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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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All sourcesNASA NTRSDOE OSTI
DOE OSTI2022

Coupled Interfacial and Bulk Kinetics Govern the Timescales of Multiphase Ozonolysis Reactions

Chemical transformations in aerosols impact the lifetime of particle phase species, the fate of atmospheric pollutants, and both climate- and health-relevant aerosol properties. Timescales for multiphase reactions of ozone in atmospheric aqueous phases are governed by coupled kinetic processes between the gas phase, the particle interface, and its bulk, which respond dynamically to reactive consumption of O 3 . However, models of atmospheric aerosol reactivity often do not account for the coupled nature of multiphase processes. Herein, to examine these dynamics, we use new and prior experimental observations of aqueous droplet reaction kinetics, including three systems with a range of surface affinities and ozonolysis rate coefficients ( trans -aconitic acid (C 6 H 6 O 6 ), maleic acid (C 4 H 4 O 4 ), and sodium nitrite (NaNO 2 )). Using literature rate coefficients and thermodynamic properties, we constrain a simple two-compartment stochastic kinetic model which resolves the interface from the particle bulk and represents O 3 partitioning, diffusion, and reaction as a coupled kinetic system. Our kinetic model accurately predicts decay kinetics across all three systems, demonstrating that both the thermodynamic properties of O 3 and the coupled kinetic and diffusion processes are key to making accurate predictions. An enhanced concentration of adsorbed O 3 , compared to gas and bulk phases is rapidly maintained and remains constant even as O 3 is consumed by reaction. Multiphase systems dynamically seek to achieve equilibrium in response to reactive O 3 loss, but this is hampered at solute concentrations relevant to aqueous aerosol by the rate of O 3 arrival in the bulk by diffusion. As a result, bulk-phase O 3 becomes depleted from its Henry's law solubility. This bulk-phase O 3 depletion limits reaction timescales for relatively slow-reacting organic solutes with low interfacial affinity (i.e., trans-aconitic and maleic acids, with k rxn ≈ 10 3 -10 4 M -1 s -1 ), which is in contrast to fast-reacting solutes with higher surface affinity (i.e., nitrite, with k rxn ≈ 10 5 M -1 s -1 ) where surface reactions strongly impact the observed decay kinetics.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2023

Species, Pathways, and Timescales for NH 3 Formation by Low-Temperature Atmospheric Pressure Plasma Catalysis

Species, pathways, and timescales for NH3 production by plasma catalysis over transition-metal wools are determined by measuring plasma-derived species densities [N, H, and N 2 (v)], quantitatively correlating consumption of these species with NH 3 formation, and measuring consumption of plasma-derived species at different residence times. These findings are enabled by a capillary flow through Ar/N 2 /H 2 plasma jet reactor setup that allows for the measurement of gas-phase species densities by molecular beam mass spectrometry. Surface-mediated reactions involving N radicals are responsible for NH 3 formation over Fe, Ni, and Ag surfaces. N reacts to form NH 3 with ~100% selectivity over Ni and Ag when H/N > 3 and % H 2 ≥ 0.5. The selectivity to ammonia drops as H and H 2 densities decrease for each catalyst. A comparison between amounts of NH 3 formed and N consumed with and without catalysts present shows that surface reactions enable higher and more selective conversion of N to NH 3 than gas-phase reactions alone. The conversion of N to NH 3 is negligible in the absence of H, demonstrating that H is required to produce NH 3 at these operating conditions. The consumption of N occurs on the same timescale as NH 3 formation, further confirming that reactions involving N contribute to NH 3 formation. Though vibrationally excited N 2 [N 2 (v)] is produced in quantities exceeding N by 100-fold, consumption of N 2 (v) on the catalytic surface does not contribute to NH 3 formation. Furthermore, these findings show that for low-temperature atmospheric pressure plasma catalysis, surface- mediated reactions among radical N and H species drive NH 3 formation.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
DOE OSTI2024

Timescale Dependence of the Precipitation Response to CO 2 ‐Induced Warming in Millennial‐Length Climate Simulations

