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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 541 records · Page 30
All sourcesNASA NTRSDOE OSTI
NASA NTRSDate not supplied

Diversity of Energy Generation and Storage Methods on the Lunar Surface

Solar light, solar wind, differences between temperatures of the lunar surface, solar photosphere, and deep space, as well as noticeable changes of surface temperature in the absence of atmosphere provide opportunities for energy production and storage on the Moon using generators ranging from solar panels and thermocouples to devices using phase transitions or magnetism. There are multiple and diverse possibilities for energy generation and storage. Compositions of the relevant materials can be compared to abundances of chemical elements in lunar regolith.

Energy↗
NASA NTRS1982

Laser-excitation technique for the measurement of absolute transition probabilities of weak atomic lines

A new technique is presented for the measurement of transition probabilities for weak allowed, intersystem, and forbidden lines. The method exploits the fact that oscillator strength is proportional to the number of stimulated absorptions and emissions produced by a narrow-band laser pulse of known energy which is in resonance with an atomic transition. The method is tested for a particular transition of Mg I with a known oscillator strength value and of appropriate magnitude. The number densities are measured using a Mach-Zehnder interferometer and the hook method for the lower level population and by measuring an absorption-equivalent width for the other. The apparatus consisted of a high-power tunable laser and a magnesium oven to produce excited Mg vapor, and a laser-plasma background continuum. The results are in good agreement with theoretical and other experimental data.

Kwong, H. S.↗
NASA NTRS1992

Why all stars should possess circumstellar temperature inversions

The paper shows that the circumstellar temperature inversions possessed by all stars are the consequence of the 'velocity filtration' process described by Scudder (1992), according to which a stellar envelope is hotter than its underlying layers. The filtration scenario relies on the theoretically predicted and experimentally determined non-Maxwellian velocity distributions of ions and/or electrons in other sampled astrophysical plasmas and the transition region. The most immediate consequence is that the temperature and quasi-neutral plasma density become anticorrelated with increasing radius in a thin transition region, leaving the temperature profile inverted in excess of 10 exp 6 K up into a corona, without depositing a wave of magnetic field energy into the gas above the base of the transition region.

Scudder, Jack D.↗
NASA NTRS2022

Ab initio Screening of Refractory Nitrides and Carbides for High Temperature Hydrogen Permeation Barriers

Density functional theory was used to screen eleven refractory materials – two pure metals, six nitrides, and three carbides–as high-temperature hydrogen permeation barriers to prevent hydrogen embrittlement. Activation energies were calculated for atomic hydrogen (H) diffusion into the first subsurface layer from the lowest energy surface of the high-temperature phase of each candidate material. The candidate barrier materials with the highest activation energies are h-BN, c-BN, HfN, and ZrN with predicted barriers of 3.25 eV, 3.23 eV, 3.14 eV, and 2.76 eV, respectively. Strain energies, Bader charges, and density of states were calculated for the diffusing H at the relaxed initial state and the transition state to provide insight into contributing factors to high energy barriers. The diffusing H atom in materials with the highest predicted barriers are protic. In addition, interstitial H atoms induce mid-gap states in the density of states of both BN polymorphs. The nitrogen retention of each nitride material at high temperatures was predicted using nitrogen vacancy formation energies with respect to gaseous nitrogen. Experimental evaluation of nitrogen retention in h-BN, ZrN, and TiN confirmed their resistance to nitrogen loss at 1773 K. However, of these nitrides, TiN is predicted to be the least stable. This work identifies multiple promising materials that are predicted to be effective hydrogen barriers at high temperatures and that are stable at temperatures above 2700 K, with BN predicted to perform best.

