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At least 541 records · Page 30
All sourcesNASA NTRSDOE OSTI
DOE OSTI2023

CO 2 /Brine/Rock Interactions in the Cedar Keys-Lawson Formation

It has been reported that among the various geologic storage options, deep saline aquifers have the largest estimated capacity for CO 2 storage. Obtaining knowledge of possible artificially geochemically induced changes to the permeability and porosity of host CO 2 storage deposits will enable us to gain insight on long-term reservoir behavior under CO 2 storage conditions. An experimental study of the interaction of CO 2 /brine/rock on saline formations was conducted in a static system under CO 2 storage conditions. Chemical interactions in the Cedar Keys-Lawson Formation carbonate during exposure to CO 2 and brine under sequestration conditions were studied. Samples were exposed to the simulated in-situ reaction conditions for one and six months. The samples were exposed to a model brine at 55 °C and CO 2 pressure of 23.8 MPa (3,500 psig). Computed tomography (CT), x-ray diffraction (XRD), scanning electron microscopy (SEM)-energy dispersive x-ray spectroscopy (EDS), brine composition, core porosity, and core permeability analyses were conducted prior to and after the exposure experiments. Preliminary permeability measurements obtained from the core samples showed changes after they were exposed to CO 2 -saturated brine for one and six months. This observation suggests that mineral dissolution and mineral precipitation could occur in the host deposit altering its characteristics for CO 2 storage over time. The 3D images of the pore space clearly illustrate the degree of dissolution that occurred during exposure. It is noted that the dissolution that occurred during the six-month exposure could have enhanced the connectivity between voids. This may contribute the increase of permeability after the CO 2 /brine exposure. In addition, the primary minerals comprising the core are dolomite and gypsum. Both minerals could dissolve in the CO 2 /brine environment resulting in the increase of permeability after the six-month exposure.

58 GEOSCIENCES↗
DOE OSTI2020

Data from: Leaching losses of dissolved organic carbon and nitrogen from agricultural soils in the upper US Midwest

Leaching losses of dissolved organic carbon (DOC) and nitrogen (DON) from agricultural systems are important to water quality and carbon and nutrient balances but are rarely reported; the few available studies suggest linkages to litter production (DOC) and nitrogen fertilization (DON). In this study we examine the leaching of DOC, DON, NO3-, and NH4+ from no-till corn (maize) and perennial bioenergy crops (switchgrass, miscanthus, native grasses, restored prairie, and poplar) grown between 2009 and 2016 in a replicated field experiment in the upper Midwest U.S. Leaching was estimated from concentrations in soil water and modeled drainage (percolation) rates. DOC leaching rates (kg ha-1 yr-1) and volume-weighted mean concentrations (mg L-1) among cropping systems averaged 15.4 and 4.6, respectively; N fertilization had no effect and poplar lost the most DOC (21.8 and 6.9, respectively). DON leaching rates (kg ha-1 yr-1) and volume-weighted mean concentrations (mg L-1) under corn (the most heavily N-fertilized crop) averaged 4.5 and 1.0, respectively, which was higher than perennial grasses (mean: 1.5 and 0.5, respectively) and poplar (1.6 and 0.5, respectively). NO3- comprised the majority of total N leaching in all systems (59-92%). Average NO3- leaching (kg N ha-1 yr-1) under corn (35.3) was higher than perennial grasses (5.9) and poplar (7.2). NH4+ concentrations in soil water from all cropping systems were relatively low (<0.07 mg N L-1). Perennial crops leached more NO3- in the first few years after planting, and markedly less after. Among the fertilized crops, the leached N represented 14-38% of the added N over the study period; poplar lost the greatest proportion (38%) and corn was intermediate (23%). Requiring only one third or less of the N fertilization compared to corn, perennial bioenergy crops can substantially reduce N leaching and consequent movement into aquifers and surface waters.