Abstract Previous work has shown that estimates of climate sensitivity vary over time in response to abrupt CO 2 forcing in climate model simulations. The energy fluxes that drive warming in response to increasing CO 2 also influence precipitation, which prompts the question: Does the precipitation response therefore also vary over time? We investigate by examining the response of precipitation to warming forced by greenhouse gases—the hydrological sensitivity—in a set of millennial‐length climate simulations with multiple climate models, Long Run Model Intercomparison Project (LongRunMIP). We compare hydrological sensitivity calculated from three different timescales of the simulations: years 1–20, 21–150, and 151–1000. We show that the hydrological sensitivity lacks a consistent dependence on timescale, in contrast to climate sensitivity. Decomposition of the surface energy budget reveals that the relative muting of the multi‐model mean hydrological sensitivity is driven by surface downwelling shortwave flux.

Him (Kinen) Kao, Wing↗
DOE OSTI2025

Increased water availability at various timescales has different effects on stomatal closure point in isohydric piñon pine and anisohydric juniper

Abstract Stomatal Closure Point (SCP) has commonly been used to describe drought response strategies in plants, with isohydric species maintaining relatively high, constant SCP compared to anisohydric species that can lower SCP with increasing drought severity. However, there is evidence that, within these groups, SCP may respond dynamically to environmental conditions. Here, we explored how increasing water availability affects SCP in classically isohydric piñon pine and anisohydric one-seed or Utah juniper at various spatial- (i.e., from branch, to tree, to ecosystem) and temporal- (i.e., hours to decades) scales. Our results show that short-term increases in water availability decreased SCP in isohydric piñon pine, making it more anisohydric, while short-term rehydration had no effect on SCP in anisohydric juniper. Increasing mean annual precipitation, on the other hand, increased SCP in both species. Our findings are consistent with documented differences in the use of ABA to control stomata in iso- and aniso-hydric species on short timescales, and with structural acclimation in both species at long timescales. These results illustrate that the local environment plays a large role in determining SCP.

Kraklow, Vachel↗
DOE OSTI2022

Rapid early gas accretion for the inner Galactic disc: A case for short accretion timescale

Recent observations of the Milky Way and galaxies at high redshifts suggest that galaxy discs were already in place soon after the Big Bang. While the gas infall history of the Milky Way in the inner disc has long been assumed to be characterised by a short accretion timescale, this has not been directly constrained using observations. Using data for the inner regions of the Milky Way recently produced by APOGEE and Gaia and of unprecedented quantity and quality, we aim to derive strong constraints on the infall history of the inner (< 6 kpc) Galaxy (with a focus on stars between 4 and 6 kpc, which we show is an appropriate proxy for the entire inner disc). We implemented gas infall into a chemical evolution model of the Galaxy disc, and used a Schmidt–Kennicutt law to connect the infall to the star formation. We explore a number of models, and two different formulations of the infall law. In one formulation, the infall is non-parametric, and in the other the infall has an explicitly exponential form. We fit the model parameters to the time–[Si/Fe] distribution of solar vicinity stars, and the metallicity and [Si/Fe] distribution function of stars with a galactocentric radius of between 4 and 6 kpc from APOGEE. Our results point to a fast, early gas accretion, and an upper limit on the accretion timescale of around 2 Gyr in the inner disc of the Milky Way. This suggests that at least half the baryons were in place within 2–3 Gyr of the Big Bang, and that half the stars of the inner disc formed within the first 5 Gyr, during the thick disc formation phase. This implies that the stellar mass of the inner disc is dominated by the thick disc, supporting our previous work, and that the gas accretion onto the inner disc was rapid and early.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2023

Multi-timescale operations of nuclear-renewable hybrid energy systems for reserve and thermal product provision

In this paper, an optimal operation strategy of a nuclear-renewable hybrid energy system (N-R HES), in conjunction with a district heating network, is developed within a comprehensive multi-timescale electricity market framework. The grid-connected N-R HES is simulated to explore the capabilities and benefits of N-R HES of providing energy products, different reserve products, and thermal products. An N-R HES optimization and control strategy is formulated to exploit the benefits from the hybrid energy system in terms of both energy and ancillary services. A case study is performed on the customized NREL-118 bus test system with high renewable penetrations, based on a multi-timescale (i.e., three-cycle) production cost model. Both day-ahead and real-time market clearing prices are determined from the market model simulation. In conclusion, the results show that the N-R HES can contribute to the reserve requirements and also meet the thermal load, thereby increasing the economic efficiency of N-R HES (with increased revenue ranging from 1.55% to 35.25% at certain cases) compared to the baseline case where reserve and thermal power exports are not optimized.