Density Functional Theory (DFT)↗
NASA NTRS1997

High-Resolution Studies of Extreme-Ultraviolet Emission from CO by Electron Impact

We report a high-resolution study (0.0036 nm full width at half maximum) of electron-impact-induced emission spectra of CO at 30-, 75-, and 100-eV electron-impact energies. The spectral features were acquired in optically thin conditions. At the specified resolution, attainable with our 3-m vacuum ultraviolet spectrometer, we observe rotationally resolved emission bands of CO in the extreme ultraviolet, from the vibronic states B (sup 1)sigma(sup +)(0), C (sup 1)sigma(sup+)(0), and E (sup 1)pi(0), to the ground state X (sup 1)sigma(sup +)(0). A simple model of these bands, based on the Honl-London factors and the rotational constants, is constructed and is shown to be in good agreement with the observed spectra. The predissociation yield for the E (sup 1)pi electronic state has been determined, showing that the E state has the largest predissociation cross section of CO for all singlet-state Rydberg series members. The excitation function of the [E (sup 1)pi(0) yields X (sup 1)sigma(sup +)(0)] transition, in the 0-800-eV impact energy range, is measured, permitting determination of the oscillator strength by using a modified Born approximation analytical fit.

Ciocca, Marco↗
NASA NTRS1974

Boundary-layer development and transition due to free-stream exothermic reactions in shock-induced flows

A study of the effect of free-stream thermal-energy release from shock-induced exothermic reactions on boundary-layer development and transition is presented. The flow model is that of a boundary layer developing behind a moving shock wave in two-dimensional unsteady flow over a shock-tube wall. Matched sets of combustible hydrogen-oxygen-nitrogen mixtures and inert hydrogen-nitrogen mixtures were used to obtain transition data over a range of transition Reynolds numbers from 1,100,000 to 21,300,000. The heat-energy is shown to significantly stabilize the boundary layer without changing its development character. A method for application of this data to flat-plate steady flows is included.

Hall, J. L.↗
NASA NTRS1989

Accurate quantum chemical calculations

An important goal of quantum chemical calculations is to provide an understanding of chemical bonding and molecular electronic structure. A second goal, the prediction of energy differences to chemical accuracy, has been much harder to attain. First, the computational resources required to achieve such accuracy are very large, and second, it is not straightforward to demonstrate that an apparently accurate result, in terms of agreement with experiment, does not result from a cancellation of errors. Recent advances in electronic structure methodology, coupled with the power of vector supercomputers, have made it possible to solve a number of electronic structure problems exactly using the full configuration interaction (FCI) method within a subspace of the complete Hilbert space. These exact results can be used to benchmark approximate techniques that are applicable to a wider range of chemical and physical problems. The methodology of many-electron quantum chemistry is reviewed. Methods are considered in detail for performing FCI calculations. The application of FCI methods to several three-electron problems in molecular physics are discussed. A number of benchmark applications of FCI wave functions are described. Atomic basis sets and the development of improved methods for handling very large basis sets are discussed: these are then applied to a number of chemical and spectroscopic problems; to transition metals; and to problems involving potential energy surfaces. Although the experiences described give considerable grounds for optimism about the general ability to perform accurate calculations, there are several problems that have proved less tractable, at least with current computer resources, and these and possible solutions are discussed.

