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At least 541 records · Page 30

Remote Sensing of Spatial Distributions of Greenhouse Gases in the Los Angles Basin

The Los Angeles air basin is a significant anthropogenic source of greenhouse gases and pollutants including CO2, CH4, N2O, and CO, contributing significantly to regional and global climate change. Recent legislation in California, the California Global Warming Solutions Act (AB32), established a statewide cap for greenhouse gas emissions for 2020 based on 1990 emissions. Verifying the effectiveness of regional greenhouse gas emissions controls requires high-precision, regional-scale measurement methods combined with models that capture the principal anthropogenic and biogenic sources and sinks. We present a novel approach for monitoring the spatial distributions of greenhouse gases in the Los Angeles basin using high resolution remote sensing spectroscopy. We participated in the CalNex 2010 campaign to provide greenhouse gas distributions for comparison between top-down and bottom-up emission estimates.

Los Angeles air basin↗

Global Ocean Phytoplankton

Marine phytoplankton are responsible for roughly half the net primary production (NPP) on Earth, fixing atmospheric CO2 into food that fuels global ocean ecosystems and drives the ocean's biogeochemical cycles. Phytoplankton growth is highly sensitive to variations in ocean physical properties, such as upper ocean stratification and light availability within this mixed layer. Satellite ocean color sensors, such as the Sea-viewing Wide Field-of-view Sensor (SeaWiFS; McClain 2009) and Moderate Resolution Imaging Spectroradiometer (MODIS; Esaias 1998), provide observations of sufficient frequency and geographic coverage to globally monitor physically-driven changes in phytoplankton distributions. In practice, ocean color sensors retrieve the spectral distribution of visible solar radiation reflected upward from beneath the ocean surface, which can then be related to changes in the photosynthetic phytoplankton pigment, chlorophyll- a (Chla; measured in mg m-3). Here, global Chla data for 2013 are evaluated within the context of the 16-year continuous record provided through the combined observations of SeaWiFS (1997-2010) and MODIS on Aqua (MODISA; 2002-present). Ocean color measurements from the recently launched Visible and Infrared Imaging Radiometer Suite (VIIRS; 2011-present) are also considered, but results suggest that the temporal calibration of the VIIRS sensor is not yet sufficiently stable for quantitative global change studies. All MODISA (version 2013.1), SeaWiFS (version 2010.0), and VIIRS (version 2013.1) data presented here were produced by NASA using consistent Chla algorithms.

phytoplankton↗

Real Time 3D Observations of Portland Cement Carbonation at CO2 Storage Conditions

Depleted oil reservoirs are considered a viable solution to the global challenge of CO 2 storage. A key concern is whether the wells can be suitably sealed with cement to hinder the escape of CO 2 . Under reservoir conditions, CO 2 is in its supercritical state, and the high pressures and temperatures involved make real-time microscopic observations of cement degradation experimentally challenging. Here, we present an in situ 3D dynamic X-ray micro computed tomography (μ-CT) study of well cement carbonation at realistic reservoir stress, pore-pressure, and temperature conditions. The high-resolution time-lapse 3D images allow monitoring the progress of reaction fronts in Portland cement, including density changes, sample deformation, and mineral precipitation and dissolution. By switching between flow and nonflow conditions of CO 2 -saturated water through cement, we were able to delineate regimes dominated by calcium carbonate precipitation and dissolution. For the first time, we demonstrate experimentally the impact of the flow history on CO 2 leakage risk for cement plugging. In-situ μ-CT experiments combined with geochemical modeling provide unique insight into the interactions between CO 2 and cement, potentially helping in assessing the risks of CO 2 storage in geological reservoirs.

