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At least 541 records · Page 30

Redox gating-induced modulation of charge carrier density and lattice expansion in LaNiO 3 thin films

Redox gating involves the use of reversible redox functionalities combined with ionic electrolytes to substantially alter the charge carrier density in functional condensed materials. This modification leads to the emergence of physical properties not observed in the original material. Here, in our study, we focus on redox gating applied to a LaNiO 3 (001) film within a field-effect device and identify a critical gate voltage of 0.7 V. Hall measurements indicate that redox gating markedly increases the charge carrier density in LaNiO 3 , reaching over 10 14 cm −2 . This increase is primarily due to the injection of electrons into LaNiO 3 , which offsets the existing hole carriers. These adjustments in the carrier concentration result in reversible lattice expansion in LaNiO 3 when gate voltages are below 0.7 V. This expansion correlates well with theoretical models that consider adjustments to the Ni–O bond length, influenced by oxygen ligand holes. Conversely, at gate voltages above 0.7 V, there are significant changes in resistivity, lattice structure, and Ni valence, stemming from the formation of oxygen vacancies in the LaNiO 3 film.

36 MATERIALS SCIENCE↗

A two-dimensional numerical study of the magneto-Rayleigh–Taylor instability with FLASH: Application to the staged Z-pinch concept

Magnetically driven implosions involving a liner collapsing onto a target are inherently vulnerable to the magneto-Rayleigh–Taylor instability (MRTI). Among the various approaches proposed to achieve fusion conditions within the target, the staged Z-pinch (SZP) concept employs a high-Z liner, the advantages of which remain an active area of investigation. Consequently, ongoing design optimization efforts are essential, while critical physical processes such as magnetic field (B-field) diffusion and radiation transport increase the complexity of required simulations. In this study, we utilize the new capabilities of the FLASH code to simulate in 2D, for the first time using this code, staged Z-pinch configurations (designated SZP1 and SZP1*), focusing on their stability. First, a comparison of simulation results with theoretical predictions of MRTI growth provide new insights into the often-overlooked influences of high mesh resolution and initial perturbation seeding on instability dynamics. These findings then lead to a discussion on potential improvements for future SZP experiments. These include the use of an axial B-field stabilization and the optimization of radiation transport processes during the implosion. The results presented herein establish the framework for simulating multi-dimensional Z pinches using the FLASH code and pave the way for the development of innovative experimental configurations leveraging its advanced simulation capabilities.

Adaptive mesh refinement↗

Theory of the strange metal Sr 3 Ru 2 O 7

The bilayer perovskite Sr 3 Ru 2 O 7 has been widely studied as a canonical strange metal. It exhibits T -linear resistivity and a T log(1/ T ) electronic specific heat in a field-tuned quantum cr itical fan. Criticality is known to occur in “hot” Fermi pockets with a high density of states close to the Fermi energy. We show that while these hot pockets occupy a small fraction of the Brillouin zone, they are responsible for the anomalous transport and thermodynamics of the material. Specifically, a scattering process in which two electrons from the large, “cold” Fermi surfaces scatter into one hot and one cold electron renders the ostensibly noncritical cold fermions a marginal Fermi liquid. From this fact the transport and thermodynamic phase diagram is reproduced in detail. To conclude, we show that the same scattering mechanism into hot electrons that are instead localized near a 2D van Hove singularity explains theanomalous transport observed in strained Sr 2 RuO 4 .

36 MATERIALS SCIENCE↗

Holography of the photon ring

Space-based next-generation interferometers propose to measure the Lyapunov exponents of the nearly bound geodesics that comprise the photon ring surrounding the black hole M87*. We argue that these classical Lyapunov exponents equal the quantum Ruelle resonances describing the late-time approach to thermal equilibrium of the quantum microstate holographically dual to any Kerr black hole such as M87*. Moreover, we identify 'near-ring regions' in the phase space of fields propagating on Kerr that exhibit critical behavior, including emergent conformal symmetries. These are analogues for sub-extremal Kerr of the much-studied 'near-horizon regions' of (near-)extremal black holes. Here, the emergent conformal symmetries greatly constrain the observational predictions for the fine photon ring substructure around M87* and for quasinormal gravitational-wave ringdowns, as well as any proposal for a quantum holographic dual to the Kerr black hole. More generally, we hope that our identification of several universal features of Kerr spectroscopy provides a useful starting point for a bottom-up approach to holography for astrophysical black holes.

