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At least 55 records · Page 3
All sourcesNASA NTRSDOE OSTI
NASA NTRS2020

The Role of Declining Snow Cover in the Desiccation of the Great Salt Lake, Utah, using MODIS Data

The Great Salt Lake (GSL) in Utah has been shrinking since the middle of the 19th Century, leading to decreased area and volume, and increased salinity. We use satellite data products from the Terra and Aqua MODerate-resolution Imaging Spectroradiometer (MODIS) and the Landsat-7 and -8 satellites, along with meteorological and streamflow data, and modeled data products to study the relationship between changing snow-cover conditions and the decline of the GSL since 2000 in the context of the historical record of lake levels. The GSL basin includes much of the snow-dominated Wasatch and Uinta mountain ranges to the east of the lake. Snowmelt feeds the Bear, Jordan, and Weber rivers which are the three main rivers that flow into the lake. Snowmelt-timing maps, derived from a new MODIS standard snow-cover product, MOD10A1F, show that snow melted ~9.5 days earlier in the GSL basin during the study period, extending from 2000 – 2018. Air temperatures derived from 26 meteorological stations and surface temperatures measured by the Aqua MODIS land-surface temperature (LST) products, MYD21A1D and MYD21A1N, show trends of increasing temperature of ~0.94°C (a=0.05), and ~2.18°C, respectively, with most of the LST trends in the GSL basin being statistically significant (a=0.05). Increasing air temperatures in the basin have led to less precipitation falling as snow, lower snow depth (by ~34.5 mm (=0.01)) and snow-water equivalent (0.02 mm (a=0.01)), and earlier snowmelt. Also during the study period, Global Land surface Evaporation Amsterdam Model data show evaporation increasing by ~3.2 mm/yr, with trends in much of the basin being statistically significant (a=0.05). Trends calculated from the various products are generally in agreement indicating higher temperatures, greater evaporation, less snowfall and snow-on-the ground, and earlier snowmelt. Earlier snowmelt contributes to increasing evaporative loss from water flowing toward the lake. Furthermore, a lower mountain snowpack and less precipitation falling as snow (versus rain) is associated with lower stream discharge even if overall precipitation stays the same. The surface-water temperature of the GSL also increased over the study period by ~ 0.69°C, according to the MODIS LST data products, and the surface-water elevation of the lake dropped by ~1.7 m between 2000 and 2018 based on United States Geological Survey measurements, and the areal extent of the lake decreased by ~901 km2 as measured using Landsat imagery. Desiccation of the lake is associated with deleterious effects on wildlife, recreational activities, and some local industries. And, importantly, an expanding lake bed can also fuel dust storms that promote dangerous air quality along the Wasatch Front. This work elucidates the key role that satellite remote sensing can play in documenting earlier snowmelt and other changes in the GSL basin that influence the ongoing decline of the Great Salt Lake.

Dorothy K Hall↗
NASA NTRS2020

Montana Water Resources: Developing a Composite Moisture Index Utilizing NASA Earth Observations for Drought Monitoring in the Missouri River Basin

The Missouri River Basin provides irrigation water for a substantial part of the domestic agricultural sector within the United States. Drought events pose a significant threat to the economic livelihoods of dependent individuals, industries, and ecosystems (e.g. farmers, local tribes, hydroelectric power, wildlife). In 2017 alone, the Missouri River Basin experienced a severe drought that resulted in a $2.6 billion loss to the U.S. Northern Plains. In response to such events, organizations throughout the basin, such as the Montana Climate Office, have dedicated efforts for drought monitoring and communicating relevant information to local stakeholders. In an effort to aid regional decision-making capabilities, the project team partnered with the Montana Climate Office, NOAA National Weather Service (NWS) Missouri Basin River Forecast Center, and NOAA Regional Climate Services, Central Region to create a monthly Composite Moisture Index (CMI) that relies on NASA Earth observations from the Terra Moderate Resolution Imaging Spectroradiometer (MODIS) and the Soil Moisture Active Passive (SMAP) mission. From these satellites, as well as the NOAA NWS National Operational Hydrologic Remote Sensing Center’s Snow Data Assimilation System (SNODAS), our team aggregated climate datasets including soil moisture, snow cover, snow depth, and snow water equivalent to compute a CMI that indicates regional moisture conditions during the winter months. The March CMI values produced over the Missouri River headwater subbasin strongly correlate (r = 0.75) with spring and early summer stream discharge, demonstrating the use of this metric to indicate moisture conditions for the snowmelt and growing seasons.

