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At least 541 records · Page 30

Control of nucleation and growth in protein crystal growth

The potential advantages of nucleation and growth control through temperature, rather than the addition of precipitants or removal of solvent, are discussed. A simple light scattering arrangement for the characterization of nucleation and growth conditions in solutions is described. The temperature dependence of the solubility of low ionic strength lysozyme solutions is applied in preliminary nucleation and growth experiments.

Rosenberger, Franz↗

'Fluffy' Type A Ca-, Al-rich inclusions in the Allende meteorite

Inclusions called 'fluffy' Type A's or FTA's in the Allende meteorite are examined as possible candidates for relict vapor-solid condensate grains, remaining from the original solar nebula. Type A inclusions are characterized by abundant melilite and absence of primary anorthite and titaniferous pyroxene. Fluffy Type A's were probably loosely bound clumps of crystals drifting in the solar nebula, analogous to dustballs or snowflakes. Polished thin sections of all samples were studied optically and with a JEOL JSM-35 scanning electron microscope. It is reasonably clear that neither whole FTA's nor constituent nodules of the coarser grained ones were ever molten. Despite solid-state recrystallization which has affected these inclusions to varying degrees, the coarser grained material remaining in many of them is probably a relic of vapor-solid condensation in the solar nebula.

Macpherson, G. J.↗

Optical Correlation

Pattern recognition may supplement or replace certain navigational aids on spacecraft in docking or landing activities. The need to correctly identify terrain features remains critical in preparation of autonomous planetary landing. One technique that may solve this problem is optical correlation. Correlation has been successfully demonstrated under ideal conditions; however, noise significantly affects the ability of the correlator to accurately identify input signals. Optical correlation in the presence of noise must be successfully demonstrated before this technology can be incorporated into system design. An optical correlator is designed and constructed using a modified 2f configuration. Liquid crystal televisions (LCTV) are used as the spatial light modulators (SLM) for both the input and filter devices. The filter LCTV is characterized and an operating curve is developed. Determination of this operating curve is critical for reduction of input noise. Correlation of live input with a programmable filter is demonstrated.

Cotariu, Steven S.↗

Parameterizations of the Vertical Variability of Tropical Cirrus Cloud Microphysical and Optical Properties

Our multi-investigator effort was targeted at the following areas of interest to CRYSTAL-FACE: (1) the water budgets of anvils, (2) parameterizations of the particle size distributions and related microphysical and optical properties (3) characterizations of the primary ice particle habits, (4) the relationship of the optical properties to the microphysics and particle habits, and (5) investigation of the ice-nuclei types and mechanisms in anvil cirrus. Dr. Twohy's effort focused on (l), (2), and (5), with the measurement and analysis of ice water content and cirrus residual nuclei using the counterflow virtual impactor (CVI).

Twohy, Cynthia↗

Particle Size Calibration Testing in the NASA Propulsion Systems Laboratory

The particle size characterization portion of the 2017 Propulsion Systems Laboratory (PSL) Cloud Calibration is described. The work focuses on characterizing the particle size distribution of the icing cloud as a function of simulated atmospheric conditions.These results will aid in upcoming ice crystal and supercooled liquid icing tests in PSL. Measurements acquired with the Phase Doppler Interferometer and High Speed Imaging instruments are presented. Experimental results indicate that the particle size distribution is primarily a function nozzle air and water pressures, and that air speed is not a significant effect for ice crystal clouds in PSL and both thermodynamic conditions and air speed are not significant effects for supercooled liquid water clouds in PSL.

Engine icing↗

Particle Size Calibration Testing in the NASA Propulsion Systems Laboratory

The particle size characterization portion of the 2017 Propulsion Systems Laboratory (PSL) Cloud Calibration is described. The work focuses on characterizing the particle size distribution of the icing cloud as a function of simulated atmospheric conditions.These results will aid in upcoming ice crystal and supercooled liquid icing tests in PSL. Measurements acquired with the Phase Doppler Interferometer and High Speed Imaging instruments are presented. Experimental results indicate that the particle size distribution is primarily a function nozzle air and water pressures, and that air speed is not a significant effect for ice crystal clouds in PSL and both thermodynamic conditions and air speed are not significant effects for supercooled liquid water clouds in PSL.

Engine Icing↗

Developing a Novel Platform for Characterizing Thermoelectric Materials for Uncooled Detectors for Land Imaging Applications

Thermal land imaging (imaging at ~8-14 micron optical wavelength) is an essential tool for understanding and managing terrestrial freshwater resources. Current thermal imaging instruments employ low temperature detectors, which require cryocoolers. Consequently, cost-saving reductions in size, weight, and power can be achieved by employing uncooled detectors. One uncooled detector concept, which NASA is pursuing, is a thermopile detector with sub-micron thick doped-Si thermoelectric materials. In order to characterize the thermoelectric properties of the doped silicon, we designed and optimized a novel apparatus. This simple apparatus measures the Seebeck coefficient with thermally isolated stages and LABVIEW automation. We optimized thermal stability using PID tuning and optimized the thermal contact between the thin film samples and stages using electrically conductive springs. Utilizing our apparatus, we measured the Seebeck coefficient of 0.45 micron thick phosphorus-doped single crystal Si samples bonded to alumina substrates. Using these Seebeck coefficient measurements and four-wire electrical resistivity measurements, we determined the relationship between the thermoelectric figure of merit and dopant concentration. These characterization results for doped-Si will guide our thermopile detector design to provide an optimal and competitive detector alternative for future thermal imaging instruments.

