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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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All sourcesNASA NTRSDOE OSTI
DOE OSTI2022

On-Demand Designing of Cathode Internal Surface Architecture for Dramatic Enhancement of SOFC Performance and Durability

This project is aimed to design and modify the internal surfaces of porous composite cathode from currently commercially viable Solid Oxide Fuel Cells (SOFCs), using additive manufacturing process of Atomic Layer Deposition (ALD). The material systems being investigated are commercial composite electrodes complex three-dimensional topographies. In term of the chemistry of the ALD layer applied on the internal surface of the porous cathode, this project has employed commercially relevant electrolyte, electrocatalyst and noble metal materials set. Such materials are fully compatible with the commercial fuel cells, and this project has developed special nanostructure on the surface of the commercial composite cathodes. The formation of the designed nanoarchitecture on the surface of SOFC cathode has been achieved through precise control of ALD parameters and their effect on overall cell performance and resultant electrochemical reaction mechanism of cathodes has been investigated through full cell electrochemical performance testing and nanostructure characterization by transmission electron microscopy (TEM). Under the support of this award, following has been achieved: (1). For cathode materials in solid oxide fuel cells (SOFCs), such as perovskite mixed conductor La 0.6 Sr 0.4 Co 0.2 Fe 0.8 O 3-x (LSCF), cation surface segregation and consequently losing conductivity and active sites for the oxygen reduction reaction (ORR) are problematic. To mitigate the cation segregation and enhance SOFC durability, further decorating the internal backbone surface using the desired electrocatalysts could be a promoting approach. Commonly, the cation segregation such as Sr is very volatile, so the effective surface decoration is ideally conformal. Nevertheless, the conformal surface coating would inevitably alter the ORR pathways that initially take place on the surface of the backbone. To reveal the impact of the conformal coating on both the catalytic activity and the conductivity of the cathode, the unary electrocatalyst of Pt or CoO x , was applied to the LSCF/SDC composite electrode of inherently functional SOFCs, respectively. Both ALD coating layers evolve strong interaction with the LSCF composite cathode. Upon operations, the Pt coating layer remains conformal on LSCF grain surfaces but turns into discrete particles on SDC grain surfaces. Meanwhile, CoO x conformal coating grows to be the discrete nanograins on both the LSCF and SDC grains. ALD coating of the cathode alone reduces the ohmic resistance up to 28 % for the entire cells. The increased conductivity induced by the ALD coating of Pt or CoO x is ascribed to different mechanisms. For the inherent functional SOFCs, the present study presents a novel and feasible approach to apply a conformal, dense coating layer on the surface of a mixed conductor, simultaneously increasing the conductivity and durability of the SOFC cathode. (2). High resistance of the oxygen electrode still significantly hinders the state-of-the-art Solid Oxide Fuel Cells (SOFCs). In particular, for an oxygen electrode consisting of mixed electronic and ionic conductors, such as perovskite lanthanum strontium cobalt ferrite (LSCF), it deteriorates due to its low chemical stability of the grain surface. Such degradation is often associated with the segregation of cations. To prevent the cation surface segregation and its resultant perovskite phase decomposition, we demonstrate a conformal ultra-thin (7-10 nm) surface heterogeneous coating layer consisting of subjacent discrete Pt nanoparticles capped with a superjacent fully dense conformal CoO x layer. The performance studies indicate the ALD coating reduces the cell series resistance by up to 40 %. The conformal CoO x layer consists of randomly orientated but single-layered nanograins, with high-density intergranular and surface grain boundaries serving as the electrochemical reaction sites and facilitating mass transport. The conformal coating layer appears to have successfully suppressed the Sr outward diffusion and confined the Sr enriched layer to a ~ 2 nm interface perovskite phase between the coating layer and the LSCF grain surface. Moreover, this ultra-thin Sr enriched perovskite layer presumably possesses high oxygen vacancy and high ionic conductivity and further imposes tensile strain to the LSCF grain surfaces. With the combination of a conformal CoO x nanoionics, Sr enriched layer, and its strained interface, the ALD coating induced surface layer is estimated to have a conductivity of ~ 1.27x10 4 S/cm, which is over two orders magnitude of that from LSCF at 750 ºC.

