The entanglement region and non-Newtonian polymer flow
Shear dependence of viscosity for concentrated polymer systems related to polymer molecular weight distribution
MOLECULAR WEIGHT↗
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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.
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Low-thrust vehicle concept studies
Part of NASA's orbit transfer vehicle propulsion program is devoted to the development of analytical tools to define propulsion system performance, weight, size, and other parameters, and to develop packing concepts for LSS mission propulsion and payload systems. Packing studies discussed relate to shuttle cargo bay constraints; low thrust engine profile and performance; large space frame concept and weight; low thrust vehicles stowed in shuttle, LSS payload capability, and weight distribution. Further study is needed to determine interactions among propulsion system, payload structures, and shuttle. Low thrust-to-weight ratios are desirable to maximize payload weights and deployed areas.
Smolak, G. R.↗
Lunar soils grain size catalog
This catalog compiles every available grain size distribution for Apollo surface soils, trench samples, cores, and Luna 24 soils. Original laboratory data are tabled, and cumulative weight distribution curves and histograms are plotted. Standard statistical parameters are calculated using the method of moments. Photos and location comments describe the sample environment and geological setting. This catalog can help researchers describe the geotechnical conditions and site variability of the lunar surface essential to the design of a lunar base.
Graf, John C.↗
Comparison of the properties of some synthetic crudes with petroleum crudes
Physical properties and chemical compositions of six synthetic crudes were determined. The results were compared to those of typical petroleum crudes, with the interest being the feasibility of making jet fuels from oil shale and coal syncrudes. The specific gravity, viscosity, and pour point were measured, showing that these crudes would be described as heavier rather than lighter crudes. The boiling range distribution of the crudes was determined by distillation and by gas chromatography. In addition, gel permeation chromatograms were obtained, giving a unique molecular weight distribution profile for each crude. Analyses for carbon, hydrogen, nitrogen and sulfur concentrations were performed, as well as for hydrocarbon group type and trace element concentrations. It was found that the range in concentration of vanadium, an element whose presence in turbine fuels is of major concern, was lower than that of petroleum crudes. Sodium and potassium, other elements of concern, were present in comparatively high concentrations.
Antoine, A. C.↗
Cradles for Support in Transit
C-shaped cradles distribute weight of large objects. Originally developed for holding satellite in bay of Space Shuttle orbiter, concept also adaptable to such terrestrial uses as carrying odd-shaped equipment by truck. Cradle set consists of single prime cradle and several basic cradles. Composed of bar bent into a half circle, each cradle has own keel and longeron trunnions that brace structure by mating with receptacles in vehicle and its own foam pads, on which load rests. One 548-lb (249-kg) cradle supports up to 3,000 lb (1,361 kg); thus, 15,000-lb (6,800-kg) object requires five cradles distributed along its length. Through their trunnions, cradles spread weight of load along vehicle.
Crane, W. H.↗
Optimization of step rockets by the discrete maximum principle.
Optimum stage weight distribution in multistage rocket obtained by discrete maximum principle
WEIGHT FACTOR↗
Suspension of SiC Powders in Allyhydridopolycarbosilane (AHPCS): Control of Rheology
Inert particulate fillers can be blended with preceramic polymers prior to infiltration of composite preforms to increase pyrolysis yield and decrease shrinkage, thus reducing the number of infiltration/ pyrolysis cycles required for densification. However, particulate filler loadings and concentration of added dispersants necessary to maintain low viscosity (< 0.50 N.s/sq m) slurries vary with the characteristics of the particular AHPCS polymer batch. These batch to batch variations occur with alterations in the synthesis process and method of allyl substitution, which in turn alter polymer structure and molecular weight distribution. A number of different polymer batches were characterized by NMR, GPC and thermal analysis, and the influence of polymer structure on rheology of filled systems determined. When the high molecular weight fraction increased to too great a level, suitably fluid slurries could no longer be attained.
Hurwitz, Frances I.↗
Erectile antenna study Final report, 2 Mar. - 15 Sep. 1967
Optimum antenna weight distribution curves for six techniques to erect large aperture antennas
SPACE ERECTABLE STRUCTURE↗
Gel Permeation Chromatography of Fluoroether Polymers
A Method is described for determining the molecular weight distribution of fluorinated polymers by gel permeation chromatography. Porous silica-packed columns are used with Freon 113 as the chromatographic solvent. Fluoroether oligomers are used for column calibration in the molecular weight range of 1400 to 12000.