09 BIOMASS FUELS↗
DOE OSTI2021

Assessment of the ParFlow–CLM CONUS 1.0 integrated hydrologic model: evaluation of hyper-resolution water balance components across the contiguous United States

Abstract. Recent advancements in computational efficiency and Earth system modeling have awarded hydrologists with increasingly high-resolution models of terrestrial hydrology, which are paramount to understanding and predicting complex fluxes of moisture and energy. Continental-scale hydrologic simulations are, in particular, of interest to the hydrologic community for numerous societal, scientific, and operational benefits. The coupled hydrology–land surface model ParFlow–CLM configured over the continental United States (PFCONUS) has been employed in previous literature to study scale-dependent connections between water table depth, topography, recharge, and evapotranspiration, as well as to explore impacts of anthropogenic aquifer depletion to the water and energy balance. These studies have allowed for an unprecedented process-based understanding of the continental water cycle at high resolution. Here, we provide the most comprehensive evaluation of PFCONUS version 1.0 (PFCONUSv1) performance to date by comparing numerous modeled water balance components with thousands of in situ observations and several remote sensing products and using a range of statistical performance metrics for evaluation. PFCONUSv1 comparisons with these datasets are a promising indicator of model fidelity and ability to reproduce the continental-scale water balance at high resolution. Areas for improvement are identified, such as a positive streamflow bias at gauges in the eastern Great Plains, a shallow water table bias over many areas of the model domain, and low bias in seasonal total water storage amplitude, especially for the Ohio, Missouri, and Arkansas River basins. We discuss several potential sources for model bias and suggest that minimizing error in topographic processing and meteorological forcing would considerably improve model performance. Results here provide a benchmark and guidance for further PFCONUS model development, and they highlight the importance of concurrently evaluating all hydrologic components and fluxes to provide a multivariate, holistic validation of the complete modeled water balance.

O'Neill, Mary M. F. (ORCID:0000000221455165)↗
DOE OSTI2025

Long-term hydro-economic analysis tool for evaluating global groundwater cost and supply: Superwell v1.1

Abstract. Groundwater plays a key role in meeting water demands, supplying over 40 % of irrigation water globally, with this role likely to grow as water demands and surface water variability increase. A better understanding of the future role of groundwater in meeting sectoral demands requires an integrated hydro-economic evaluation of its cost and availability. Yet substantial gaps remain in our knowledge and modeling capabilities related to groundwater availability, recharge, feasible locations for extraction, extractable volumes, and associated extraction costs, which are essential for large-scale analyses of integrated human–water system scenarios, particularly at the global scale. To address these needs, we developed Superwell, a physics-based groundwater extraction and cost accounting model that operates at sub-annual temporal and at the coarsest 0.5° (≈50 km × 50 km) gridded spatial resolution with global coverage. The model produces location-specific groundwater supply–cost curves that provide the levelized cost to access different quantities of available groundwater. The inputs to Superwell include recent high-resolution hydrogeologic datasets of permeability, porosity, aquifer thickness, depth to water table, recharge, and hydrogeological complexity zones. It also accounts for well capital and maintenance costs, as well as the energy costs required to lift water to the surface. The model employs a Theis-based scheme coupled with an amortization-based cost accounting formulation to simulate groundwater extraction and quantify the cost of groundwater pumping. The result is a spatiotemporally flexible, physically realistic, economics-based model that produces groundwater supply–cost curves. We show examples of these supply–cost curves and the insights that can be derived from them across a set of scenarios designed to explore model outcomes. The supply–cost curves produced by the model show that most (90 %) nonrenewable groundwater in storage globally is extractable at costs lower than USD 0.57 m−3, while half of the volume remains extractable at under USD 0.108 m−3. The global unit cost is estimated to range from a minimum of USD 0.004 m−3 to a maximum of USD 3.971 m−3. We also demonstrate and discuss examples of how these cost curves could be used by linking Superwell's outputs with other models to explore coupled human–environmental system challenges, such as water resources planning and management, or broader analyses of multisectoral feedbacks.

