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At least 541 records · Page 30

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NASA NTRS1991

COSP - A computer model of cyclic oxidation

A computer model useful in predicting the cyclic oxidation behavior of alloys is presented. The model considers the oxygen uptake due to scale formation during the heating cycle and the loss of oxide due to spalling during the cooling cycle. The balance between scale formation and scale loss is modeled and used to predict weight change and metal loss kinetics. A simple uniform spalling model is compared to a more complex random spall site model. In nearly all cases, the simpler uniform spall model gave predictions as accurate as the more complex model. The model has been applied to several nickel-base alloys which, depending upon composition, form Al2O3 or Cr2O3 during oxidation. The model has been validated by several experimental approaches. Versions of the model that run on a personal computer are available.

Lowell, Carl E.↗

NASA NTRS1992

Oxidation characteristics of Ti-25Al-10Nb-3V-1Mo

Static oxidation kinetics of the super-alpha 2 titanium-aluminide alloy Ti-25Al-10Nb-3V-1Mo (at. percent) were investigated in air over the temperature range of 650 to 1000 C using thermogravimetric analysis. The oxidation kinetics were complex at all exposure temperatures and displayed up to three distinct oxidation rates. Breakaway oxidation occurred after long exposure times at high temperatures. Oxidation products were determined using X-ray diffraction techniques, electron microprobe analysis, and energy dispersive X-ray analysis. Oxide scale morphology was examined by scanning electron microscopy of the surfaces and cross sections of oxidized specimens. The oxides during the parabolic stages were compact and multilayered, consisting primarily of TiO2 doped with Nb, a top layer of Al2O3, and a thin bottom layer of TiN. The transition between the second and third parabolic stage was found to be linked to the formation of a TiAl layer at the oxide-metal interface. Porosity was formed during the third stage, causing degradation of the oxide and the beginning of breakaway oxidation.

Wallace, T. A.↗

NASA NTRS1990

Quantification of hydrochloric acid and particulate deposition resulting from Space Shuttle launches at John F. Kennedy Space Center, Florida, U.S.A.

Results are presented from studies designed to identify deposition patterns and quantify the ecosystem loading rates of exhaust constituents (which are primarily Al2O3 and HCl) from the Space Shuttle solid rocket motors in the area of the Kennedy Space Center launch pad. Results of measurements indicate that, under certain meteorological conditions, as much as 7.1 x 10 exp 3 kg of particulates and 3.4 x 10 exp 3 kg HCL can be deposited to the near-field environment beyond the launch pad perimeter fence during one STS launch.

Dreschel, Thomas W.↗

NASA NTRS1992

Effectiveness of metal matrix and ceramic matrix composites as orbital debris shield materials

The effectiveness of two metal matrix composites and one ceramic matrix material in defeating hypervelocity impacts at about 3.8 km/s are evaluated to determine the potential of these composites as spacecraft shield materials. The metal matrix composites investigated consist of SiC particles (70 percent by volume) in an aluminum matrix and Al2O3 particles (50 percent by volume) in an Al matrix. The ceramic composite consists of ZrB2 platelets in a ZrC matrix. Both the metal matrix and ceramic matrix composites are found to perform as well or better than 6061-T6 aluminum, which is presently used in the Whipple type bumper shield of Space Station Freedom. Test results indicate that the composites tested may have applications as micrometeoroid/orbital debris shield materials.

Mcgill, Preston B.↗

NASA NTRS1992

Environmental durability of ceramics and ceramic composites

An account is given of the current understanding of the environmental durability of both monolithic ceramics and ceramic-matrix composites, with a view to the prospective development of methods for the characterization, prediction, and improvement of ceramics' environmental durability. Attention is given to the environmental degradation behaviors of SiC, Si3N4, Al2O3, and glass-ceramic matrix compositions. The focus of corrosion prevention in Si-based ceramics such as SiC and Si3N4 is on the high and low sulfur fuel combustion-product effects encountered in heat engine applications of these ceramics; sintering additives and raw material impurities are noted to play a decisive role in ceramics' high temperature environmental response.