Korus, Roger A.↗
Optimization of step rockets by the discrete maximum principle.
Optimum stage weight distribution in multistage rocket obtained by discrete maximum principle
MULTISTAGE ROCKET↗
On the decoder error probability of linear codes
By using coding and combinatorial techniques, an approximate formula for the weight distribution of decodable words of most linear block codes is evaluated. This formula is then used to give an approximate expression for the decoder error probability P(sub E)(u) of linear block codes, given that an error pattern of weight u has occurred. It is shown that P(sub E)(u) approaches the constant Q as u gets large, where Q is the probability that a completely random error pattern will cause decoder error.
Cheung, K.-M.↗
Insight into the Competitive Adsorption Behavior of Polymer Chains in Silica Nanopores by Small-Angle Neutron Scattering
Processive hydrogenolysis catalysts, in which a metal nanoparticle (e.g., Pt) embedded at the bottom of a cylindrical silica nanopore can repeatedly cleave polymer chains and produce value-added hydrocarbon products, offer a potential solution for billions of tons of waste plastics. As the chain stays longer near the Pt catalysts, it would have a higher chance of getting cut, and therefore the molecular weight distribution of the product could be affected by the adsorption behavior of virgin chains (long polymers) versus cleaved chains (short polymers) into the nanopores. Further, this work reports a model study to understand the competitive adsorption behavior of the two different molecular weight polymers that are mixed, mimicking the reaction medium in the intermediate stage of the catalytic reaction. This study employs small-angle neutron scattering (SANS), which takes advantage of contrast differences between hydrogenous and deuterated polystyrenes to experimentally observe the relative composition of the two polymers in the silica nanopores. Our results reveal preferential adsorption of longer chains in the silica nanopores, which is consistent with the theoretical prediction in the literature for the case of the enthalpic attraction between polymers and pore walls.
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
The Southern Argentina Agile Meteor Radar Orbital System (SAAMER-OS): An Initial Sporadic Meteoroid Orbital Survey in the Southern Sky
We present an initial survey in the southern sky of the sporadic meteoroid orbital environment obtained with the Southern Argentina Agile MEteor Radar (SAAMER) Orbital System (OS), in which over three-quarters of a million orbits of dust particles were determined from 2012 January through 2015 April. SAAMER-OS is located at the southernmost tip of Argentina and is currently the only operational radar with orbit determination capability providing continuous observations of the southern hemisphere. Distributions of the observed meteoroid speed, radiant, and heliocentric orbital parameters are presented, as well as those corrected by the observational biases associated with the SAAMER-OS operating parameters. The results are compared with those reported by three previous surveys performed with the Harvard Radio Meteor Project, the Advanced Meteor Orbit Radar, and the Canadian Meteor Orbit Radar, and they are in agreement with these previous studies. Weighted distributions for meteoroids above the thresholds for meteor trail electron line density, meteoroid mass, and meteoroid kinetic energy are also considered. Finally, the minimum line density and kinetic energy weighting factors are found to be very suitable for meteoroid applications. The outcomes of this work show that, given SAAMERs location, the system is ideal for providing crucial data to continuously study the South Toroidal and South Apex sporadic meteoroid apparent sources.
meteorites↗
An analytical study of electric vehicle handling dynamics
Hypothetical electric vehicle configurations were studied by applying available analytical methods. Elementary linearized models were used in addition to a highly sophisticated vehicle dynamics computer simulation technique. Physical properties of specific EV's were defined for various battery and powertrain packaging approaches applied to a range of weight distribution and inertial properties which characterize a generic class of EV's. Computer simulations of structured maneuvers were performed for predicting handling qualities in the normal driving range and during various extreme conditions related to accident avoidance. Results indicate that an EV with forward weight bias will possess handling qualities superior to a comparable EV that is rear-heavy or equally balanced. The importance of properly matching tires, suspension systems, and brake system front/rear torque proportioning to a given EV configuration during the design stage is demonstrated.