DEVELOP Project Summary↗
NASA NTRS2021

Montana Water Resources: Developing a Composite Moisture Index Utilizing NASA Earth Observations for Drought Monitoring in Montana and the Missouri River Basin

The Missouri River Basin provides irrigation water for a substantial part of the domestic agricultural sector within the United States. Drought events pose a significant threat to economic livelihoods of dependent individuals, industries, and ecosystems (e.g., farmers, local tribes, hydroelectric power, wildlife). In 2017 alone, the Missouri River Basin experienced a severe drought that resulted in a $2.6 billion loss to the U.S. Northern Plains. In response to such events, organizations throughout the basin, such as the Montana Climate Office, have dedicated efforts for drought monitoring and communicating relevant information to local stakeholders. In an effort to aid regional decision-making capabilities, the project team partnered with the Montana Climate Office, NOAA National Weather Service (NWS) Missouri Basin River Forecast Center, and NOAA Regional Climate Services, Central Region to create a monthly Composite Moisture Index (CMI) that relies on NASA Earth observations from the Terra Moderate Resolution Imaging Spectroradiometer (MODIS) and the Soil Moisture Active Passive (SMAP) mission. From these satellites, as well as the NOAA NWS National Operational Hydrologic Remote Sensing Center Snow Data Assimilation System (SNODAS), our team aggregated climate datasets including soil moisture, snow cover, snow depth, and snow water equivalent to compute a CMI that indicates regional moisture conditions during the winter months. The March CMI values produced over the Missouri River headwater subbasin strongly correlate (r = 0.75) with spring and early summer stream discharge, demonstrating the use of this metric to indicate moisture conditions for the snowmelt and growing seasons.

DEVELOP Tech Paper↗
NASA NTRS1974

Venting characteristics of gaseous helium and nitrogen discharging into a free stream at Mach numbers from 0.60 to 1.57

An experimental investigation was conducted in the Lewis Research Center 8- by 6-Foot Supersonic Wind Tunnel to compare the effects on discharge coefficient of venting gaseous helium and gaseous nitrogen into a free stream. The test was conducted from Mach 0.06 to 1.57 with the vent mounted in a flat plate. The plate was strut mounted to the tunnel ceiling and at a 0 angle of attack. The gases were discharged from a plenum chamber through a 2.54-centimeter (1.00-in.) diameter vent. The ratio of local static pressure to plenum pressure was varied from 0.51 to 0.975. The ratio of boundary layer thickness to vent diameter varied from a maximum of 1.34 at Mach 0.60 to a minimum of 0.55 at Mach 1.37.

Johns, A. L.↗
DOE OSTI2023

Hydrobiogeochemical Controls on the Delivery of Dissolved Organic Matter to Boreal Headwater Streams

Understanding controls on the delivery of dissolved organic matter (DOM) from terrestrial to aquatic systems is key for constraining carbon balances and fluxes in boreal headwater catchments. The largest export of DOM generally occurs during intense periods of water delivery to the landscape (e.g., rain events); however, the timing and magnitude of DOM is complicated by geomorphological, hydrometeorological, and biogeochemical variability. To better assess mechanisms controlling the delivery of DOM to boreal streams, DOM was investigated in two morphologically distinct catchments of an experimental forest watershed in western Newfoundland, one dominated by low relief wetlands and the other by steep hillslopes. The DOM was compared during two fall storms of similar magnitude but contrasting moisture conditions during the autumn transition. Variable concentrations and optical character highlighted antecedent conditions are important for the delivery of DOM to boreal streams. Concentration-discharge relationships with stream hydrograph separation analysis suggest preferential flowpaths through shallow mineral horizons as a key pathway for delivery of DOM in the hillslope dominated catchment compared to rapid input from near-stream wetlands in the low relief catchment. Loss of DOM via preferential pathways suggests an additional mechanism for surface soil carbon loss not directly informed by lateral flow and soil hydrology, which has important implications for our conceptualization and modeling of carbon fluxes in boreal systems. These results suggest watershed scale responses of DOM in boreal headwater catchments are complex, and better linkages between catchment scale hydrology and landscape hydrobiogeochemistry are required to constrain terrestrial to aquatic carbon fluxes in boreal landscapes.

