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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 55 records · Page 3

Intrinsic Li Distribution in Layered Transition-Metal Oxides Using Low-Dose Scanning Transmission Electron Microscopy and Spectroscopy

Understanding Li distribution in layered lithium transition-metal oxide (LiTMO) cathodes in Li-ion batteries has been a major challenge at the atomic scale and nanoscale. Li is extremely difficult to study by transmission electron microscopy (TEM) because the high-energy electrons impart significant energy and cause massive migration. Here, we directly map the intrinsic spatial distribution and bonding of Li in LiNiO 2 -layered cathode materials using low-dose and low-loss electron energy loss spectroscopy (EELS). EELS spectra of the Li–K edge are measured simultaneously with O–K and Ni–L, M 3,2 edges from layered, cation-mixed, and rock-salt phases and directly matched with atomic-resolution scanning TEM images to correlate the changes in peak intensities and positions to the stoichiometry changes with continual loss of Li and O. Changes in the Li content in the LiNiO 2 particles as a function of electron beam dose are studied by sequential Li spectroscopic mapping. We show that the “intrinsic” Li distribution can be observed using a total dose of less than ~1.5 × 10 8 e – nm –2 at an accelerating voltage of 80 kV. The method of nanoscale mapping of Li distribution introduced in this study is applicable to high-Ni LiTMO cathode materials (>89% of Ni) as well as LiNiO 2 . Further study on the extra peaks of the Li–K edge reveals that the peak at ~59 eV is from the Li ions intercalated in between NiO 2 layers barely interacting with each other with less Li K shell electrons pulled to the L shell electrons in NiO 2 . Furthermore, the results shown here provide improved low-loss TEM characterization approaches that can be used to understand the intrinsic fundamental behaviors in Li-ion batteries.

25 ENERGY STORAGE↗

A Case Study on Pathogen Transport, Deposition, Evaporation and Transmission: Linking High-Fidelity Computational Fluid Dynamics Simulations to Probability of Infection

A high-fidelity, low-Mach computational fluid dynamics simulation tool that includes evaporating droplets and variable-density turbulent flow coupling is well-suited to ascertain transmission probability and supports risk mitigation methods development for airborne infectious diseases such as COVID-19. A multi-physics large-eddy simulation-based paradigm is used to explore droplet and aerosol pathogen transport from a synthetic cough emanating from a kneeling humanoid. For an outdoor configuration that mimics the recent open-space social distance strategy of San Francisco, maximum primary droplet deposition distances are shown to approach 8.1 m in a moderate wind configuration with the aerosol plume transported in excess of 15 m. In quiescent conditions, the aerosol plume extends to approximately 4 m before the emanating pulsed jet becomes neutrally buoyant. A dose–response model, which is based on previous SARS coronavirus (SARS-CoV) data, is exercised on the high-fidelity aerosol transport database to establish relative risk at eighteen virtual receptor probe locations.

59 BASIC BIOLOGICAL SCIENCES↗

Optimizing Transmission of Acoustic Signals to Monitor Internal Conditions of Canisters for Dry Storage of Commercial Spent Nuclear Fuel

Safe storage of spent nuclear fuel (SNF) is critical to the nuclear fuel cycle and the future of nuclear energy. In the United States, SNF is stored primarily via two methods regulated by the U.S. Nuclear Regulatory Commission: wet storage in SNF pools and dry storage in dry cask storage systems (DCSSs). After about five years of cooling in spent fuel pools, the fuel assemblies are transferred into DCSSs, and the systems are filled with helium and sealed by welding. Deterioration of conditions inside of a DCSS is reflected in changes in the internal gas properties; this motivates the development of acoustic techniques to monitor internal gas properties, over extended storage periods, using sensors mounted on the exterior of the storage packages. However, a major challenge in collecting acoustic signals is the impedance mismatch between the steel canister shell and the gas. Only a small fraction of the ultrasonic signal can be transmitted through the gas medium. This paper documents experimental studies conducted on a full-scale canister mock-up to capture the gas-borne signals. Damping materials were pasted on the outside, and blocking and unblocking tests were conducted to identify the gas-borne signal. The results show that the excitation frequency plays an important role in maximizing the gas-borne signals. The gas-borne signal was successfully detected at around the theoretical time-of-flight. A high signal-to-noise ratio was achieved in the measurements. Next, the acoustic impedance matching layers were introduced, and the gas signal was drastically improved compared with that using no AIM layers.

