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At least 541 records · Page 30

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DOE OSTI2021

A universal and facile approach for building multifunctional conjugated polymers for human-integrated electronics

Polymer semiconductors have shown distinct promise for the development of human- integrated electronics, owing to their solution processability and mechanical softness. However, numerous functional properties required for this application domain face synthetic challenges to be imparted onto conjugated polymers and thus combined with efficient charge- transport property. Here, we develop a “click-to-polymer” (CLIP) synthesis strategy for conjugated polymers, which uses a click reaction for the facile and versatile attachment of diverse types of functional units to a pre-synthesized conjugated-polymer precursor. With four types of functional groups, we show that functionalized polymers from this CLIP method can still retain good charge-carrier mobility. Here, we take two realized polymers to showcase the photo-patternable property and biochemical sensing function, both of which advance the state of the art of realizing these two types of functions on conjugated polymers. We expect the expanded use of this synthesis approach can largely enrich the functional properties from conjugated polymers.

36 MATERIALS SCIENCE↗

DOE OSTI2024

Statistical analysis of HAADF-STEM images to determine the surface coverage and distribution of immobilized molecular complexes

The surface immobilization of molecular catalysts is attractive because it combines the benefits of homogeneous and heterogeneous catalysis. However, determining the surface coverage and distribution of a molecular catalyst on a solid support is often challenging, inhibiting our ability to design improved catalytic systems. Here, in this work, we demonstrate that the combination of scanning transmission electron microscopy (STEM) and image analysis of the individual positions of heavy atoms in transition metal complexes via a convolutional neural network (CNN) allows statistically robust determination of the surface coverage and distribution of immobilized molecular catalysts. These observations provide information about how changes in the functionalization conditions, attachment group, and structure of the molecular catalyst affect the surface coverage and distribution, providing insight into the chemical mechanism of surface immobilization. The method could be generally valuable for correlating the surface coverage and distribution to the activity, selectivity, and stability of a catalytic system.

HAADF-STEM↗

DOE OSTI2021

Rethinking production of machine tool bases: Polymer additive manufacturing and concrete

Cast iron and steel weldments are the most common machine tool base elements. However, both construction methods have associated disadvantages for domestic machine tool manufacturers. Here, this paper documents the investigation of an alternative method for machine tool base production using concrete to fill an additively manufactured polymer mold, where the motion components are attached to the concrete base after the initial concrete curing. Modal testing results for a three-axis, vertical spindle prototype indicate high damping and stiffness can be achieved using the concrete base construction. Advantages are reduced cost and lead time compared to traditional methods.

Additive manufacturing↗

DOE OSTI2022

A machining digital twin for hybrid manufacturing

Hybrid manufacturing consisting of metal additively manufactured preforms and computer numerical control (CNC) machining has been established to be an effective method for high material use rates. However, hybrid manufacturing introduces unique challenges. Near-net shape designs are typically selected, which result in a smaller margin for part placement within the stock and stringent requirements for work coordinate system identification. Additionally, less stock material reduces the preform stiffness, which limits the material removal rates during machining. This paper demonstrates a digital twin for CNC machining of a wire arc additively manufactured preform that implements: 1) structured light scanning for stock model identification and tool path generation; 2) a fused filament fabrication apparatus to attach temporary fiducials and scan targets to the preform that enable coordinate system definition for both the CAM and CNC machine; 3) preform and tool tip frequency response function measurements to enable stable milling parameter selection; and 4) post-manufacturing measurements of geometry, surface finish, and structural dynamics to confirm designer intent. These efforts define key components of the machining digital twin for hybrid manufacturing.

36 MATERIALS SCIENCE↗

DOE OSTI2026

Servomotor-driven leveling elements for machine tool frame-to-floor alignment

This paper presents the results of aligning the frame to concrete floor of a large 5-axis machine tool by leveling element adjustments using servomotors instead of manual operation. The machine tool leveling elements used in this study are mechanical devices that attach the machine tool frame to the concrete foundation. These leveling elements are also adjustable so that each location along the machine tool can be uniquely adjusted such that the geometric errors of the frame are minimized, and the accuracy of the machine tool is improved. Off-the-shelf servomotors and connection equipment were installed at each of 12 leveling element locations for a precision 5-axis machine tool at Oak Ridge National Laboratory. The servomotors allow a technician to align the machine tool frame remotely, instead of crawling under the machine tool to iteratively manually adjust each of the 12 leveling elements. The open-loop servomotor-leveling element system design is presented in this paper as well as machine tool frame alignment results. The servomotor system significantly reduces leveling element adjustment time, eliminates the need for under-machine access, reduces technician physical strain, and significantly improves the adjustment repeatability.

