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At least 541 records · Page 30

BLEECAM™ (Benchmarking Life Cycle Environmental, Economic, and Social Metrics for Critical and Advanced Minerals and Materials) [SWR-25-125]

The National Laboratory of the Rockies' (NLR) Benchmarking Life Cycle Environmental, Economic, and Social Metrics for Critical and Advanced Minerals and Materials (BLEECAM™) is an open-source, integrated decision-support tool for evaluating the impacts, risks, and trade-offs across U.S. and global materials supply chains. Funded by the U.S. Department of Energy, BLEECAM supports supply chain and market analysis. The tool integrates multi-objective supply chain optimization, system dynamics, network design, lifecycle assessment, techno-economic modeling, and social impact assessment methods to evaluate how supply chains evolve over time, geography, and deployment scenarios. BLEECAM also supports analysis related to energy infrastructure, data centers and digital infrastructure, advanced manufacturing, and other sectors that depend on critical materials.

Khalifa, SherifA. [National Laboratory of the Rock↗

FWP FEW0223: "Advanced Manufactured Carbonate Materials for Algal Biomass Production: Joint LLNL SNL Program" (Final Report)

The ability to easily and cheaply transport carbon dioxide (CO 2 ) from coal-fired power plants equipped with capture facilities to multiple, potentially distant utilization sites of widely varying scales will enable wider use of CO 2 captured from flue gas. In the case of algal biomass cultivation, delivery of CO 2 in the form of carbonate-based materials may provide a more efficient and economical method of inorganic carbon delivery than CO 2 sparging, reducing the cost of algae cultivation and increasing the value of carbon capture. Lawrence Livermore National Laboratory (LLNL) has developed advanced manufactured materials that are well-suited for carbon capture, storage, transport, and delivery. These materials consist of aqueous sodium carbonate, which captures CO 2 as sodium bicarbonate, extruded or 3D printed in a CO 2 permeable polymer to increase the surface area and improve capture kinetics. By encapsulating carbonate solutions, LLNL has demonstrated order-of-magnitude enhancements in carbon capture rates compared with liquid carbonates, enabling the use of these (otherwise kinetically-limited) inexpensive, environmentally-benign solvents for carbon capture.

20 FOSSIL-FUELED POWER PLANTS↗

High temperature thick film sensor development based on doped lanthanum chromites refractory semiconductors materials

High temperature advanced sensing materials have generated high demand due the high accuracy temperature measurements requirements for process optimization, controlling and sensing. Some technological applications of harsh conditions sensing include monitoring tiles of space shuttles, rotating bearings in aircraft engines, turbines, jet engines dynamics and chemical reactors. High temperature conditions limit the sensing strategies, where typically traditional metal thermocouples are unstable, and the sensing options are limited to optical spectroscopy methods. Recently, refractory semiconductors thick- and thin-film thermocouples have been developed and, in many cases, preferred over conventional metallic thermocouples due their spatial resolution, and capability of direct deposition on any surface. Rare earth chromites ceramics materials, exhibit some properties of interest for high temperature sensing technologies development, such as: high microstructure and sintering stability, excellent conductive behavior at high temperatures, and matching thermal expansion coefficients relative to other conductors and refractory ceramics. In this work, high performance ultra-high temperature thermocouples using p-type and n-type doped lanthanum chromites materials were fabricated and tested at temperatures up to 1500 o C. Thermoelectric voltage, Seebeck Coefficients were established for all devices, evidencing high stability and performance in prolongated operational time and harsh conditions.

20 FOSSIL-FUELED POWER PLANTS↗

Incorporating A Risk-Informed, Performance-Based Concept into Nuclear Fuel and Materials Development for Advanced Reactors

The NRC’s regulatory concept for advanced reactors under 10 CFR Part 53 promotes the use of an RIPB concept. RIPB is usually referenced as a general, overarching concept. This paper is focused on how to, and if it would be worthy to, incorporate an RIPB concept into nuclear fuel and materials development for advanced reactors. This paper proposes three potential RIPB applications for nuclear fuel and materials development, including RIPB test matrix development, RIPB test matrix reduction, and RIPB design optimization. This paper discusses the projected benefits from incorporating RIPB in reducing development timeline, cost, and regulatory risk.

