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At least 55 records · Page 3

The importance of mesoscale circulations generated by subgrid-scale landscape heterogeneities in general circulation models

A mesoscale atmospheric model was used to evaluate the impact of subgrid-scale landscape discontinuities on the vertical profiles of resolved temperature, moisture, and moist static energy in the planetary boundary layer (PBL) of general circulation models (GCMs). These profiles were produced with a 3D version of the model (using a horizontal grid resolution of 7.5 km and 13 vertical layers in the PBL) by averaging horizontally the various atmospheric variables over a 180 x 180 sq km domain-about the size of the horizontal domain represented by a single grid element in a GCM. They were compared to corresponding vertical profiles produced with a 1D version of the model, which simulates the PBL, as in a GCM, over a single horizontal grid element. Differences obtained between the horizontally averaged atmospheric variables produced with the 3D simulations and the 1D simulations emphasize the impact of subgrid-scale landscape discontinuities on GCM-resolved variables. Various types of landscape discontinuities, characterized by horizontal contrasts of surface wetness and size of land patches, were simulated under various background-wind conditions. Differences of temperature, specific humidity, and moist static energy as large as 4 K, 6 g/kg, and 10 kJ/kg were obtained in some cases. These differences were not affected significantly by moderate winds but were sensitive to the spatial distribution of surface wetness. These results emphasize the need to parameterize mesoscale processes induced by landscape discontinuities in GCMss.

Lynn, Barry H.↗

Benchmarking the AirSquared All-Metal Scroll Pump Against the Normetex 15 - Preliminary report

Tritium operations require specialized equipment for material compatibility, safety, and waste considerations. Non-metallic pump materials (polymer, oil, or grease) on a tritium-wetted surface can absorb tritium and/or undergo isotope exchange between tritium and more common protium, creating tritiated compounds that can result in material property modification via beta-radiolysis, inventory loss, reduced performance and special waste considerations, all of which increase the operating cost for a facility. Vacuum pumps move gas via a pressure differential between volumes of an operation. Several types of all-metal vacuum pumps exist for this application including metal bellows, diaphragm and scroll pumps. A metal bellows pump incorporates only metal components at the wetted surfaces. The common metal bellows pump employed in tritium facilities, the MB601 (Senior Metal Bellows, Sharon, PA, USA) creates a gas-motive force with a vacuum pressure between 30-40 torr. These pumps can efficiently move gas from one process step to another, as long as sub-30 torr pressures are not required. However, for higher vacuum demand, an all-metal scroll pump can be used with the bellows pump serving as a “backing” pump. This configuration typically provides an achievable vacuum of less than 20 mTorr. All-metal scroll pumps are a technology uniquely applicable to tritium gas handling. The industry standard all-metal scroll pump for glovebox-scale tritium operations is the Normetex 15 m 3 /hr, typically referred to as the Normetex 15 (Normetex Pompes, Pont Audemer, France). However, the final Normetex pumps were manufactured in 2012, rendering them no longer available. Eumeca SaRL (formerly Normetex) has developed and is marketing a scroll pump based on the design of the Normetex 15. A US company, AirSquared (Broomfield, Colorado), has developed and is marketing a potential alternative to the Normetex 15. The Gas Transfer Systems group (Q-7) of the Los Alamos National Laboratory (LANL) procured serial number 0001 of the AirSquared All Metal Vacuum Scroll pump model number V16H034A-C01 in 2019. The LANL Hydrogen Processing Laboratory (HPL) has been evaluating the performance of the pump compared to a Normetex pump as a potential replacement in tritium and fusion facilities requiring this type of pump.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

The Influence of Nonlocal Metal–Dielectric Environments on Physical and Chemical Processes

