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At least 55 records · Page 3
All sourcesNASA NTRSDOE OSTI
DOE OSTI2025

Achieving High-Yield Conversion of Janus Transition Metal Dichalcogenides on Diverse Substrates

Janus transition metal dichalcogenides (TMDCs) with intrinsic broken mirror symmetry and vertical dipole moment provide an additional degree of freedom to manipulate material symmetry down to atomic-layer thickness. However, despite advances in synthesis strategies, fundamental understanding of this atomic substitution process remains limited, which has impeded their implementation in advanced devices. Here, by using a room-temperature atomic-layer substitution (RT-ALS) strategy, we systematically investigate the critical factors facilitating the high-yield conversion of Janus TMDCs on diverse substrates. Combining Raman spectroscopy probes, X-ray photoelectron spectroscopy (XPS) measurements, and density functional theory (DFT) calculations, we demonstrate that substrates with enhanced electron doping or larger surface polarity substantially benefit the conversion of Janus TMDCs reaching a near-unity yield. Intriguingly, the strong affinity between Janus TMDCs and substrates (e.g., Au) brings about abnormal Raman spectroscopic phenomena. These findings highlight the significance of substrates in achieving the reliable synthesis of Janus two-dimensional materials with improved homogeneity on various substrates. In addition, this takes us one step closer to utilizing Janus TMDCs as a versatile platform in next-generation optoelectronic devices, sensors, and quantum technologies.

Doping↗
NASA NTRS1978

Users' instructions for the NASA/MSFC cloud-rise preprocessor program, version 6, and the NASA/MSFC multilayer diffusion program, version 6: Research version for Univac 1108 system

The cloud-rise preprocessor and multilayer diffusion computer programs were used by NASA in predicting concentrations and dosages downwind from normal and abnormal launches of rocket vehicles. These programs incorporated: (1) the latest data for the heat content and chemistry of rocket exhaust clouds; (2) provision for the automated calculation of surface water pH due to deposition of HCl from precipitation scavenging; (3) provision for automated calculation of concentration and dosage parameters at any level within the vertical grounds for which meteorological inputs have been specified; and (4) provision for execution of multiple cases of meteorological data. Procedures used to automatically calculate wind direction shear in a layer were updated.

Bjorklund, J. R.↗
NASA NTRS2005

Enhancement and Analysis of Real-Time Radiography Images

Shuttle Redesigned Solid Rocket Motor (RSRM) nozzle interiors fabricated from carbon phenolic composite exhibit "ply lift" when hot fired. The composite surface is smooth when fabricated, but the individual plies separate and lift away from the surface when exposed to high temperature and high-pressure exhaust gas. It shows a cross section of a post-fired composite in which ply lift is evident as dark fissures. Surface charring is also visible as a darker band about 0.2 inches thick. Charring is normal, but ply lift is not desirable since the fissures could possibly initiate an abnormal exhaust path from the RSRM. The underlying mechanisms of ply lift are under investigation as part of the Shuttle Return-To-Flight Program.

Doering, Edward R.↗
NASA NTRS1999

The value of assessing pulmonary venous flow velocity for predicting severity of mitral regurgitation: A quantitative assessment integrating left ventricular function