58 GEOSCIENCES↗

Spatially-Explicit Monitoring of Crop Photosynthetic Capacity Through the Use of Space-Based Chlorophyll Fluorescence Data

Plant functional traits such as photosynthetic capacity are critical parameters for terrestrial biosphere models. However, their spatial and temporal characteristics are still poorly represented. In this study, we used satellite observations of sun-induced fluorescence (SIF) to estimate top-of-canopy photosynthetic capacity (maximum carboxylation rate, V(sub cmax) at a reference temperature of 25 deg C) for crops, which was in turn utilized to simulate regional gross primary production (GPP). We first estimate the key parameter, V(sub cmax), in the widely-used FvCB photosynthesis model using field measurements of CO2 and water fluxes during 2007-2012 at seven crop eddy covariance flux sites over the US Corn Belt. The results showed that satellite far-red SIF retrievals have a stronger link to V(sub cmax) at the seasonal scale (R(squared)=0.70 for C4 and R(squared)=0.63 for C3 crop) as compared with widely-used vegetation indices. We calibrate an empirical model linking V(sub cmax) with SIF that was used to estimate spatially and temporally varying crop V(sub cmax) for the US Corn Belt region. The resulting V(sub cmax) maps are used together with meteorological data from MERRA reanalysis data and vegetation structural parameters derived from the satellite- based spectral reflectance data to constrain the Soil-Canopy Observation of Photosynthesis and Energy (SCOPE) balance model in order to estimate regional crop GPP. Our results show a substantial improvement in the seasonal and spatial patterns of cropland GPP when compared with crop yield inventory data. The evaluation with tall tower atmospheric CO2 measurements further supports our estimation of spatiotemporal V(sub cmax) from space-borne SIF. Considering that SIF has a direct link to photosynthetic activity, our findings highlight the potential to infer regional V(sub cmax) using remotely sensed SIF data and to use this information for a better quantification of regional cropland carbon cycles.

Drought↗

Impact of reservoir parameters and wellbore permeability uncertainties on CO 2 and brine leakage potential at the Shenhua CO 2 Storage Site, China

Here, this paper describes a system-level risk assessment for the Shenhua CO 2 storage site, China, using the National Risk Assessment Partnership Integrated Assessment Model for Carbon Storage (NRAP-IAM-CS). Here, we begin by determining the optimal number of Monte Carlo (MC) simulations to achieve CO 2 and brine leakage result convergence. Then, we calculate mass CO 2 and brine leakage to the atmosphere and a hypothetical shallow aquifer. Finally, we assess the geochemical impacts in the event of leakage as if there were a shallow freshwater aquifer at the Shenhua site. Simulation results show that leakage results tend to stabilize after 300 Monte Carlo simulations. When the three wells on site are assigned a permeability of 10 -11 m 2 (representing significantly leaking wells), moderate CO 2 and brine leakages occur, and the percentage of CO 2 leakage exceeds the threshold value we set based on the Intergovernmental Panel on Climate Change (IPCC). This is, however, unlikely to be the case for the Shenhua site. For all the other scenarios, the CO 2 leakage is trivial although there is still the possibility of CO 2 leakage into the groundwater aquifer exceeding the 1% threshold over 1000 years, assuming constant legacy wellbore permeability. For the significantly leaking scenario, there is a 10% probability to have a moderate (2.7 × 10 7 m 3 ) leakage-affected volume in the shallow aquifer with the pH below 6.5, and a large (1.4 × 10 8 m 3 ) volume with the total dissolved solids (TDS) above 500 ppm, hence pH and TDS may be considered for site monitoring plans. Based on the simulation results, there is a very low probability of significant CO 2 /brine leakage through the existing wells at the Shenhua CO 2 storage site.