Plasmonic nanolayers and laminar metallic/dielectric multilayers were originally developed for optical cloaking applications and lensing applications that could potentially image objects whose size was below the diffraction limit. These assemblies were initially formed from gold or silver nanorods grown within an alumina mesh. However, more recently, assemblies with similar properties have also been prepared by sequential thin-layer deposition of alternating layers of gold and magnesium fluoride (MgF 2 ). These metal/dielectric composite materials enable control of the dielectric constant in the directions perpendicular to the layers and balance the real and imaginary dielectric constants of the assembly such that the speed and the amplitude of the waves traveling through the assembly are not attenuated. In this Account, we will also focus on a few of the applications ranging from surface wetting to fluorescence quenching to enhancement of photochemical reactions. First, we will share an introduction to processes used to create these materials, which are combinations of low refractive index metals and transparent higher index materials arranged in a scalable repeating fashion. Two fabrication methods were employed: an electrochemical deposition of Ag nanorods into an anodized alumina matrix which produced materials with an anisotropic negative refractive index material within the plane of the film and lamellar metal/dielectric layers in which the negative index perpendicular to the growth direction. These alternating layers of plasmonic metals and dielectric materials were ultimately chosen to prepare films for further testing, because of their relative ease of fabrication. We will continue with a discussion of a few of the applications of both of these nonlocal dielectric composite materials including more specialized plasmonic, composite, and hyperbolic metamaterials including fluorescence quenching, photochemical reactions, and surface wetting. In each of these applications, the unique response caused by the enhancement of the electric field and the interface between hyperbolic materials and plasmonic materials as they interact photophysically with their near neighbors is presented. In each of the applications, the enhanced electric field extends from the composite substrate layer to interact with its near neighbors and beyond. Furthermore, the presence of this extended interaction can be observed in the form of decreased emission lifetime, enhancement of photochemical reaction rates, and changes in the surface energies measured by contact angle goniometry. In this Account, all of these situations will be addressed. Finally, we will conclude with a summary and vision for the future as well as a discussion of the unique challenges and opportunities available as research active faculty at an HBCU.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Experimental Studies of Low-Pressure Turbine Flows and Flow Control. Streamwise Pressure Profiles and Velocity Profiles

This report summarizes research performed in support of the NASA Glenn Research Center (GRC) Low-Pressure Turbine (LPT) Flow Physics Program. The work was performed experimentally at the U.S. Naval Academy faculties. The geometry corresponded to "Pak B" LPT airfoil. The test section simulated LPT flow in a passage. Three experimental studies were performed: (a) Boundary layer measurements for ten baseline cases under high and low freestream turbulence conditions at five Reynolds numbers of 25,000, 50,000, 100,000, 200,000, and 300,000, based on passage exit velocity and suction surface wetted length; (b) Passive flow control studies with three thicknesses of two-dimensional bars, and two heights of three-dimensional circular cylinders with different spanwise separations, at same flow conditions as the 10 baseline cases; (c) Active flow control with oscillating synthetic (zero net mass flow) vortex generator jets, for one case with low freestream turbulence and a low Reynolds number of 25,000. The Passive flow control was successful at controlling the separation problem at low Reynolds numbers, with varying degrees of success from case to case and varying levels of impact at higher Reynolds numbers. The active flow control successfully eliminated the large separation problem for the low Reynolds number case. Very detailed data was acquired using hot-wire anemometry, including single and two velocity components, integral boundary layer quantities, turbulence statistics and spectra, turbulent shear stresses and their spectra, and intermittency, documenting transition, separation and reattachment. Models were constructed to correlate the results. The report includes a summary of the work performed and reprints of the publications describing the various studies.This report summarizes research performed in support of the NASA Glenn Research Center (GRC) Low-Pressure Turbine (LPT) Flow Physics Program. The work was performed experimentally at the U.S. Naval Academy faculties. The geometry corresponded to "Pak B" LPT airfoil. The test section simulated LPT flow in a passage. Three experimental studies were performed: (a) Boundary layer measurements for ten baseline cases under high and low freestream turbulence conditions at five Reynolds numbers of 25,000, 50,000, 100,000, 200,000, and 300,000, based on passage exit velocity and suction surface wetted length; (b) Passive flow control studies with three thicknesses of two-dimensional bars, and two heights of three-dimensional circular cylinders with different spanwise separations, at same flow conditions as the 10 baseline cases; (c) Active flow control with oscillating synthetic (zero net mass flow) vortex generator jets, for one case with low freestream turbulence and a low Reynolds number of 25,000. The Passive flow control was successful at controlling the separation problem at low Reynolds numbers, with varying degrees of success from case to case and varying levels of impact at higher Reynolds numbers. The active flow control successfully eliminated the large separation problem for the low Reynolds number case. Very detailed data was acquired using hot-wire anemometry, including single and two velocity components, integral boundary layer quantities, turbulence statistics and spectra, turbulent shear stresses and their spectra, and intermittency, documenting transition, separation and reattachment. Models were constructed to correlate the results. The report includes a summary of the work performed and reprints of the publications describing the various studies. The folders in this supplement contain processed data in ASCII format. Streamwise pressure profiles and velocity profiles are included. The velocity profiles were acquired using single sensor and cross sensor hot-wire probes which were traversed from the wall to the freestream at various streamwise locations. In some of the flow control cases (3D Trips and Jets) profiles were acquired at multiple spanwise locations.