Global Change Analysis Model (GCAM)↗
DOE OSTI2022

Technical note: Using long short-term memory models to fill data gaps in hydrological monitoring networks

Abstract. Quantifying the spatiotemporal dynamics in subsurface hydrological flows over a long time window usually employs a network of monitoring wells. However, such observations are often spatially sparse with potential temporal gaps due to poor quality or instrument failure. In this study, we explore the ability of recurrent neural networks to fill gaps in a spatially distributed time-series dataset. We use a well network that monitors the dynamic and heterogeneous hydrologic exchanges between the Columbia River and its adjacent groundwater aquifer at the U.S. Department of Energy's Hanford site. This 10-year-long dataset contains hourly temperature, specific conductance, and groundwater table elevation measurements from 42 wells with gaps of various lengths. We employ a long short-term memory (LSTM) model to capture the temporal variations in the observed system behaviors needed for gap filling. The performance of the LSTM-based gap-filling method was evaluated against a traditional autoregressive integrated moving average (ARIMA) method in terms of error statistics and accuracy in capturing the temporal patterns of river corridor wells with various dynamics signatures. Our study demonstrates that the ARIMA models yield better average error statistics, although they tend to have larger errors during time windows with abrupt changes or high-frequency (daily and subdaily) variations. The LSTM-based models excel in capturing both high-frequency and low-frequency (monthly and seasonal) dynamics. However, the inclusion of high-frequency fluctuations may also lead to overly dynamic predictions in time windows that lack such fluctuations. The LSTM can take advantage of the spatial information from neighboring wells to improve the gap-filling accuracy, especially for long gaps in system states that vary at subdaily scales. While LSTM models require substantial training data and have limited extrapolation power beyond the conditions represented in the training data, they afford great flexibility to account for the spatial correlations, temporal correlations, and nonlinearity in data without a priori assumptions. Thus, LSTMs provide effective alternatives to fill in data gaps in spatially distributed time-series observations characterized by multiple dominant frequencies of variability, which are essential for advancing our understanding of dynamic complex systems.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2023

Developing Methods to Assess Changes in Mechanical Properties of Shale Modified by Engineered Mineral Precipitation

Fractures in subsurface shale formations serve multiple purposes, for example, in the recovery of resources in hydraulic fracturing or as potential harmful leakage passages through caprocks that may contribute undesired fluids to the atmosphere or functional groundwater aquifers. A proposed method to seal or influence fracture properties is Ureolysis-Induced Calcium Carbonate Precipitation (UICP), a bio-mineralization technology driven by the enzymatic hydrolysis of urea, resulting in the formation of calcium carbonate. The resulting calcium carbonate can bridge the gaps in fractured shale and reduce fluid flow through fractures. This study represents the first step toward determining the influence of UICP treatment on shale material and its subsequent mechanical strength properties. The goal of this preliminary work is twofold: first, we aim to identify a method to test tensile strength along a core axis and second, we seek to assess the effect of temperature on the tensile strength of intact, unfractured shale cores (2.54 cm (1 in) diameter, 5.08 cm (2 in) long for comparison with future fractured and UICP-treated cores. A modified Brazilian indirect tensile strength test successfully measured splitting tensile strength of shale cores from Eagle Ford and Wolfcamp formations at room temperature and 60°C.

clastic rock↗
NASA NTRS1971

Remote sensing in hydrology: A survey of applications with selected bibliography and abstracts

Remote infrared sensing as a water exploration technique is demonstrated. Various applications are described, demonstrating that infrared sensors can locate aquifers, geothermal water, water trapped by faults, springs and water in desert regions. The potentiality of airborne IR sensors as a water prospecting tool is considered. Also included is a selected bibliography with abstracts concentrating on those publications which will better acquaint the hydrologist with investigations using thermal remote sensors as applied to water exploration.

Sers, S. W.↗
NASA NTRS1971

Proceedings of the 2nd Columbia River Basalt Symposium: Maar volcanoes

Examination of maar-type volcanic cones, including tuff rings, from more than 40 localities in western North America indicates that water had access to volcano orifices during their activity. The most convincing evidence is the abundance of sideromelane (chilled basaltic glass) or its palagonitic decomposition products in the ejecta. Moreover, the volcanoes which were examined erupted in basins that either contained surface water, or else they grew above highly permeable aquifers at shallow dept. Characteristic features of maar ejecta are continuous thin beds, undulations and antidunes characteristic of base surge stratification, abundant accretionary lapilli or mud-armored rock particles, bedding sags that show soft sediment deformation, and in the subaqueous parts of the maar ramparts, great piles of subtly graded thin lenses of hyaloclastic debris.