Fox, Dennis S.↗

NASA NTRS1992

Petrogenesis of mare basalts - A record of lunar volcanism

The classification, sources, and overall petrogenesis of mare basalts are reviewed. All mare basalt analyses are used to define a sixfold classification scheme using TiO2 contents as the primary division. A secondary division is made using Al2O3 contents, and a tertiary division is defined using K contents. Such divisions and subdivisions yield a classification containing 12 categories, of which six are accounted for by the existing Apollo and Luna collections. A variety of postmagma-generation such as fractional crystallization, either alone or combined with wallrock assimilation, are invoked to explain the compositional ranges of the various mare basalt suites. High-Ti mare basalts are found at Apollo 1 and Apollo 17 sites; the A-11 basalts contain lower TiO2 abundances, a considerably larger range in trace-element contents, and the only occurrence of high-Ti/high-K mare basalts. The low-Ti basalts exhibit a wide range of major-and trace-element compositions and require source heterogeneity, fractional crystallization, and some assimilation.

Neal, Clive R.↗

NASA NTRS1990

Initial evaluation of continuous fiber reinforced NiAl composites

NiAl is being evaluated as a potential matrix material as part of an overall program to develop and understand high-temperature structural composites. Currently, continuous fiber composites have been fabricated by the powder cloth technique incorporating either W(218) or single crystal Al2O3 fibers as reinforcements in both binary NiAl and a solute strengthened NiAl(.05 at. pct Zr) matrix. Initial evaluation of these composite systems have included: fiber push-out testing to measure matrix/fiber bond strengths, bend testing to determine strength as a function of temperature and composite structure, and thermal cycling to establish the effect of matrix and fiber properties on composite life. The effect of matrix/fiber bond strength and matrix strength on several composite properties will be discussed.

Noebe, R. D.↗

NASA NTRS1979

A low-cost solar-cell front contact using trapped silver mesh and electrostatic bonding

A new system to provide a contact with a silver mesh trapped between the cell and an encapsulating glass cover is described. Borosilicate glass is joined to the cell by electrostatic bonding during which the glass is deformed around the silver mesh to form a permanent optically coupled integral bond to the cell. The hermetic seal prevents the silver from oxidizing and destroying the electrical contact formed during the bonding process. It is demonstrated that electrostatic glass/silicon bonds have excellent stability under a variety of accelerated environmental tests. Electrostatic bonds to thin films of AL2O3, Ta2O5, and ZrO2 on glass can be used to make antireflective coatings for solar cells manufactured by this process. Test solar cells were manufactured by electrostatic bonding with good curve fill factors and efficiencies of 10 percent.

Landis, Geoffrey A.↗

NASA NTRS1992

Olivine in Antarctic micrometeorites - Comparison with other extraterrestrial olivine

The compositions of 5-micron or larger Mg-rich olivines from 26 Antarctic micrometeorite particles were examined and compared with those of other extraterrestrial olivine. The following differences were noted between the Antarctic meteorites and the generally recognized meteorite groups: (1) while refractory-rich (e.g., high Al2O3 or CaO) are common in C2, C3, and UOC meteorites, there are only rare, or possibly no refractory-rich olivines in Antarctic micrometeorites; (2) Mg-rich olivine compositions with FeO less than 1.9 wt pct are underrepresented in the Antarctic micrometeorites, relative to other unequilibrated meteorites; and (3) no Mn-rich, high-Mg olivines were found similar to those described in interplanetary dust, C1, C2, C3, and UOC meteorites.

Steele, Ian M.↗

NASA NTRS1992

Thermal degradation events as health hazards - Particle vs gas phase effects, mechanistic studies with particles

Experiments on animal subjects are performed to demonstrate that significant lung injury can result from the inhalation of ultrafine TiO2 or Al2O3 particles. The methods include intratracheal instillation of particles, long-term inhalation of particles, and in vitro studies of alveolar macrophages (AMs) to study the production of fibroplast growth factors. The ultrafine TiO2 particles are shown to induce more acute inflammatory reactions than larger particles and lead to persistent chronic effects in the AM-mediated clearance function of particles. The ultrafine particles also induce cytokines more readily, and the data generally suggests that the occurrence of such particles in thermal degradation events makes the fumes highly toxic. The exposure to thermal degradation products is therefore a critical concern for manned space missions with potentially degradable plastic products.

Oberdoerster, G.↗

NASA NTRS1993

High-Emittance, Low-Absorbance Thermal-Control Coating

Modified process for anodizing 5657 aluminum alloy results in Al2O3 surfaces with infrared emissivities as great as 0.92 and solar absorptivities as small as 0.2. Coating enables fabrication of radiators requiring less surface, and hence less weight: radiators with coating weigh approximately 7 percent less than thermally equivalent radiators made with older anodizing processes. Coating applied easily and economically, and retains all of desirable properties of standard anodized coatings.