58 GEOSCIENCES↗

Peroxy radical measurements with NCAR's chemical amplifier

The present NCAR instrument for HO2/RO2 measurements has been described previously. It is based on the reactions involving HO2, RO2, and HO radicals with CO and NO. Since (HO2) + (RO2) + (HO) is much greater than (HO) for most atmospheres, it is useful as a peroxy radical detector. Operation of the instrument depends on the creation of a chemical chain reaction which is initiated as HO2 and RO2 radicals in ambient air encounter added NO gas; this forms an NO2 molecule and an HO or RO radical: HO2(RO2) + NO yields HO(RO) + NO2. RO radicals react relatively efficiently with O2 to form an HO2 radical, and subsequently an HO-radical, by reaction with NO. CO gas added to the reaction chamber during part of the operating cycle, recycles the HO to HO2; HO + CO (+O2) yields HO2 + CO2. The reaction sequence may form several hundred NO2 molecules per HO2 (RO2) originally present, before chain termination occurs. The added CO is replaced by N2 addition periodically so that the chain reaction is suppressed, and a 'blank' signal resulting from NO2, O3 and possibly other NO2-forming species (non-chain processes) in ambient air is recorded. The difference between the signal with and without CO is proportional to the peroxy radical concentration. The NO2 produced is monitored using a sensitive luminol chemiluminescence detector system. In the NCAR instrument the length of the amplification chain is determined using a stable source of HO2 radicals (H2O2 thermal decomposition); the ratio of the signal seen with CO present to that with N2 present gives the sensitivity of the instrument to HO2 (molecules of NO2 formed/peroxy radical). The instrument is automated to carry out in hourly repeated cycles: (1) chain length determination; (2) NO2 calibration; and (3) linearity check on the response of signals. One minute averages of signals are normally recorded. The sensitivity of the instrument to detect peroxy radicals is in the pptv range. The present instrument has operated continuously (24 hr/day) in the field studies which extended over a period of several weeks. The major advantages of this instrument are as follows: (1) its relative simplicity; (2) low power requirements; and (3) its rapid response to all types of peroxy radicals--HO2, CH3O2 and the higher alkyl and acyl peroxy radicals; however not all RO2 species generate HO2 radicals with perfect efficiency and hence have somewhat lower response/molecule than HO2 radicals.

Cantrell, Christopher↗

The East and Southeast Asia Initiatives: Aerosol Column Measurements

Airborne dusts from northern China contribute a significant part of the air quality problem and, to some extent, regional climatic impact in Asia during spring- time. However, with the economical growth in China, increases in the emission of air pollutants generated from industrial and vehicular sources will not only impact the radiation balance, but adverse health effects to humans all year round. In addition, both of these dust and air pollution clouds can transport swiftly across the Pacific reaching North America within a few days, possessing an even larger scale effect. The Asian dust and air pollution aerosols can be detected by its colored appearance on current Earth observing satellites (e.g., MODIS, SeaWiFS, TOMS, etc.) and its evolution monitored by satellites and surface network. Biomass burning has been a regular practice for land clearing and land conversion in many countries, especially those in Africa, South America, and Southeast Asia. However, the unique climatology of Southeast Asia is very different than that of Africa and South America, such that large-scale biomass burning causes smoke to interact extensively with clouds during the peak-burning season of March to April. Significant global sources of greenhouse gases (e.g., CO2, CH4), chemically active gases (e.g., NO, CO, HC, CH3,Br), and atmospheric aerosols are produced by biomass burning processes. These gases influence the Earth- atmosphere system, impacting both global climate and tropospheric chemistry. Some aerosols can serve as cloud condensation nuclei, which play an important role in determining cloud lifetime and precipitation, hence, altering the earth's radiation and water budget. Biomass burning also affects the biogeochemical cycling of nitrogen and carbon compounds from the soil to the atmosphere; the hydrological cycle (i.e., run off and evaporation); land surface reflectivity and emissivity; as well as ecosystem biodiversity and stability. Two new initiatives, EAST-AIRE (East Asian Study of Tropospheric Aerosols: an International Regional Experiment) and BASE-ASIA (Biomass-burning Aerosols in South East-Asia: Smoke Impact Assessment) will be presented and discussed their contribution to better understand the impacts of aerosols on regional-to- global climate, hydrological and carbon cycles, and tropospheric chemistry.

Tsay, Si-Chee↗

Dust, Pollution, and Biomass Burning Aerosols in Asian Pacific: A Column Satellite-Surface Perspective