54 ENVIRONMENTAL SCIENCES↗
NASA NTRS1973

Self-cycling fluid heater

A self-cycling fluid heater is described which includes a high temperature upstream preheater for elevating the stream temperature. A high intensity jet arc heater heats the preheated fluid stream to ultrahigh reaction temperatures and discharges the stream into an electric resistance tubular heat exchanger. The heat exchanger has variations in wall thickness at measured intervals along its length to control the temperature of the fluid passing through the heat exchanger for desired time intervals to provide the specified chemical reactions desired.

Moen, W. K.↗
DOE OSTI2025

The Role of Snowmelt and Subsurface Heterogeneity in Headwater Hydrology of a Mountainous Catchment in Colorado: A Model‐Data Integration Approach

Mountainous headwater streams are sustained by both snowmelt‐driven streamflow and groundwater discharge in the Upper Colorado River Basin. However, predicting headwater stream discharge magnitude and peak flow timing is challenging in mountainous terrains, where snowmelt rates vary with vegetation type and elevation, and heterogeneous subsurface physical properties influence groundwater storage and its release. We used a model‐data integration approach to investigate the roles of snowmelt and subsurface structure in stream discharge and groundwater level. We ran an ensemble of 100 integrated surface‐subsurface hydrologic models for a mountainous headwater catchment near Crested Butte, Colorado, USA. We also evaluated and calibrated these models against observed data sets, including snow depth measurements using distributed temperature probes, stream discharge, and groundwater levels. Calibration with multiple data sources using neural density estimators has further constrained uncertainty in subsurface properties and snowmelt rates. Results indicated that observed slower snowmelt rates in evergreen forests delayed the peak flow and baseflow onset. In upstream areas with lower subsurface permeability, water was stored within the subsurface but was not released as interflow or shallow groundwater flow, and thereby not contributing to downstream streamflow during recession limb periods. Double peaks in groundwater occurred in areas with spatial subsurface heterogeneity, in our case due to the contrast between granodiorite and Mancos shale. These process‐based insights into groundwater and snowmelt dynamics in mountainous headwaters will help improve predictions of headwater hydrology.

Wang, Lijing [University of Connecticut, Storrs, C↗
DOE OSTI2023

Train, Inform, Borrow, or Combine? Approaches to Process–Guided Deep Learning for Groundwater–Influenced Stream Temperature Prediction

Although groundwater discharge is a critical stream temperature control process, it is not explicitly represented in many stream temperature models, an omission that may reduce predictive accuracy, hinder management of aquatic habitat, and decrease user confidence. We assessed the performance of a previously-described process-guided deep learning model of stream temperature in the Delaware River Basin (USA). We found lower accuracy (root mean square error [RMSE] of 1.71 versus 1.35°C) and stronger seasonal bias (absolute mean monthly bias of 1.06 vs. 0.68°C) for reaches primarily influenced by deep groundwater as compared to atmospheric conditions. We then tested four approaches for improving groundwater process representation: (a) a custom loss function leveraging the unique patterns of air and water temperature coupling characteristic of different temperature drivers, (b) inclusion of additional groundwater-relevant catchment attributes, (c) incorporation of additional process model outputs, and (d) a composite model. The custom loss function and the additional attributes significantly improved the predictive accuracy in groundwater-dominated reaches (RMSE of 1.37 and 1.26°C) and reduced the seasonal bias (absolute mean monthly bias of 0.44 and 0.48°C), but neither approach could identify holdout groundwater reaches. Variable importance analysis indicates the custom loss function nudges the model to use the existing inputs more efficiently, whereas with the added features the model relies on a broader suite of inputs. This analysis is a substantial step toward more accurately representing groundwater discharge processes in stream temperature models and will improve predictive accuracy and inform habitat management.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2025

Walker Branch Watershed: Daily Stream Metabolism and Organic Carbon Spiraling Metrics in the West Fork of Walker Branch, Tennessee, USA, 2004-2010