Although alteration in pulmonary venous flow has been reported to relate to mitral regurgitant severity, it is also known to vary with left ventricular (LV) systolic and diastolic dysfunction. There are few data relating pulmonary venous flow to quantitative indexes of mitral regurgitation (MR). The object of this study was to assess quantitatively the accuracy of pulmonary venous flow for predicting MR severity by using transesophageal echocardiographic measurement in patients with variable LV dysfunction. This study consisted of 73 patients undergoing heart surgery with mild to severe MR. Regurgitant orifice area (ROA), regurgitant stroke volume (RSV), and regurgitant fraction (RF) were obtained by quantitative transesophageal echocardiography and proximal isovelocity surface area. Both left and right upper pulmonary venous flow velocities were recorded and their patterns classified by the ratio of systolic to diastolic velocity: normal (>/=1), blunted (<1), and systolic reversal (<0). Twenty-three percent of patients had discordant patterns between the left and right veins. When the most abnormal patterns either in the left or right vein were used for analysis, the ratio of peak systolic to diastolic flow velocity was negatively correlated with ROA (r = -0.74, P <.001), RSV (r = -0.70, P <.001), and RF (r = -0.66, P <.001) calculated by the Doppler thermodilution method; values were r = -0.70, r = -0.67, and r = -0.57, respectively (all P <.001), for indexes calculated by the proximal isovelocity surface area method. The sensitivity, specificity, and predictive values of the reversed pulmonary venous flow pattern for detecting a large ROA (>0.3 cm(2)) were 69%, 98%, and 97%, respectively. The sensitivity, specificity, and predictive values of the normal pulmonary venous flow pattern for detecting a small ROA (<0.3 cm(2)) were 60%, 96%, and 94%, respectively. However, the blunted pattern had low sensitivity (22%), specificity (61%), and predictive values (30%) for detecting ROA of greater than 0.3 cm(2) with significant overlap with the reversed and normal patterns. Among patients with the blunted pattern, the correlation between the systolic to diastolic velocity ratio was worse in those with LV dysfunction (ejection fraction <50%, r = 0.23, P >.05) than in those with normal LV function (r = -0.57, P <.05). Stepwise linear regression analysis showed that the peak systolic to diastolic velocity ratio was independently correlated with RF (P <.001) and effective stroke volume (P <.01), with a multiple correlation coefficient of 0.71 (P <.001). In conclusion, reversed pulmonary venous flow in systole is a highly specific and reliable marker of moderately severe or severe MR with an ROA greater than 0.3 cm(2), whereas the normal pattern accurately predicts mild to moderate MR. Blunted pulmonary venous flow can be seen in all grades of MR with low predictive value for severity of MR, especially in the presence of LV dysfunction. The blunted pulmonary venous flow pattern must therefore be interpreted cautiously in clinical practice as a marker for severity of MR.

Non-NASA Center↗
NASA NTRS1982

The Mg II resonance line emission at 2800 A in stars with different rotational velocities and different metal abundances

In many investigations, a study of the Mg II 2800 A emission was conducted in order to derive more information about the correlation of chromospheric emission with the properties of the convection zone. It has been suggested by Ayres and Linsky (1980) that there is a positive correlation between rotation and chromospheric emission at least for binary stars. The present investigation is concerned with such a correlation between rotation and chromospheric emission. Since large differences in rotational velocities are observed for F stars for which also strong chromospheric emission is observable, this particular study deals mainly with F stars. On the basis of observations of the Mg II emission in F and G stars, it is found that the emission is abnormally strong in close binary F stars. This may be explained by the generation of a large differential rotation due to tidal effects which may give very efficient dynamo generation of a surface magnetic field.

Boehm-Vitense, E.↗
NASA NTRS2001

Detection and Characterization of Imperfections in Composite Pressure Vessels

The thermographic evaluation of composite structures for delaminations, disbonds, inclusions, porosity and microcracking has proven to be a valuable asset in the field of nondestructive testing. Coupling large area coverage, variable sensitivity and minimal surface contact with a photographic type image representation of structural anomalies; thermography has become a primary inspection method for composite structures. Thermography works well for locating both surface and subsurface defects in most composite systems ranging in thickness of up to 0.25 inch (0.64 cm) or more. The thermographic method for inspection of composite structures typically involves applying an external source of heat to the structure and then recording the changes in the surface heat profile manifested by embedded defects or by material property variations. If these temperature variations are large enough and an infrared camera with sufficient sensitivity is used, then the material or structural abnormality can be detected and referred back to its source. Interpreting the information given in a thermogram, can be a difficult task under ideal circumstances and extremely challenging in a real world setting. Variables including depth, thermal conductivity, orientation and size of the abnormality can all have a great influence on how its heat pattern will be seen by the imager. The work discussed in this paper illustrates how the microstructure of several commonly found defects in composite structures relate to their thermographic image counterpart. Two test cases are studied herein, including a large graphite/epoxy RP-1 fuel tank and a graphite composite cryogenic fuel feedline. The structures used in this study were designed to serve as manufacturing proof of concept specimens and to undergo hydroburst testing to verify manufacturing practices and structural design. Prior to hydrostatic testing the structures underwent 100% thermographic evaluation to ensure that no manufacturing or handling damage was present. Due to a large inclusion found in the feedline, it was pulled from service and dissected without performing the hydroproof The thermographic indications found in the RP-1 tank were below critical limits so it underwent a complete hydroproof loading series and finally a hydroburst. Following the hydroburst samples were cut from the tank in regions where thermography had located damage before the test. These regions were thermographically and then were cross-sectioned and photomicrographed.