30 DIRECT ENERGY CONVERSION↗
DOE OSTI2021

“Transition from dissipative fluid dynamics to particles in heavy ion collisions”(Final Technical Report)

This report summarizes research activities and achievements made under Award No. DE-SC00016524. We advanced the following areas: i) self-consistent bulk viscous and baryon number diffusion corrections from kinetic theory, ii) hadron gas bulk viscosity determination, and iii) discovery of novel mechanisms of elliptic flow generation and suppression in heavy-ion collisions.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗
DOE OSTI2021

Power System Resilience Metrics Augmentation for Critical Load Prioritization

One of the major goals of new grid operation regimes, such as transactive energy systems (TESs), is to make the power grid more resilient to withstand natural or man-made disasters and potential reliability events, and to continue to serve the maximum number of its customers. But it is a well-known fact to system operators that not all customers are the same. This implies that any discussion of TESs’ impacts on the resilience of the power system should consider the needs of its critical customers (such as the power system operation centers, fire and police stations, and hospitals) over those of other customers. When evaluating the resilience of the system, bonus points must be awarded to any system that could maintain its power supply to critical customers during a disturbance that may cause an outage. This report discusses critical infrastructure (CI) as found in the literature and then categorizes it based on the field to which the operations belong (such as human life/safety-related, operations management, necessary city operation, industrial customers, etc.). Each of these CI categories is further divided into types of critical customers (e.g., the human life/safety-related category has different types of customers like hospitals, fire and police stations, etc.). The entire demand of each of the critical customer types is not categorized as critical load (CL); instead, only a portion of the total load of these critical customers is characterized as critical load. This is done based on the categories of equipment, the function of which is crucial in the operation of the overall facility. CL categorization is performed to provide the ratio of the critical load portion to the overall load , so that it can serve as a parameter in the resilience evaluation of the grid through a metrics-based approach. Such categorization is important as it helps to augment the existing quantifiable resilience metrics with CL categorization. The metrics for a power system need to not only consider how well a system performed during a disturbance event, but also how it reduced strain and supplied power to its CLs. The first step in this process is characterize CLs in the system. After CL characterization, the next step is the inclusion of these loads in the resilience metrics. To that end, in this report weight-based augmentation of resilience metrics is proposed, where certain customers (the ones that are categorized as critical) are assigned higher weights than others. Though an overview of assigning weights to customers is discussed, there is no one-size-fits-all approach for every power system. The decisions made about assigning such weights to customers vary greatly from one operator to another, based on their unique systems and the current and predicted states of critical customers. This decision-making can include the type of disturbance event, which might only affect certain parts of the system. In general, analyzing critical customers before an event helps understand system vulnerabilities. It also helps in planning and conducting operations during the event, evaluating system performance after the event, and supporting better planning for future events. An alternative to the current practices of managing the grid for outages is an innovative TES, which has the potential to provide a platform for including distributed energy resources for managing CLs. This report also describes how TES qualities can help (1) to maintain power supply to critical customers for uninterrupted operations and (2) to restore lost power supply to the critical customers rapidly.

24 POWER TRANSMISSION AND DISTRIBUTION↗
DOE OSTI2021

Nanoporous weakly coordinating anionic frameworks (Final Technical Report)