99 GENERAL AND MISCELLANEOUS↗

HydroGEN Overview: A Consortium on Advanced Water Splitting Materials

HydroGEN (https://www.h2awsm.org/) Energy Materials Network (EMN) is an U.S. Department of Energy (DOE) EERE Hydrogen and Fuel Cell Technologies Office (HFTO)-funded consortium that aims to accelerate the discovery and development of advanced water splitting materials (AWSM) for clean, low-cost hydrogen production. This is in line with the H2@Scale initiative (https://www.energy.gov/eere/fuelcells/h2-scale), with the goal to meet U.S. DOE's Hydrogen Shot production cost target of $1/kg H2 within 1 decade. Materials innovations are key to enhancing performance, durability, and cost of hydrogen generation technologies. Large scale, low cost hydrogen from diverse domestic resources can enable an economically competitive and environmentally beneficial future energy system across multiple sectors. HydroGEN is focused on low technology readiness level AWS technologies, including low- (alkaline exchanged membrane electrolysis) and high-temperature electrolysis (proton-conducting solid oxide electrolysis), photoelectrochecmical (PEC) and solar thermochemical (STCH) water splitting. This presentation will provide an overview of the HydroGEN EMN and technical highlights of a few lab-led and FOA-awarded R&D projects. HydroGEN continues to grow its community of industry, university, and national laboratories, forming a national innovation ecosystem focused on renewable hydrogen production.

clean hydrogen↗

A new capability facilitating nuclear materials research: the Activated Materials Laboratory at the Advanced Photon Source

The Activated Materials Laboratory (AML), located in the Long Beamline Building (LBB) of the Advanced Photon Source (APS) of Argonne National Laboratory (ANL), serves as a centralized radiological facility for preparing radioactive samples for APS beamline experiments. The AML is equipped to receive shipments, handle open-form radioactive materials, encapsulate samples, and transport samples to-and-from beamline end-stations. The AML works closely with users and the APS radiological safety committee to make sure the safe conduct of experiments.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗

FY23 Status Report of the Activated Materials Laboratory at the Advanced Photon Source

The Activated Materials Laboratory (AML) is a new radiological facility located at the Advanced Photon Source (APS) in Argonne National Laboratory (ANL), adjacent to the high-energy x-ray microscopy (HEXM) beamline in the long beamline building (LBB) constructed under the APS-upgrade (APS-U) project. The AML is a centralized facility to facilitate the safe conduct of experiments on activated materials at the APS. This report provides an overview of the status of the AML as a Nuclear Science User Facilities (NSUF) partner user facility in preparation for the general user access in 2024 upon the commissioning of the APS-U beamlines. Specifically, details are provided regarding the laboratory's scope, functionality, components, operational blueprint, and data management approach. The plans on augmenting the instrumentation, refining operational procedures and developing a robust data management strategy for FY24 and beyond are also discussed.

43 PARTICLE ACCELERATORS↗

Advanced Manufacturing and Materials for Hydropower: Challenges and Opportunities

Hydropower is a well-established industry that has been largely contributing to the global generation of clean and renewable energy for more than a century. In the United States in 2021, it accounted for 30% of all renewable energy generation and 6.1% of the total energy portfolio. Hydropower technology and designs have been optimized throughout the years, but manufacturing of hydropower components still relies heavily on traditional methods and materials. Changes in global energy production systems and international supply chain issues are inspiring the manufacturing sector to reconsider their processes. Similarly, the hydropower industry is facing manufacturing challenges stemming from well-known maintenance issues, environmental impact mitigations, and changes in operations. These challenges, along with continued innovation in new hydropower and pumped storage development and modernization of the fleet, present an opportunity for advanced manufacturing and materials (AMM) to provide immense value to the hydropower industry. In support of the US Department of Energy’s (DOE’s) Water Power Technologies Office (WPTO), this report aims to characterize the current and emerging manufacturing-related challenges in US hydropower and to identify the high-impact opportunities in AMM that could address these challenges. The results highlighted in this report were collected through literature review, individual stakeholder interviews, and an in-person workshop organized at DOE’s Oak Ridge National Laboratory Manufacturing Demonstration Facility that brought together hydropower industry stakeholders, advanced manufacturing R&D, and the government.