Reid, Riley A.↗

Further characterization of spectral features attributable to titanium on the moon

The following transitions are observed in the electronic absorption spectra of lunar titanaugites: Fe(2+) spin-allowed and spin-forbidden crystal field; Ti(3+) spin allowed and Jahn-Teller split crystal field; Ti(3+)-Ti(4+) CT; Fe(2+)-Ti(4+) CT; and O(2-)-Fe(2+), Ti(3+), Ti(4+) CT. Of these, the transitions involving Ti(3+) are unique to lunar or nonferric-bearing titanaugites. All titanaugites have the Fe(2+) crystal field and Fe(2+)-Ti(4+) CT transitions in common. These features in the diffuse reflectance spectra of lunar materials give rise to the '1.0 band' and to the observed absorption around 0.5-0.6 micron, respectively. Since regolith contains a variety of phases with coexisting Fe(2+), Ti(3+), and Ti(4+) ions, several metal-metal charge transfer processes are possible.

Burns, R. G.↗

Analytical ultrasonics for characterization of metallurgical microstructures and transformations

The application of contact (piezoelectric) and noncontact (laser generation and detection) ultrasonic techniques for dynamic investigation of precipitation hardening processes in aluminum alloys, as well as crystallization and phase transformation in rapidly solidified amorphous and microcrystalline alloys is discussed. From the variations of the sound velocity and attenuation the precipitation mechanism and kinetics were determined. In addition, a correlation was established between the observed changes in the velocity and attenuation and the mechanical properties of age-hardenable aluminum alloys. The behavior of the elastic moduli, determined ultrasonically, were found to be sensitive to relaxation, crystallization and phase decomposition phenomena in rapidly solidified metallic glasses. Analytical ultrasonics enables determination of the activation energies and growth parameters of the reactions. Therefrom theoretical models can be constructed to explain the changes in mechanical and physical properties upon heat treatment of glassy alloys. The composition dependence of the elastic moduli in amorphous Cu-Zr alloys was found to be related to the glass transition temperature, and consequently to the glass forming ability of these alloys. Dynamic ultrasonic analysis was found to be feasible for on-line, real-time, monitoring of metallurgical processes.

Rosen, M.↗

Radiative properties of visible and subvisible Cirrus: Scattering on hexagonal ice crystals

One of the main objectives of the First International Satellite Cloud Climatology Project (ISCCP) Regional Experiment (FIRE) is to provide a better understanding of the physics of upper level clouds. The focus is on just one specific aspect of cirrus physics, namely on characterizing the radiative properties of single, nonspherical ice particles. The basis for further more extensive studies of the radiative transfer through upper level clouds is provided. Radiation provides a potential mechanism for strong feedback between the divergence of in-cloud radiative flux and the cloud microphysics and ultimately on the dynamics of the cloud. Some aspects of ice cloud microphysics that are relevant to the radiation calculations are described. Next, the Discrete Dipole Approximation (DDA) is introduced and some new results of scattering by irregular crystals are presented. The Anomalous Diffraction Theory (ADT) was adopted to investigate the scattering properties of even larger crystals. In this way the scattering properties of nonspherical particles were determined over a range of particle sizes.

Flatau, Piotr J.↗

Sample 67955 - A description and a problem

Clasts in breccia sample 67955 contain relatively coarse olivine and plagioclase in part enveloped by poikilitic hypersthene and diopside. This distinctive texture is concluded to result from high temperature crystallization in the presence of a fluid phase, probably a silicate melt. A problem posed by this rock is whether the bulk chemistry, characterized by a high Mg/Fe ratio but low total Fe + Mg, is the result of primary igneous processes on the moon or whether it is the residual end product of a multiple distillation process resulting from repeated meteorite impacts.

Hollister, L. S.↗

Microstructure and mechanical properties of a single crystal NiAl alloy with Zr or Hf rich G-phase precipitates

The possibility of producing NiAl reinforced with the G-phase (Ni16X6Si7), where X is Zr or Hf, has been investigated. The microstructure of these NiAl alloys have been characterized in the as-cast and annealed conditions. The G-phases are present as fine cuboidal precipitates (10 to 40 nm) and have lattice parameters almost four times that of NiAl. They are coherent with the matrix and fairly resistant to coarsening during annealing heat treatments. Segregation and nonuniform precipitate distribution observed in as-cast materials were eliminated by homogenization at temperatures near 1600 K. Slow cooling from these temperatures resulted in large plate shaped precipitates, denuded zones, and a loss of coherency in some of the large particles. Faster cooling produced a homogeneous fine distribution of cuboidal G-phase particles in the matrix. Preliminary mechanical properties for the Zr-doped alloy are presented and compared to binary single crystal NiAl. The presence of these precipitates appears to have an important strengthening effect at temperatures not less than 1000 K compared to binary NiAl single crystals.