Walker, James L.↗
NASA NTRS1982

Volcanoes and climate

The evidence that volcanic eruptions affect climate is reviewed. Single explosive volcanic eruptions cool the surface by about 0.3 C and warm the stratosphere by several degrees. Although these changes are of small magnitude, there have been several years in which these hemispheric average temperature changes were accompanied by severely abnormal weather. An example is 1816, the "year without summer" which followed the 1815 eruption of Tambora. In addition to statistical correlations between volcanoes and climate, a good theoretical understanding exists. The magnitude of the climatic changes anticipated following volcanic explosions agrees well with the observations. Volcanoes affect climate because volcanic particles in the atmosphere upset the balance between solar energy absorbed by the Earth and infrared energy emitted by the Earth. These interactions can be observed. The most important ejecta from volcanoes is not volcanic ash but sulfur dioxide which converts into sulfuric acid droplets in the stratosphere. For an eruption with its explosive magnitude, Mount St. Helens injected surprisingly little sulfur into the stratosphere. The amount of sulfuric acid formed is much smaller than that observed following significant eruptions and is too small to create major climatic shifts. However, the Mount St. Helens eruption has provided an opportunity to measure many properties of volcanic debris not previously measured and has therefore been of significant value in improving our knowledge of the relations between volcanic activity and climate.

Toon, O. B.↗
NASA NTRS1983

A review of tropospheric refraction effects on Earth-to-satellite systems

Abnormal refractivity gradients may cause radio waves to be trapped within tropospheric layers, thus producing regions through which the waves do not pass called radio holes. For some locations and for many applications, refractive corrections based on the surface refractivity are adequate for elevation angles above a few degrees. However, new systems which operate at elevation angles near the horizon often require improved accuracies. Techniques for obtaining these improved corrections are reviewed.

Althsuler, E. E.↗
NASA NTRS1975

Crater studies in the Apollo 17 region

As part of crater analysis in the Apollo 17 region, cumulative size-frequency curves were constructed, the density distribution of small craters was determined, and the effects of secondary crater clusters near the landing site were studied. The cumulative curves indicate that the old dark-mantled mare is similar in age to Apollo 11 mare, and that the adjacent young light mare of Central Serenitatis is similar in age to Apollo 15 mare. The old dark-mantled surface is markedly deficient in craters between 100 and 200 m in diameter, and the analysis suggests that this deficiency is a consequence of the old dark mantle which gives rise to an unusually thick unconsolidated layer that causes abnormally rapid degradation of small craters.

Lucchitta, B. K.↗
NASA NTRS2005

Strategies and Approaches to TPS Design

Thermal protection systems (TPS) insulate planetary probes and Earth re-entry vehicles from the aerothermal heating experienced during hypersonic deceleration to the planet s surface. The systems are typically designed with some additional capability to compensate for both variations in the TPS material and for uncertainties in the heating environment. This additional capability, or robustness, also provides a surge capability for operating under abnormal severe conditions for a short period of time, and for unexpected events, such as meteoroid impact damage, that would detract from the nominal performance. Strategies and approaches to developing robust designs must also minimize mass because an extra kilogram of TPS displaces one kilogram of payload. Because aircraft structures must be optimized for minimum mass, reliability-based design approaches for mechanical components exist that minimize mass. Adapting these existing approaches to TPS component design takes advantage of the extensive work, knowledge, and experience from nearly fifty years of reliability-based design of mechanical components. A Non-Dimensional Load Interference (NDLI) method for calculating the thermal reliability of TPS components is presented in this lecture and applied to several examples. A sensitivity analysis from an existing numerical simulation of a carbon phenolic TPS provides insight into the effects of the various design parameters, and is used to demonstrate how sensitivity analysis may be used with NDLI to develop reliability-based designs of TPS components.