This dataset contains daily metabolism estimates of gross primary production (GPP), ecosystem respiration (ER), and net ecosystem production (NEP), in addition to organic carbon spiraling length (SOC) and mineralization velocity (VfOC) estimates at the West Fork of Walker Branch, a small headwater stream, in the Walker Branch Watershed, Tennessee, USA. Observations were made from 2004-2010 (2004-01-01 to 2010-12-31). These data were generated to assess seasonal and interannual variability in metabolism and organic carbon spiraling and to explore potential driver variables, as analyses of intra- and interannual variability in metabolism and organic carbon spiraling are currently limited, leaving knowledge gaps in the driving mechanisms of and future changes to stream metabolism and carbon processing under climate change. Additionally, measurements of discharge (Q), stream width, stream- and canopy-level photosynthetically active radiation (PAR), water temperature, and precipitation from this time frame are included. This dataset contains one data file in comma separated (*.csv) format.

54 ENVIRONMENTAL SCIENCES↗
NASA NTRS1973

Remote-sensing studies of hydrologic environments in the lower Raritan River System, New Jersey

A series of remote sensing experiments were conducted in January and November 1968. The airborne multisensor missions included photographic and thermal-infrared sensors operated over a single site at a time when streamflow and water temperature observations were being made on the ground. Remote sensing data show: (1) effect of thermal waste water discharges on stream temperatures, (2) cross-channel variations in thermal characteristics due to waste water discharge, channel characteristics, and tidal currents, (3) influence of flow rates on dispersion, (4) patterns and distribution of ice cover, and (5) movement of sediment loads.

Anderson, P. W.↗
NASA NTRS2005

High Energy Cutting and Stripping Utilizing Liquid Nitrogen

The Aerospace Industry has endeavored for decades to develop hybrid materials that withstand the rigors of mechanized flight both within our atmosphere and beyond. The development of these high performance materials has led to the need for environmentally friendly technologies for material re-work and removal. The NitroJet(TM) is a fluid jet technology that represents an evolution of the widely used, large-scale water jet fluid jet technology. It involves the amalgamation of fluid jet technology and cryogenics technology to create a new capability that is applicable where water jet or abrasive jet (water jet plus entrained abrasive) are not suitable or acceptable because of technical constraints such as process or materials compatibility, environmental concerns and aesthetic or legal requirements. The NitroJet(TM) uses ultra high-pressure nitrogen to cut materials, strip numerous types of coatings such as paint or powder coating, clean surfaces and profile metals. Liquid nitrogen (LN2) is used as the feed stream and is pressurized in two stages. The first stage pressurizes sub cooled LN2 to an intermediate pressure of between 15,000 and 20,000 psi at which point the temperature of the LN2 is about -250 F. The discharge from this stage is then introduced as feed to a dual intensifier system, which boosts the pressure from 15,000 - 20,000 psi up to the maximum operating pressure of 55,000 psi. A temperature of about -220 F is achieved at which point the nitrogen is supercritical. In this condition the nitrogen cuts, strips and abrades much like ultra high-pressure water would but without any residual liquid to collect, remove or be contaminated. Once the nitrogen has performed its function it harmlessly flashes back into the atmosphere as pure nitrogen gas. The system uses heat exchangers to control and modify the temperature of the various intake and discharge nitrogen streams. Since the system is hydraulically operated, discharge pressures can be easily varied over a very wide range providing considerable flexibility for various operations. The NitroJet(TM) is an advance on the nitrogen fluid jet technology initially developed at the Idaho National Engineering Laboratory in Idaho Falls, Idaho. NitroCision(R) first introduced the NitroJet(TM) into a commercial setting in 2003 and there has been considerable interest from many diverse sectors of government and industry since then. While the current system is an industrial system with the size and mass normally associated with industrial applications, a smaller system that is much more compact is being contemplated for those applications that do not need the full capabilities of the larger system. The NitroJet(TM) can be deployed as a fixed or mobile system with multiple end effectors capable of cutting, stripping, cleaning, and surface profiling either in robotic or manual applications.