Bauschlicher, Charles W., Jr.↗
NASA NTRS2018

Payload Utilization in NASA's Space Launch System

With Space Policy Directive 1, the United States administration has directed the National Aeronautics and Space Administration’s (NASA’s) Human Exploration & Operations Mission Directorate (HEOMD) to return to the Moon with missions and infrastructure designed to support a sustained presence in cislunar space, with robotic and human lunar surface operations. NASA’s new deep space exploration system — the super heavy-lift Space Launch System (SLS), the Orion crew spacecraft and revamped launch facilities at Kennedy Space Center (KSC) — will enable NASA and its commercial and international partners to meet this goal for human exploration of deep space. SLS is the most capable launch vehicle for these efforts, as well as for sending robotic missions deep into the solar system, or even to interstellar space. The vehicle will be available in crew and cargo configurations in progressively more powerful block variants. The initial Block 1 lift capability of at least 26 metric tons (t) to trans-lunar injection (TLI) will be followed by a more powerful Block 1B with the power to loft more than 37 t to TLI. The ultimate Block 2 variant will lift more than 45 t to TLI. For payload accommodation, the Block 1 vehicle can utilize a 5 meter (m) fairing in its cargo configuration with the crew version also able to provide berths for 6U and 12U CubeSats as secondary payloads. The Block 1B crew vehicle will provide as much volume as the space shuttle payload bay in a Universal Stage Adapter (USA) for co-manifested payloads (CPLs). Block 1B cargo vehicles will offer 8.4 m-diameter fairings in 19.1 m and possibly longer lengths, with enough volume to accommodate lunar-orbiting habitat modules and other elements of NASA’s Gateway science outpost. For Mars-class payloads, larger fairings for the Block 2 cargo launcher are under consideration. For missions beyond the Earth-Moon system, SLS offers greater characteristic energy (C3) than any other launch vehicle, enabling shorter transit times or heavier payloads with more robust science packages for missions to the outer solar system. Indeed, the unmatched combination of thrust, payload volume and departure energy that SLS provides opens new opportunities for human and robotic exploration of deep space. This paper will provide an overview of the various vehicle block configurations, their capabilities and payload accommodations for sending primary, co-manifested and secondary payloads to deep space

Creech, Stephen D.↗
NASA NTRS1999

Computational Study of Field Initiated Surface Reactions for Synthesis of Diamond and Silicon

This project involves using quantum chemistry to simulate surface chemical reactions in the presence of an electric field for nanofabrication of diamond and silicon. A field delivered by a scanning tunneling microscope (STM) to a nanometer scale region of a surface affects chemical reaction potential energy surfaces (PES) to direct atomic scale surface modification to fabricate sub-nanometer structures. Our original hypothesis is that the applied voltage polarizes the charge distribution of the valence electrons and that these distorted molecular orbitals can be manipulated with the STM so as to change the relative stabilities of the electronic configurations over the reaction coordinates and thus the topology of the PES and reaction kinetics. Our objective is to investigate the effect of applied bias on surface reactions and the extent to which STM delivered fields can be used to direct surface chemical reactions on an atomic scale on diamond and silicon. To analyze the fundamentals of field induced chemistry and to investigate the application of this technique for the fabrication of nanostructures, we have employed methods capable of accurately describing molecular electronic structure. The methods we employ are density functional theory (DFT) quantum chemical (QC) methods. To determine the effect of applied bias on surface reactions we have calculated the QC PESs in various applied external fields for various reaction steps for depositing or etching diamond and silicon. We have chosen reactions which are thought to play a role in etching and the chemical vapor deposition growth of Si and diamond. The PESs of the elementary reaction steps involved are then calculated under the applied fields, which we vary in magnitude and configuration. We pay special attention to the change in the reaction barriers, and transition state locations, and search for low energy reaction channels which were inaccessible without the applied bias.

Musgrave, Charles Bruce↗
NASA NTRS1989

Longitudinal aerodynamic characteristics of a subsonic, energy-efficient transport configuration in the National Transonic Facility

The Reynolds number, aeroelasticity, boundary layer transition, and nonadiabatic wall temperature effects, and data repeatability was determined in the National Transonic Facility (NTF) for a subsonic, energy efficient transport model. The model was tested over a Mach number range of 0.50 to 0.86 and a Reynolds number range of 1.9 million to approximately 23.0 million (based on mean geometric chord). The majority of the data was taken using cryogenic nitrogen (data at 1.9 million Reynolds number was taken in air). Force and moment, wing pressure, and wing thermocouple data are presented. The data indicate that increasing Reynolds number resulted in greater effective camber of the supercritical wing and horizontal tail, resulting in greater lift and pitching moment coefficients at nearly all angles of attack for M = 0.82. As Reynolds number was increased, untrimmed L/D increased, the angle of attack for maximum L/D decreased, drag creep was reduced significantly, and drag divergence Mach number increased slightly. Data repeatability for both modes of operation of the NTF (air and cryogenic nitrogen) was generally very good, and nonadiabatic wall effects were estimated to be small. Transition-free and transition-fixed configurations had significantly different force and moment data at M = 0.82 for low Reynolds number, and very small differences were noted at high Reynolds numbers.