Under this award, we synthesized and characterized new weakly coordinating, anionic covalent organic frameworks. The motivation was to expand the class of covalent organic frameworks though the introduction of the first weakly coordinating anionic ones. The significance of the weakly coordinating anionic character of these frameworks is associated with the character of the counter (metal) cations in their pores. Those counter-cations, due to the inability to effectively coordinate to the pore walls, have a “naked”, and thus highly electrophilic, Lewis acidic character. Such properties are expected to translate to a number of interesting physical properties that can be potentially used for a range of energy-relevant applications. One of these applications is gas adsorption, separation, and storage. The electrophilic, Lewis acidic character of the counter-cations are expected to strongly bind to gas molecules entering the pores leading to higher gas sorption capacities. Other applications include heterogeneous catalysis, ion exchange, and solid state ion conduction. Within the project we explored a range of chemical blocks, and tested synthesis conditions to polymerize these building blocks to form the target materials. In particular, we focused on materials with group 15 elements like phosphorus in the oxidation state +5 and the coordination number 6, that have a formal -1 charge. The synthesis of such materials is challenging because its success depends on the absence of residual monomeric and oligomeric side-products in the pores, and the absence of significant framework interpenetration. Crystalline forms of these materials require sufficient reversibility of the polymerization reaction (which is difficult to achieve because group 15 elements like P tend to make strong covalent bonds with neighbored elements), as well as suitable polymerization rates that prevent the formation of kinetically controlled products. We had success with the preparation of anionic porous organic frameworks with anionic building blocks containing P(V)O6 octahedra synthesized through Yamamoto coupling reactions. These materials are non-crystalline because of the irreversible nature of the Yamamoto coupling reaction, but show porosity. The porosity and surface area can be significantly increased by co-reaction with electrostatically neutral co-reactants. Very high porosity and surface areas can be achieved when the materials are washed with hydrochloric acid. This method is commonly used to free products from Yamamoto coupling reactions from by-products. Indeed, this method removed by products from the pores of our materials, however it also led to the hydrolysis of the PO6 octahedra to form pending phosphonic acid groups (-PO3H)-groups in the frameworks (PA-POFs) which was actually not desired. Nonetheless, these materials showed high CO2 sorption capacities. In addition, they show extremely high (actually record) sorption capacities for the removal of a range of common micropollutants such as bisphenol A (BPA) and 4-nitrophenol in water. BPA is a wide-spread organic pollutant and a known endocrine disruptor. The maximum adsorption capacity of BPA at equilibrium is found to be as high as 3,366 mg g-1 by Langmuir adsorption model, which is more than 10 times greater than peer materials. The polymer also rapidly removes various other organic micropollutants with more than 90% removal efficiencies. In addition, the PA-POF material can be regenerated at least five times by mild washing using methanol without significant loss in removal efficiency. This is significant advantage over commonly used activated carbon materials (that are in Brita water faucet filters, for example). Comparison studies showed that only materials with the phosphonate groups show extreme sorption although the number of PA group is actually small according to solid state NMR and EDX data. More research would be needed to investigate why this is (a possibility is that the phosphonate groups have a multiplying effect in which a PA-induced initial adsorption leads to the adsorption of much more adsorbate). The extreme sorption capabilities can also be visually seen when colored adsorbates such as 4-nitrophenol are used, as the adsorption of the nitrobenzene leads to the decoloration of the solution. We have produced three short videos that illustrate the sorption capabilities compared to two peer materials (activated carbon from dismantled Brita water filters, and a electrostatically neutral, chemically related, porous organic polymer, respectively).

36 MATERIALS SCIENCE↗
DOE OSTI2021

Ligand-Controlled Energetics and Charge Transfer in Pure and Doped Nanocrystals

The research in this award period initially focused on the spectroscopy and dynamics of spherical CdSe nanocrystals and CdSe nanoplatelets. In the later part of the grant period we turned our attention to InP-based nanocrystals. It has long been believed that the transient absorption signal from approximately spherical CdSe nanocrystals is dominated by conduction band state filling. However, this long-held belief has recently been challenged, based on femtosecond absorption measurements. However, the recent studies challenging the conventional wisdom do not account of finite rates of spin-lattice relaxation. Our work showed that this is a crucial error and that the recent results are misinterpreted, that is, the previous prevailing wisdom is correct. Another study focused on CdSe nanocrystal photochemistry used transient absorption (TA) spectroscopy to determine the spatial extents of CdSe nanoplatelet (NPL) excitons. Our work shows that the spatial extents of the excitons in the NPLs are far less than the physical dimension of the NPL. Using a model developed to understand the transient absorption spectroscopy, we obtain an average excitonic area of 21.2 ± 2.5 nm 2 , independent of the nanoplatelet size. Our work on InP/ZnSe and InP/ZnS core/shell nanocrystals shows that when there is a small lattice mismatch (InP-ZnSe, 3.5%) a coherent core-shell interface is obtained. In contrast, the InP-ZnS lattice mismatch is much larger, 8.3%. In this case, the experimental results showed best agreement with calculations in which lattice strain is ignored, indicating that the interfaces in InP/ZnS nanocrystals are largely incoherent.