29 ENERGY PLANNING, POLICY, AND ECONOMY↗
DOE OSTI2021

Timescales of excited state relaxation in α–RuCl 3 observed by time-resolved two-photon photoemission spectroscopy

The nonequilibrium properties of strongly correlated materials present a target in the search for new phases of matter. It is important to observe the types of excitations that exist in these materials and their associated relaxation dynamics. We have studied the photoexcitations in a spin-orbit assisted Mott insulator α–RuCl 3 using time-resolved two-photon photoemission spectroscopy and transient reflection spectroscopy. We find that photoexcited carriers (doublons) in the upper Hubbard band rapidly relax to Mott-Hubbard excitons on a timescale of less than 200 fs. Subsequently, further relaxation of these lower-energy quasiparticles occurs with an energy-dependent time constant of that ranges from 370 to 600 fs due to exciton cooling. The population of Mott-Hubbard excitons persists for timescales up to several microseconds.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2021

The Effect of Pressure on NO x Entitlement and Reaction Timescales in a Premixed Axial Jet-In-Crossflow

This paper investigates the pressure dependency of a lean premixed jet injected into a lean vitiated crossflow with an experimentally verified detailed chemistry computational fluid dynamics (CFD) model and 53 species considered. Experimental data were taken in an axially staged combustor with an optically accessible test section, allowing the use of particle image velocimetry (PIV) and CH* chemiluminescence techniques as well as point measurement of species concentration, temperature, and pressure. The experimental data cases at one, three, and five atmospheres were selected to describe the flame stabilization dependency on pressure and gain the required knowledge for an extrapolation to engine condition. Simulated exit nitrogen oxide levels were validated with experimental emission data, and a global emission trend for the NO reduction at elevated pressure and constant turbine inlet temperature level was defined. The nitrogen oxide benefit at elevated operating pressure was justified with the significantly smaller flame surface area: the analysis of the simulated spanwise and top-view profiles showed a relatively short receded core flame with nitrogen oxide production in the center at high pressure relative to a longer and larger shear layer flame at atmospheric condition that produced NO toward the inner and outer side of the flame. Furthermore, decomposition of the Damköhler number revealed the strong influence of the reaction timescales with higher reaction rates at elevated pressure, along with a moderate influence of the turbulent timescales, showing higher turbulence intensity in the lee-side recirculation zone at lower pressure.

03 NATURAL GAS↗
DOE OSTI2022

Dynamic wavelength control of laser pulse profiles at picosecond to nanosecond timescales

We report on a novel combined laser pulse shaping and dynamic wavelength encoding capability based on a simple architecture implementing direct space to time mapping. There are several potential applications that can be enabled by the ability to control the instantaneous intensity or wavelength of an optical waveform on a picosecond-to-nanosecond timescale. To our knowledge, no known methods can access this temporal regime with a practical architecture. Here, we demonstrate an extension of the Space–Time Induced Linearly Encoded Transcription for Temporal Optimization (STILETTO) technique that can generate optical waveforms with a programmable instantaneous wavelength vs. time. We experimentally demonstrate the technique by generating self-gated spectrograms and show that it can encode dynamic wavelength vs time profiles at timescales not achievable by any other known method.

