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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 541 records · Page 30
All sourcesNASA NTRSDOE OSTI
DOE OSTI2023

Aerosols overtake greenhouse gases causing a warmer climate and more weather extremes toward carbon neutrality

To mitigate climate warming, many countries have committed to achieve carbon neutrality in the mid-21 st century. Here, we assess the global impacts of changing greenhouse gases (GHGs), aerosols, and tropospheric ozone (O 3 ) following a carbon neutrality pathway on climate and extreme weather events individually using the Community Earth System Model version 1 (CESM1). The results suggest that the future aerosol reductions significantly contribute to climate warming and increase the frequency and intensity of extreme weathers toward carbon neutrality and aerosol impacts far outweigh those of GHGs and tropospheric O 3 . It reverses the knowledge that the changing GHGs dominate the future climate changes as predicted in the middle of the road pathway. Therefore, substantial reductions in GHGs and tropospheric O 3 are necessary to reach the 1.5 °C warming target and mitigate the harmful effects of concomitant aerosol reductions on climate and extreme weather events under carbon neutrality in the future.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2024

Anthropogenic aerosols mask increases in US rainfall by greenhouse gases

A comprehensive understanding of human-induced changes to rainfall is essential for water resource management and infrastructure design. However, at regional scales, existing detection and attribution studies are rarely able to conclusively identify human influence on precipitation. Here we show that anthropogenic aerosol and greenhouse gas (GHG) emissions are the primary drivers of precipitation change over the United States. GHG emissions increase mean and extreme precipitation from rain gauge measurements across all seasons, while the decadal-scale effect of global aerosol emissions decreases precipitation. Local aerosol emissions further offset GHG increases in the winter and spring but enhance rainfall during the summer and fall. Our results show that the conflicting literature on historical precipitation trends can be explained by offsetting aerosol and greenhouse gas signals. At the scale of the United States, individual climate models reproduce observed changes but cannot confidently determine whether a given anthropogenic agent has increased or decreased rainfall.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2023

Rapidly evolving aerosol emissions are a dangerous omission from near-term climate risk assessments

Abstract Anthropogenic aerosol emissions are expected to change rapidly over the coming decades, driving strong, spatially complex trends in temperature, hydroclimate, and extreme events both near and far from emission sources. Under-resourced, highly populated regions often bear the brunt of aerosols’ climate and air quality effects, amplifying risk through heightened exposure and vulnerability. However, many policy-facing evaluations of near-term climate risk, including those in the latest Intergovernmental Panel on Climate Change assessment report, underrepresent aerosols’ complex and regionally diverse climate effects, reducing them to a globally averaged offset to greenhouse gas warming. We argue that this constitutes a major missing element in society’s ability to prepare for future climate change. We outline a pathway towards progress and call for greater interaction between the aerosol research, impact modeling, scenario development, and risk assessment communities.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2024

Optical constants measurements of liquids for modeling aerosolized threats

Spectroscopic identification of aerosolized chemical threats is challenging due to the complex nature of the photon/particle interaction, as well as the diversity of possible particle sizes, morphologies, and compositions. Constructing a database of laboratory - measured transmittance spectra that covers each permutation is not practical. However, calculation of the spectra using the measured optical constants as a function of wavenumber, n(?) and k(?), for each of the liquids and/or solids composing the aerosol particles provides a viable alternative. These synthetic spectra (vis-à-vis laboratory-measured spectra) can be used to identify chemicals of interest and subtract out background interferents in field measurements. Using a well-established multiple pathlength approach, we measure the optical constants n/k for liquids that may be found as chemical species of interest or common background interferents aerosolized in plumes. These measurements are also used to generate several test case aerosol synthetic spectra.

Lockwood, Schuyler↗
DOE OSTI2020

Reducing the aerosol forcing uncertainty using observational constraints on warm rain processes

Global climate models (GCMs) disagree with other lines of evidence on the rapid adjustments of cloud cover and liquid water path to anthropogenic aerosols. Attempts to use observations to constrain the parameterizations of cloud processes in GCMs have failed to reduce the disagreement. We propose using observations sensitive to the relevant cloud processes rather than only to the atmospheric state and focusing on process realism in the absence of aerosol perturbations in addition to the process susceptibility to aerosols. We show that process-sensitive observations of precipitation can reduce the uncertainty on GCM estimates of rapid cloud adjustments to aerosols. The feasibility of an observational constraint depends on understanding the precipitation intensity spectrum in both observations and models and also on improving methods to compare the two.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2025

Shoreline wave breaking strongly enhances the coastal sea spray aerosol population: Climate and air quality implications