Spent nuclear fuel (SNF), Canisters, Internal cond↗

Structural characterization and gas reactions of small metal particles by high resolution in-situ TEM (Transmission Electron Microscopy) and TED (Transmission Electron Diffraction)

The detection and size analysis of small metal particles supported on amorphous substrates becomes increasingly difficult when the particle size approaches that of the phase contrast background structures of the support. An approach of digital image analysis, involving Fourier transformation of the original image, filtering, and image reconstruction was studied with respect to the likelihood of unambiguously detecting particles of less than 1 nm diameter on amorphous substrates from a single electron micrograph.

Heinemann, K.↗

An Enhanced Computational Framework for Energy Storage Participation in Transmission Planning with Electricity Market Participation: Dynamic Market Participation Restriction Estimation

In the previous study and report, we developed a computational framework to explore the technical and economic viability of the dual use of pumped storage hydropower (PSH) for both transmission assets and market participation. The rationale for the dual-use application is to improve the resource utilization rate and reduce the cost recovery burden. A PSH-based transmission solution generally has a large capacity, which corresponds to a higher investment cost compared to a traditional line solution. Market participation may allow the PSH asset to offset part of its high investment cost. A critical question is whether it is economically and technically viable to allow dual use of a PSH-based transmission project without jeopardizing transmission system reliability. And a more specific follow-up question is how to improve market participation performance while maintaining transmission reliability. In this study, we extend the computational framework by updating the method to determine transmission service obligation requirements dynamically based on the possibility of the need for transmission service in operation. Specifically, we correlate the need for transmission service with the probability of thermal overloading on a monitored transmission line, which is essentially based on the probability distribution of power flow and its probability of exceeding the line rating based on system dispatch and operational uncertainties. In addition, the need depends on the level of risk that a system operator is willing to take. The higher the risk tolerance, the lower the requirement that the system operator would apply to the PSH project as a transmission asset. The requirements are updated every day before the PSH project determines its market participation strategy. With the updated transmission service requirements, it is expected that a PSH project can serve as a transmission asset when the transmission system is at risk and really needs it, while it can participate in a market with sufficient information and certain restrictions. In this way, the transmission service quality and market participation performance can both be improved.

29 ENERGY PLANNING, POLICY, AND ECONOMY↗

Laboratory Experiments Examining the Effect of Thermal and Mechanical Processes on Hydraulic Transmissivity Evolution

Using laboratory slide-hold-slide experiments, at temperatures from 22 to 200 degrees C, to examine effects of fracture reactivation and quasi-static loading on the evolution of fluid transport properties of simulated fractures in Westerly granite. At all temperatures, the in-plane hydraulic transmissivity consistently decays during hold periods resulting in an overall reduction in transmissivity. During the first three to fifteen hours of an experiment, transmissivity decreases rapidly due to the generation of wear products, development of a sliding surface, and compaction of the resulting gouge. Once the sliding surface has developed, the long-term transmissivity decay rate at 22 and 100 degrees C is significantly lower than the transmissivity decay rate during the initial 3-15 hours of the experiment. However, at 200 degrees C, the decay of hydraulic transmissivity remains high throughout the experiment. The long-term decay of hydraulic transmissivity can be fitted with a power law model with more rapid reduction of hydraulic transmissivity at higher temperature. Periods of sliding on the fracture surface result in transient increases in the transmissivity, due to shear dilation, as is expected for Coulomb materials. These transients are superimposed on the long-term decay. When sliding ceases and a new hold period commences, there is a rapid reduction in transmissivity and return to the long-term rate of transmissivity decay. The rate of decay of the transmissivity transients is inversely correlated with temperature, in contrast to the long-term decay and the expected behavior for processes like subcritical crack growth and indentation creep. The higher decay rates that are observed during the initial 3-15 hours of the tests and following sliding, are associated with times that the porosity of the gouge is expected to be high. The difference in decay rates suggests that when the gouge is driven far from equilibrium by active shearing, densification may be dominated by a different mechanism from long-term compaction.

