Engineering Papers⌕ Search

SEARCH · Engineering Papers

Results for “Diffusion coefficient”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 541 records · Page 30

Vertical and horizontal fluxes of ozone at the tropopause from the first year of GASP data

Ozone measurements taken from commercial airlines (GASP data) are used to estimate the vertical and horizontal fluxes of ozone near the tropopause. The annual average flux of O3 into the troposphere at 30 to 50 deg N is nearly the same as indirect estimates based on surface O3 data, thus supporting the hypothesis that the amount of ozone in the troposphere is essentially controlled by injection from the stratosphere. The present GASP estimates of the total flux of O3 into the troposphere verify the model results of Cunnold et al. (1975), although the distribution of flux between mean motions and diffusion is different and suggests that models with coarse horizontal resolution must continue to parameterize much vertical transport by diffusion coefficients. A significant variation in the east-west spatial autocorrelation function of O3 near the tropopause is found to be about 1900 km. Monthly estimates of the horizontal transient eddy flux of ozone are generally smaller than seasonal or yearly results based on ozonesonde data. This is perhaps because the present estimates are made over monthly periods to reduce the influence of correlation between the annual variations in ozone and meridional wind. The available data support the hypothesis that transient eddy fluxes of O3 have large longitudinal variations.

Nastrom, G. D.↗

Numerical analyses for treating diffusion in single-, two- and three-phase binary alloy systems

Numerical solutions were applicable for planar, cylindrical, or spherical geometries with any diffusion-zone size and any continuous variation of the diffusion coefficient with concentration. Special techniques were included in the analyses to account for differences in molal volumes, initiation and growth of an intermediate phase, disappearance of a phase, and the presence of an initial composition profile in the specimen. A major improvement in solution accuracy was achieved in the two phase analysis by employing a mass conservation criterion to establish the location of the interface rather than the conventional interface-flux-balance criterion. In the three phase analysis, computation time was minimized without sacrificing solution accuracy by treating the three phase problem as a two phase problem when the thickness of the intermediate phase was less than a preset small value. Three computer codes were developed to perform these analyses.

Tenney, D. R.↗

Theoretical brightness temperature profiles of atmospheric pure H2 rotational quadrupole lines - Jupiter and Uranus

With the advent of high-resolution instruments and their use high above most of the telluric water vapor, the hydrogen pure rotational quadrupole lines at 28, 17, and 12 microns from the atmospheres of the outer planets may be observed. Best values for the line strengths, pressure-broadening coefficients, diffusion constants, and pressure shifts for these rotational transitions are calculated. The collisionally narrowed Galatry profile is used to calculate brightness temperature line profiles for these H2 transitions for the outer planets, Jupiter and Uranus. The effects of the H2 rotational-translational continuum and of the NH3 v2 band are also included.

Goorvitch, D.↗

Simple analytical solutions for spherically symmetric production and modulation of energetic solar particles

Exact analytical solutions are presented for the standard time-independent spherically symmetric convection-diffusion-adiabatic deceleration equation governing the transport of cosmic rays in the interplanetary medium for the case in which particles are produced with spherical symmetry at the sun. It is assumed that the solar-wind speed is constant and radial, and that the spatial diffusion coefficient has a power-law dependence on momentum. The Green's function describing the modulation of a monoenergetic production of particles is presented. The solutions provide a useful basis for the study of time-integrated properties of energetic solar-flare particle spectra.

Gross, M. W.↗

Computer simulation of the velocity diffusion of cosmic rays

Monte Carlo simulation experiments have been performed in order to study the velocity diffusion of charged particles in a static turbulent magnetic field. By following orbits of particles moving in a large ensemble of random magnetic field realizations with suitably chosen statistical properties, a pitch-angle diffusion coefficient is derived. Results are presented for a variety of particle rigidities and rms random field strengths and compared with the predictions of standard quasi-linear theory and the nonlinear partially averaged field theory.

Kaiser, T. B.↗

Transport properties in the Jovian atmosphere

Transport properties in a Jupiter-like atmosphere (89 mol % hydrogen and 11 mol % helium) are obtained by using the method of the kinetic theory of gases. The transport collision integrals are calculated by fitting various two-body semiempirical interaction potentials for which the collision integrals are tabulated to ab initio quantum mechanical calculations of the two-body interactions. The collision integrals are used to calculate the binary diffusion coefficients, viscosity, and 'total' thermal conductivity of the pure gases and the gas mixtures at 1-atm pressure from 1000 K to 25,000 K.