Volino, Ralph↗

Evaluation of GEOS Precipitation Flagging for SMAP Soil Moisture Retrieval Accuracy

The precipitation flag in the Soil Moisture Active Passive (SMAP) Level 2 passive soil moisture (L2SMP) retrieval product indicates the presence or absence of heavy precipitation at the time of the SMAP overpass. The flag is based on precipitation estimates from the Goddard Earth Observing System (GEOS) Forward Processing numerical weather prediction system. An error in flagging during an active or recent precipitation event can produce either 1) an overestimation of soil moisture due to short-term surface wetting of vegetation and/or surface ponding (if soil moisture retrieval was attempted in the presence of rain) or 2) an unnecessary nonretrieval of soil moisture and loss of data (if retrieval is flagged due to an erroneous indication of rain). Satellite precipitation estimates from the Integrated Multisatellite Retrievals for GPM (IMERG), version 06, Early Run (latency of ~4 h) precipitationCal product are used here to evaluate the GEOS-based precipitation flag in the L2SMP product for both the 1800 local time (LT) ascending and 0600 LT descending SMAP overpasses over the first five years of the mission (2015–20). Consisting of blended precipitation measurements from the Global Precipitation Mission (GPM) satellite constellation, IMERG is treated as the “truth” when comparing to the GEOS model forecasts of precipitation used by SMAP. Key results include (i) IMERG measurements generally show higher spatial variability than the GEOS forecast precipitation, (ii) the IMERG product has a higher frequency of light precipitation amounts, and (iii) the effect of incorporating IMERG rainfall measurements in lieu of GEOS precipitation forecasts are minimal on the L2SMP retrieval accuracy (determined vs in situ soil moisture measurements at core validation sites). Our results indicate that L2SMP retrievals continue to meet the mission’s accuracy requirement [standard deviation of the unbiased RMSE (ubRMSE) less than 0.04 cu. m/cu. m].

IMERG-precipitationCal↗

Observations of Land Surface Variability Using Passive Microwave Sensing

Understanding the global variability of land surface wetness (soil moisture), skin temperature, and related surface fluxes of heat and moisture is key to assessing the importance of the land surface in influencing climate. The feasibility of producing model estimates of these quantities is being studied as part of the International Satellite Land Surface Climatology Project (ISLSCP) Global Soil Wetness Project (GSWP). In the GSWP approach, meteorological observations and analyses are used to drive global circulation models. Satellite measurements can provide independent estimates of key land surface parameters that are needed for initializing and validating the climate models and for monitoring long-term change. Satellite observations of the land surface can also be assimilated into soil models to estimate moisture in the root zone. In our research, passive microwave satellite data recorded during 1978-1987 from the Nimbus-7 Scanning Multichannel Microwave Radiometer (SMMR) are being used to examine spatial and temporal trends in surface soil moisture, vegetation, and temperature. These data include observations at C and X bands (6.6 and 10.7 GHz), which are not available on the current Special Sensor Microwave/Imager (SSM/I) and are precursors to data that will become available from the Advanced Microwave Scanning Radiometer (AMSR) on Advanced Earth Observing Satellite (ADEOS-II) and Earth Observing System (EOS) PM1 in the year 2000. A chart shows a time-series of SMMR-derived surface temperature, T-e and surface soil moisture M, retrieved on a 0.5 deg x 0.5 deg grid and further averaged over a 4 deg x 10 deg study region in the African Sahel. Also shown are National Center for Environmental Prediction (NCEP) model outputs of surface temperature, T-sfc, and soil wetness, Soil-w. The variables have been scaled to have similar dynamic ranges on the plots. The NCEP data from the NCEP Reanalysis Project are monthly averages on a 2.5 deg x 2.5 deg grid averaged over the 4 deg x 10 deg study area. Comparisons of SMMR retrievals with forecast model output show the potential of the satellite data for validating model output and monitoring long-term trends. Continuing work will extend these results to other regions to validate the retrievals more quantitatively. In preparation for the launch of AMSR, field experiments are planned in collaboration with the Global Energy and Water Cycle Experiment (GEWEX) Coordinated Enhanced Observing Period (CEOP) experiments to evaluate the satellite-derived soil moisture measurements and to demonstrate their usefulness for land surface hydrology and climate. Additional information is contained in the original.

