for assessing the needs for, and types of, remediation in the vadose zone and groundwater. The framework to characterize attenuation and transport processes provided in U.S. Environmental Protection Agency (EPA) guidance documents was used to guide the laboratory effort with the following objectives:

54 ENVIRONMENTAL SCIENCES↗