SEARCH · Engineering Papers

Results for “Dendrites”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

SourceResearch connectionFrom yearThrough year

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 541 records · Page 30

All sources NASA NTRS DOE OSTI

NASA NTRS1989

Ground-based simulation of telepresence for materials science experiments

A series of ground-based telepresence experiments have been performed to determine the minimum video frame rate and resolution required for the successive performance of materials science experiments in space. The approach used is to simulate transmission between earth and space station with transmission between laboratories on earth. The experiments include isothermal dendrite growth, physical vapor transport, and glass melting. Modifications of existing apparatus, software developed, and the establishment of an inhouse network are reviewed.

Johnston, James C.↗

NASA NTRS1988

Undercooling studies on Nb-Pt and Nb-Si alloys using the 105 meter drop tube

Niobium-platinum samples of compositions ranging from 16 to 32 at. pct have been undercooled to as much as 540 K in the low gravity, containerless environment of a 105 meter drop tube. Undercooling was terminated in the Nb-Pt samples by the nucleation and growth of the Nb3Pt phase. In the 16-18 at. pct Pt samples, this resulted in samples which are completely Nb3Pt, in contrast to both the equilibrium phase diagram and the nonundercooled samples which formed with Nb dendrites and interdendritic Nb3Pt. Undercoolings for the Nb-Si samples were up to 670 K, which corresponds to 27 percent of the liquidus temperature or 80 percent of the estimated hypercooling limit. In the Nb-Si system, a coupled zone was identified as well as a metastable extension of the solubility limit of Si in Nb due to deep undercooling.

Robinson, M. B.↗

NASA NTRS1989

Calibration approach to electron probe microanalysis: A study with PWA-1480, a nickel base superalloy

The utility of an indirect calibration approach in electron probe microanalysis is explored. The methodology developed is based on establishing a functional relationship between the uncorrected k-ratios and the corresponding concentrations obtained using one of the ZAF correction schemes, for all the desired elements in the concentration range of interest. In cases where a very large number of analyses are desired, such a technique significantly reduces the total time required for the microprobe analysis without any significant loss of precision in the data. A typical application of the method in the concentration mapping of the transverse cross-section of a dendrite in directionally solidified PWA-1480, a nickel-based superalloy, is described.

Terepka, F. M.↗

NASA NTRS1989

Arcjet Cathode Phenomena

Cathode tips made from a number of different materials were tested in a modular arcjet thruster in order to examine cathode phenomena. Periodic disassembly and examination, along with the data collected during testing, indicated that all of the tungsten-based materials behaved similarly despite the fact that in one of these samples the percentage of thorium oxide was doubled and another was 25 percent rhenium. The mass loss rate from a 2 percent thoriated rhenium cathode was found to be an order of magnitude greater than that observed using 2 percent thoriated tungsten. Detailed analysis of one of these cathode tips showed that the molten crater contained pure tungsten to a depth of about 150 microns. Problems with thermal stress cracking were encountered in the testing of a hafnium carbide tip. Post test analysis showed that the active area of the tip had chemically reacted with the propellant. A 100 hour continuous test was run at about 1 kW. Post test analysis revealed no dendrite formation, such as observed in a 30 kW arcjet lifetest, near the cathode crater. The cathodes from both this test and a previously run 1000 hour cycled test displayed nearly identical arc craters. Data and calculations indicate that the mass losses observed in testing can be explained by evaporation.

Curran, Francis M.↗

NASA NTRS1990

Synthesis, characterization and evaluation of CO-oxidation catalysts for high repetition rate CO2 TEA lasers

An extremely active class of noble metal catalysts supported on titania was developed and fabricated at Hughes for the recombination of oxygen (O2) and carbon monoxide (CO) in closed-cycle CO2 TEA lasers. The incipient wetness technique was used to impregnate titania and alumina pellets with precious metals including platinum and palladium. In particular, the addition of cerium (used as an oxygen storage promoter) produced an extremely active Pt/Ce/TiO2 catalyst. By comparison, the complementary Pt/Ce/ gamma-Al2O3 catalyst was considerably less active. In general, chloride-free catalyst precursors proved critical in obtaining an active catalyst while also providing uniform metal distributions throughout the support structure. Detailed characterization of the Pt/Ce/TiO2 catalyst demonstrated uniform dendritic crystal growth of the metals throughout the support. Electron spectroscopy for Chemical Analysis (ESCA) analysis was used to characterize the oxidation states of Pt, Ce and Ti. The performance of the catalysts was evaluated with an integral flow reactor system incorporating real time analysis of O2 and CO. With this system, the transient and steady-state behavior of the catalysts were evaluated. The kinetic evaluation was complemented by tests in a compact, closed-cycle Hughes CO2 TEA laser operating at a pulse repetition rate of 100 Hz with a catalyst temperature of 75 to 95 C. The Pt/Ce/TiO2 catalyst was compatible with a C(13)O(16)2 gas fill.