Paul Kolodziej↗
DOE OSTI2024

Acoustic sensing and autoencoder approach for abnormal gas detection in a spent nuclear fuel canister mock-up

Currently, spent nuclear fuel (SNF) from commercial nuclear power plants is stored in stainless-steel canisters for interim dry storage. To provide an inert environment, these canisters are backfilled with helium after vacuum drying. However, the helium environment may be contaminated during extended storage because of the material degradation. For example, the heavier fission gas xenon may be released from the fuel rods into the canister cavity should the fuel cladding be breached. Other gases such as air and water vapor may also be present as a result of leakage caused by chloride-induced stress corrosion cracking on the canister walls or by insufficient vacuum drying. Therefore, monitoring the gas composition can provide critical information about the health of SNF canisters. In this study, noninvasive testing was conducted on a 2/3-scaled SNF canister mock-up using acoustic sensing. Ultrasonic transducers were placed on the exterior surface of the canister to probe the gas composition. A dataset was collected by sealing the canister mock-up and introducing up to 1.53% argon or 1.29% air into the helium background gas. Three methods were used to detect changes in the gas composition: the time-of-flight (TOF) method, the differential method, and the autoencoder method. Results showed that the TOF method had sufficient resolution to detect abnormal gas concentrations of less than 1.0%. The differential method demonstrated a periodic in-phase and out-of-phase behavior between the benchmark (i.e., pure helium) and abnormal (i.e., with argon or air) state signals. The variational autoencoder (VAE) and the Wasserstein autoencoder (WAE) were trained on the benchmark data and were applied directly to the abnormal state data. It was found that both the unsupervised VAE and the WAE were able to distinguish the benchmark and abnormal states of the canister mock-up based on the reconstruction error.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗
NASA NTRS2004

Immunity-Based Aircraft Fault Detection System

In the study reported in this paper, we have developed and applied an Artificial Immune System (AIS) algorithm for aircraft fault detection, as an extension to a previous work on intelligent flight control (IFC). Though the prior studies had established the benefits of IFC, one area of weakness that needed to be strengthened was the control dead band induced by commanding a failed surface. Since the IFC approach uses fault accommodation with no detection, the dead band, although it reduces over time due to learning, is present and causes degradation in handling qualities. If the failure can be identified, this dead band can be further A ed to ensure rapid fault accommodation and better handling qualities. The paper describes the application of an immunity-based approach that can detect a broad spectrum of known and unforeseen failures. The approach incorporates the knowledge of the normal operational behavior of the aircraft from sensory data, and probabilistically generates a set of pattern detectors that can detect any abnormalities (including faults) in the behavior pattern indicating unsafe in-flight operation. We developed a tool called MILD (Multi-level Immune Learning Detection) based on a real-valued negative selection algorithm that can generate a small number of specialized detectors (as signatures of known failure conditions) and a larger set of generalized detectors for unknown (or possible) fault conditions. Once the fault is detected and identified, an adaptive control system would use this detection information to stabilize the aircraft by utilizing available resources (control surfaces). We experimented with data sets collected under normal and various simulated failure conditions using a piloted motion-base simulation facility. The reported results are from a collection of test cases that reflect the performance of the proposed immunity-based fault detection algorithm.

Dasgupta, D.↗
NASA NTRS2001

Efficient Cache use for Stencil Operations on Structured Discretization Grids

We derive tight bounds on the cache misses for evaluation of explicit stencil operators on structured grids. Our lower bound is based on the isoperimetrical property of the discrete octahedron. Our upper bound is based on a good surface to volume ratio of a parallelepiped spanned by a reduced basis of the interference lattice of a grid. Measurements show that our algorithm typically reduces the number of cache misses by a factor of three, relative to a compiler optimized code. We show that stencil calculations on grids whose interference lattice have a short vector feature abnormally high numbers of cache misses. We call such grids unfavorable and suggest to avoid these in computations by appropriate padding. By direct measurements on a MIPS R10000 processor we show a good correlation between abnormally high numbers of cache misses and unfavorable three-dimensional grids.

Frumkin, Michael↗
NASA NTRS1983

NASA flight electronics environmental stress screening survey

Data compiled by the Institute of Environmental Sciences were used to establish guidelines for identifying defective, abnormal, or marginal parts as well as manufacturing defects. These data are augmented with other available sources of similar information in conjunction with NASA centers' data and presented in a form that may be useful to all NASA centers in planning and developing effective environmental stress screens. Information relative to thermal and vibration screens as the most effective methods for surfacing latent failures in electronic equipment at the component level is considered.