Njoku, Eni G.↗

Laminar drag reduction in microchannels with liquid infused textured surfaces

Liquid infused surfaces (LIS) achieve non-wetting properties through asperity structures containing pockets of a lubricating liquid rather than air. Although studies have demonstrated several potential applications of LIS, the effect of liquid infused texture on the flow of liquid in microchannels has not been systematically addressed. The present work focuses on the effect of liquid-infused texture geometry and the infused liquid properties on the flow characteristics of a bulk fluid in rectangular and round microchannel geometries. Considering four different textured geometries of transverse ridges, longitudinal ridges, in-lined square posts and staggered squares, a detailed parametric study is presented to assess the resulting drag reduction and friction factor, expressed in terms of the Poiseuille number, on the flow in microchannels. The effect of geometrical parameters is investigated for different asperity solid fraction (Φ s ), asperity height (h s ) and channel thickness (H) or tube diameter (D), while the effect of the infused fluid is studied in terms of a ratio of its viscosity relative to the viscosity of the flowing bulk fluid. Based on the results of the parametric study an extension of the conventional Moody diagram for non-wetting surfaces is developed. Finally, a design of experiments study is conducted to relate the drag reduction and Poiseuille number to the various governing parameters, using which conditions that maximize drag reduction are identified.

42 ENGINEERING↗

New method of extrapolation of the resistance of a model planing boat to full size

The previously employed method of extrapolating the total resistance to full size with lambda(exp 3) (model scale) and thereby foregoing a separate appraisal of the frictional resistance, was permissible for large models and floats of normal size. But faced with the ever increasing size of aircraft a reexamination of the problem of extrapolation to full size is called for. A method is described by means of which, on the basis of an analysis of tests on planing surfaces, the variation of the wetted surface over the take-off range is analytically obtained. The friction coefficients are read from Prandtl's curve for turbulent boundary layer with laminar approach. With these two values a correction for friction is obtainable.

Sottorf, W↗

Wetting behavior of polyelectrolyte complex coacervates on solid surfaces

The wetting behavior of complex coacervates underpins their use in many emerging applications of surface science, particularly wet adhesives and coatings. Many factors dictate if a coacervate phase will condense on a solid surface, including solution conditions, the nature of the polymer–substrate interaction, and the underlying supernatant–coacervate bulk phase behavior. In this work, we use a simple inhomogeneous mean-field theory to study the wetting behavior of complex coacervates on solid surfaces both off-coexistence (wetting transitions) and on-coexistence (contact angles). Here we focus on the effects of salt concentration, the polycation/polyanion surface affinity, and the applied electrostatic potential on the wettability. We find that the coacervate generally wets the surface via a first order wetting transition with second order transitions possible above a surface critical point. Applying an electrostatic potential to a solid surface always improves the surface wettability when the polycation/polyanion–substrate interaction is symmetric. For asymmetric surface affinity, the wettability has a nonmonotonic dependence with the applied potential. We use simple scaling and thermodynamic arguments to explain our results.