47 OTHER INSTRUMENTATION↗
DOE OSTI2020

Distended clads gas pressurization and material failure timescales

This document presents timescales for additional failure modes, including pressurization of void space in the pellet to the estimated tensile strength of the pellet. Because helium is known to be captured in the fuel as well as evolved as gas, previous timescales are adjusted to account for the substantial dissolution of helium in the matrix of the fuel at normal fuel temperatures. Helium arises from the decay of the 238Pu in the fuel, and can appear as a gas, creating bubbles within the fuel. The majority of helium is known to be captured within the fuel matrix at the operating temperatures of an isolated clad.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗
DOE OSTI2020

Multi-Stage and Multi-Timescale Robust Co-Optimization Planning for Reliable and Sustainable Power Systems. Final Report

In this project, Clarkson University, in collaboration with Southern Methodist University and University of Pittsburgh, conducted the research to model, design, and implement a sophisticated generation and transmission co-optimization planning decision tool, called Multi-stage and Multi-timescale robust Co-Optimization Planning (MMCOP). The MMCOP decision tool intends to facilitate generation and transmission co-optimization planning of emerging power systems, while mitigating risks and uncertainties in both short-term operation dynamics and long-term policy and technology changes. Long-term power system planning aims at optimizing asset utilization by investing in a proper mix of various generation technologies and transmission lines to supply the future load growth. In particular, the Clean Power Plan (CPP), which is designed to combat climate change and reduce carbon emissions by setting a national limit on carbon pollution from power plants, may dramatically change the landscape of the power industry by further promoting clean energy and phasing out emissions-intensive generation technologies. In addition, novel non-wire alternatives (e.g., demand response (DR), distributed generation (DG), energy efficiency (EE), and smart grid technologies) and the computational complexity for large-scale systems significantly complicate the system planning procedure even further. However, existing conventional planning approaches neglect short-term variability and uncertainty of renewable energy, hourly chronological operation details, and physical nonlinear characteristics of the alternating current transmission network. As a result, existing conventional planning approaches may not work properly, and power systems reliability could be in jeopardy. In observing the limitations of existing conventional planning approaches and addressing new challenges of emerging power systems, the main scope of this project to develop co-optimization planning models within a multi-stage and multi-timescale framework. In particular, random contingencies, key uncertainty factors, and AC power flows are included to derive expansion plans while considering both long-term reliability and short-term flexibility.

24 POWER TRANSMISSION AND DISTRIBUTION↗
DOE OSTI2023

Abbreviated Technical Report: Experimentally Interrogating Detonation Chemistry on Sub-Nanosecond to Nanosecond Timescales

Direct experimental measurement of chemical reactions during high explosive detonation remains challenging. Theory and modeling have long preceded experiment in the fundamental physical and chemical kinetic properties of detonation, and experimentation at the relevant timescales are needed to both validate models and provide fundamental understanding of detonation. In this LDRD-ER project, two approaches, x-ray diffraction and core-level x-ray Raman, were developed and used to further experimental capabilities to address this gap. We further developed dynamic x-ray diffraction to directly detect nanodiamond formation during detonation, providing experimental data towards resolving longstanding controversy in the scientific literature, and although the full kinetics have not yet been fully mapped, diamond diffraction appears on the same timescales as detonation soot formation. In the second research thrust, we have developed core-level x-ray Raman for use with high explosives. This technique provides information analogous to x-ray absorption spectroscopy and electron energy loss spectroscopy, but uses inelastic scattering of hard x-rays that can interrogate chemistry around light elements much deeper into the material. The low cross section and requisite high solid angle collection have hindered its use for ultra-fast spectroscopy. We developed and tested a high-q spectrometer which will substantially increase cross section and signal-to-noise, showing this method will also not dramatically alter, compared to x-ray absorption, the most discriminating spectral features of C, N, and O from various high explosives and expected detonation products. We have also used x-ray Raman combined with OCEAN electronic structure calculations to explore dynamic photodegradation mechanisms in PETN and CL-20 explosives. This provides a pathway towards implementing capability to dynamically explore chemistry at an x-ray free electron laser.

36 MATERIALS SCIENCE↗
DOE OSTI2024

Multi-Period Optimization of Multi-Timescale Energy Systems: Application to Solid-Oxide Electrolysis Cells

A presentation detailing the recent progress in the optimization of Solid-Oxide Cells under Chemical Degradation. The existing methods typically involve a quasi-steady state assumption to make this large-scale problem tractable. Here, we introduce an extension to this method that allows for adaptive coupling of degradation with the fast-timescale process based on a variety of error thresholds. This reduces the error accumulated during long-term optimization of the SOC under degradation and allows for decision making at multiple timescales. The results presented include long-term operating profiles of the SOC under degradation with both steady-state and fluctuating day to day operation.