Airborne dusts from northern China contribute a significant part of the air quality problem and, to some extent, regional climatic impact in Asia during spring-time. However, with the economical growth in China, increases in the emission of air pollutants generated from industrial and vehicular sources will not only impact the radiation balance, but adverse health effects to humans all year round. In addition, both of these dust and air pollution clouds can transport swiftly across the Pacific reaching North America within a few days, possessing an even larger scale effect. The Asian dust and air pollution aerosols can be detected by its colored appearance on current Earth observing satellites (e.g., MODIS, SeaWiFS, TOMS, etc.) and its evolution monitored by satellites and surface network. Biomass burning has been a regular practice for land clearing and land conversion in many countries, especially those in Africa, South America, and Southeast Asia. However, the unique climatology of Southeast Asia is very different than that of Africa and South America, such that large-scale biomass burning causes smoke to interact extensively with clouds during the peak-burning season of March to April. Significant global sources of greenhouse gases (e.g., CO2, CH4), chemically active gases (e.g., NO, CO, HC, CH3Br), and atmospheric aerosols are produced by biomass burning processes. These gases influence the Earth-atmosphere system, impacting both global climate and tropospheric chemistry. Some aerosols can serve as cloud condensation nuclei, which play an important role in determining cloud lifetime and precipitation, hence, altering the earth's radiation and water budget. Biomass burning also affects the biogeochemical cycling of nitrogen and carbon compounds from the soil to the atmosphere; the hydrological cycle (i.e., run off and evaporation); land surface reflectivity and emissivity; as well as ecosystem biodiversity and stability. Two new initiatives, EAST-AIRE (East Asian Study of Tropospheric Aerosols: an International Regional Experiment) and BASE-ASIA (Biomass-burning Aerosols in South East-Asia: Smoke Impact Assessment) will be presented and discussed their contribution to better understand the impacts of aerosols on regional-to-global climate, hydrological and carbon cycles, and tropospheric chemistry.

Tsay, Si-Chee↗

A new approach for measuring the carbon and oxygen content of atmospherically relevant compounds and mixtures

Abstract. Due to its complexity, gas- and particle-phase organic carbon in the atmosphere is often classified by its bulk physicochemical properties. However, there is a dearth of robust, moderate-cost approaches to measure the bulk chemical composition of organic carbon in the atmosphere. This is particularly true for the degree of oxygenation, which critically affects the properties and impacts of organic carbon but for which routine measurement approaches are lacking. This gap has limited the understanding of a wide range of atmospheric components, including particulate matter, the mass of which is monitored worldwide due to its health and environmental effects but the chemical characterization of which requires relatively high capital costs and complex operation by highly trained technical personnel. In this work, we demonstrate a new approach to estimate the mass of carbon and oxygen in analytes and mixtures that relies only on robust, moderate-cost detectors designed for use with gas chromatography. Organic compounds entering a flame ionization detector were found to be converted with approximately complete efficiency to CO2, which was analyzed downstream using an infrared detector to measure the mass of carbon analyzed. The ratio of the flame ionization detector (FID) signal generated to CO2 formed (FID∕CO2) was shown to be strongly correlated (R2=0.89) to the oxygen-to-carbon ratio (O∕C) of the analyte. Furthermore, simple mixtures of analytes behaved as the weighted average of their components, indicating that this correlation extends to mixtures. These properties were also observed to correlate well with the sensitivity of the FID estimated by structure activity relationships (quantified as the relative effective carbon number). The relationships between measured FID∕CO2, analyte O∕C, and FID sensitivity allow the estimation of one property from another with <15 % error for mixtures and <20 % error for most individual analytes. The approach opens the possibility of field-deployable, autonomous measurement of the carbon and oxygen content of particulate matter using time-tested, low-maintenance detectors, though such an application would require some additional testing on complex mixtures. With some instrumental modifications, similar measurements on gas-phase species may be feasible. Moreover, the potential expansion to additional gas chromatography detectors may provide concurrent measurement of other elements (e.g., sulfur, nitrogen).

42 ENGINEERING↗

Development Unit Configuration and Current Status of the MIP/MAAC Experiment

The Mars In-Situ Propellant Production (ISPP) Precursor (MIP) experiment package is planned for inclusion on the Mars 2001 Lander. This experiment package consists of five experiments whose purpose is to demonstrate the performance of various ISPP processes in-situ on Mars. The demonstrated ability to produce propellant for Mars Return Vehicles (MRV) is considered to be a necessary precursor to any future manned mission to Mars. The Mars Atmosphere Acquisition and Compression (MAAC) experiment is part of the MIP package and is intended to demonstrate that, by using a sorption compressor, CO2 can be preferentially adsorbed at about 6 torr from the Mars atmosphere during the night when the bed is cold then subsequently compressed to about 800 torr by heating the bed and desorbing CO2 during the day. The compressed CO2 produced by MAAC is to be fed to the Oxygen Generator Subsystem (OGS) where pure oxygen is to be produced. Pure oxygen is considered to be one of the primary constituents of a future manned MRV propellant system. A MAAC Development Unit (DU) has been fabricated and tested at JPL. The MAAC DU consists of 1) a sorption bed filled with a CO2 selective sorbent material, 2) a purge system to be used to periodically backflush non-CO2 gases from the sorbent bed during adsorption, 3) a JPL-developed gas-gap heat switch that allows heat transfer to a radiator for heat removal from the bed during the night time adsorption period and that impedes heat transfer during the day time desorption period, 4) a radiator to radiate heat to the night sky during the adsorption period, 5) a set of three isolation valves and connecting tubing. 6) two pressure transducers and several thermocouples for monitoring the MAAC operating conditions, and command and data handling electronics. This paper will describe the operational theory and the configuration of the MAAC DU and will discuss the current status of the MAAC experiment development including some selected results of performance testing that has been completed prior to the ISRU III meeting.