36 MATERIALS SCIENCE↗

Traction Characteristics of a 30 by 11.5-14.5, Type 8, Aircraft Tire on Dry, Wet and Flooded Surfaces

A limited test program was conducted to extend and supplement the braking and cornering data on a 30 x 11.5-14.5, type VIII, aircraft tire to refine the tire/runway friction model for use in the development of an aircraft ground performance simulation. Tire traction data were obtained on dry, wet and flooded runway surfaces at ground speeds ranging from 5 to 100 knots and at yaw angles extending up to 12 deg. These friction coefficients are presented as a function of slip characteristics, namely, the maximum and skidding drag coefficients and the maximum cornering coefficients are presented as a function of both ground speed and yaw angle to extend existing data on that tire size. Tire braking and cornering capabilities were shown to be affected by vehicle ground speed, wheel yaw attitude and the extent of surface wetness.

Yager, T. J.↗

Surface-Tailoring and Morphology Control as Strategies for Sustainable Development in Transport Sector

Surface wetting plays an important role in the corrosion protection processes of aerospace applications. Here, we demonstrate the use of ultrafast femtosecond (fs) laser processing techniques to tailor the wetting properties of aluminum (Al) substrates by creating diverse surface morphologies. Specifically, two distinct laser scanning methods—dot-hatching and cross-hatching—were employed to fabricate microstructures on the substrates. By varying the incident laser parameters, we confirmed that the resulting surface morphologies exhibit different wetting behaviors, spanning from hydrophilicity to hydrophobicity. Furthermore, time-resolved spreading tests validate that dynamic wetting behaviors can also be modified. This fs laser processing approach provides a straightforward, one-step fabrication method for effectively modifying the wetting properties of Al alloys.

de Almeida Prado, Luis Antonio Sanchez↗

The wetting characteristics and surface tension of some Ni-based alloys on yttria, hafnia, alumina, and zirconia substrates

The surface tension and wetting characteristics of four commercial Ni-based alloys (UD718, Waspaloy, UD720, and UD520), pure Ni, and three special alloys (Ni-20 percent Cr, Ni-20 percent Cr-1 percent Al, and Ni-20 percent Cr-4 percent Al) on various ceramic substrates (including alumina, zirconia, hafnia, and yttria) were investigated using sessile drop experiments. Most of the systems studied exhibited a nonwetting behavior. Wetting improved with holding time at a given temperature to the point that some systems, such as Ni-20Cr on alumina, Ni-20Cr-4Al on alumina and on yttria, became marginally wetting. Wetting characteristics were apparently related to constitutional undercooling, which in turn could be affected by the metal dissolving some of the substrate during measurements.

Kanetkar, C. S.↗

Experimental investigation of the braking and cornering characteristics of 30 x 11.5-14.5, type 8, aircraft tires with different tread patterns

An investigation was conducted at the aircraft landing loads and traction facility to study the braking and cornering characteristics, including the drag-force and cornering-force friction coefficients, of 30 by 11.5-14.5, type VIII aircraft tires with five different tread patterns. Test data were obtained on dry, damp, and flooded runway surfaces over a range of yaw angles from 0 deg to 12 deg at ground speeds from 5 knots to 100 knots. The results of this investigation indicate that a tread pattern consisting of transverse cuts across the entire width of the tread slightly improved the tire traction performance on wet surfaces. The braking and cornering capability of the tires was degraded by thin-film lubrication and tire hydroplaning effects on the wet runway surfaces. The braking capability of the tires decreased when the yaw angle was increased.

Dreher, R. C.↗

Advanced high performance horizontal piezoelectric hybrid synthetic jet actuator

The present invention comprises a high performance, horizontal, zero-net mass-flux, synthetic jet actuator for active control of viscous, separated flow on subsonic and supersonic vehicles. The present invention is a horizontal piezoelectric hybrid zero-net mass-flux actuator, in which all the walls of the chamber are electrically controlled synergistically to reduce or enlarge the volume of the synthetic jet actuator chamber in three dimensions simultaneously and to reduce or enlarge the diameter of orifice of the synthetic jet actuator simultaneously with the reduction or enlargement of the volume of the chamber. The present invention is capable of installation in the wing surface as well as embedding in the wetted surfaces of a supersonic inlet. The jet velocity and mass flow rate for the SJA-H will be several times higher than conventional piezoelectric actuators.