Biolsi, L.↗

Quiet time interplanetary cosmic ray anisotropies observed from Pioneer 10 and 11

Cerenkov counters on the Pioneer 10 and 11 spacecraft, capable of detecting alpha particles and protons with energies up to 480 MeV, and nucleons and electrons with energies up to 6 MeV, have yielded data on cosmic ray anisotropies during periods of low solar activity. Observations from Pioneer 11 place east-west anisotropy at 0.41 plus or minus 0.11%, and the north-south anisotropy at near zero; Pioneer 10 results show east-west anisotropy to be approximately 0.59 plus or minus 0.18%, and the north-south component at 0.25 plus or minus 0.08%. It is noted that the Pioneer 10 observations were obtained at the 6 AU range, while those from Pioneer 11 originated closer to the sun (1.1 to 2.7 AU). Attention is given to the ratio of the perpendicular to parallel components of the diffusion coefficient, and to the large north-south anisotropy reported by Pioneer 10, an effect due possibly to gradient drift, and to an additional streaming independent of the magnetic field polarity.

Ip, W.-H.↗

Some effects of ablation on transport properties in the Jovian atmosphere

In this paper the transport properties at the inner and outer boundary for mixing between ablation products and a Jovian-like atmosphere are calculated. The dominant species at these boundaries are C, H, O, He, H+, and e. Accurate potential energy curves are obtained for the fifteen possible two-body interactions among these species by fitting good semiempirical potentials for which transport collision cross sections have been tabulated to accurate experimental and theoretical information. Results are obtained for the viscosity and translational thermal conductivity of the pure species and the binary diffusion coefficients from 1000 K to 25,000 K. In addition, the mixture translational thermal conductivity and viscosity are calculated at the inner and outer mixing boundaries. This information is required for calculating flowfield properties and surface heating. The most important conclusion is that the translational thermal conductivity is substantially lower at the inner mixing boundary than it is at the outer mixing boundary.

Biolsi, L.↗

Transport properties of monatomic carbon

Transport collision integrals for each of the 18 molecular C2 states that dissociate into ground state carbon atoms are presented. The integrals are obtained by fitting two-body semiempirical interaction potentials, for which the collision integrals are tabulated, to experimental and/or accurate theoretical calculations for each of these states. The collision integrals are applied to calculate the diffusion coefficient, viscosity, and translational contribution to the thermal conductivity of monatomic carbon at 1-atm pressure from 1000 K to 25,000 K. Because of ablation injection, monatomic carbon is an important flow field constituent of ablative flow during planetary entry, and knowledge of the transport properties for carbon species is required for calculating the flow field properties and surface heating.

Biolsi, L.↗

Cooling rates of group IVA iron meteorites

Cooling rates of six group IVA iron meteorites were estimated by a taenite central Ni concentration-taenite half-width method. Calculated cooling rates range from 13 to 25 C/Myr, with an average of 20 C/Myr. No correlation between cooling rate and bulk Ni content is observed, and the data appear to be consistent with a uniform cooling rate as expected from an igneous core origin. This result differs from previous studies reporting a wide range in cooling rates that were strongly correlated with bulk Ni content. The differences result mainly from differences in the phase diagram and the selected diffusion coefficients. Cooling rates inferred from taenite Ni concentrations at the interface with kamacite are consistent with those based on taenite central Ni content.

Willis, J.↗

A core origin for group IVA iron meteorites - A reply to Moren and Goldstein

Because uncertainties in experimental data are large, one has considerable latitude in choosing the input parameters needed to calculate iron meteorite cooling rates. The best way to test input parameters is by examining their ability to yield the observed properties of the meteorites. Our phase diagram yields fits to kamacite profiles that are superior to those based on the Moren-Goldstein phase diagram. Our method of allowing for the effect of P on the Ni diffusion coefficient takes into account the enhancement in this effect with decreasing temperature; Moren and Goldstein use a relationship derived for a temperature of 1100 C, well outside the 700-350 C range where kamacite growth occurs. Use of our input parameters yields cooling rates in IVA irons that are independent of composition, consistent with a core origin. Since the fractionation of siderophiles in group IVA also indicates a core origin, we conclude that this is the correct model for this group.