Sea spray aerosol (SSA) emission is a major source of atmospheric aerosols, influencing global climate and coastal air quality. Much of our knowledge about SSA derives from coastal observations near shorelines, but whether and when these observations accurately represent open oceans remain unclear. Here, we show that strong nearshore SSA production during high-wave periods greatly enhances downwind cloud condensation nuclei (CCN) and aerosol mass concentrations. Strong shoreline wave breaking is widespread globally, and swell waves, which are decoupled from local winds, play a dominant role in many coastal regions. Therefore, extrapolating results based on coastal measurements to open oceans may significantly overestimate SSA concentration and its contribution to CCN and, by extension, the impact of SSA on clouds and climate. Additionally, the strong enhancement of coastal aerosol population by shoreline wave breaking and its environmental impact on coastal communities cannot be captured by current regional models, which do not parameterize nearshore SSA generation using wave energy or completely neglect it.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2023

Rat bronchoalveolar lavage proteome changes following e-cigarette aerosol exposures

E-cigarette liquids are complex mixtures of chemicals consisting of humectants, such as propylene glycol (PG) and vegetable glycerin (VG), with nicotine or flavorings added. Published literature emphasizes the toxicity of e-cigarette aerosols with flavorings whereas much less attention has been given to the biologic effects of humectants. The purpose of the current study was to provide a comprehensive view of the acute biologic effects of e-cigarette aerosols on rat bronchoalveolar lavage (BAL) using mass spectrometry-based global proteomics. Sprague–Dawley rats were exposed to e-cigarette aerosol for 3 h/day for three consecutive days. Groups included: PG/VG alone, PG/VG + 2.5% nicotine (N), or PG/VG + N + 3.3% vanillin (V). Right lung lobes were lavaged for BAL and supernatants prepared for proteomics. Extracellular BAL S100A9 concentrations and BAL cell staining for citrullinated histone H3 (citH3) were also performed. From global proteomics, ~2,100 proteins were identified from rat BAL. Overall, the greatest change in number of BAL proteins occurred with PG/VG exposures alone compared with controls with biological pathways enriched for acute phase responses, extracellular trap formation, and coagulation. Extracellular BAL S100A9 concentrations and the number of citH3 + BAL cells also increased significantly in PG/VG and PG/VG + 2.5% N. In contrast to PG/VG or PG/VG + N, the addition of vanillin to PG/VG + N increased BAL neutrophilia and downregulated lipid transport proteins. In summary, global proteomics support e-cigarette aerosol exposures to PG/VG alone as having a significant biologic effect on the lung independent of nicotine or flavoring with increased markers of extracellular trap formation.

59 BASIC BIOLOGICAL SCIENCES↗
DOE OSTI2025

Experiment of Sea Breeze Convection, Aerosols, Precipitation, and Environment (ESCAPE)

Convective clouds play an important role in Earth’s climate system and are a known source of extreme weather. Gaps in our understanding of convective vertical motions, microphysics, and precipitation across a full range of aerosol and meteorological regimes continue to limit our ability to predict the occurrence and intensity of these cloud systems. To improve predictability, the National Science Foundation (NSF) sponsored a large field experiment entitled “Experiment of Sea Breeze Convection, Aerosols, Precipitation, and Environment (ESCAPE).” ESCAPE took place between 30 May and 30 September 2022 in the vicinity of Houston, Texas, because this area frequently experiences isolated deep convection that interacts with the region’s mesoscale circulations and its range of aerosol conditions. ESCAPE focused on collecting observations of isolated deep convection through innovative sampling and developing novel analysis techniques. This included the deployment of two research aircraft, the National Research Council of Canada Convair-580 and the Stratton Park Engineering Company Learjet, which combined conducted 24 research flights from 30 May to 17 June. On the ground, three mobile X-band radars and one mobile Doppler lidar truck equipped with soundings were deployed from 30 May to 28 June. From 1 August to 30 September 2022, a dual-polarization C-band radar was deployed and operated using a novel, multisensor agile adaptive sampling strategy to track the entire life cycle of isolated convective clouds. Analysis of the ESCAPE observations has already yielded preliminary findings on how aerosols and environmental conditions impact the convective life cycle.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2021

Technical Assistance for RingIR Aerosol Penetration Study with RingIR

Sandia provided technical assistance to RingIR to test and evaluate of the RingIR molecular detector. The detector can identify gas phase species using molecular fingerprinting and has potential application for SARS-CoV-2 detection in near real time. As part of the development process Sandia will utilize the biological aerosol test bed deployed at the Aerosol Complex to evaluate the penetration of MS2 bacteriophage aerosol through the RingIR system. The objective of this project is to provide experimentally derived measurements of the RingIR molecular detector penetration efficiency, including external exhaust filter for mitigation of exhaust aerosol and operation using MS2 bacteriophage as a biological surrogate to the SARS-CoV-2 virus.