Moser, Thomas P.↗

NASA NTRS1989

Solidification processing of monotectic alloy matrix composites

Directionally solidified aluminum-indium alloys of the monotectic composition were found to form an in situ rod composite which obeys a lambda exp 2 R = constant relation. The experimental data shows good agreement with previously reported results. A theoretical boundary between cellular and dendritic growth conditions was derived and compared with experiments. The unique wetting characteristics of the monotectic alloys can be utilized to tailor the interface structure in metal matrix composites. Metal matrix composites with monotectic and hypermonotectic Al-In matrices were made by pressure infiltration, remelted and directionally solidified to observe the wetting characteristics of the alloys as well as the effect on structure of solidification in the constrained field of the fiber interstices. Models for monotectic growth are modified to take into account solidification in these constrained fields.

Frier, Nancy L.↗

NASA NTRS1990

Transient magmatic convection prolonged by solidification

Fluid dynamic experiments have been conducted on the solidification of a paraffin layer, in order to elucidate the transient stage of convection created in cooling magma by the fact that strong changes in viscosity with crystallization lock up within an inwardly propagating crust much buoyancy that would otherwise be available to drive convection. The interior of the magma remains isothermal, and the temperature decreases uniformly until it is locked at the convective liquidus; the crystals are fine hairlike dendrites without major compositional differentiations. Measurements over time are presented of crust thickness, convective velocity, and heat transfer.

Brandeis, Genevieve↗

NASA NTRS1990

Compression behavior of the forged Ll2 compounds Al67Ti25Cr8 and Al66Ti25Mn9

The paper presents the findings of a compression study as a function of temperature from cryogenic temperatures to 1373 K at a strain rate of about 0.0001/s on forged Al67Ti25Cr8 and Al66Ti25Mn9 compounds. The creep response of these alloys is analyzed at strain rates varying from 2 x 10 to the -4th to 2 x 10 to the -7th /s at 1000 K and 1100 K. It is shown that as-cast microstructures for both compounds are dendritic, while both intermetallics forged very well with no edge cracking, with the microstructures appearing fully recrystallized. True comprehensive stress-strain diagrams determined at 1100 K as a function of nominal strain rate reveal a range of behaviors in both materials.

Brown, S. A.↗

NASA NTRS1991

Modified Furnace Makes More Silicon Ribbon

Simple change in lid and heat shields makes faster growth rates possible. In modified furnace, slots in shields making up lid grow progressively wider from bottom to top of lid. Allows ribbon to cool faster by radiation. Result, crucible maintains at higher temperature, 5.8-cm-wide ribbon thicker, and ribbon is pulled faster. Used in pilot production line to demonstrate dendritic-web technology.

Piotrowski, Paul A.↗

NASA NTRS1989

The influence of advanced processing on PWA 1480

High thermal gradient casting of PWA 1480 was evaluated as an avenue for reducing the size of casting porosity. Hot isostatic pressing (HIP) was also employed for the elimination of casting pores. An alternate to the standard PWA 1480 coating plus diffusion bonding aging heat treatment cycle was also evaluated for potential improvements in the properties of interest to the Space Shuttle Main Engine (SSME) application. Microstructural changes associated with the high thermal gradient casting process were quantified by measurement of the size and density of the casting porosity, the amount of retained casting eutectic, and dendrite arm spacings. The results of the advanced processing have shown an improvement in material microstructure due to high thermal gradient casting. Improved homogeneity of PWA 1480 is advantageous in providing an improved solution heat treatment window and, potentially, easier HIP. High thermal gradient casting improves fatigue life by reducing casting pore size. The alternate heat treatment improves the balance of strength and ductility which appears to improve low cycle fatigue life, but with a reduction in short time stress rupture life. Based upon these tests, hot isostatic pressing appears to afford further improvements in cyclic life, though additional evaluation is suggested. Development of the alternate heat treatment is not recommended due to the reduced stress rupture capability and the need to develop a new properties data base. High thermal gradient casting and HIP are recommended for application to single crystal castings.

Fritzemeier, L. G.↗

NASA NTRS1989

Millimeter wave radiative transfer studies for precipitation measurements

Scattering calculations using the discrete dipole approximation and vector radiative transfer calculations were performed to model multiparameter radar return and passive microwave emission for a simple model of a winter storm. The issue of dendrite riming was addressed by computing scattering properties of thin ice disks with varying bulk density. It was shown that C-band multiparameter radar contains information about particle density and the number concentration of the ice particles. The radiative transfer modeling indicated that polarized multifrequency passive microwave emission may be used to infer some properties of ice hydrometers. Detailed radar modeling and vector radiative transfer modeling is in progress to enhance the understanding of simultaneous radar and radiometer measurements, as in the case of the proposed TRMM field program. A one-dimensional cloud model will be used to simulate the storm structure in detail and study the microphysics, such as size and density. Multifrequency polarized radiometer measurements from the SSMI satellite instrument will be analyzed in relation to dual-frequency and dual-polarization radar measurements.