Hume, Howard↗
DOE OSTI2022

A new large-scale suspended sediment model and its application over the United States

Abstract. Suspended sediment plays a vital role in the regional and global cycling of carbon and nutrients by carrying carbon and nutrients from headwaters into lowland rivers and the oceans. Sediment transport through river systems is often fundamentally modified by human activities such as reservoir management. However, a physically based representation of sediment transport is still missing in most existing Earth system models (ESMs), which are essential tools for modeling and predicting Earth system changes. Here, we introduce a multi-process river sediment module for ESMs, which includes (1) hillslope soil erosion and sediment discharge into streams, (2) sediment transport processes through river networks, (3) reservoir operation based on the inflows from upstream areas and water demand from downstream areas, and (4) sediment trapping by reservoirs. All model parameters are estimated a priori without calibration. We apply this new sediment modeling framework to the contiguous United States and validate it against historical observations of monthly streamflow and sediment discharges at 35 river gauges. The model reasonably well captures the long-term balance and seasonal variations of suspended sediment in large river systems. Furthermore, our model results show that suspended sediment discharge in managed rivers is affected more by reservoirs' direct trapping of sediment particles than by their flow regulation. This new sediment module enables future modeling of the transportation and transformation of carbon and nutrients carried by the fine sediment along the river–ocean continuum to close the global carbon and nutrient cycles.

54 ENVIRONMENTAL SCIENCES↗
NASA NTRS1997

West-Antarctic Ice Streams: Analog to Ice Flow in Channels on Mars

Sounding of the sea floor in front of the Ross Ice Shelf in Antarctica recently revealed large persistent patterns of longitudinal megaflutes and drumlinoid forms, which are interpreted to have formed at the base of ice streams during the list glacial advance. The flutes bear remarkable resemblance to longitudinal grooves and highly elongated streamlined islands found on the floors of some large martian channels, called outflow channels. ln addition, other similarities exist between Antarctic ice streams and outflow channels. Ice streams are 30 to 80 km wide and hundreds of kilometers long, as are the martian channels. Ice stream beds are below sea level. Floors of many martian outflow channels lie below martian datum, which may have been close to or below past martian sea levels. The Antarctic ice stream bed gradient is flat and locally may go uphill, and surface slopes are exceptionally low. So are gradients of martian channels. The depth to the bed in ice streams is 1 to 1.5 km. At bankful stage, the depth of the fluid in outflow channels would have been 1 to 2 km. These similarities suggest that the martian outflow channels, whose origin is commonly attributed to gigantic catastrophic floods, were locally filled by ice that left a conspicuous morphologic imprint. Unlike the West-Antarctic-ice streams, which discharge ice from an ice sheet, ice in the martian channels came from water erupting from the ground. In the cold martian environment, this water, if of moderate volume, would eventually freeze. Thus it may have formed icings on springs, ice dams and jams on constrictions in the channel path, or frozen pools. Given sufficient thickness and downhill surface gradient, these ice masses would have moved; and given the right conditions, they could have moved like Antarctic ice streams.

Lucchitta, B. K.↗
DOE OSTI2020

Capture of Iodine from Nuclear-Fuel-Reprocessing Off-Gas: Influence of Aging on a Reduced Silver Mordenite Adsorbent after Exposure to NO/NO 2

Iodine radioisotopes released during nuclear fuel reprocessing must be removed from the off-gas stream before discharge. One promising material for iodine capture is reduced silver mordenite (Ag 0 Z). Nevertheless, the adsorbent’s capacity will degrade, or age, over time when the material is exposed to other off-gas constituents. Though the overall impact of aging is known, the underlying physical and chemical processes are not. To examine these processes, Ag 0 Z samples were prepared and aged in 2% NO 2 in dry air and in 1% NO in N 2 gas streams at 150 °C for up to six months. Aged samples were then characterized using scanning electron microscopy, X-ray diffraction, Raman spectroscopy, and X-ray absorption spectroscopy. These techniques show that aging involves two overarching processes: (i) oxidation of the silver nanoparticles present in Ag 0 Z and (ii) migration of oxidized silver into the mordenite’s inner network. Silver on the nanoparticle’s surface is oxidized through adsorption of O 2 , NO, and NO 2 . Additionally, Raman spectroscopy and X-ray absorption spectroscopy indicate that nitrates are the primary products of this adsorption. Most of these nitrates migrate into the interior of the mordenite and exchange at framework binding sites, returning silver to its unreduced state (AgZ). The remaining nitrates exist at a persistent concentration without aggregating into bulk-phase AgNO 3 . X-ray absorption spectroscopy results further indicate that iodine adsorption occurs on not just Ag 0 Z but also on AgZ and a portion of the nitrates in the system. AgZ adsorbs a sizable quantity of iodine early in the aging process, but its capacity drops rapidly over time. For well-aged samples, nitrates are responsible for up to 95% of mordenite’s iodine capacity. Overall, these results have enhanced our understanding of the aging process in silver mordenite and are expected to guide the development of superior adsorbents for the capture of radioactive iodine from reprocessing off-gas.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗
DOE OSTI2025