59 BASIC BIOLOGICAL SCIENCES↗
DOE OSTI2021

Aerosol Deposition Inside a Spent Fuel Transportation and Storage Canister (Interim Report)

This report documents the progress in preparing the ANSYS/Fluent ® and MELCOR models to perform characterization studies of aerosols dispersal and deposition within a select spent fuel cask system. Steady state thermal-hydraulic cask response is modeled with both codes, at present, while the MELCOR source code is being modified to allow imposed thermal-hydraulic conditions with aerosol physics calculations. This will allow the MELCOR model to assume the thermal-hydraulic calculation from the ANSYS/Fluent ® , while only computing the aerosol physics. Detailed results are presented on the thermal-hydraulic analysis of the MAGNASTOR ® cask for the current ANSYS/Fluent ® model, with convergent conditions observed over two fidelities. While the MELCOR computation computes the steady state conditions, they differ sufficiently from that computed with ANSYS/Fluent ® . The MELCOR analysis include a set of UO 2 sources to investigate system response for interim reporting. The airborne concentrations and evolving distributions are presented. Model development is anticipated to continue as additional components impacting flow conditions or aerosol deposition within the MAGNASTOR ® cask and Westinghouse fuel assemblies are identified.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗
DOE OSTI2021

Secondary Aerosol Formation in an Arctic Oil Field (Campaign Report)

Atmospheric aerosols contribute significantly to arctic warming, yet significant differences in aerosol concentration levels and seasonal cycles often exist between models and observations. Recent studies of cloud properties across the North Slope of Alaska show the significant, regional influence of oil field emissions. Development across the Arctic motivates the need to characterize these oilfield emissions to further predict their roles in changing future arctic climate. Our previous August-September 2016 Atmospheric Radiation Measurement (ARM) user facility field campaign resulted in improved understanding of atmospheric particles emitted within the North Slope of Alaska (NSA) oil fields, as well as the aging of sea spray aerosol. Following Polar Sunrise during arctic spring, chlorine chemistry is active, and we hypothesize that oxidation of oil field hydrocarbons by chlorine atoms (Cl) generates oxygenated volatile organic compounds (OVOCs) leading to springtime arctic secondary organic aerosol (SOA) formation.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2020

Progress Report on Model Development for the Transport of Aerosol Through Microchannels

Accuracy of consequence assessments could be improved by accounting for the leak path deposition of aerosol in the source term. Recent experimental measurements from Sandia (2018) provided evidence of partial microchannel plugging due to particulate deposition. This filtration effect is relevant to the source term assessments and it is not unreasonable to anticipate that aerosol deposition in more realistic geometries could even lead to complete plugging of the leak path. This report summarizes current progress (as of end of Q3 FY 2020) on the development of a phenomenological model of aerosol transport, deposition, and plugging through microchannels. The purpose is to introduce a generic, reliable numerical model for the prediction of aerosol transport, deposition, and plugging in leak paths while accounting for potential plugging formation. This report includes (1) an overview of recent additions and improvements on the recently developed numerical model to analyze the various deposition processes in leak paths, to provide quantitative estimates of penetration factors, and to gain an understanding of the variables that affect them and (2) a summary of recent benchmarking results of the model’s validity with recent experimental measurements from Sandia.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2022

Experimental Set-up for the Study of Chemical Fractionation and Aerosol Dynamics

Experimental investigations of chemical fractionation/phase partition and aerosol dynamics in high-temperature environment were reviewed and discussed. Particle composition and size distribution are the key data for aerosol dynamics predictive model and simulation. However, there were no particle size distribution available from the previous works. Nucleation, condensation, and coagulation are three key physical processes driving the fractionation or phase partition thereby the aerosol dynamics. A new approach was proposed to experimentally observe fractionation/phase partition and provide data for validating the predictive model for aerosol dynamics in the simulation of bomb debris formation.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2022

Multiscale Aerosol Modeling Across Space and Composition (Final Report)

The objective of this project was to harness the capabilities of our unique particle-resolved aerosol model PartMC as an integrating tool between models and measurements across scales. This particle-resolved model explicitly resolves aerosol aging processes that must be approximated in large-scale models, making it ideal for quantifying structural uncertainty and rigorously deriving simplified parameterizations (“coarse graining”) to be used in large-scale models. It also directly connects with laboratory and field measurements at both particle and bulk scales. The significant accomplishments of this project are as follows: 1. Advancing the state of the art in particle-resolved modeling; 2. Connecting modeling with ASR/ARM measurements; 3. Bridging from the process level to aerosol impacts on the global scale; 4. Community engagement through leading and participating in ASR program activities and publishing a review paper on aerosol mixing state that synthesizes experimental and modeling perspectives.