Honeycutt, Andrew [ORNL]↗

DOE OSTI2022

Interdiffusion and Formation of Intermetallic Compounds in High-Temperature Power Electronics Substrate Joints Fabricated by Transient Liquid Phase Bonding

Power electronics packages typically comprise a dielectric substrate bonded to a metal layer and attached to heat sinks using a low-thermal-conductivity solder. These multiple layers increase the effective thermal resistance of the package and are responsible for package failures under cyclic thermal loads. Bonding the aluminum nitride dielectric layer (AlN) directly to a low coefficient of thermal expansion (CTE) aluminum silicon carbide (AlSiC) cold plate using copper-aluminum (Cu-Al) transient liquid phase (TLP) bonding has been shown to improve the mechanical reliability of the power electronic packages while making the package more compact by bringing the cooling solutions closer to the devices. This study aims to characterize the Cu-Al bonds formed during the TLP bonding of AlSiC with three different power electronics substrates: pure aluminum nitride (AlN), aluminum (DBA), and copper (DBC). The material compositions and microstructures of the bonds were analyzed using scanning electron microscopy (SEM), x-ray spectroscopy (EDS), confocal scanning acoustic microscopy (C-SAM), and x-ray diffraction (XRD). ..alpha..-Al solid compound was identified as the dominant phase in AlN-AlSiC and Al-AlSiC, with a notable presence of SiC particles. In contrast, three intermetallic phases - ..theta..-CuAl2, ..eta..-CuAl, and ..gamma..'- Cu9Al4 - were observed in the Cu-AlSiC bond. A computational solid-state diffusion model was developed to predict the intermetallic compounds (IMCs) formed during Cu-Al TLP bonding in each system, which supported the observation that an initial Cu volume fraction of 20 % in the material layers produced a final bond composition of >95 % Al with minimal IMC growth. However, increased Cu concentrations produced higher concentration gradients, leading to increased growth of IMCs, Kirkendall voids, and interstitial cracks.

DIRECT ENERGY CONVERSION↗

DOE OSTI2021

Journal Pre-proof3D printed polylactic acid and acrylonitrile butadiene styrene fluidicstructures for biological applications: tailoring bio-material interfaceviasurface modification

Three-dimensional (3D) printing is a rapidly growing technology that best fits for cell culture and other biological applications due to its potential to build immensely complex structures from customized designs. However, use of 3D printed structures for cell adhesion, proliferation, and activation requires tailoring of surface characteristics. In this context, this work investigates the use of two biocompatible 3D printable polymer materials, Poly-L-lactic Acid (PLA) and Acrylonitrile Butadiene Styrene (ABS) for bio applications, and the effect of their post-printing surface modification processes to achieve desired bio functionality. Three post-printing surface modification techniques, alkaline hydrolysis, ultraviolet ozone plasma irradiation and gold thin film deposition are performed with the objective of introducing useful levels of surface functionalities. Poly-L-lysine (PLL) labelled with FITC chromophore is immobilized on the surface modified samples following standard protocols. The effect of surface roughness and porosity of the 3D printed structures on the polypeptide immobilization is compared on as-printed versus mechanically polished surfaces. Different characterization methods, viz., Fluorescence microscopy, Raman Spectroscopy and UV–vis spectroscopy, are used to study the efficacy of the surface modification and PLL immobilization techniques. Our results demonstrated denser PLL attachment on polished hydrolyzed PLA and ABS surfaces which enables the use of these printable polymers for a range of applications such as tissue scaffolds and microfluidics.

3D Printing, PLA, ABS, Biodegradable Polymer, Surf↗

DOE OSTI2025

Direct ink writing of shear exfoliated two-dimensional nanomaterial- elastomeric multifunctional nanocomposite

Direct ink writing (DIW) of polymer nanocomposites with high loadings of two-dimensional (2D) nanofillers (graphene and hexagonal boron nitride (hBN)) is challenging because of potential clogging, use of hazardous solvents, and agglomeration. Here, in this work, a shear exfoliation and sieving method to prepare DIW ink with high loading of nanofillers produced from low-cost bulk layered materials such as graphite and bulk hBN powder for successful DIW printing without the use of any solvents, binders, or plasticizers. The single-step exfoliation technique resulted in a composite with substantial layer reduction along the c-axis, as confirmed by SEM, TEM, XRD, and Raman analysis. Incorporating exfoliated graphene (40 wt%) increased viscosity by ∼6 orders of magnitude due to enhanced particle–matrix interactions, leading to pronounced yield stress behavior and a yield stress of approximately 1598 Pa, which enabled excellent shape retention during extrusion. Using the DIW technique, porous structures such as desalination membranes, self-sensing bone scaffolds, thermal management coating, and serpentine strain sensors were fabricated. When tested in a direct contact membrane distillation setup, the fabricated membrane demonstrated a promising permeate flux of 21.85 Lm −2 h −1 and a salt rejection of 74.3 %. The fabricated serpentine sensor exhibited stable signal variations under cyclic tensile loading, with a working range of 0–200 % strain and a maximum gauge factor of 43,735. A cell culture test using the printed bone scaffold demonstrated promising cell attachment and proliferation. The DIW printed hBN nanocomposite exhibited reversible shape change under heat, demonstrating potential 4D printing capability and efficient thermal management when exposed to high heat or flame.