Karlmann, P. B.↗

Development Unit Configuration Status of the MIP/MAAC Experiment

The Mars In-Situ Propellant Production (ISPP) Precursor (MIP) experiment package is planned for inclusion on the Mars 2001 Lander. This experiment package consists of five experiments whose purpose is to demonstrate the performance of various ISPP processes in-situ on Mars. The demonstrated ability to produce propellant for Mars Return Vehicles (MRV) is considered to be a necessary precursor to any future manned mission to Mars. The Mars Atmosphere Acquisition and Compression (MAAC) experiment is part of the MIP package and is intended to demonstrate that, by using a sorption compressor, CO2 can be preferentially adsorbed at about 6 torr from the Mars atmosphere during the night when the bed is cold then subsequently compressed to about 800 torr by heating the bed and desorbing C02 during the day. The compressed CO2 produced by MAAC is to be fed to the Oxygen Generator Subsystem (OGS) where pure oxygen is to be produced. Pure oxygen is considered to be one of the primary constituents of a future manned MRV propellant system. A MAAC Development Unit (DU) has been fabricated and tested at JPL. The MAAC DU consists of: (1) a sorption bed filled with a CO2 selective sorbent material; (2) a purge system to be used to periodically backflush non-CO2 gases from the sorbent bed during adsorption; (3) a JPL-developed gas-gap heat switch that allows heat transfer to a radiator for heat removal from the bed during the night time adsorption period and that impedes heat transfer during the day time desorption period; (4) a radiator to radiate heat to the night sky during the adsorption period; (5) a set of three isolation valves and connecting tubing; (6) two pressure transducers and several thermocouples for monitoring the MAAC operating conditions, and command and data handling electronics. This paper will describe the operational theory and the configuration of the MAAC DU and will discuss the current status of the MAAC experiment development including some selected results of performance testing that has been completed prior to the ISRU III meeting.

Karlmann, P. B.↗

COMPASS-FME Synoptic Site Tree Greenhouse Gas Concentrations

These data are tree stem greenhouse gas concentrations collected from tree gas wells at some of the COMPASS-FME (Coastal Observations, Mechanisms, and Predictions Across Systems and Scales; see https://compass.pnnl.gov/) 'synoptic' sites in the Chesapeake Bay region: Moneystump (MSM), Goodwin Islands (GWI), and GCReW (GCW). The sap flow monitoring trees at these sites in the Upland (UP) and Transition (TR) zones were cored and had gas wells installed at breast height. There were also some dead standing trees cored, gas well installed, and sampled at MSM and GWI. The GCW UP samples overlap with the TEMPEST experiment control plot, so the GCW UP data was pulled from the TEMPEST page and included here. These data provide crucial information about possible pathways for the greenhouse gas (carbon dioxide and methane, CO2 and CH4 respectively) production and emission (or in the case of CH4, perhaps taken up from) the atmosphere.All data are plain text CSV (comma separated value) files and require no special software to read.Updated 2025-10-09 to fix two missing dates (lines 77 and 78 in the data file).