79 ASTRONOMY AND ASTROPHYSICS↗

Meta-uncertainty for particle image velocimetry

Uncertainty quantification for Particle Image Velocimetry (PIV) is critical for comparing experimentally measured flow fields with Computational Fluid Dynamics (CFD) results, and model design and validation. However, PIV features a complex measurement chain with coupled, non-linear error sources, and quantifying the uncertainty is challenging. Multiple assessments show that none of the current methods can reliably measure the actual uncertainty across a wide range of experiments, and estimates can vary. Because the current methods differ in assumptions regarding the measurement process and calculation procedures, it is not clear which method is best to use for an experiment where the error distribution is unknown. To address this issue, we propose a method to estimate an uncertainty method's sensitivity and reliability, termed the Meta-Uncertainty. The novel approach is automated, local, and instantaneous, and based on perturbation of the recorded particle images. We developed an image perturbation scheme based on adding random unmatched particles to the interrogation window pair considering the signal-to-noise (SNR) of the correlation plane. Each uncertainty scheme's response to several trials of random particle addition is used to estimate a reliability metric, defined as the rate of change of the inter-quartile range (IQR) of the uncertainties with increasing levels of particle addition. We also propose applying the meta-uncertainty as a weighting metric to combine uncertainty estimates from individual schemes, based on ideas from the consensus forecasting literature. We use planar and stereo PIV measurements across a range of canonical flows to assess the performance of the uncertainty schemes. Further, a novel method is introduced to assess an uncertainty scheme's performance based on a quantile comparison of the error and uncertainty distributions, generalizing the current method of comparing the RMS of the two distributions. Here, the results show that the combined uncertainty method outperforms the individual methods, and this work establishes the meta-uncertainty as a useful reliability assessment tool for PIV uncertainty quantification.

47 OTHER INSTRUMENTATION↗

Status of the development and testing of in-vessel and ECH-protection components for the ITER low-field side reflectometer

The ITER Low-Field Side Reflectometer (LFSR) is a critical diagnostic system designed to measure edge electron density profiles, fluctuations, and plasma rotation in ITER. This paper presents the latest developments in the design, testing, and validation of key in-vessel and Electron Cyclotron Heating (ECH) protection components. The LFSR antenna array has been optimized to provide robust coverage over expected plasma vertical displacements and a Doppler measurement for plasma rotation. Further, a comprehensive assessment of a 170-GHz diffraction grating and a novel stray-ECH power monitor demonstrates effectiveness in mitigating the impact of stray ECH power on sensitive microwave electronics. Additionally, an advancement in anti-reflective technology for millimeter waves significantly improves transmission of LFSR's vacuum window while meeting ITER's stringent safety and operational requirements. These results support the continued integration of LFSR into ITER, ensuring its diagnostic capabilities remain resilient under reactor-relevant conditions.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Diagnostic x-ray source using electrons produced by a 100 J-class picosecond laser

Many laser-based high-energy-density science (HEDS) facilities have one or more short-pulse (sub- to few-picosecond) laser beams for diagnostics. For the past decade, we have been developing a novel x-ray probing capability using such picosecond lasers interacting with an underdense plasma to produce relativistic electrons. The ultimate goal of these experiments is to demonstrate a new type of x-ray backlighter using the short-pulse ARC laser at the National Ignition Facility (NIF). Before this diagnostic is fielded at the NIF, it is critical to demonstrate the viability and reproducibility of the x-ray source on comparable high-power short-pulse laser systems. We present experiments that were carried out with the OMEGA EP laser at the University of Rochester’s laboratory for laser energetics. In these experiments, high-energy electrons are produced through a combination of the self-modulation instability and direct laser acceleration in an underdense gas jet. These electrons generate directional x-rays with characteristic energies up to several tens of keV as they execute betatron motion in the ion channel, and the inverse Compton scattering process generates even harder x-rays, with characteristic photon energies of 60–240 keV. When implemented on the OMEGA EP laser(s), this x-ray source yields results that are comparable to those obtained recently on the short-pulse Titan laser at the Jupiter Laser Facility at Lawrence Livermore National Laboratory, after accounting for differences in laser energy, peak intensity, focusing f/#, and plasma source. Applications of such an x-ray source for HEDS experiments are discussed.