Waters, A. C.↗
NASA NTRS1973

Glaciation of northwestern Wyoming interpreted from ERTS-1

Analysis of ERTS Imagery has shown a number of alpine glacial features can be recognized and mapped successfully. Although the Wyoming mountains are generally regarded as the type locality for Rocky Mountain glaciation some areas have not been studied from a glacial standpoint because of inaccessibility or lack of topographic control. ERTS imagery provides an excellent base for this type of regional geomorphic study. A map of maximum extent of Wisconsin Ice, flow directions and major glacial features was compiled from interpretation of the ERTS imagery. Features which can be mapped are large moraines, outwash fans and terraces. Present-day glaciers and snowfields are easily discriminated and mapped. Glaciers and glacial deposits which serve as aquifers play a significant role in the hydrologic cycle and are important because of the increasing demand placed on our water resources. ERTS provides a quick and effective method for change detection and inventory of these vital resources.

Breckenridge, R. M.↗
NASA NTRS1974

Hydrologic applications of Nimbus 5 ESMR data

A region of low brightness temperature lying along the Mississippi River from Cairo, Illinois, to Morganza, Louisiana was observed in early Nimbus 5 Electrically Scanning Microwave Radiometer images. This region, which generally corresponds to an outwash aquifer in the Mississippi Valley, had brightness temperatures, at times as much as 40 K below the surrounding (drier) older uplands. Fluctuations of as much as 30 K were observed during the time interval 15 December 1972 to 28 February 1973. Comparison images taken from the Earth Resources Technology Satellite indicate that the study area is aligned with the Mississippi River floodplain, a region of potentially high soil moisture content. The brightness temperature fluctuations were compared with variations in precipitation and other hydrologic parameters in order to delineate the causative factors.

Schmugge, T. J.↗
NASA NTRS1974

Geological evaluation and applications of ERTS-1 imagery over Georgia

ERTS-1 70mm and 9 x 9 film negatives are being used by conventional and color enhancement methods as a tool for geologic investigation. Geologic mapping and mineral exploration by conventional methods is very difficult in Georgia. Thick soil cover and heavy vegetation cause outcrops of bed rock to be small, rare and obscure. ERTS imagery, and remote sensing in general have helped delineate: (1) major tectonic boundaries; (2) lithologic contacts; (3) foliation trends; (4) topographic lineaments; and (5) faults. The ERTS-1 MSS imagery yields the greatest amount of geologic information on the Piedomont, Blue Ridge, and Valley and Ridge Provinces of Georgia where topography is strongly controlled by the bedrock geology. ERTS imagery, and general remote sensing techniques, have provided us with a powerful tool to assist geologic research; have significantly increased the mapping efficiency of our field geologists; have shown new lineaments associated with known shear and fault zones; have delineated new structural features; have provided a tool to re-evaluate our tectonic history; have helped to locate potential ground water sources and areas of aquifer recharge; have defined areas of geologic hazards; have shown areas of heavy siltation in major reservoirs; and by its close interval repetition, have aided in monitoring surface mine reclamation activities and the environmental protection of our intricate marshland system.

Pickering, S. M.↗
NASA NTRS1974

Geologic evaluation and applications of ERTS-1 imagery over Georgia

Satellite imagery and other remote sensing tools and techniques have provided a powerful tool to assist geologic research; significantly increased the mapping efficiency of field geologists; shown new lineaments associated with known shear and fault zones; delineated new structural features; provided a tool to reevaluate tectonic history; helped to locate potential ground-water sources and areas of aquifer recharge; defined areas of geologic hazards; shown areas of heavy siltation in major reservoirs; and, by close interval repetition, aided in monitoring surface mine reclamation activities and the environmental protection of the intricate marshland system. The Georgia Geological Survey has been engaged in regional mapping for the new state geologic map. ERTS-1 images enlarged to compatible mapping scales have increased field geologic mapping efficiency by at least 25%. There are a number of areas where data from ERTS-1 imagery has allowed a notably higher level of precision than has been available with any amount of field work on the ground.

Pickering, S. M.↗
NASA NTRS1974

Overview of Reclamation's geothermal program in Imperial Valley, California

The Bureau of Reclamation is presently involved in a unique Geothermal Resource Development Program in Imperial Valley, California. The main purpose of the investigations is to determine the feasibility of providing a source of fresh water through desalting geothermal fluids stored in the aquifers underlying the valley. Significant progress in this research and development stage to date includes extensive geophysical investigations and the drilling of five geothermal wells on the Mesa anomaly. Four of the wells are for production and monitoring the anomaly, and one will be used for reinjection of waste brines from the desalting units. Two desalting units, a multistage flash unit and a vertical tube evaporator unit, have been erected at the East Mesa test site. The units have been operated on shakedown and continuous runs and have produced substantial quantities of high-quality water.