Desalination↗

DOE OSTI2020

Enhanced hindrance from phenyl outer side chains on nonfullerene acceptor enables unprecedented simultaneous enhancement in organic solar cell performances with 16.7% efficiency

Inner side-chain engineering on Y6 has been a proven successful in improving short-circuit current density (JSC) through fine-tuning aggregated structures of acceptors. However, it fails in tuning the lowest unoccupied molecular orbital level (LUMO) and open-circuit voltage (V OC ). In this paper, we turn to focus on engineering the outer side chains on the flanking thienothiophene units with 4-hexylphenyl (PhC6) and 6-phenylhexyl (C6Ph) chains. Use of PhC6 enhances the steric effect between the attached phenyl and the ending group, which in combination with the additional conjugation effect provided by the linking phenyl leads to upshifted energy levels and increased V OC as a result. Again, substitution with the bulkier PhC6 unprecedentedly improves film-morphology with reduced paracrystalline disorder and long period and increased root-mean-square composition variations as well, leading to increased electron and hole mobilities and suppressed monomolecular recombination with J SC and fill-factor (FF) simultaneously enhanced. The PM6:BTP-PhC6-based devices yield a higher efficiency value of 16.7% than the PM6:BTP-C6Ph-based one (15.5%). Furthermore, this study shows a conceptual advance in materials design towards reducing the conflict between V OC and J SC in binary blended organic solar cells, which can be achieved by introducing bulkier chains to twist the backbone and simultaneously enhance the packing order.

14 SOLAR ENERGY↗

DOE OSTI2020

Rooting MnO 2 into protonated g-C 3 N 4 by intermolecular hydrogen bonding for endurable supercapacitance

Composited electrode materials for energy storage typically benefit from the merits of each component but meanwhile largely suffer from the vulnerable structural integrity during repetitive cycling. Realizing the merely physical attachment in most composited structures being too weak to survive harsh cycling, we report here a facile one-step synthesis strategy with generation of chemical bonds, more specifically, intermolecular hydrogen bonds, to tightly combine each component. Here, we demonstrate this concept by designing a composite featuring MnO 2 nanorods chemically rooted into protonated g-C 3 N 4 , where the protonation of 2D g-C 3 N 4 substrate (pg-C 3 N 4 ), the nucleation/growth of MnO 2 and the formation of hydrogen bonding between pg-C 3 N 4 and MnO 2 simultaneously occur. The obtained composite, when applied for supercapacitive energy storage, yields maximum specific capacitances of 348.4 F·g -1 at a current density of 1.0 A·g -1 as well as a high retention of ~85.0% after 10000 cycles at 6.0 A·g -1 , surpassing most previously reported composited electrode materials based on either MnO 2 or g-C 3 N 4 . Finally, we expect this work to inspire the synthesis of composited electrode materials with consolidated 3D architecture for endurable energy storage performance.

25 ENERGY STORAGE↗

DOE OSTI2021

Hybrid printing of wearable piezoelectric sensors

Piezoelectricity provides an ideal electromechanical mechanism with emerging applications in wearable devices due to its simplicity and self-powered nature. However, the 3D printing of piezoelectric devices still faces many challenges, including material printability, high energy poling process, and low dimensional accuracy. This study demonstrates, for the first time, a tellurium nanowire-based piezoelectric device fabricated by a hybrid printing method integrating highly complementary aerosol jet printing and extrusion printing in a single printing platform. The aerosol-jet-printed tellurium nanowire demonstrates piezoelectric properties without the need for any poling processing due to the unique properties of the tellurium nanowires. The silver nanowire electrodes printed by aerosol jet printing demonstrate excellent conductivity and stretchability without the need for sintering. An extrusion method is employed to print the silicone films, which serve as the stretchable substrate and the electrical insulation layers between the printed tellurium and silver. The printed wearable piezoelectric devices were attached to a human wrist to detect different hand gestures and to a human neck to detect heartbeat without using an external power source. In conclusion, the fully printed, sintering-free and poling-free, and stretchable piezoelectric device opens enormous opportunities for facile integration with a broad range of printed electronics and wearable devices.