Jacobs, Peter F.↗
NASA NTRS2004

Interaction of a Boundary Layer with a Turbulent Wake

The objective of this grant was to study the transition mechanisms on a flat-plate boundary layer interacting with the wake of a bluff body. This is a simplified configuration presented and designed to exemplify the phenomena that occur in multi-element airfoils, in which the wake of an upstream element impinges on a downstream one. Some experimental data is available for this configuration at various Reynolds numbers. The first task carried out was the implementation and validation of the immersed-boundary method. This was achieved by performing calculations of the flow over a cylinder at low and moderate Reynolds numbers. The low-Reynolds number results are discussed, which is enclosed as Appendix A. The high-Reynolds number results are presented in a paper in preparation for the Journal of Fluid Mechanics. We performed calculations of the wake-boundary-layer interaction at two Reynolds numbers, Re approximately equal to 385 and 1155. The first case is discussed and a comparison of the two calculations is reported. The simulations indicate that at the lower Reynolds number the boundary layer is buffeted by the unsteady Karman vortex street shed by the cylinder. This is shown: long streaky structures appear in the boundary layer in correspondence of the three-dimensionalities in the rollers. The fluctuations, however, cannot be self-sustained due to the low Reynolds-number, and the flow does not reach a turbulent state within the computational domain. In contrast, in the higher Reynolds-number case, boundary-layer fluctuations persist after the wake has decayed (due, in part, to the higher values of the local Reynolds number Re achieved in this case); some evidence could be observed that a self-sustaining turbulence generation cycle was beginning to be established. A third simulation was subsequently carried out at a higher Reynolds number, Re=3900. This calculation gave results similar to those of the Re=l155 case. Turbulence was established at fairly low Reynolds number, as a consequence of the high level of the free-stream perturbation. An instantaneous flow visualization for that case is shown. A detailed examination of flow statistics in the transitional and turbulent regions, including the evolution of the turbulent kinetic energy (TKE) budget and frequency spectra showed the formation and evolution of turbulent spots characteristic of the bypass transition mechanism. It was also observed that the turbulent eddies achieved an equilibrium, fully developed turbulent states first, as evidenced by the early agreement achieved by the terms in the TKE budget with those observed in turbulent flows. Once a turbulent Reynolds stress profile had been established, the velocity profile began to resemble a turbulent one, first in the inner region and later in the outer region of the wall layer. An extensive comparison of the three cases, including budgets, mean velocity and Reynolds stress profiles and flow visualization, is included. The results obtained are also presented.

Piomelli, Ugo↗
NASA NTRS1976

Low-energy particle events associated with sector boundaries

Onsets of some 40 to 45 low-energy proton events during the years 1957-1969 coincided in time with transits of well-defined sector boundaries across the earth. These events can be interpreted as long-lived proton streams filling up some of the magnetic sectors, indicating an acceleration of protons which is not associated with typical proton-producing flares. The sharp onsets of these particle streams, as well as a deficiency of flare-associated particle events shortly before the boundary transit, indicate that in some cases magnetic sector boundaries can inhibit transverse propagation of low-energy particles in the solar corona or in interplanetary space.

Svestka, Z.↗
NASA NTRS1972

Angular dependence of electron impact excitation cross sections of O2.