58 GEOSCIENCES↗
DOE OSTI2024

Cloud Water Chemistry and Aerosol Processing: Assessing the Hydroxyl Radical Burst in Newly Formed Cloud Droplets (Field Campaign Report)

Aerosol particles are tiny liquid or solid particles in the atmosphere, ranging in size from a few nanometers to several micrometers in diameter. Aerosol-cloud interactions are the most uncertain aspect of the climate system, and models routinely underpredict aerosol particle formation. Clouds are well known to alter aerosol size, chemical composition, and radiative properties, but the processes are poorly characterized. Organics and sulfates are the most abundant materials in particles, and for each of these there are significant gaps in the understanding of the role of clouds in their formation and/or aging. Many of the cloud processes are driven by aqueous chemistry that depends on hydroxyl (OH) radicals, the subject of this project.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2024

Numerical study on aerosol sampling in a nuclear facility duct with a 90-degree elbow

Due to the challenging design requirements, elbows are often unavoidable in duct configuration, and these 90-degree bends introduce swirl, velocity variations, recirculation, and secondary flow. These disturbances make it difficult for nuclear facilities to meet particle sampling standards. A series of numerical analyses are conducted to track aerosols in a nuclear facility duct having a 90-degree elbow with the assistance of computational fluid dynamics (CFD). A turbulence model, a continuity, and a momentum, a discrete phase model, and species transport equations are solved simultaneously to track aerosols in the duct. The effect of turbulence models, turbulent dispersion models, droplet drag model, aerosol amount, aerosol spray configuration, guide vanes, and mixers are investigated. Simulation results are analyzed per relevant testing codes such as DOE-HDBK-1169, ASME AG1, ISO 14644-3, ACGIH, and ANSI/HPS N13.1.

Han, Kai [Savannah River Nuclear Solutions (SRNS),↗
DOE OSTI2025

Targeted Mobile Measurements to Isolate the Impacts of Aerosols and Meteorology on Deep Convection

One of the main goals of the Department of Energy (DOE) Atmospheric Radiation Measurement (ARM) Tracking Aerosol Convection Interactions Experiment (TRACER) field campaign near Houston, TX was to improve understanding of meteorology and aerosol effects on deep convective storms. To help TRACER achieve its goals of disentangling aerosol-cloud interactions from meteorology, the Texas A&M University (TAMU) team deployed the new fully mobile Rapid Onsite Atmospheric Measurement Van (ROAM-V) carrying instruments to measure aerosol and atmospheric properties that was moved to multiple locations on a deployment day of isolated convection initiated by the sea breeze.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2020

Second ARM Aerosol Chemical Speciation Monitor Users’ Meeting Report

The aerosol chemical speciation monitor (ACSM) was developed to adapt the technology of the aerosol mass spectrometer (AMS) to routine, long-term, standalone monitoring. The calculation of particulate mass concentration from ACSM data requires the measurement of the response of the instrument to aerosol of specific size and composition as well as assumptions about the instrument response based on laboratory measurements and field experience acquired over more than two decades of operation of AMS and a decade of operation of the ACSM. Three parameters in the concentration calculations that are particularly important are the NO3 response factor (RFNO3), relative ionization efficiency (RIE), and the collection efficiency (CE). The values of RFNO3 and RIEs are determined from calibration, however the jump calibration method previously used in calibration can result in errors in the RIE for sulfate. This has been corrected by implementing a continuous calibration method. The default collection efficiency is 0.5. This has been shown to result in mass loadings that do not agree with mass determinations from other instruments because of effects of composition on the vaporization of the particles. The previous work of investigators addressing this issue is discussed. After preliminary work on ACSM and scanning mobility particle sizer (SMPS) data from the U.S. Department of Energy (DOE) Atmospheric Radiation Measurement (ARM) user facility Southern Great Plains (SGP) observatory collected in late 2016 and 2017 produced a parameterization of composition dependent collection efficiency very different from the results of previous studies, SMPS data were examined and we determined that there was significant mass that the instrument did not capture because the particles with diameters larger than 465 nm are not counted by this instrument. Data for the ultra-high-sensitivity aerosol spectrometer (UHSAS), SMPS, and ACSM are available for nearly all of 2019. The data from UHSAS and SMPS collected in 2019 were compared. We found that the UHSAS data has particle counts and total volumes significantly less than measured by the condensation particle counter (CPC) and SMPS. The SMPS data were extended by fitting the average volume distribution with a log normal curve and using this relationship to estimate a mass value for the SMPS over extended diameter range. The extended SMPS mass values result in a CDCE parameterization that is in better agreement with the results of other investigators, but is still different from other formulations. The working group recommends that the ACSM data be processed with a collective efficiency (CE)=1, that this be documented clearly in the metadata, and the use of the default CE of 0.5 or a formulation of composition-dependent collection efficiencies (CDCE) chosen by the user should be implemented based on the ammonium nitrate mass fraction. This is clearly necessary for the wintertime SGP ACSM data because of the high nitrate concentrations.

47 OTHER INSTRUMENTATION↗