backlighter↗

Monitored Fluctuating Hydrodynamics

We introduce a hydrodynamic framework for describing monitored classical stochastic processes. We study the conditional ensembles for these monitored processes—i.e., we compute spacetime correlation functions conditioned on a fixed, typical measurement record. In the presence of global symmetries we show that these conditional ensembles can undergo measurement-induced “sharpening” phase transitions as a function of the monitoring rate; moreover, even weak monitoring can give rise to novel critical phases, derived entirely from a classical perspective. We give a simple hydrodynamic derivation of the known “charge-fuzzy phase” for weakly monitored diffusive many-body quantum systems. We show that although the unmonitored symmetric and asymmetric exclusion processes are in different universality classes of transport, the fluctuations in their conditional ensembles flow to the same fixed point with emergent relativistic invariance under monitoring. On the other hand, weakly monitored systems with non-Abelian symmetries enter a novel strongly coupled fixed point with nontrivial dynamical exponent, which we characterize. Our formalism naturally accounts for monitoring general observables, such as currents or density gradients, and allows for a direct calculation of information-theoretic diagnostics of sharpening transitions, including the Shannon entropy of the measurement record.

classical statistical mechanics↗

Stray-Capacitance As a Simple Tool for Monitoring and Locating Heat Generation Demonstrated in Three Superconducting Magnets

Real-time monitoring of heat loads in cryogenic systems is critical for many applications, particularly high field magnets. In this work, we demonstrated that by monitoring changes in the capacitance of local probes consisting of thin metal strips with a porous glass fiber dielectric, boiling helium from as little as 0.1 J of deposited heat can be located by an analysis of the response speed and amplitude in nearby probes. We further implemented stray-capacitance monitoring of a magnet's metal support structures, a more global probe of the magnet volumes, in three high temperature superconducting Bi-2212 magnet types. Global structural stray-capacitance monitoring was evaluated for a single racetrack coil, a common coil dipole, and a canted cosine theta winding, showing a quench response comparable to voltage signals without inductive effects. The response of the local and global probes was compared in the single racetrack coil with well-known quench properties. Monitoring the cool-down of the common coil dipole demonstrated the added benefit of the global stray-capacitance as a liquid level monitor. This simple method of monitoring the capacitance has proven to be a versatile and robust technique for monitoring and locating heat.

43 PARTICLE ACCELERATORS↗

New capabilities of the MORET 6 Monte Carlo neutron transport code

The MORET code is a simulation tool that solves the transport equation for neutrons using the Monte Carlo method. It allows users to model complex three-dimensional geometrical configurations in a user-friendly way. New features have been introduced to extend the application field of MORET beyond the usual criticality calculations for which it has been initially designed. The most important change is the addition of an analog fixed source mode which allows studies of systems of any reactivity combined with very flexible outputs. Other useful improvements have been added concerning the geometric part, the fission matrix, the multigroup sensitivity coefficients and the outputs. This paper presents an overview of these new features. (authors)

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Evaluation of Ceramic Heat Exchanger for Next-Generation Concentrated Solar Power

The U.S. Department of Energy has identified a third generation of concentrated solar power (Gen3 CSP) technologies to minimize cost of CSP produced electricity. By developing these technologies further, it is forecasted that Gen3 CSP will meet the levelized cost of electricity (LCOE) SunShot target of 6 cents/kWh to compete with dominant, conventional nonrenewable energy sources (1). The focus for advancing CSP systems for Gen3 is to increase overall system efficiency. Thus, reevaluating second-generation systems, superheated steam-turbine power cycles, and implementing more advanced power cycles is essential. Specifically, it has been identified that a supercritical carbon dioxide (sCO 2 ) Brayton cycle can increase the net thermal-to-electric efficiency to over 50% for CSP power tower configurations (2). Compared to conventional superheated steam Rankine cycle systems, more extreme operating conditions are required and pose critical barriers to overcome in the field of materials and manufacturing for Gen3 CSP.

14 SOLAR ENERGY↗

Workforce Development Programs [Slides]

As educational institutions of New Mexico, develop educational, training, and research programs in support of the pit manufacturing related STEM fields, which directly benefit LANL with critical hires.