47 OTHER INSTRUMENTATION↗

DOE OSTI2021

Role of Aberrant Spontaneous Neurotransmission in SNAP25-Associated Encephalopathies

SNARE (soluble N-ethylmaleimide sensitive factor attachment protein receptor) complex, composed of synaptobrevin, syntaxin, and SNAP25, forms the essential fusion machinery for neurotransmitter release. Recent studies have reported several mutations in the gene encoding SNAP25 as a causative factor for developmental and epileptic encephalopathies of infancy and childhood with diverse clinical manifestations. However, it remains unclear how SNAP25 mutations give rise to these disorders. In this work, we show that although structurally clustered mutations in SNAP25 give rise to related synaptic transmission phenotypes, specific alterations in spontaneous neurotransmitter release are a key factor to account for disease heterogeneity. Importantly, we identified a single mutation that augments spontaneous release without altering evoked release, suggesting that aberrant spontaneous release is sufficient to cause disease in humans.

60 APPLIED LIFE SCIENCES↗

DOE OSTI2021

A custom high-stability pulse generator for the test of a novel in-situ magnetic sensor developed to detect radiation damage in undulators

High-performance analog-to-digital converters (ADC) have been widely applied in many areas of science. For instance, magnetic field measurements based on the Faraday’s induction law require high-precision voltmeters to measure induced voltages. In this study in the context of free-electron lasers technology, the Magnetic Measurements Team at SLAC National Accelerator Laboratory proposed a novel in-situ radiation damage detection system (RDDS) for detecting small field variations in undulators. The system measures the flux change in a flexible printed-circuit coil attached to the magnet array during the undulator gap movement. The gap movement changes the magnetic field, which induces a voltage signal in the coil that is measured and integrated with an ADC. Although the system is capable of detecting relative flux changes better than 100 ppm, drift in the ADC’s gain or offset can cause apparent changes in the relative flux. This paper describes the first attempt to developed a high-precision verification circuit to perform ADC testing in the framework of the novel RDDS. The circuit generates a reference voltage pulse with a voltage–time integral relative precision better than 50 ppm for a few hundreds of mVs — the typical order of magnitude measured with the RDDS. The circuit’s design combines a fast and precise switch with a low-noise voltage reference. Long-term measurements allowed statistical analysis and showed that averaging the voltage–time integral of ten pulses gives the required 50 ppm stability. Moreover, reproducibility tests confirmed that the circuit’s output is invariable under small power supply instabilities and equipment shutdown. Instruments and applications designed to quantify the magnetic field by integrating voltage signals may use the pulse generator proposed in this paper for verification purposes.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

DOE OSTI2021

6 MeV novel hybrid (standing wave - traveling wave) photo-cathode electron gun for a THz superradiant FEL

A novel 6 MeV hybrid photo-injector has been designed and constructed, based on a smaller-scale prototype previously built in UCLA’s Particle Beam Physics Laboratory. It has been commissioned at Ariel University in Israel as an on-going collaboration between the two universities. This unique, new generation design provides a radically simpler approach to RF feeding of a gun/buncher system, leading to a much shorter beam via velocity bunching owed to an attached traveling wave section of the photo-injector. This design offers better performance in beam parameters, providing a high quality electron beam, with energy of 6 MeV. The hybrid photo-injector was designed to provide emittance of approximately 3 μm, and pulse duration of 150 fs at up to 1 nC per pulse. The hybrid gun is driven by a SLAC XK5 klystron as the high power RF source, and third harmonic of a ~35 fs IR Laser amplifier (266 nm) to extract electrons from the photo-cathode. The unique electron gun will produce a bunched electron pulse to drive a THz FEL, which will operate at the super-radiant regime, and therefore requires ambitious beam properties. This paper describes the gun and presents experimental results from the gun and its sub-systems, including energy and charge measurements, compared with the design simulations.