Greene, J. E.↗
A solution-adaptive mesh algorithm for dynamic/static refinement of two and three dimensional grids
An adaptive grid algorithm has been developed in two and three dimensions that can be used dynamically with a solver or as part of a grid refinement process. The algorithm employs a transformation from the Cartesian coordinate system to a general coordinate space, which is defined as a parallelepiped in three dimensions. A weighting function, independent for each coordinate direction, is developed that will provide the desired refinement criteria in regions of high solution gradient. The adaptation is performed in the general coordinate space and the new grid locations are returned to the Cartesian space via a simple, one-step inverse mapping. The algorithm for relocation of the mesh points in the parametric space is based on the center of mass for distributed weights. Dynamic solution-adaptive results are presented for laminar flows in two and three dimensions.
Benson, Rusty A.↗
A three-dimensional dynamic solution-adaptive mesh algorithm
A solution-adaptive grid algorithm has been developed for use in two and three dimensions. The algorithm uses a transformation from the cartesian coordinate system to a general coordinate space, which will be defined as a parallelepiped. A weighting function for adaption of the grid is developed that will allow adaption to the gradients of any combination of dependent variables in the flow. The adaption is carried out in the parametric space and a simple inverse mapping to return the new parametric space to the physical space is derived. The concept used to relocate the grid-points in the parametric space is based on the center of mass of distributed weights. Solution-adaptive results are presented for various laminar flows in two dimensions and for mathematical weighting functions in three dimensions.
Benson, Rusty A.↗
Tissue fluid shift, forelimb loading, and tail tension in tail-suspended rats
The tail suspension model (head-down tilt) simulates hypogravity in terms of musculoskeletal loss in the rat. However, little is known of tissue fluid shifts and body weight distribution in this model. Tissue fluid pressures were measured by wick catheters in 12 Munich-Wistar rats before, during, and after 48 hrs of tail suspension (about 30 deg head-down tilt). Subcutaneous tissue fluid pressure in the neck increased from -2.2 + or - 0.4 (normal horizontal position) to +4.0 + or - 1.5 cm H2O during tail suspension, indicating a cephalic fluid shift and significant edema during head-down tilt. In a separate study, six rats were suspended at 30-70 deg, and forelimb load and tail tension were measured by a balance and force transducer, respectively. Approximately 50 percent of body weight (BW) was loaded on forelimbs at a head-down tilt angle of 30 deg and forelimb load declined linearly to 10 percent BW at 70 deg. Furthermore, tail tension increased from 50 percent BW at 30 deg to 85 percent BW at 70 deg. These results indicate that less than normal loads are applied to forelimbs of rats suspended at angles of less than 30 deg and that the tail bears an increasing proportion of the rat's body weight at head-down tilt angles of less than 30 deg.
Hargens, A. R.↗
Novel insight into the kinetics of amide bond glycolysis for nylon-6 depolymerization
Chemical recycling of nylon-6 to short-chain oligomers and monomer ε-caprolactam via catalytic glycolysis is a potential solution for plastic waste remediation. Here, in this work, the kinetics of amide bond glycolysis (with ethylene glycol) in nylon-6 and the model compound N-phenethyl-3-phenylpropanamide (M1) were evaluated at 473 K in the presence of the cyclic amidine catalyst 1,5,7-triazabicyclo[4.4.0]dec-5-ene. Rates of polymer glycolysis were determined by the time-dependent shift in molecular weight distribution, whereas rates of M1 glycolysis were determined using liquid chromatography. The similarity of the first-order rate constants for glycolysis of nylon-6 and M1 at 473 K with 0.03 M amidine catalyst (5 mol% relative to amide bonds), 1.22 × 10 −5 s −1 and 2.18 × 10 −5 s −1 , respectively, confirmed the suitability of M1 as a model compound for nylon-6 glycolysis. Similar rates of glycolysis in the presence of other cyclic amidine catalysts as well as sodium methoxide revealed little influence of base strength. Glycolysis rates were unexpectedly non-linear in catalyst loading and deactivation occurred with long reaction times, presumably by non-selective decomposition of products as detected by liquid chromatography.
Depolymerization rate and rate constant↗