15 GEOTHERMAL ENERGY↗

Electricity Subsector Transmission Resilience Maturity Model (TRMM) User Guide

The electric transmission sector is facing a range of threats to its functionality that are either new, more severe than experienced in earlier years, or more well understood. Such threats include more frequent and more severe extreme weather events, wildfires, droughts, and human-caused physical and cyberattacks. They also include geological, electromagnetic, and biological events. The novelty or increasing severity of these threats creates a significant need for transmission owners to implement programs to prevent, prepare for, respond to, and recover from such incidents. The national and economic security of the United States depends on the reliable functioning of the Nation’s critical infrastructure in the face of such threats, and the transmission networks are essential components of that infrastructure. The Electricity Subsector Transmission Resilience Maturity Model (TRMM) is a tool that a transmission organization can use to objectively evaluate and benchmark its currently established transmission resilience strategies, programs, policies, and investments, in order to target and prioritize enhancements where needed. The TRMM was developed to address the unique characteristics of the transmission system. The model can enable users to: • evaluate and benchmark their organization’s resilience capabilities, effectively and consistently • prioritize actions and investments to improve the resilience of their systems • share transmission-related knowledge, best practices, and relevant references within their organization and with business partners as a means to improve resilience capabilities • contribute to increasing the overall resilience of the Nation’s transmission systems. The TRMM provides descriptive rather than prescriptive industry-focused guidance. The model content is presented at a high level of abstraction so that it can be interpreted by transmission organizations of various types, structures, and sizes. The model is designed to an be easy-to-use, self-assessment tool.

24 POWER TRANSMISSION AND DISTRIBUTION↗

Atlantic Offshore Wind Transmission Study

The Atlantic Offshore Wind Transmission Study (AOSWTS) is part of the U.S. Department of Energy's (DOE) efforts to understand and facilitate the transmission of electricity from wind in the Atlantic Ocean. It was informed by the Atlantic Offshore Wind Transmission Literature Review and Gaps Analysis (Bothwell et al. 2021) and the convening workshops hosted in 2022-2023 by DOE and the U.S. Department of the Interior's Bureau of Ocean Energy Management. The study results help to inform An Action Plan for Offshore Wind Transmission Development in the U.S. Atlantic Region (Baker et al. 2023). DOE's Wind Energy Technologies Office funded AOSWTS. The AOSWTS identifies and evaluates pathways to enable offshore wind energy deployment in the Atlantic Ocean through coordinated offshore transmission solutions in the near term (by 2030) and long term (by 2050). The study fills gaps in prior analyses by providing a multiregional planning perspective that evaluates offshore wind generation development with transmission planning. It incorporates environmental, ocean co-use, and other siting considerations into defining potential offshore transmission routes. The study also compares different multiregional offshore transmission topologies and their associated costs (using potential cable routes) and benefits (in terms of production cost savings and enhanced resource adequacy). In addition, the AOSWTS analyzes reliability impacts from a multiregional perspective. The study provides guidance for policymakers and transmission stakeholders on possible outcomes resulting from a proactive, coordinated, and interregional approach to transmission planning for offshore wind energy development in the Atlantic. While this study presents possibilities, additional work following system operator methods and procedures can help build on this analysis.

17 WIND ENERGY↗

Atlantic Offshore Wind Transmission Study: Executive Summary

The Atlantic Offshore Wind Transmission Study (AOSWTS) is part of the U.S. Department of Energy's (DOE) efforts to understand and facilitate the transmission of electricity from wind in the Atlantic Ocean. It was informed by the Atlantic Offshore Wind Transmission Literature Review and Gaps Analysis (Bothwell et al. 2021) and the convening workshops hosted in 2022-2023 by DOE and the U.S. Department of the Interior's Bureau of Ocean Energy Management. The study results help to inform An Action Plan for Offshore Wind Transmission Development in the U.S. Atlantic Region (Baker et al. 2023). DOE's Wind Energy Technologies Office funded AOSWTS. The AOSWTS identifies and evaluates pathways to enable offshore wind energy deployment in the Atlantic Ocean through coordinated offshore transmission solutions in the near term (by 2030) and long term (by 2050). The study fills gaps in prior analyses by providing a multiregional planning perspective that evaluates offshore wind generation development with transmission planning. It incorporates environmental, ocean co-use, and other siting considerations into defining potential offshore transmission routes. The study also compares different multiregional offshore transmission topologies and their associated costs (using potential cable routes) and benefits (in terms of production cost savings and enhanced resource adequacy). In addition, the AOSWTS analyzes reliability impacts from a multiregional perspective. The study provides guidance for policymakers and transmission stakeholders on possible outcomes resulting from a proactive, coordinated, and interregional approach to transmission planning for offshore wind energy development in the Atlantic. While this study presents possibilities, additional work following system operator methods and procedures can help build on this analysis.