13 HYDRO ENERGY↗

Intercalation as a versatile tool for fabrication, property tuning, and phase transitions in 2D materials

Recent advances in two-dimensional (2D) materials have led to the renewed interest in intercalation as a powerful fabrication and processing tool. Intercalation is an effective method of modifying the interlayer interactions, doping 2D materials, modifying their electronic structure or even converting them into starkly different new structures or phases. Herein, we discuss different methods of intercalation and provide a comprehensive review of various roles and applications of intercalation in next-generation energy storage, optoelectronics, thermoelectrics, catalysis, etc. The recent progress in intercalation effects on crystal structure and structural phase transitions, including the emergence of quantum phases are also reviewed.

2D materials↗

A Regulatory Approach to Accelerated Deployment for New Material or Applications in Advanced Reactors

New advanced reactor developers may embark on deploying materials in novel and unique environments where a material’s long-term performance may be in question or unknown. In many cases, sufficient test data may not exist for the material in the desired application, or that no prescript or applicable regulatory testing requirements are available to demonstrate the safety of the application explicitly. This study endeavors to develop the framework for a regulatory and technical approach for safe and predictable accelerated materials use in advanced reactors guided by 10 CFR Part 50.43(e)(1), Advanced Reactor Design Criteria contained in Regulatory Guide 1.232, and Reliability Integrity Management Program (RIM) principles.

99 GENERAL AND MISCELLANEOUS↗

Materials descriptors for advanced water dissociation catalysts in bipolar membranes

The voltage penalty driving water dissociation (WD) at high current density is a major obstacle in the commercialization of bipolar membrane (BPM) technology for energy devices. Here, in this study, we show that three materials descriptors, that is, electrical conductivity, microscopic surface area and (nominal) surface-hydroxyl coverage, effectively control the kinetics of WD in BPMs. Using these descriptors and optimizing mass loading, we design new earth-abundant WD catalysts based on nanoparticle SnO 2 synthesized at low temperature with high conductivity and hydroxyl coverage. These catalysts exhibit exceptional performance in a BPM electrolyser with low WD overvoltage (η wd ) of 100 ± 20 mV at 1.0 A cm -2 . The new catalyst works equivalently well with hydrocarbon proton-exchange layers as it does with fluorocarbon-based Nafion, thus providing pathways to commercializing advanced BPMs for a broad array of electrolysis, fuel-cell and electrodialys is applications.

Sasmal, Sayantan↗

Materials Development and Advanced Process Simulation for Additive Manufacturing with Fiber-Reinforced Thermoplastics (Final Technical Report)

DuPont, Local Motors, and the Composites Manufacturing and Simulation Center (CMSC) at Purdue worked together to advance process simulation capabilities for Additive Manufacturing (AM) and develop printable short fiber reinforced semi-crystalline engineering thermoplastics suitable for vehicle components. DuPont provided one candidate thermoplastic material, which was evaluated against the following three criteria: 1) Printability using extrusion additive manufacturing processes. 2) Suitability for vehicle applications based on mechanical coupon screening tests. 3) Predictive capability of process simulations. Indiana Manufacturing Institute provided modeling and simulation technology and access to Purdue’s lab scale AM printer. Local Motors provided mechanical property requirements and printed demonstration prototype components using their Thermwood Large Scale Additive Manufacturing (LSAM) printer. To meet the performance and cost requirements of the automotive industry, high fiber content semi-crystalline engineering materials are required. Printing experience and property data for a 50% by weight short glass fiber reinforced material were gathered. Further, material properties required for simulating the printing process with the glass-fiber reinforced material were characterized. Knowledge was acquired with regards to the processability and performance of this thermoplastic material. Predictions of part deformation and crystallinity level were verified against experimental observations. Any significant results other than verification of simulation, e.g., novel material identified here would be impactful.