54 ENVIRONMENTAL SCIENCES↗

TRACER-CAT-LANL Aerosol Optics and Chemical Speciation - Tracegases

Aerosol size distribution, optical properties, and speciation data collected in La Port TX, during TRACER-CAT-LANL, July 2022, with basic trace gas measurements. All sampling was conducted with an identical aerosol inlet as the standard ARM-AOS systems. The TRacking Aerosol Convection interactions ExpeRiment Carbonaceous Aerosols Thrust by Los Alamos National Laboratory (TRACER-CAT-LANL, July 2022) was designed to complement the larger ARM TRACER science goals to understand convective cloud lifecycles and aerosol-convection interactions. TRACER-CAT-LANL is focused on understanding the relationship between particle composition and light absorption and the influence of water uptake on this relationship. This aerosol and trace gas data can be used to understand the relationship between particle composition and light absorption and the influence of water uptake on this relationship. Instruments Include: Picarro GHG Photoacoustic Soot Spectrometer (PASS-3) Humidified-cavity attenuated phase shift-single scattering albedo particulate matter monitor (H-CAPS-PMSSA) Soot Particle Aerosol Mass Spectrometer (SPAMS) Single-Particle Soot Photometer (SP2) Cloud Condensation Nuclei Counter (CCNc) Aerodynamic Particle Sizer (APS) Scanning Mobility Particle Sizer (SMPS)

54 ENVIRONMENTAL SCIENCES↗

Development of a solar-cell dust opacity measurement instrument for Mars Pathfinder

The atmosphere of Mars has a considerable load of suspended dust. Over time, this dust is deposited out of the atmosphere. The mechanism and the temporal and geographical variation of this deposition are not well characterized. Measurements of settling rates and dust properties are of considerable scientific interest. Atmospheric dust affects the atmospheric solar absorption and thus the heat balance of Mars, as well as serving as nucleation sites for water and CO2 frost. Knowledge of dust properties is of critical interest to design and prediction of the lifetime and power output of solar arrays, and also to design of mechanical mechanisms and radiators. An instrument has been designed and fabricated to measure the dust accumulation during the course of the Mars Pathfinder rover mission. The solar-cell coverglass transmission experiment will measure the change in optical opacity of a transparent coverglass as dust settles on the surface, and a quartz crystal monitor will measure the mass deposited.

Geoffrey A. Landis↗

A Decade of Global Volcanic SO2 Emissions Measured from Space

The global flux of sulfur dioxide (SO2) emitted by passive volcanic degassing is a key parameter that constrains the fluxes of other volcanic gases (including carbon dioxide, CO2) and toxic trace metals (e.g., mercury). It is also a required input for atmospheric chemistry and climate models, since it impacts the tropospheric burden of sulfate aerosol, a major climate-forcing species. Despite its significance, an inventory of passive volcanic degassing is very difficult to produce, due largely to the patchy spatial and temporal coverage of ground-based SO2 measurements. We report here the first volcanic SO2 emissions inventory derived from global, coincident satellite measurements, made by the Ozone Monitoring Instrument (OMI) on NASA's Aura satellite in 2005-2015. The OMI measurements permit estimation of SO2 emissions from over 90 volcanoes, including new constraints on fluxes from Indonesia, Papua New Guinea, the Aleutian Islands, the Kuril Islands and Kamchatka. On average over the past decade, the volcanic SO2 sources consistently detected from space have discharged a total of approximately 63 kt/day SO2 during passive degassing, or approximately 23 +/- 2 Tg/yr. We find that approximately 30% of the sources show significant decadal trends in SO2 emissions, with positive trends observed at multiple volcanoes in some regions including Vanuatu, southern Japan, Peru and Chile.

Carn, S. A.↗

Atmospheric Temperature from Raman Scattering

Raman scattering signatures are functions of the scattering-gas temperature, and are therefore of potential use for practical atmospheric temperature probes. The method described uses either ratios of pure rotational Raman scattering intensities for air utilizing various spectral bandpasses, or, alternatively, ratios of air-rotational to nitrogen-vibrational scattering intensities. Three aspects of work relating to the development of such probes are discussed in this presentation: (1) fundamental absolute Raman data, (2) construction of air spectra from these data, and (3) temperature-sensitivity of the signature. The fundamental data described are the absolute rotational and vibrational scattering cross sections. Recent measurements in this laboratory of rotational cross sections for N2, O2, and CO2 are emphasized, as are their use in predicting absolute magnitudes of Raman scattering signals. Next is described the computation of air rotational Raman spectra as a function of temperature calculated through use of the experimentally-measured cross sections. The spectra are based additively upon nitrogen and oxygen contributions, since pure rotational Raman scattering from water vapor is very weak. Finally, the sensitivity of the scattering intensity ratios to temperature is explored as a function of choice of spectral bandpass for the monitored rotational Raman scattering. Various compromises will be discussed which must be made in choosing bandpasses appropriate for specific purposes and experimental conditions.

