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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 541 records · Page 30

Experimental Calibration of a Numerical Model of Prepreg Tack for Predicting AFP Process Related Defects

Wrinkles, puckers, and fiber bridging are among the major defects encountered in the Automated Fiber Placement (AFP) process, and are all different manifestations of fiber misalignment. The main driver for these defects are the residual stresses introduced in the tow during the deposition stage by the AFP head. In contrast, the tack between the deposited tape and the substrate is the resisting force against the formation of such defects. Tack may be defined as the ability of a material to form a bond immediately on contact with another surface. Tack is a very complex phenomenon that is influenced by a variety of process parameters including temperature, head pressure and speed, as well as degree of cure, moisture content, and surface roughness A physics-based modeling framework for simulation of tack was developed in this study that allows for prediction of tack response. The developed tack model is incorporated in the AFP placement modelling framework developed to simulate AFP defects.

Forghani, Alireza↗

Wear and friction of oxidation-resistant mechanical carbon graphites at 650 C in air

Studies were conducted to determine the friction and wear properties of experimental carbon-graphites. Hemispherically tipped carbon-graphite rider specimens were tested in sliding contact with rotating Inconel X-750 disks in air. A surface speed of 1.33 m/sec, a load of 500 g, and a specimen temperature of 650 C were used. Results indicate: (1) hardness is not a major factor in determining friction and wear under the conditions of these studies. (2) Friction and wear as low as or lower than those observed for a good commercial seal material were attained with some of the experimental materials studied. (3) The inclusion of boron carbide (as an oxidation inhibitor) has a strong influence on wear rate. (4) Phosphate treatment reduces the friction coefficient when boron carbide is not present in the base material.

Allen, G. P.↗

Diamond and diamondlike carbon as wear-resistant, self-lubricating coatings for silicon nitride

Recent work on the friction and wear properties of as-deposited fine-grain diamond, polished coarse-grain diamond, and as-deposited diamondlike carbon (DLC) films in humid air at a relative humidity of approximately 40 percent and in dry nitrogen is reviewed. Two types of chemical vapor deposition (CVD) processes are used to deposit diamond films on silicon nitride (Si3N4) substrates: microwave-plasma and hot-filament. Ion beams are used to deposit DLC films of Si3N4 substrates. The diamond and DLC films in sliding contact with hemispherical bare Si3N4 pins have low steady-state coefficients of friction (less than 0.2) and low wear rates (less than 10(exp -7) mm(exp 2)/N-m), and thus, can be used effectively as wear-resistant, self-lubricating coatings for Si3N4 in the aforementioned two environments.

Miyoshi, Kazuhisa↗

Thermal contacts between metal and glass for use at cryogenic temperatures

Thermal contacts designed to cool a 50-cm diam fused-silica mirror to 5 K without serious distortion of the optical surfaces were tested. Rubber cement and copper-filled rubber cement were found to be well suited for maintaining thermal contact between the fused-silica and copper straps. A variety of other adhesives proved to be unreliable because they spalled the glass. The thermal resistances of the rubber cement and copper-filled rubber cement were determined. For the copper-filled rubber cement, the thermal resistances varied from 570 K/W at 60 K to 15,000 K/W at 10 K.

Obrien, K.↗

Sensitivity analysis of high-efficiency silicon solar-cell design parameters

Silicon solar cell design parameters were investigated to determine their bearing on cell efficiency. Among the parameters reviewed were: (1) bulk resistivity, (2) minority carrier lifetime cell thickness, (3) front junction depth, (4) front surface doping concentration, (5) front surface recombination velocity, and (6) back surface contact. The following were concluded: (1) there is good agreement between experimental and simulation results; (2) sheet material quality improvement is needed for high efficiency cells; (3) 20% cell of this design is feasible with 10 ms bulk lifetime material; and (4) for achieving efficiencies higher than 20% new cell designs including thin cells with light trapping and back surface field should be considered.