Willis, J.↗

Global circulation and distribution of hydrogen in thermosphere of Venus

The global density distribution of atomic H in the upper atmosphere of Venus is determined in terms of a global circulation model. It is shown that H produced on the dayside is efficiently advected to the nightside by the major gas CO2 where it is then convected to lower altitudes and recombines. A maximum night/day H density ratio of about 5 is derived, in which case exospheric return flow from night to day strongly limits the nightside density enhancement. A previously postulated constraint connecting the eddy diffusion coefficient with the escape flux of H in one dimensional models is no longer required when global circulation of H is considered.

Hartle, R. E.↗

Degassing procedure for ultrahigh vacuum

Calculations based on diffusion coefficients and degassing rates for stainless-steel vacuum chambers indicate that baking at lower temperatures for longer periods give lower ultimate pressures than rapid baking at high temperatures. Process could reduce pressures in chambers for particle accelerators, fusion reactors, material research, and other applications.

Moore, B. C.↗

Temperature and moisture analysis in composites

Advanced fiber-reinforced polymeric matric composites have emerged as strong candidate materials for airframe applications. Favorable aspects include high strength, stiffness, and low density. Temperature and Moisture Analysis in Composites (TMAC) program was developed to study effect of variations in diffusion coefficients, surface properties, panel tilt, ground reflection, and geographical location on moisture-concentration profiles and average moisture contents of composite laminates.

Tenney, D. R.↗

Scratch encourages selective doping

Dislocations induced by scratching produce deep narrow spikes of zinc diffused in gallium arsenide. Density of defects formed locally increases zinc diffusion coefficient. Enhancements by factor of 6 have been observed. Technique works for other dopants than zinc and for other semiconductors besides GaAs.

Hawrylo, F. Z.↗

Mathematical model for steady state, simple ampholyte isoelectric focusing: Development, computer simulation and implementation

The elimination of Ampholine from the system by establishing the pH gradient with simple ampholytes is proposed. A mathematical model was exercised at the level of the two-component system by using values for mobilities, diffusion coefficients, and dissociation constants representative of glutamic acid and histidine. The constants assumed in the calculations are reported. The predictions of the model and computer simulation of isoelectric focusing experiments are in direct importance to obtain Ampholine-free, stable pH gradients.

Palusinski, O. A.↗

Mathematical model investigation of long-term transport of ocean-dumped sewage sludge related to remote sensing

An existing, three-dimensional, Eulerian-Lagrangian finite-difference model was modified and used to examine the transport processes of dumped sewage sludge in the New York Bight. Both in situ and laboratory data were utilized in an attempt to approximate model inputs such as mean current speed, horizontal diffusion coefficients, particle size distributions, and specific gravities. The results presented are a quantitative description of the fate of a negatively buoyant sewage sludge plume resulting from continuous and instantaneous barge releases. Concentrations of the sludge near the surface were compared qualitatively with those remotely sensed. Laboratory study was performed to investigate the behavior of sewage sludge dumping in various ambient density conditions.

Kuo, C. Y.↗

Decay of the zincate concentration gradient at an alkaline zinc cathode after charging

The transport of the zincate ion to the alkaline zinc cathode was studied by observing the decay of the zincate concentration gradient at a horizontal zinc cathode after charging. This decay was found to approximate first order kinetics as expected from a proposed boundary layer model. The concentrations were calculated from polarization voltages. The decay half life was shown to be a linear function of the thickness of porous zinc deposit on the cathode indicating a very rapid transport of zincate through porous zinc metal. The rapid transport is attributed to an electrochemical mechanism. From the linear dependence of the half life on the thickness the boundary layer thickness was found to be about 0.010 cm when the cathode was at the bottom of the cell. No significant dependence of the boundary layer thickness on the viscosity of electrolyte was observed. The data also indicated a relatively sharp transition between the diffusion and convection transport regions. When the cathode was at the top of the cell, the boundary layer thickness was found to be roughly 0.080 cm. The diffusion of zincate ion through asbestos submerged in alkaline electrolyte was shown to be comparable with that predicted from the bulk diffusion coefficient of the zincate ion in alkali.

Kautz, H. E.↗