150fs↗

DOE OSTI2024

Fast spark-detection system for GEM detectors

The sPHENIX experiment is currently under commissioning at the Relativistic Heavy Ion Collider (RHIC) at Brookhaven National Lab (BNL). The Time Projection Chamber (TPC) serves as a tracking detector for the experiment. The sPHENIX TPC uses a stack of four Gas Electron Multipliers (GEMs) as a gain stage in a reduced ion back-flow configuration. To mitigate the damaging effects of sparks in the GEMs, an online spark monitoring system was created. Once the system detects a spark in a GEM stack, the voltages across the GEMs in that stack can be lowered to prevent further sparking without affecting the gain and efficiency of the other modules. Spark signals are coupled out of the GEM stack by a pick-off capacitor attached to the bottom of the bottom GEM. Custom PCBs convert the oscillatory spark signal into a mono-polar pulse that is then digitized. The software then saves the waveform in a server and uses experimentally derived thresholds to determine how to react. As a result, the system has so far proven to be effective at improving the stability of the TPC and preventing damaging events while collecting cosmic ray data.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

DOE OSTI2025

The imaging Time-of-Propagation detector at Belle II

Here, we report on the construction, operation, and performance of the Time-of-Propagation detector with imaging used for the Belle II experiment running at the Super-KEKB e + e - collider. This detector is located in the central barrel region and uses Cherenkov light to provide particle identification among hadrons. The Cherenkov light is radiated in highly polished bars of synthetic fused silica (quartz) and transported to the ends of the bars via total internal reflection. One bar end is instrumented with finely segmented micro-channel-plate photomultiplier tubes to record the light, while the other end has a mirror attached to reflect the photons back to the instrumented end. Both the propagation times and hit positions of the Cherenkov photons are measured; these depend on the Cherenkov angle and together provide good discrimination among charged pions, kaons, and protons with momenta up to around 4 GeV/ c . To date, the detector has been used to record and analyze almost 600 fb −1 of Belle II data.

43 PARTICLE ACCELERATORS↗

DOE OSTI2022

Integration of high confinement, high poloidal beta plasma with dual radiated power and detachment controls for divertor protection and ELM suppression

Divertor detachment without serious core confinement quality loss in DIII-D’s high poloidal β scenario has been combined with impurity-induced ELM mitigation without disruption. Use of Ne previously granted access to a detached, non-ELMing regime that retained high confinement quality due to stimulation of Internal Transport Barrier (ITB) growth, but suffered from on-going core fuel dilution and high disruptivity. Excess Ne accumulation in the core plasma has now been avoided by feeding back core radiated power ($P_{rad}$) measurements to control Ne seeding, rather than using attachment fraction ($A_{frac}$) control with Ne; this also reduces disruptivity. At the same time, N 2 seeding is used in a feedback loop with $A_{frac}$ measurements, which previously posed low disruption risk. In this way, the effect of Ne in the core is managed while avoiding excess seeding, and N 2 acts to correct for any excess heat exhaust that might interfere with detachment. The average Ne flow rate was 38% of what was used in pure Ne $A_{frac}$ control, plus average N 2 flow that was 43% of pure N 2 $A_{frac}$ control, even while meeting an even deeper detachment target. Meanwhile, a steep pressure gradient in the core plasma reduces sensitivity to impurity-induced degradation of the pedestal and reasonable confinement quality was maintained despite operational challenges that blocked formation of an ITB in these experiments.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

DOE OSTI2024

Survey of tungsten gross erosion from main plasma facing components in WEST during a L-mode high fluence campaign

An initial high fluence campaign was performed in WEST, in 2023, on the newly installed actively cooled tungsten divertor composed of ITER-grade monoblocks. The campaign consisted in the repetition of a 60 s long Deuterium L-mode pulse in attached divertor conditions, cumulating over 10000s of plasma exposure. A maximum deuterium fluence of approximately 5⋅1⁢026 m−2 was reached in the outer strike point region, representative of a few high performance ITER pulses. Gross tungsten erosion inferred from visible spectroscopy shows that the most eroded plasma facing component is the inner divertor target with rates ten times larger than on the outer divertor target. The outer midplane tungsten bumpers, located a few centimeters from the plasma, show gross erosion rates two times lower than at the outer divertor. We conclude that the outer midplane bumpers have a negligible contribution to the long range tungsten migration and deposition onto the lower divertor. The cumulated gross erosion rate on the inner divertor translates in an effective gross erosion thickness of about 20μ⁢m, while it is about 2μ⁢m for the outer divertor. Strikingly, these orderings coincide with the thickness of deposits found locally on the divertor: the exposed surfaces of high field side monoblocks are covered with several tens of μ⁢m tungsten deposits, while on the lower field side, few μ⁢m thin tungsten deposits are only found on the magnetically shadowed parts of monoblocks. The strong impact of those deposits on WEST operation, namely perturbation of surface temperature measurement with infra-red thermography, and the emission of flakes causing radiative perturbation of the confined plasma, calls for anticipating similar issues in ITER. In particular, the start of research operation shall consider the definition of a divertor erosion budget in order to anticipate the formation of deleterious deposits.

Fedorczak, N.↗