Xu, Tian-Bing↗

Enhanced liquid metal wetting on oxide surfaces via patterned particles

Liquid metals typically do not intrinsically wet oxide surfaces due to chemical dissimilarity, preventing the formation of well-bonded interfaces in many applications. This paper investigates how the wetting and spreading of liquid silver (Ag) droplets on oxide surfaces can be enhanced via patterned nickel (Ni) particles using multiscale modeling. First, a force field (FF) for an Ag/yttria-stabilized-zirconia system was developed by fitting the interfacial binding energy to density-functional theory (DFT) calculations. Then, molecular dynamics (MD) simulations using these FF parameters revealed that the good wetting of Ag on Ni caused Ag droplets to be attracted to the Ni particles, promoting spreading. Thus, the optimal hexagonal Ni pattern was shown to enhance the wetting area by 224% compared to a bare oxide surface. Second, an analytical model predicting the maximum possible enhancement in wetting area as a function of the intrinsic wetting angle, size of the Ag droplet, and size of the Ni particles was derived and validated with MD simulations, to generalize this method to other substrates. Here, both the analytical model and MD results suggested that the ability of Ni patterns to enhance the Ag wetting area becomes more significant as the wettability of substrate becomes worse.

36 MATERIALS SCIENCE↗

Disinfection of Spacecraft Potable Water Systems by Passivation with Ionic Silver

Microbial growth is common on wetted surfaces in spacecraft environmental control and life support systems despite the use of chemical and physical disinfection methods. Advanced control technologies are needed to limit microorganisms and increase the reliability of life support systems required for long-duration human missions. Silver ions and compounds are widely used as antimicrobial agents for medical applications and continue to be used as a residual biocide in some spacecraft water systems. The National Aeronautics and Space Administration (NASA) has identified silver fluoride for use in the potable water system on the next generation spacecraft. Due to ionic interactions between silver fluoride in solution and wetted metallic surfaces, ionic silver is rapidly depleted from solution and loses its antimicrobial efficacy over time. This report describes research to prolong the antimicrobial efficacy of ionic silver by maintaining its solubility. Three types of metal coupons (lnconel 718, Stainless Steel 316, and Titanium 6AI-4V) used in spacecraft potable water systems were exposed to either a continuous flow of water amended with 0.4 mg/L ionic silver fluoride or to a static, pre-treatment passivation in 50 mg/L ionic silver fluoride with or without a surface oxidation pre-treatment. Coupons were then challenged in a high-shear, CDC bioreactor (BioSurface Technologies) by exposure to six bacteria previously isolated from spacecraft potable water systems. Continuous exposure to 0.4 mg/L ionic silver over the course of 24 hours during the flow phase resulted in a >7-log reduction. The residual effect of a 24-hour passivation treatment in 50 mg/L of ionic silver resulted in a >3-log reduction, whereas a two-week treatment resulted in a >4-log reduction. Results indicate that 0.4 mg/L ionic silver is an effective biocide against many bacteria and that a prepassivation of metal surfaces with silver can provide additional microbial control.

Birmele, Michele N.↗

Liquid–Solid Mixtures of Ga Metal Infused with Cu Microparticles and Nanoparticles for Microscale and Nanoscale Patterning of Solid Metals at Room Temperature

This paper demonstrates and characterizes a simple ink for nanopatterning of solid metallic structures under ambient conditions by taking advantage of the low melting point of gallium and its affinity to form intermetallics with other metals. Bare copper micro- and nanoparticles readily mix with liquid gallium near room temperature to form a paste that ultimately amalgamates into a dense solid when mixed at the appropriate concentration ratios. The paste has sufficient shelf life that can be extruded from a nozzle at modest temperatures to form solid three-dimensional (3D) shapes. Additionally, the paste can be molded at room temperature to replicate feature sizes ranging from a few millimeters down to hundreds of nanometers. In situ X-ray diffraction (XRD) and thermo-mechanical analysis (TMA) data show gallium and copper readily interdiffuse to form the thermodynamically expected intermetallic phase. We describe the capabilities and limitations of a simple way to pattern solid metals in an additive fashion (syringe-based extrusion) and with high resolution (molding) at or near room temperature. Here, the use of a paste that solidifies provides a novel route for 3D printing of solid metals at ambient temperatures as well as the creation of micro- and nanostructured metallic surfaces that may be useful for optics, non-wetting surfaces, or electronic microcomponents.

36 MATERIALS SCIENCE↗