Marian, E. J.↗
NASA NTRS1992

Properties data for opening the Galileo's partially unfurled main antenna

An investigation was conducted into the friction and wear behavior of both unlubricated and dry-film-lubricated (Tiolube 460) titanium alloy (Ti-6Al-4V) in contact with an uncoated high-nickel-content superalloy (Inconel 718) both in vacuum and in air. The acquisition of friction and wear data for this sliding couple was motivated by the need for input data for the 'antenna stuck ribs model' effort to free Galileo's High Gain Antenna. The results of the investigation indicate that galling occurred in the unlubricated system in vacuum and that the coefficient of friction increased to 1.2. The abnormally high friction (1.45) was observed when relatively large wear debris clogged at the sliding interface. The coefficient of friction for the dry-film-lubricated system in vacuum is 0.04, while the value in air is 0.13. The endurance life of the dry-film lubricant is about three orders of magnitude greater in vacuum than in air. The worn surfaces of the dry-film-lubricated Ti-6Al-4V pin and Inconel 718 disk first run in humid air and then rerun in vacuum was completely different from that of the pin and disk run only in vacuum. When galling occurred in the humid-air and vacuum contact, coefficient of friction rose to 0.32 when sliding in humid air and to 1.4 when sliding in vacuum. The galling was accompanied by severe surface damage and extensive transfer of the Ti-6Al-4V to the Inconel 718, or vice versa. When spalling occurred in the dry-film-lubricated Ti-6Al-4V pin run only in vacuum, the coefficient of friction rose to 0.36 or greater. The wear damage caused by spalling can self-heal when rerun in vacuum - the coefficient of friction decreased to 0.05. The friction and wear data obtained can be used for the 'antenna stuck ribs model' effort to free Galileo's high gain antenna.

Miyoshi, Kazuhisa↗
NASA NTRS2011

Modeling Weather Impact on Ground Delay Programs

Scheduled arriving aircraft demand may exceed airport arrival capacity when there is abnormal weather at an airport. In such situations, Federal Aviation Administration (FAA) institutes ground-delay programs (GDP) to delay flights before they depart from their originating airports. Efficient GDP planning depends on the accuracy of prediction of airport capacity and demand in the presence of uncertainties in weather forecast. This paper presents a study of the impact of dynamic airport surface weather on GDPs. Using the National Traffic Management Log, effect of weather conditions on the characteristics of GDP events at selected busy airports is investigated. Two machine learning methods are used to generate models that map the airport operational conditions and weather information to issued GDP parameters and results of validation tests are described.

Wang, Yao↗
NASA NTRS1995

Dynamic Processes in Be Star Atmospheres.: Simultaneous X-Ray, Ultraviolet, and Optical Variations in lambda Eridani - 6

This report describes a joint X ray/ultraviolet/ground based study of the abnormal Be star lambda Eri which has previously shown evidence of X ray flaring from Rosat observations in 1991. The 1991 flare event caught the astronomical hot star community by surprise because x ray flares have not been observed from other single B-type stars, before or since. Both optical (H-alpha) and UV/Voyager observations provide evidence for transient heating events near the surface of lambda Eri.

Smith, Myron A.↗
NASA NTRS1980

The HD 200775/NGC 7023 complex - A question of reddening

The separation of the observed reddening of HD 200775 into intrinsic and interstellar components is rediscussed in the light of new surface-brightness data for NGC 7023, the reflection nebula surrounding HD 200775. Appropriate correction for the nebular contribution to reported ultraviolet flux measurements of HD 200775 leads to new values due to dust reddening: E(B-V) sub D = 0.44, and due to intrinsic reddening: E(B-V) sub I = 0.13-0.26. The newly derived extinction curve for HD 200775 is characterized by an abnormally weak interstellar 2200 A absorption feature, and the deduced nebular brightness in the far-ultraviolet is consistent either with dust in NGC 7023 having a relatively high albedo (a approximately equal to 0.6) and a nearly isotropic phase function (g approximately equal to 0.2), or with low albedo dust (a approximately equal to 0.3) with a forward-throwing phase function (g approximately equal to 0.6).

Witt, A. N.↗