Study of the electron-impact excitation spectrum of O2 at 20 and 45 eV impact energies and at scattering angles ranging from 10 to 90 deg. The angular behavior of the differential scattering cross sections for excitation of the a super 1 delta sub g, b super 1 sigma sub g (+), B super 3 sigma sub u (-) states for the 9.97-eV ('longest' band) and the 10.29-eV ('second' band) transitions, for the broad feature at 6.1 eV energy-loss, and for elastic scattering is determined. The experimentally measured relative differential and integral cross sections for these processes are approximately normalized to the absolute scale. The intensities of the different transitions in optical and electron-impact spectra are compared, and the importance of spin-orbit coupling and exchange processes is discussed. It is found that the energy-loss feature at 6.1 eV in the electron-impact spectrum is mostly due to the excitation of the c super 1 sigma sub u (-) state, and not the A super 3 sigma sub u (+) state, as had been previously thought.

Trajmar, S.↗
NASA NTRSDate not supplied

EAS Optical Cherenkov Signatures of Tau Neutrinos for Space and Suborbital Detectors

Multi-messenger observations of transient astrophysical sources have the potential to characterize the highest energy accelerators and the most extreme environments in the Universe. Detection of neutrinos, in particular tau neutrinos generated by neutrino oscillations in transit from their sources to Earth, is possible for neutrino energies above 10 PeV using optical Cherenkov detectors imaging upward-moving extensive air showers (EAS). These EAS are produced from Earth-interacting tau neutrinos leading to tau leptons that subsequently decay in the atmosphere. We compare neutrino detection sensitivities for generic short- and long-burst transient neutrino sources and sensitivities to the diffuse neutrino flux for the second generation Extreme Universe Space Observatory on a Super-Pressure Balloon (EUSO-SPB2) balloon-borne mission and the proposed space-based Probe of Extreme Multi-Messenger Astrophysics (POEMMA) mission.

Mary Hall Reno↗
NASA NTRS1977

The influence of molecular rotation on vibration-translation energy transfer

A three-dimensional vibration-rotation collision model is formulated within a semiclassical framework to study the effect of coupled rotational motion on the rate of vibrational energy transfer for collisions between anharmonic diatomic molecules and structureless atoms. Emphasis is on the net rates of vibrational energy transfer summed over all final rotational states rather than those for individual vibration-rotation transitions. The corresponding three-dimensional rate parameters are cast into forms that may be identified with equivalent parameters associated with the collinear approximation. Their comparisons allow the validity of a collinear model to be evaluated and some constraints on its application to be implied. The mechanisms of vibrational energy transfer including rotational transitions are shown to be separable into three classes which are identified and discussed

Mckenzie, R. L.↗
NASA NTRS1979

Two-potential approach for electron-molecular collisions at intermediate and high energies - Application to e-N2 scatterings

A general theoretical approach is proposed for the calculation of elastic, vibrational, and rotational transitions for electron-molecule scattering at intermediate and high-electron-impact energies. In this formulation, contributions to the scattering process come from the incoherent sum of two dominant potentials: a short-range shielded nuclear Coulomb potential from individual atomic centers, and a permanent/induced long-range potential. Application to e-N2 scattering from 50-500 eV incident electron energies has yielded good agreement with absolutely calibrated experiments. Comparisons with other theoretical approaches are made. The physical picture as well as the general features of electron-molecule scattering process are discussed within the framework of the two-potential approach.

Choi, B. H.↗
NASA NTRS1976

Tabulation of hybrid theory calculated e-N2 vibrational and rotational cross sections

Vibrational excitation cross sections of N2 by electron impact are tabulated. Integrated cross sections are given for transitions v yields v prime where o=or v=or 8 in the energy range 0.1 eV=or E=or 10 eV. The energy grid is chosen to be most dense in the resonance region (2 to 4 eV) so that the substructure is present in the numerical results. Coefficients in the angular distribution formula (differential scattering cross section) for transitions v=0 yields v prime = or 8 are also numerically given over the same grid of energies. Simultaneous rotation-vibration coefficients are also given for transitions v=o,j=o; 1 yields v prime=o, j=o,2,4; 1,3,5. All results are obtained from the hybrid theory.

Chandra, N.↗