Mokashi, A. R.↗

Joule Thomson refrigerator

A bi-directional Joule Thomson refrigerator is described, which is of simple construction at the cold end of the refrigerator. Compressed gas flowing in either direction through the Joule Thomson expander valve and becoming liquid, is captured in a container in direct continuous contact with the heat load. The Joule Thomson valve is responsive to the temperature of the working fluid near the valve, to vary the flow resistance through the valve so as to maintain a generally constant flow mass between the time that the refrigerator is first turned on and the fluid is warm, and the time when the refrigerator is near its coldest temperature and the fluid is cold. The valve is operated by differences in thermal coefficients of expansion of materials to squeeze and release a small tube which acts as the expander valve.

Chung K Chan↗

Ultrasonic imaging of textured alumina

Ultrasonic images representing the bulk attenuation and velocity of a set of alumina samples were obtained by a pulse-echo contact scanning technique. The samples were taken from larger bodies that were chemically similar but were processed by extrusion or isostatic processing. The crack growth resistance and fracture toughness of the larger bodies were found to vary with processing method and test orientation. The results presented here demonstrate that differences in texture that contribute to variations in structural performance can be revealed by analytic ultrasonic techniques.

Stang, David B.↗

Ultrasonic imaging of textured alumina

Ultrasonic images representing the bulk attenuation and velocity of a set of alumina samples were obtained by a pulse-echo contact scanning technique. The samples were taken from larger bodies that were chemically similar but were processed by extrusion or isostatic processing. The crack growth resistance and fracture toughness of the larger bodies were found to vary with processing method and test orientation. The results presented here demonstrate that differences in texture that contribute to variations in structural performance can be revealed by analytic ultrasonic techniques.

Stang, D. B.↗

Calcium-Magnesium-Alumino-Silicates (CMAS) Reaction Mechanisms and Resistance of Advanced Turbine Environmental Barrier Coatings for SiC/SiC Ceramic Matrix Composites

Environmental barrier coatings (EBCs) and SiC/SiC ceramic matrix composites (CMCs) systems will play a crucial role in future turbine engines for hot-section component applications because of their ability to significantly increase engine operating temperatures, reduce engine weight and cooling requirements. The development of prime-reliant environmental barrier coatings is an essential requirement to enable the applications of the 2700-3000 F EBC - CMC systems. This presentation primarily focuses on the reaction mechanisms of advanced NASA environmental barrier coating systems, when in contact with Calcium-Magnesium Alumino-Silicates (CMAS) at high temperatures. Advanced oxide-silicate defect cluster environmental barrier coatings are being designed for ultimate balanced controls of the EBC temperature capability and CMAS reactivity, thus improving the CMAS resistance. Further CMAS mitigation strategies are also discussed.

Environmental barrier coatings (EBCs)↗

Surface Enhancement Improves Crack Resistance

The low plasticity burnishing (LPB) process produces a deep layer of surface compression in a quick and affordable manner to produce metal surfaces free of scratches, nicks, and gouges. The process, designed for easy inclusion in the manufacturing environment, can be performed with conventional Computer Numerical Control machine tools. This allows parts to be processed during manufacturing, rather than as a post process in a separate facility. A smooth, free-rolling spherical ball suspended in a fluid allows for single-point contact. The ball comes into mechanical contact only with the surface to be burnished, and can be moved in any direction. LPB can be applied to all types of carbon and alloy steel, stainless steel, cast iron, aluminum, titanium, and nickel- based super alloys. In addition to improving a surface's resistance to fatigue and damage, treatment stops the growth of shallow cracks. The LPB process is used on the leading edges of turbine blades to improve resistance to foreign object damage and crack growth. This means significant savings for aircraft owners, since maintenance requirements to inspect for fatigue damage, replace parts, and remove corrosion damage increase the cost of operation.

Source record↗

Long term exposure of metals to hydrazine nitrate blend

A long term testing program is being conducted to determine the effects of materials in contact with a hydrazine nitrate blend for the purpose of designing chemical propulsion systems which can be used for current as well as future planetary spacecraft. Analysis of this data indicates that some aluminum alloys are acceptable for use with the particular blend of fuel used. Titanium alloy was identified as being acceptable for 10-year applications. Corrosion resistant steels, however, were found to have excessive corrosion rates and are therefore considered unacceptable for long-term use. There is also some evidence that the propellant decomposed at a rate far in excess of the acceptable rate of 0.1 percent per year when in contact with stainless steel.