Giridhar, Nishant↗
DOE OSTI2020

Lyapunov and Clearing Timescales in Planetary Chaotic Zones

Debris disks in planetary systems are known to possess gaps “opened” by planets in their close-to-coorbital neighborhoods; the gaps are free from low-mass material such as planetesimals. We consider the escape process of the initially zero-eccentric particles from the gap zone in a scenario consisting of two basic consequent stages: (1) the particle orbit's eccentricity is inflated, while its specific energy is relatively constant, and (2) the particle orbit's semimajor axis is inflated, while its specific angular momentum is relatively constant. During the first stage, the chaotic transport (diffusion) proceeds along the “staircase” of (p + 1):p (with integer p ≫ 1) overlapping particle–planet resonances, and during the second stage, it proceeds along the p:1 particle–planet resonance staircase. A specialized two-dimensional area-preserving map (a “tokamap” version) is derived to describe the first stage, while a multiharmonic Kepler map theory is used to describe the second stage. We derive the μ (mass parameter) scaling for the clearing timescale in the planetary chaotic zone. At small μ, it turns out to be inverse-quadratic in μ. The μ scaling for the Lyapunov timescale inside the gap is also derived. The derived scalings are in qualitative agreement with available numerical-experimental data.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2021

Multicolor Variability of Young Stars in the Lagoon Nebula: Driving Causes and Intrinsic Timescales

Space observatories have provided unprecedented depictions of the many variability behaviors typical of low-mass, young stars. However, those studies have so far largely omitted more massive objects (~2 M {sub ⊙} to 4–5 M {sub ⊙}) and were limited by the absence of simultaneous, multiwavelength information. We present a new study of young star variability in the ~1–2 Myr old, massive Lagoon Nebula region. Our sample encompasses 278 young, late B to K-type stars, monitored with Kepler/K2. Auxiliary u, g, r, i, Hα time-series photometry, simultaneous with K2, was acquired at the Paranal Observatory. We employed this comprehensive data set and archival infrared photometry to determine individual stellar parameters, assess the presence of circumstellar disks, and tie the variability behaviors to inner disk dynamics. We found significant mass-dependent trends in variability properties, with B/A stars displaying substantially reduced levels of variability compared to G/K stars for any light-curve morphology. These properties suggest different magnetic field structures at the surface of early-type and later-type stars. We also detected a dearth of some disk-driven variability behaviors, particularly dippers, among stars earlier than G. This indicates that their higher surface temperatures and more chaotic magnetic fields prevent the formation and survival of inner disk dust structures corotating with the star. Finally, we examined the characteristic variability timescales within each light curve and determined that the day-to-week timescales are predominant over the K2 time series. These reflect distinct processes and locations in the inner disk environment, from intense accretion triggered by instabilities in the innermost disk regions to variable accretion efficiency in the outer magnetosphere.

47 OTHER INSTRUMENTATION↗
DOE OSTI2022

The Variability of the Black Hole Image in M87 at the Dynamical Timescale

The black hole images obtained with the Event Horizon Telescope (EHT) are expected to be variable at the dynamical timescale near their horizons. For the black hole at the center of the M87 galaxy, this timescale (5–61 days) is comparable to the 6 day extent of the 2017 EHT observations. Closure phases along baseline triangles are robust interferometric observables that are sensitive to the expected structural changes of the images but are free of station-based atmospheric and instrumental errors. We explored the day-to-day variability in closure-phase measurements on all six linearly independent nontrivial baseline triangles that can be formed from the 2017 observations. We showed that three triangles exhibit very low day-to-day variability, with a dispersion of ∼3°–5°. The only triangles that exhibit substantially higher variability (∼90°–180°) are the ones with baselines that cross the visibility amplitude minima on the u–v plane, as expected from theoretical modeling. We used two sets of general relativistic magnetohydrodynamic simulations to explore the dependence of the predicted variability on various black hole and accretion-flow parameters. We found that changing the magnetic field configuration, electron temperature model, or black hole spin has a marginal effect on the model consistency with the observed level of variability. On the other hand, the most discriminating image characteristic of models is the fractional width of the bright ring of emission. Models that best reproduce the observed small level of variability are characterized by thin ring-like images with structures dominated by gravitational lensing effects and thus least affected by turbulence in the accreting plasmas.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2023