Le, Huong G.↗

NASA NTRS1992

Impactites from Popigai Crater

Impactites (tagamites and suevites) from Popigai impact crater, whose diameter is about 100 km, are distributed over an area of 5000 sq km. The continuous sheet of suevite overlies the allogenic polymict breccia and partly authogenic breccia, and may also be observed in lenses or irregular bodies. The thickness of suevites in the central part of the crater is more than 100 m. Suevites may be distinguished by content of vitroclasts, lithoclasts, and crystalloclasts, by their dimensions, and by type of cementation, which reflects the facial settings of ejection of crushed and molten material, its sedimentation and lithification. Tagamites (impact melt rocks) are distributed on the surface predominantly in the western sector of the crater. The most characteristic are thick sheetlike bodies overlying the allogenic breccia and occurring in suevites where minor irregular bodies are widespread. The maximal thickness of separate tagamite sheets is up to 600 m. Tagamites, whose matrix is crystallized to a different degree, include fragments of minerals and gneiss blocks, among them shocked and thermally metamorphosed ones. Tagamite sheets have a complex inner structure; separate horizontal zones distinguish in crystallinity and fragment saturation. Differentiation in the impact melt in situ was not observed. The average chemical compositions of tagamites and suevites are similar, and correspond to the composition of biotite-garnet gneisses of the basement. According to the content of supplied Ir, Ni, and other siderophiles, impact melt was contaminated by 5 percent cosmic matter of collided body, probably ordinary chondrite. The total volume of remaining products of chilled impact melt is about 1750 cu km. Half this amount is represented by tagamite bodies. Though impact melt was in general well homogenized, the trend analysis showed that the concentric zonation is distribution of SiO2, MgO, and Na2O and the bandlike distribution of FeO and Al2O3 content testifies to a certain inheritance and heterogeneity in country rock composition laterally and vertically in the melting zone.

Masaitis, V. L.↗

NASA NTRS1991

Predicted rocket and shuttle effects on stratospheric ozone

The major chemical effluents of either solid- or liquid-fueled rockets that can potentially perturb stratospheric ozone include chlorine compounds (HCl), nitrogen compounds (NO(x)), and hydrogen compounds (H2 and H2O). Radicals (Cl, ClO, H, OH, HO2, NO, and NO2) formed directly or indirectly from rocket exhaust can cause the catalytic destruction of ozone. Other exhaust compounds that could presumably lead to ozone destruction either by direct reaction with ozone or by providing a surface for heterogeneous processes include the particulates Al2O3, ice, and soot. These topics are discussed in terms of the possible effects of rocket exhausts on stratospheric ozone.

Harwood, Robert S.↗

NASA NTRS1992

Silicon carbide fiber reinforced strontium aluminosilicate glass-ceramic matrix composite

A SrO-Al2O3 - 2SrO2 (SAS) glass ceramic matrix is reinforced with CVD SiC continuous fibers. This material is prepared by casting a slurry of SAS glass powder into tapes. Mats of continuous CVD-SiC fibers are alternately stacked with the matrix tapes. This tape-mat stack is warm-pressed to produce a 'green' composite. Organic constituents are burned out of the 'green' composite, and the remaining interim material is hot pressed.

Bansal, Narottam↗

NASA NTRS1992

Superplastic forming of ceramic insulation

Superplasticity has been demonstrated in many fine-grained structural ceramics and ceramic composites, including yttria-stabilized tetragonal zirconia polycrystal (YTZP), alumina, and Al2O3-reinforced zirconia (Al2O3/YTZ) duplex composites and SiC-reinforced Si3N4. These superplastic ceramics obviously offer the potential benefit of forming net shape or near net shape parts. This could be particularly useful for forming complicated shapes that are difficult to achieve using conventional forming techniques, or require elaborate, subsequent machining. In the present study, we successfully demonstrated the following: (1) superplastic 3Y-TXP and 20 percent Al2O3/YTZ composite have for the first time been successfully deformed into hemispherical caps via a biaxial gas-pressure forming technique; (2) no experimental difficulty was encountered in applying the required gas pressures and temperatures to achieve the results, thus, it is certain that higher rates of deformation than those presented in this study will be possible by using the current test apparatus at higher temperatures and pressures; and (3) an analytical model incorporating material parameters, such as variations during forming in the strain rate sensitivity exponent and grain growth-induced strain hardening, is needed to model accurately and therefore precisely control the biaxial gas-pressure forming of superplastic ceramics. Based on the results of this study, we propose to fabricate zirconia insulation tubes by superplastic extrusion of zirconia polycrystal. This would not only reduce the cost, but also improve the reliability of the tube products.