17 WIND ENERGY↗

Gulf of Mexico Offshore Wind Transmission - Literature Review and Gaps Analysis: Environmental Considerations, Community Readiness, and Infrastructure

The ability to effectively and efficiently connect offshore wind energy resources to end users in the Gulf of Mexico, requires coordinated transmission planning to ensure that electric transmission facilities can adequately support future offshore development. The Gulf of Mexico has substantial wind resources in both shallow shelf waters and deeper waters off the shelf where fixed bottom and floating wind technologies would be most appropriate. Most interest in offshore wind development to date has been in the central and western portions of the Gulf of Mexico (Louisiana and Texas) in federal and state waters. As a companion study to other federal activities in the offshore wind transmission space, including the Atlantic Offshore Wind Transmission Literature Review and Gaps Analysis, the Atlantic Offshore Wind Transmission Study, the West Coast Offshore Wind Transmission Literature Review and Gaps Analysis, the West Coast Offshore Wind Transmission Study, and the Advancing Offshore Wind Energy in the United States: U. S. Department of Energy Strategic Contributions Toward 30 Gigawatts and Beyond Report, this literature review and gaps analysis for offshore wind transmission in the Gulf of Mexico builds off previous literature reviews and supports the role of federal leadership to facilitate offshore wind energy. The overarching goal of this document is to identify gaps and lay the groundwork to inform coordinated transmission planning, ocean co-use, existing energy infrastructure, and siting associated with offshore wind energy development in the Gulf of Mexico. There are unique regional considerations for offshore wind transmission, which are summarized herein based on a review and assessment of publicly available information.

08 HYDROGEN↗

Empirical Indicators of Transmission Value in the Southeast United States

Concurrent differences in energy price between different parts of the electric grid are a key indicator of the value of additional transmission. In areas without a wholesale electricity market, such as the Southeast, an alternative indicator to price is the Federal Energy Regulatory Commission’s (FERC) system lambda data. This economic metric represents the minimized marginal production costs of thermal generators, including fuel and other variable operation and maintenance expenses. Balancing Authorities report a single system lambda for their entire balancing area. Most Southeastern lambdas exhibit sufficient price variation to support a transmission valuation analysis, although incomplete accounting of congestion costs or scarcity rents during peak load hours may underestimate the true value of transmission capacity. With transmission value defined as the annual average hourly absolute price difference between two regions and FERC’s system lambda data used as a price proxy, we find the following results in the Southeast region during 2012-2023 (reported in $\$2024$/MWh): Intra‐regional findings: Annual averages historically span $\$2$–$\$28$/MWh and average $\$12$/MWh in SERTP and span $\$4$–$\$19$/MWh and average $\$9$/MWh in FRCC, disregarding transmission value driven by anomalous data. The ranges of transmission value reported here are large, spanning an order of magnitude in some cases. Much of this variation is driven by year-to-year changes, with 2022 having a particularly high intra-regional transmission value due to elevated natural gas prices. Inter‐regional corridors: Annual average transmission values across three broader regions range from $\$6$ to $\$28$/MWh with a long-term average of $\$11$/MWh. Much of the transmission value is concentrated in a small portion of hours. Across all regions, severe weather—particularly polar vortex events in January 2018, February 2021, and December 2022—drives the largest price spreads. Seasonal patterns also emerge, with summer afternoons and fall mornings contributing consistently to transmission value, as for example between MISO and SOCO in 2023.

24 POWER TRANSMISSION AND DISTRIBUTION↗