Ab-initio General-relativistic Neutrino-radiation Hydrodynamics Simulations of Long-lived Neutron Star Merger Remnants to Neutrino Cooling Timescales

Abstract We perform the first 3D ab-initio general-relativistic neutrino-radiation hydrodynamics of a long-lived neutron star merger remnant spanning a fraction of its cooling timescale. We find that neutrino cooling becomes the dominant energy loss mechanism after the gravitational-wave dominated phase (∼20 ms postmerger). Electron flavor antineutrino luminosity dominates over electron flavor neutrino luminosity at early times, resulting in a secular increase of the electron fraction in the outer layers of the remnant. However, the two luminosities become comparable ∼20–40 ms postmerger. A dense gas of electron antineutrinos is formed in the outer core of the remnant at densities ∼10 14.5 g cm −3 , corresponding to temperature hot spots. The neutrinos account for ∼10% of the lepton number in this region. Despite the negative radial temperature gradient, the radial entropy gradient remains positive, and the remnant is stably stratified according to the Ledoux criterion for convection. A massive accretion disk is formed from the material squeezed out of the collisional interface between the stars. The disk carries a large fraction of the angular momentum of the system, allowing the remnant massive neutron star to settle to a quasi-steady equilibrium within the region of possible, stable, rigidly rotating configurations. The remnant is differentially rotating, but it is stable against the magnetorotational instability. Other MHD mechanisms operating on longer timescales are likely responsible for the removal of the differential rotation. Our results indicate the remnant massive neutron star is thus qualitatively different from a protoneutron stars formed in core-collapse supernovae.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2023

Assessment of WRF (v 4.2.1) dynamically downscaled precipitation on subdaily and daily timescales over CONUS

Abstract. This study analyzes the quality of simulated historical precipitation across the contiguous United States (CONUS) in a 12 km Weather Research and Forecasting model version 4.2.1 (WRF v 4.2.1)-based dynamical downscaling of the fifth-generation ECMWF atmospheric reanalysis (ERA5). This work addresses the following questions. First, how well are the 3 and 24 h precipitation characteristics (diurnal and annual cycles, precipitation frequency, annual and seasonal mean and maximum precipitation, and distribution of seasonal maximum precipitation) represented in the downscaled simulation, compared to ERA5? And second, how does the performance of the simulated WRF precipitation vary across seasons, regions, and timescales? Performance is measured against the National Centers for Environmental Prediction/Environmental Modeling Center (NCEP/EMC) 4 km Stage IV and Oregon State University Parameter-Elevation Regressions on Independent Slopes Model (PRISM) data on 3 and 24 h timescales, respectively. Our analysis suggests that the 12 km WRF exhibits biases typically found in other WRF simulations, including those at convection-permitting scales. In particular, WRF simulates both the timing and magnitude of the summer diurnal precipitation peak as well as ERA5 over most of the CONUS, except for a delayed diurnal peak over the Great Plains. As compared to ERA5, both the month and the magnitude of the precipitation peak annual cycle are remarkably improved in the downscaled WRF simulation. WRF slightly overestimates 3 and 24 h precipitation maximum over the CONUS, in contrast to ERA5, which generally underestimates these quantities mainly over the eastern half of the CONUS. Notably, WRF better captures the probability density distribution (PDF) of 3 and 24 h annual and seasonal maximum precipitation. WRF exhibits seasonally dependent precipitation biases across the CONUS, while ERA5's biases are relatively consistent year round over most of the CONUS. These results suggest that dynamical downscaling to a higher resolution improves upon some precipitation metrics but is susceptible to common regional climate model biases. Consequently, if used as input data for domain-specific models, we suggest moderate bias correction be applied to the dynamically downscaled product.

54 ENVIRONMENTAL SCIENCES↗