36 MATERIALS SCIENCE↗

Survey of Modeling and Simulation Techniques for Advanced Manufacturing Technologies Volume II – Predicting Material Performance from Material Microstructure

This report describes the current state of modeling and simulation techniques for predicting the properties of materials fabricated with advanced manufacturing techniques, given the initial microstructure of the material. The report includes a literature survey and a gap analysis outlining and prioritizing key issues in applying these modeling and simulation techniques to nuclear reactor structural materials. The discussion covers both physics-based and data-driven modeling techniques and includes a broad range of manufacturing techniques and materials that may have future nuclear applications. This report is the second in a two-part series, with the first report covering modeling and simulation methods for predicting the initial, as-manufactured structure of advanced manufacturing materials, given a description of the process. Both reports focus on a set of manufacturing technologies likely to be applied to reactor structural components. Taken together, the two reports provide a complete summary of the current state of processing-structure-properties models for advanced manufacturing as well as a survey of applications to reactor structural materials

42 ENGINEERING↗

Thermal Gradient and Neutron Irradiation Experiment Design for Fusion Reactor Materials in the Advanced Test Reactor

This work outlines a hypothetical coupled thermal gradient and neutron irradiation experiment in the Advanced Test Reactor (ATR) at the Idaho National Laboratory. Although the ATR is a thermal spectrum test reactor and doesn’t inherently produce a flux spectrum dominated by the high-energy neutrons typical in a fusion reactor, it’s multitude of experiment positions and dynamic flux environment make it a suitable platform for investigating fusion related issues.

36 MATERIALS SCIENCE↗

Laser synthesis and processing of atomically thin 2D materials

Recent advances in laser synthesis and processing of 2D materials are described that address key issues of scalable synthesis, precise heterogeneity control, and transformative manufacturing. Here, laser spectroscopy is used to remotely characterize and optimize the structure and functionality of 2D materials, enabling their in-situ diagnostic-based synthesis and processing.

2D materials↗

Materials Discovery

Advanced energy technologies are enabled by the constituent materials found in functional devices. Scientists at the National Renewable Energy Laboratory (NREL) are leaders in discovering the new materials that provide the foundation for future innovations.

36 MATERIALS SCIENCE↗

Sol–Gel‐Based Advanced Porous Silica Materials for Biomedical Applications

Abstract Porous silica‐based materials have burgeoning applications ranging from fillers and additives, to adsorbents, catalysts, and recently therapeutic agents and vaccines in nanomedicine. The preponderance of these materials is made by sol–gel processing wherein soluble silica precursors are reacted to form amorphous networks composed of siloxane bonds. The facile sol–gel approach allows for an unlimited variety of binary tertiary and more complex chemical compositions including organic ligands and networks resulting in so‐called organic–inorganic hybrid materials. Here, a brief review of the recent progress in sol–gel‐derived silica materials prepared as particles, thin films, biosilica/silica bioreplicas (of molecules, cells and organisms), and their related preparation, properties, and bioapplications is provided. First, it highlights the recent achievements of mesoporous silica nanoparticles in biomedical applications, including therapeutic agent delivery, multimodal imaging and theranostics, and bone tissue engineering and repair. Second, the research in evaporation‐induced self‐assembly (EISA)‐based mesostructured silica thin films and cell‐directed EISA in bio/nano interfaces for various bioapplications, such as bioactive coatings, biosensing, and living cell immobilization, has been reviewed. Third, the pioneering work in biomimetic silicification/immobilization of biomolecules and bio‐organisms and silica bioreplication of complex bio‐organisms is summarized. Finally, it is concluded with personal perspectives on the directions of future work on this field.

Lei, Qi↗