99 GENERAL AND MISCELLANEOUS↗

Fabrication of Nb3Sn by Magnetron Sputtering for Superconducting Radiofrequency Application

Particle accelerators are considered as an important device that has wide applications in cancer treatment, sterilizing waste, preserving foods, ion implantation in semiconductor industry, and in production of isotopes for medical applications. Superconducting radiofrequency (SRF) cavities are the building blocks of a linear particle accelerator. Current particle accelerators use niobium (Nb) superconductors as the sheet material to fabricate a single SRF cavity for particle acceleration. With better superconducting properties (critical temperature Tc ~ 18.3 K, superheating field Hsh~ 400 mT), Nb3Sn is considered a potential candidate in SRF technology. Magnetron sputtering is a promising deposition method to fabricate Nb3Sn thin films inside SRF cavities. Superconducting Nb3Sn films were fabricated on Nb and sapphire substrates by magnetron sputtering from a single stoichiometric Nb3Sn target, by multilayer sputtering of Nb and Sn followed by annealing, and by co-sputtering of Nb and Sn followed by annealing. The variation of morphological and superconducting properties was investigated for different substrate temperatures, annealing temperatures, annealing durations, and thicknesses. The film properties were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), atomic force microscopy (AFM), and energy dispersive X-ray spectroscopy (EDS). The films had crystalline Nb3Sn structure without any presence of poor superconducting Nb6Sn5 and NbSn2 phases. The highest Tc of the films fabricated from the stoichiometric target, multilayer sputtering and co-sputtering were 17.44, 17.93, and 17.66 K respectively. Finally, a cylindrical sputter coater with two identical magnetrons was designed and commissioned to fabricate Nb3Sn films inside a 2.6 GHz SRF cavity. The magnetrons were installed facing opposite to each other in a custom designed vacuum chamber and multilayers of Nb and Sn films on 1 cm2 Nb substrates replicating the beam tubes and equator locations of the cavity and the coated multilayered films were annealed at 950 °C for 3 h. The XRD of the as?deposited and annealed films confirmed the formation of Nb3Sn after the annealing. The dissertation discusses the fabrication process, characterized results of the fabricated films, the design of the cylindrical sputter coater and the preliminary data obtained from the sputter coater.

Sayeed, Md Nizam↗

Josephson behavior in a metal-decorated topological-insulator Bi 0.91 Sb 0.09

We have fabricated W nanoscale clusters on a topological insulator Bi 0.91 Sb 0.09 . The W island arrays effectively induce two-dimensional superconductivity at the surface of Bi 0.91 Sb 0.09 via the superconducting proximity effect. We find that this heterostructure behaves as a dynamic Josephson junction, which shows a Fraunhofer-like pattern of the critical current versus the applied magnetic field. Microwave irradiation experiments reveal the existence of a 4π-periodic supercurrent carried by the topological surface state. Our results open up a route to induce topological superconductivity in a topological insulator.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Verification and Validation of Open-Source Computational Fluid Dynamics Capabilities in MOOSE

The Multiphysics Object Oriented Simulation Environment (MOOSE) advances predictive modeling in nuclear research by simplifying the application design process and making modeling more efficient and accessible to researchers and the broader community. Because of MOOSE’s critical role in the scientific computation field, verification and validation are important to evaluate the reliability and credibility of MOOSE’s code, simulations, and models. To assess MOOSE’s Navier Stokes module and turbulence models, the following verification and validation University of Manchester ERCOFTAC cases were simulated in MOOSE, and the results were compared: Case 032 Turbulent Flow in a 2D Channel Case 079 Natural Convection in an Enclosed Cavity

46 - INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AN↗

Distribution of rare earth elements and other critical elements in beneficiated Pennsylvania anthracites

The Pennsylvania Anthracite Fields are in a complex tectonic and metamorphic terrain, historically hosting one of the largest concentrations of coal mining in the USA. Anthracite mining now largely consists of the surface mining of the pillars remaining from the prime years of underground mining. The geochemical study of the sized coal products and the refuse (largely rock) from three preparation plants (breakers) demonstrates that Principal components analysis (PCA) of select major oxide, minor element, and rare earth elements illustrates some differentiation among the products from the individual plants. The rock samples, with abundant quartz and metamorphic Al-Si minerals and with a lower ash-basis REE concentration than the coals, were distinctly separated from the coal samples on the PCA plots. Plots of Gd N /Gd N * vs. Eu N /Eu N * and Ce N /Ce N * vs. Eu N / Eu N * showed differentiation between the individual suites of coals showed that the refuse samples had distinct REE distributions compared to the associated coals. Further, several minor and trace elements show enrichments in the coal samples. Lithium, with concentrations of up to 314 ppm on an ash basis, is among the most promising of the critical elements, exceeding the enrichment of the REY and Sc.

58 GEOSCIENCES↗