Vivekanandan, J.↗

NASA NTRS1990

Dynamic crystallization study of barred olivine chondrules

The 'classic' barred olivine (BO) texture was defined by Donaldson (1976) as a single-plate dendrite which shares the entire chondrule with the remaining glass or subsequent crystallization products. This paper describes experiments in which BO textures were produced experimentally from two starting compositions: one modeled after the average BO chondrule composition in L-chondrites determined by Weisberg (1987), and the other after an olivine-rich composition (CH-1) studied by Lofgren (1989). It is shown that most of the textural features observed in natural BO chondrules are replicated in the experimentally produced chondrules. Several new constraints on models for the chondrule-forming process are proposed.

Lofgren, Gary↗

NASA NTRS1990

On the facet-skeletal transition of snow crystals - Experiments in high and low gravity

A laboratory investigation of the influence of air velocity on the growth of columnar ice crystals from the vapor over the range -3 to -5 C shows that the linear growth velocity increases and that columns transform to sheath crystals or needles as air velocity increases from a few cm/s to 40 cm/s. Comparison with a similar transition of plates to dendrites shows that, macroscopically, in both cases the facets sprout rounded tips at a critical velocity which is lower for higher ambient supersaturation. Studies in low gravity show that chamber scale convection under normal gravity may have significant influence on growth even in the absence of an imposed air velocity. Falling snow crystals become more skeletal in shape as they grow and fall with increasing velocity. This development depends critically on temperature (+ or - 0.5 C) and demonstrates that the snow crystal shape is even more dependent on environmental growth conditions that previously thought.

Alena, T.↗

NASA NTRS1992

Conditions Of Directional Solidification Affect Superalloy

Report describes experiments to determine effects of gradient of temperature and rate of solidification on microstructure and fatigue properties of nickel-based superalloy MAR-M246(Hf). Enhancement of properties extends lifespans of objects, including turbo-pump blades of Space Shuttle Main Engines. Results indicate significant improvements in fatigue properties derived through manipulation of parameters of directional solidification. Particularly MAR-M246(Hf) for turbine blades contains small, well-dispersed blocky carbide and microstructure with small distances between dendrite arms, and without eutectic phase.

Schmidt, D. D.↗

NASA NTRS1989

The Marr and Albus Theories of the Cerebellum: Two Eary Models of Associative Memory

The Marr and Albus theories of the cerebellum are compared and contrasted. They are shown to be similar in their analysis of the function of the mossy fibers, granule cells, Golgi cells, and Purkinje cells. They both predict motor learning in the parallel fiber synapses on the Purkinje dendrites mediated by concurrent climbing fiber input. This prediction has been confirmed by experimental evidence. In contrast, Marr predicts these synapses would be facilitated by learning, while Albus predicts they would be weakened. Experimental evidence confirms synaptic weakening.

Albus, James S.↗

NASA NTRS1990

Atomic oxygen durability of solar concentrator materials for Space Station Freedom

The findings are reviewed of atomic oxygen exposure testing of candidate solar concentrator materials containing SiO2 and Al2O3 protective coatings for use on Space Station Freedom solar dynamic power modules. Both continuous and iterative atomic oxygen exposure tests were conducted. Iterative air plasma ashing resulted in larger specular reflectance decreases and solar absorptance increases than continuous ashing to the same fluence, and appears to provide a more severe environment than the continuous atomic oxygen exposure that would occur in the low Earth orbit environment. First generation concentrator fabrication techniques produced surface defects including scratches, macroscopic bumps, dendritic regions, porosity, haziness, and pin hole defects. Several of these defects appear to be preferential sites for atomic oxygen attack leading to erosive undercutting. Extensive undercutting and flaking of reflective and protective coatings were found to be promoted through an undercutting tearing propagation process. Atomic oxygen erosion processes and effects on optical performance is presented.

Degroh, Kim K.↗

NASA NTRS1992

Device for mechanically stabilizing web ribbon buttons during growth initiation

The invention relates to a stabilization device for stabilizing dendritic web seed buttons during initiation of crystal growth from a float melt zone. The invention includes angular maintenance means for maintaining a constant angular orientation between the axis of a growth initiation seed and the upper surface of a web button during withdrawal of the web button from the melt. In the preferred embodiment, the angular means includes an adjustable elevation tube which surrounds the seed, the weight of which may be selectively supported by the seed button during web button withdrawal.

Henry, Paul K.↗

NASA NTRS1992

An optical study of grain formation: Casting and solidification technology (2-IML-1)

By studying the unidirectional growth of a metal-model material in microgravity, an attempt is made to characterize alloy solidification. Using holograms and supporting temperature measurements obtained during processing in the Fluids Experiment System (FES), the solute and thermal fields associated with the dendrite growth front and extraneous nucleation will be measured and compared to a theoretical (computational) model. Ground based supporting experiments include particle tracking to measure the velocity fields, and optical phase shift techniques (confocal optical signal processing, interferometry, and Schlieren) to study thermal and solutal fields.

Mccay, Mary H.↗