Lapp, M.↗

Building an EPA Class VI Permit Application

Summary To accelerate the commercialization of carbon capture and storage (CCS), the US Department of Energy (US DOE) is building on decades of characterization efforts and pilot-scale projects through their CarbonSAFE program. Administered through their National Energy Technology Laboratory, this program seeks to bring fully integrated projects to the sector that can store more than 50 million tonnes of CO2 over a 30-year period. The program, which was enacted before the enhancement of Internal Revenue Code Section 45Q, is in the capture assessment, characterization, and permitting phase. The objectives of this paper are to discuss (a) the injection permitting requirements of the CarbonSAFE projects; (b) information gathering in support of the permit; (c) the timelines of field development and permit-related activities; (d) the major technical components of the field development plan; and (e) early feedback from the regulators toward acceptance of the permit. In Mississippi, more than 30,000 acres have been characterized by six deep characterization wells, a deep groundwater well, and 92 line miles of 2D seismic as part of the CarbonSAFE Project ECO2S. During the acquisition of seismic data, all receiver lines were live, which resulted in the generation of a pseudo-3D seismic design. The incorporation of a 3D seismic survey was not included as part of this project due to logistical difficulties presented by the undulating, wooded surface terrain. A suite of openhole geophysical logs was taken from each well, allowing for a detailed interpretation of prospective storage reservoirs and confining intervals to complement the analysis carried out on the 290 ft of a whole core that was cut through the prospective confining zone and storage reservoir. The detailed geologic and reservoir data were assembled and entered into a 3D model to assess the injection capacity and the area of review (AoR). This information fed into the detailed corrective action, monitoring, testing, and postinjection site care (PISC) modeling. The results have been exceptional. The geologic assessment has revealed three primary storage targets, ranging in depth from 3,500 ft to 6,000 ft. These storage reservoirs net 1,300 ft of sandstone, with mean porosity and permeability of 29% and 3.6 darcies, respectively. Together, these reservoirs have storage capacities that may exceed 20 million tonnes per square mile, making this a gigatonne prospect. Forward modeling of the project resulted in an AoR of 16 sq miles, injecting about 8000 t/d, for 30 years, via two deep injection wells. The excellent confining characteristics of the caprock, relatively simple geologic structure, and lack of historical well drilling activity in this area provide excellent containment of the injected CO2. Based on this work, the project has proposed 20 years of PISC. To date, only two US CO2 injection permits have been granted. These projects relied on a singular capture point feeding a singular sequestration point (source to sink), and considerations have not been made to garner CO2 emissions from other industrial sources. The Kemper County Storage Complex is a first-of-its-kind storage hub concept that looks to develop an area capable of storing significant quantities of CO2 from the region. Also, this work will show how characterization efforts, geological and numerical modeling efforts, and plan development were constructed in support of permit and incentives acceptance.

Energy & Fuels↗

Accelerated Aging of a Polymer-Supported Molecular Amine Direct Air Capture Sorbent: Experiments and Theory

Amine-functionalized polymer sorbents are the preferred materials for CO2 extraction from air (DAC) due to their “high” CO2 adsorption capacity and selectivity at ultra-dilute conditions. The lifetime of adsorbents is a key property of equal importance as adsorption capacity, selectivity and kinetics with direct impact on the economics of commercial-scale operations. Therefore, a detailed investigation into the contributing factors (e.g. temperature, humidity) as well as the mechanism of amine degradation is vital for the development of amines with long-term stability. Herein, in situ attenuated total reflection (ATR) Fourier transform infrared spectroscopy (FTIR) is used to monitor the real time changes to amine-based sorbents under systematically varied conditions. In addition, IR spectra obtained from density functional theory molecular dynamics are used to obtain mechanistic insights pertaining to the degradation of amine groups in DAC sorbents.

Muldoon, Patrick↗