14 SOLAR ENERGY↗
DOE OSTI2020

Connecting Dynamic Strain Aging to Deformation Processing in Magnesium-Calcium-Based Alloys

Fuel consumption can be improved by reducing car weight with substitution of aluminum and steel parts with magnesium (Mg). Magnesium formability at room temperature is limited due to strong basal texture generated prior processing. Shear band nucleation, observed under conditions in which dynamic strain aging (DSA), have been attributed to be responsible for texture weakening in dilute Mg – Rare Earths (RE) alloys. A low–cost substitution of RE is calcium (Ca) with similar atomic size. It is hypothesized that deformation of Mg – Ca alloys under DSA conditions improves Mg formability. In this study, Mg–Ca and Mg–Ca–Zn alloys were characterized using optical microscopy, XRD, and SEM/EDS. Compression testing was performed between 200 and 300C at different strain rates to observe DSA behavior. This work was performed under DOE Award Number DE-EE0007756.

Manuel, Michele↗
DOE OSTI2022

Deployment of Energy Efficiency and Clean Energy on Indians Lands – A Community Solar Project

The Eastern Band of Cherokee Indians (EBCI or Tribe) is a federally recognized Indian Tribe located on ancestral homelands in western North Carolina. The Tribe is comprised of just over 16,000 enrolled members, with an estimated 8,000 – 10,000 residing on tribal lands. The Qualla Boundary is comprised of over 56,000 acres of contiguous trust land adjacent to the Great Smoky Mountain National Park. The EBCI also possess an assortment of scattered parcels of varying sizes across western North Carolina, some in trust status and others in deeded or fee simple. This project was implemented on a trust parcel in Cherokee County, NC. The Tribe was awarded the maximum amount of $\$ $1,000,000 for the installation of a 705.6 kilowatt (kW) solar PV array to supplement the power consumed and reduce annual utility costs at the Harrah’s Cherokee Valley River (HCVR) casino and hotel in Murphy, NC. The casino is a tribal entity of the Tribe. The total cost of the project was $\$ $2.364 million. The system was officially commissioned on April 12, 2019. For the purpose of calculating the amount of power produced and reduction in utility costs, the time frame assessed is May 2019 through April 2020. All power generated was consumed onsite.Based on the first full year of data, the project achieved the estimated 8.3% reduction in utility costs. A total of six casino and tribal staff were trained and received a North American Board of Certified Energy Practitioners (NABCEP) certification, giving our staff the resources and skills to manage and operate the solar PV array. Based on the Tribal match of $\$ $1,377,797 and estimated net annual benefit of $89,000, the estimated return on investment (ROI) is 15.48 years.

14 SOLAR ENERGY↗
DOE OSTI2021

The transparent soil microcosm: a window into the spatial distribution and dynamics of carbon utilization and microbial interspecies interactions (Final Report)

This document contains the summary and final report for award DE-SC0013887 (The transparent soil microcosm: a window into the spatial distribution and dynamics of carbon utilization and microbial interspecies interactions), including the overall description of the accomplishments obtained during this work, the manuscripts published with its support, and the list of personnel funded to conduct this research.

59 BASIC BIOLOGICAL SCIENCES↗
DOE OSTI2021

Pulsating Heat Pipes for Accelerator Magnets. Phase I Final Report

The primary objective of the Phase 1 award was to investigate the performance of cryogenic pulsating heat pipes (PHPs) and their use in practical large superconducting magnet systems. PHPs exhibit an effective thermal conductivity an order of magnitude and more over high purity metals such as copper and aluminum. They can therefore be utilized to reduce cold mass and effectively transfer heat from the magnet system components such as the coil pack, shields, or current leads to cryocoolers or cryogen reservoirs.