Locci, I. E.↗

Midlatitude Cirrus Clouds Derived from Hurricane Nora: A Case Study with Implications for Ice Crystal Nucleation and Shape

Hurricane Nora traveled up the Bala Peninsula coast in the unusually warm El Nino waters of September 1997, until rapidly decaying as it approached Southern California on 24 September. The anvil cirrus blowoff from the final surge of tropical convection became embedded in subtropical flow that advected the cirrus across the western US, where it was studied from the Facility for Atmospheric Remote Sensing (FARS) in Salt Lake City, Utah. A day later, the cirrus shield remnants were redirected southward by midlatitude circulations into the Southern Great Plains, providing a case study opportunity for the research aircraft and ground-based remote sensors assembled at the Clouds and Radiation Testbed (CART) site in northern Oklahoma. Using these comprehensive resources and new remote sensing cloud retrieval algorithms, the microphysical and radiative cloud properties of this unusual cirrus event are uniquely characterized. Importantly, at both the FARS and CART sites the cirrus generated spectacular optical displays, which acted as a tracer for the hurricane cirrus, despite the limited lifetimes of individual ice crystals. Lidar polarization data indicate widespread regions of uniform ice plate orientations, and in situ particle masticator data show a preponderance of pristine, solid hexagonal plates and columns. It is suggested that these unusual aspects are the result of the mode of cirrus particle nucleation, presumably involving the lofting of sea-salt nuclei in thunderstorm updrafts into the upper troposphere. This created a reservoir of haze particles that continued to produce halide-saltcontaminated ice crystals during the extended period of cirrus cloud maintenance. The reference that marine microliters are embedded in the replicas of ice crystals collected over the CART site points to the longevity of marine effects. Various nucleation scenarios proposed for cirrus clouds based on this and other studies, and the implications for understanding cirrus radiative properties or a global scale, are discussed.

Sassen, Kenneth↗

Advances in tunable diode laser technology

The improvement of long-term reliability, the purification of mode properties, and the achievement of higher-temperature operation were examined. In reliability studies a slow increase in contact resistance during room temperature storage for lasers fabricated with In-Au or In-Pt contacts was observed. This increase is actually caused by the diffusion of In into the surface layer of laser crystals. By using a three layered structure of In-Au-Pt or In-Pt-Au, this mode of degradation was reduced. In characterizing the mode properties, it was found that the lasers emit in a highly localized, filamentary manner. For widestripe lasers the emission occurs near the corners of the junction. In order to achieve single-mode operation, stripe widths on the order of 8-10 micrometers are needed. Also, it was found that room temperature electroluminescence is possible near 4.6 micrometers.

Lo, W.↗

Hyperthermal atomic oxygen generator

Characterization of the transport properties of oxygen through silver was continued. Specifically, experiments measuring the transport through Ag(111), Ag(110), Ag(100) single crystals and through Ag0.05 Zr alloy were completed. In addition, experiments using glow discharge excitation of oxygen to assist in the transport were completed. It was found that the permeability through the different orientations of single crystal Ag was the same, but significant differences existed in the diffusivity. The experimental ratio of diffusivities, however, was in reasonable agreement with theoretical estimates. Since the solubilities of orientations must be the same, this suggests some problems with the assumption K = DS. The glow discharge experiments show that there is a substantial increase in transport (factor of six) when the upstream pressure is dissociated to some fraction of atoms (which have a much higher sticking coefficient). These results indicate that there is a significant surface limitation because of dissociative adsorption of the molecules. Experiments with the Ag0.05 Zr alloy and its high-grain boundary and defect density show a permeability of greater than a factor of two over ordinary polycrystalline Ag, but it is unclear as to whether this is because of enhanced transport through these defects or whether the Zr and defects on the surface increased the sticking coefficient and therefore the transport.

Khandelwal, Govind S.↗

Parametric amplification in AgGaSe2

AgGaSe2 has been grown, annealed, and characterized for the mid-IR. Characterization includes measurement of the average power-limiting factors including absorption and the variation of the refractive indices with temperature. Using specially annealed crystals 20 mm long and a Ho:YAG pump, parametric amplification at 3.39 microns has achieved a gain of 2.9 with a peak power input of only 8 MW/sq cm.

Barnes, Norman P.↗

Aviation Safety Program Atmospheric Environment Safety Technologies (AEST) Project

Engine Icing: Characterization and Simulation Capability: Develop knowledge bases, analysis methods, and simulation tools needed to address the problem of engine icing; in particular, ice-crystal icing Airframe Icing Simulation and Engineering Tool Capability: Develop and demonstrate 3-D capability to simulate and model airframe ice accretion and related aerodynamic performance degradation for current and future aircraft configurations in an expanded icing environment that includes freezing drizzle/rain Atmospheric Hazard Sensing and Mitigation Technology Capability: Improve and expand remote sensing and mitigation of hazardous atmospheric environments and phenomena

Colantonio, Ron↗