Moran, Clifford M.↗

Making Skew-Resistant Fabrics For Composite Layups

Fabrics used in curved composite-material structures prevented from skewing during composite layup by weaving them in modified process in which warp and fill yarns bonded together at their points of contact. (Bonding concept may prove similarly beneficial for braided and knitted fabrics.) In modified weaving process, adhesives prevent excessive shifting of warp and fill yarns with respect to each other.

Farley, Gary L.↗

Contact Sensor Attachment to Titanium Metal Composites

A Pd-13wt%Cr solid solution is a promising high-temperature strain gage alloy. In bulk form it has a number of properties that are desirable in a resistance strain gage material, such as a linear electrical-resistance-versus-temperature curve to 1000 C and stable electrical resistance in air at 1000 C. However, unprotected fine wire gages fabricated from this alloy perform well only to 600 C. At higher temperatures severe oxidation degrades their electrical performance. In this work Auger electron spectroscopy has been used to study the oxidation chemistry of the alloy wires and ribbons. Results indicate that the oxidation is caused by a complex mechanism that is not yet fully understood. As expected, during oxidation, a layer of chromium oxide is formed. This layer, however, forms beneath a layer of metallic palladium. The results of this study have increased the understanding of the oxidation mechanism of Pd-13wt%Cr.

Vargas-Aburto, Carlos↗

Low-high junction theory applied to solar cells

Recent use of alloying techniques for rear contact formation has yielded a new kind of silicon solar cell, the back surface field (BSF) cell, with abnormally high open circuit voltage and improved radiation resistance. Several analytical models for open circuit voltage based on the reverse saturation current are formulated to explain these observations. The zero SRV case of the conventional cell model, the drift field model, and the low-high junction (LHJ) model can predict the experimental trends. The LHJ model applies the theory of the low-high junction and is considered to reflect a more realistic view of cell fabrication. This model can predict the experimental trends observed for BSF cells. Detailed descriptions and derivations for the models are included. The correspondences between them are discussed. This modeling suggests that the meaning of minority carrier diffusion length measured in BSF cells be reexamined.

Godlewski, M. P.↗

Sputtered W-N diffusion barriers

The thermal stability of reactively sputtered tungsten-nitrogen alloy thin films is investigated for the application as diffusion barriers in silicon contact metallizations. The composition of W-N barriers is varied over a wide range including pure W. Aluminum, gold, and silver are used as low resistivity overlayers. Metallurgical interactions at temperatures ranging from 500 to 900 C are studied. Incorporating nitrogen into tungsten advantageously stabilizes all three systems. The overall failure takes place rapidly above critical temperatures that depend on both the metal overlayer and the microstructure of the barrier. In some cases, W-N alloys can effectively prevent interdiffusion at temperatures as high as 800 C for 30 min.

Kattelus, H. P.↗

Investigation of high efficiency silicon MINP solar cells

This paper includes results of both theoretical and experimental studies of silicon metal insulator n/p cells. Performance calculations are described which give expected efficiencies as a function of base resistivity. Fabrication and characterization of cells are discussed, and detailed analyses of current loss mechanisms are presented. Using 0.2-ohm cm FZ material and Mg tunneling contacts, AM 1 efficiencies in the range of 16.5-17 percent have been achieved.

Olsen, L. C.↗

The lubrication force between two viscous drops

The present determination of the hydrodynamic force resisting the relative motion of two unequal drops moving in Stokes flow conditions along their line of centers assumes that the drops are in near-contact, and possess sufficiently high interfacial tension to remain spherical. Depending on the ratio of drop viscosity to that of the continuous phase, as well as on the ratio of the distance between drops to their reduced radius, three possible flow situations arise: these correspond to nearly-rigid drops, drops with partially mobile interfaces, and drops with fully mobile interfaces.

Davis, Robert H.↗

SiC device development for high temperature sensor applications

Progress made in the processing and characterization of 3C-SiC for high temperature sensor applications is reviewed. Piezoresistance properties of silicon carbide and the temperature coefficient of resistivity of n-type beta-SiC are presented. In addition, photoelectrical etching and dopant selective etch-stops in SiC and high temperature Ohmic contacts for n-type beta-SiC sensors are discussed.

Shor, J. S.↗