43 PARTICLE ACCELERATORS↗
DOE OSTI2021

Further Studies on Photocatalytic Water Decomposition

The initial ideas underlying this project were first developed during a sabbatical by RT as a Senior Fulbright Scholar in the laboratory of Professor Jean-Marie Lehn at the University of Strasbourg. Professor Lehn had recently been awarded the Nobel Prize for his work on Supramolecular Chemistry. The project, as it was originally proposed upon my return to Houston, involved using the excited state of an appropriate photocatalyst to bring about the bond-breaking (O-H) and bond making (O=O and H-H) steps involved in water decomposition.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2021

Searches for a Long-Lived Heavy Photon

This award supported work on the Heavy Photon Search (HPS) experiment by three members of the Santa Cruz Institute for Particle Physics: Robert Johnson (professor), Vitaliy Fadeyev (physicist), and Alic Spellman (graduate student), from September 2018 through March 2020.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗
DOE OSTI2021

R&D Toward CUPID, a Tonne-Scale Bolometric 0vBB Experiment (Final Report)

This award supported the construction of infrastructure at MIT to test components for the future CUPID experiment. CUPID is the CUORE Upgrade with Particle ID. It uses Lithium molybdate crystals instrumented as scintillating bolometers to search for the neutrinoless double-beta decay of 100 Mo. A bolometer is a detector which uses the change in temperature of a crystal due to the passage of charged particles through the crystal to detect the particle. A scintillating bolometer uses a scintillating crystal as the primary bolometer and a germanium wafer as a secondary light-collecting bolometer. The charged particle therefore creates a heat and light signal, the ratio of these signals allows us to distinguish signal from background.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗
DOE OSTI2021

Improving Data Center Energy Efficiency Through End-to-End Cooling Modeling and Optimization. Final Report

This report summarizes the development and demonstration of the three features developed for the DOE project “Improving Data Center Energy Efficiency through End-to-End Cooling Modeling and Optimization” (Award No. DE-EE0007688). The development of the three software features, Feature 1: Optimization of Cooling System Operation, Feature 2: Optimization of Airflow Management System, and Feature 3: Simultaneous Optimization of Airflow Management and Cooling Systems, are described first. Feature 1 is implemented in Phase 1 of the project and demonstrates 15% energy savings from cooling system optimization by applying the proposed retrofit solutions. Feature 2 is implemented in Phase 2 and the assessments show cooling energy-saving potential between 19.3% and 54.0%, depending on the energy-saving measures employed. In addition, investigating the energy saving potential for a hypothetical simple data center shows about 6.8% energy savings by optimizing the server load placement. Feature 3 is implemented in Phase 3 and the results show energy savings of 53.4% and 74.6% for the two partner data centers, respectively, compared to the baselines defined in Phase 1. Lastly, the project outcomes including software releases and publications are discussed.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗
DOE OSTI2021

MCC On Boarding Section J-2 (Exhibit H) Quality Assurance Requirements [Slides]

Upon MATOC Award, SUBCONTRACTOR shall submit a Quality Assurance Program for evaluation in accordance with subcontract technical and quality requirements. This may be the Subcontractors corporate QA program. Acceptance by Triad of the SUBCONTRACTORS Quality Assurance Program (QAP), as prescribed in Exhibit H, QC-01A and 01B, allows the SUBCONTRACTOR to execute this contract using their approved QAP. SUBCONTRACTORS QAP as approved by CONTRACTOR must meet the applicable requirements of DOE Order 414.1D (see next slide) and must address flow down of the quality requirements to lower tier subcontractors. Triad acceptance of SUBCONTRACTOR’s QAP approval is required prior to Notice to Proceed with on-site work. A Project Specific QA plan may on rare occasions be required for a specific task

96 KNOWLEDGE MANAGEMENT AND PRESERVATION↗
DOE OSTI2021

Universality in Quantum Gravity. Final Technical Report

This is the final technical report for the DOE Early Career Award to PI Thomas Hartman at Cornell University, outlining the goals of the research project and summarizing its main technical achievements. These include the discovery of new constraints on quantum field theory, new theoretical methods that allow for a direct derivation of emergent spacetime from conformal field theory in certain settings, and the discovery of fundamental bounds on the dynamics of quantum information.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