Nieh, T. G.↗

NASA NTRS1992

The formation of ore mineral deposits on the Moon: A feasibility study

Most of the ore deposits on Earth are the direct result of formation by hydrothermal solutions. Analogous mineral concentrations do not occur on the Moon, however, because of the absence of water. Stratified ore deposits form in layered instrusives on Earth due to fractional crystallization of magma and crystal settling of high-density minerals, particularly chromium in the mineral chromite. We have evaluated the possibility of such mineral deposition on the Moon, based upon considerations of 'particle settling velocities' in lunar vs. terrestrial magmas. A first approximation of Stoke's Law would seem to indicate that the lower lunar gravity (1/6 terrestrial) would result in slower crystal settling on the Moon. However, the viscosity of the silicate melt is the most important factor affecting the settling velocity. The viscosities of typical lunar basaltic melts are 10-100 times less than their terrestrial analogs. These lower viscosities result from two factors: (1) lunar basaltic melts are typically higher in FeO and lower in Al2O3, Na2O, and K2O than terrestrial melts; and (2) lunar igneous melts and phase equilibria tend to be 100-150 C higher than terrestrial, largely because of the general paucity of water and other volatile phases on the Moon. Therefore, particle settling velocities on the Moon are 5-10 times greater than those on Earth. It is highly probable that stratiform ore deposits similar to those on Earth exist on the Moon. The most likely ore minerals involved are chromite, ilmenite, and native FeNi metal. In addition, the greater settling velocities of periodotite in lunar magmas indicate that the buoyancy effects of the melt are less than on Earth. Consequently, the possibility is considerably less than on Earth of deep-seated volcanism transporting upper mantle/lower crustal xenoliths to the surface of the Moon, such as occurs in kimberlites on Earth.

Taylor, Lawrence A.↗

NASA NTRS1992

Sliding durability of candidate seal fiber materials in hydrogen from 25 to 900 C

Sliding durability studies of candidate ceramic fibers were conducted in hydrogen to support the high temperature seal development program at NASA LeRC. Pin-on-disk tests were used to measure the friction and durability of a tow or bundle of ceramic fibers in sliding against a superalloy disk. This procedure was used previously to test candidate fibers in an air environment. The fibers based upon mullite (Al2O3-SiO2) chemistry (Nextel 550, 440, and 312) exhibited better durability in hydrogen than in air. HPZ, a complex silicon carboxynitride fiber which showed good durabilty in air, however, showed a significant loss of durability in hot hydrogen. These results are consistent with recent thermodynamic and experimental studies of ceramic compatibility with hydrogen at elevated temperatures. These research results indicate that only oxide fibers display good durability in both air and hydrogen environments. Also, simple, low cost testing in air can provide an adequate data base for initial seal material screening and selection, especially for oxide fiber candidates. The findings of this research provide critical input to the seal design team.

Dellacorte, Christopher↗

NASA NTRS1993

Advanced reinforcement systems for intermetallic applications

A 2-D axisymmetric model was employed to determine the magnitude of the radial, axial, and hoop stresses caused by the thermal expansion difference between fiber and matrix and which result from the fabrication temperature cycle. Finite element analysis was conducted for single fiber model systems based on SCS-6/Ti3Al+Nb and Al2O3/NiAl. The stress distribution due to the imposition of a graded intermediate layer for each system was determined and included variables of layer thickness and gradation in interlayer chemistry in order to vary the expansion gradient between fiber and matrix. Thermal cycling tests were conducted on sputter coated SCS-6 fibers selectively coated with Ti3Al+Nb, with and without an intermediate layer. Cracking of the Ti3Al+Nb layers was prevented by an interlayer based on Ti-TiN-Ti. The interlayer thickness appeared critical to its efficiency. Similarly, for the case of Al2O3/NiAl, an intermediate layer consisting of a Ni bond coat on the sapphire fiber followed by a graded Al2O3-NiAl layer did not crack when given a thermal excursion to 1100 C and then cooled to room temperature. Acoustic emission tests on single fiber specimens were unsuccessful in detecting load drops associated with the successive fracture of the fiber. For the SCS-6/Ti3Al system this was the result of several factors which included the matrix/fiber ratio and poor bonding of the matrix and fiber. In the case of the Al2O3/NiAl system brittle failure of the NiAl matrix precluded fiber breakdown during tensile loading.

Merrick, Howard F.↗