Fulcher, M. K.↗
NASA NTRS1975

Delineation of the boundaries of a buried pre-glacial valley with LANDSAT-1 data

The continuity of a narrow meandering strip of Udoll (prairie) soils running east and west for approximately 40 miles across north central Indiana in an area predominantly of Udalfs (timber soils) was detected from LANDSAT-1 data taken on June 9, 1973. This data was processed through a clustering procedure and classified with resulting increased definition of the boundaries among soils grouped according to nine categories and vegetation to two categories of reflectance. This dark stretch of prairie soil is believed to have formed in the heavy textured, poorly drained glacial debris which filled a major pre-glacial tributary of the Teays River System. Ready identification and location of the valley has significance to soil survey and land classification people as a guide to soil classification and land use and to geologists as a guide to location of a potentially economically significant aquifer.

Peterson, J. B.↗
NASA NTRS1975

Multidisciplinary study on Wyoming test sites

The author has identified the following significant results. Ten EREP data passes over the Wyoming test site provided excellent S190A and S190B coverage and some useful S192 imagery. These data were employed in an evaluation of the EREP imaging sensors in several earth resources applications. Boysen Reservoir and Hyattsville were test areas for band to band comparison of the S190 and S192 sensors and for evaluation of the image data for geologic mapping. Contrast measurements were made from the S192 image data for typical sequence of sedimentary rocks. Histograms compiled from these measurements show that near infrared S192 bands provide the greatest amount of contrast between geologic units. Comparison was also made between LANDSAT imagery and S190B and aerial photography for regional land use mapping. The S190B photography was found far superior to the color composite LANDSAT imagery and was almost as effective as the 1:120,000 scale aerial photography. A map of linear elements prepared from LANDSAT and EREP imagery of the southwestern Bighorn Mountains provided an important aid in defining the relationship between fracture and ground water movement through the Madison aquifer.

Houston, R. S.↗
NASA NTRS1977

Basic hydrogeologic and remote sensing data for selection of sanitary landfill sites

Solid waste disposal were studied in Volusia County to protect the water supply in the area. Highlands in this County are of limited areal extent and, most significantly, the sand hills and ridges are in areas where recharge of the Floridan aquifer occurs. This study proves that well drained soils meeting the current State requirements are of limited areal extent. These areas should not be utilized as sanitary landfill sites! Rather, it is recommended that the Tomoka Farm Road site into the adjacent wetlands be extended. The County site on Rima Ridge recommended by Greenleaf-Telesca as the primary waste burial site in the County should be re-evaluated because of potential danger to the Daytona Beach water supply.

Brooks, H. K.↗
NASA NTRS1977

Thermal storage for electric utilities

Applications of the thermal energy storage (TES) principle (storage of sensible heat or latent heat, or heat storage in reversible chemical reactions) in power systems are evaluated. Load leveling behind the meter, load following at conventional thermal power plants, solar thermal power generation, and waste heat utilization are the principal TES applications considered. Specific TES examples discussed include: storage heaters for electric-resistance space heating, air conditioning TES in the form of chilled water or eutectic salt baths, hot water TES, and trans-seasonal storage in heated water in confined aquifers.

Swet, C. J.↗
NASA NTRS1978

Role of remote sensing in Bay measurements

Remote measurements of a number of surface or near surface parameters for baseline definition and specialized studies, remote measurements of episodic events, and remote measurements of the Bay lithosphere are considered in terms of characterizing and understanding the ecology of the Chesapeake Bay. Geologic processes and features best suited for information enhancement by remote sensing methods are identified. These include: (1) rates of sedimentation in the Bay; (2) rates of erosion of Bay shorelines; (3) spatial distribution and geometry of aquifers; (4) mapping of Karst terrain (sinkholes); and (5) mapping of fracture patterns. Recommendations for studying problem areas identified are given.

Mugler, J. P., Jr.↗