Molecular Insights into Novel Struvite–Hydrogel Composites for Simultaneous Ammonia and Phosphate Removal

Struvite (NH 4 MgPO 4 ·6H 2 O) mineralization is an effective technique for removing ammonium and phosphate species from wastewater. However, its wider use faces obstacles because of the copresence of various pollutants in wastewater and the additional requirement for magnesium to achieve proper supersaturation conditions. To address these challenges, this study developed novel mineral–hydrogel composites that can remove ammonium and phosphate simultaneously via heterogeneous struvite and calcium phosphate (CaP) mineralization in hydrogel matrices. The composites include in situ formed struvite and CaP mineral seeds, decreasing the nucleation energy barrier of struvite and CaP formation and promoting their heterogeneous nucleation kinetics even under undersaturation conditions in bulk solution. The dual struvite and CaP seeded composites can simultaneously reduce the ammonium and total phosphate concentrations up to 60% (26.3 mg of N/g) and 91% (9.54 mg of P/g), respectively. Furthermore, the average particle sizes in composites were increased from 6.12 to 14.8 nm after wastewater treatment. Moreover, various ions commonly existing in wastewater did not significantly interfere with the removal of ammonium and phosphate. Thus, these new mineral–hydrogel composites can provide an innovative way to lower nutrient levels before discharge to streams. Moreover, encapsulating ammonium and phosphate in mineral-hydrogel composites enables their upcycling in agricultural or biorefinery applications.

Cations↗
DOE OSTI2026

Rapid organic carbon spiraling in a headwater stream linked with streamflow, biogeochemistry, and canopy phenology

Headwater streams are abundant worldwide and important to global biogeochemical cycles, serving as critical processors and transporters of C. C spiraling is a useful way to understand the retention and mineralization of organic C (OC) in streams. However, analyses of seasonal and interannual variability in OC spiraling are currently limited. In this study, we aimed to understand the temporal patterns and driving mechanisms of OC spiraling, which will inform our understanding of future OC changes under climate change. We used 7 y of daily data in a small headwater stream (Walker Branch, Tennessee, USA) to assess seasonal and interannual variability in OC spiraling length (S OC ) and mineralization velocity (v fOC ), as well as their potential related variables. On average, S OC in Walker Branch was ~10× shorter than in previously studied small streams, indicating strong connections between the water column and the benthic environment where OC mineralization mostly takes place. OC spiraling was faster during the more biologically active periods of spring and autumn compared with more elongated OC spiraling in summer and winter, when OC retention was lower and downstream transport was higher. Gross primary production (GPP) was most strongly related to S OC and v fOC . Photosynthetically active radiation (PAR) and NO 3 − were also positively and negatively related to v fOC , respectively. Trends toward earlier and longer canopy cover and reduced GPP and PAR may result in longer S OC and slower v fOC , reducing localized instream processing of OC and potentially shunting more OC downstream. However, long-term observations indicate reduced NO 3 − at Walker Branch, suggesting opposing effects to those of GPP and PAR, leading to faster v fOC and greater OC retention. Time-series analyses of OC spiraling in streams can enhance our understanding of current and future responses of OC processing and downstream transport to climate change, as well as implications for downstream OC dynamics.

biological activity↗
DOE OSTI2020

FY2020 Rotating Bed Reactor for Iodine Removal from WTP Melter Effluent to Support DFLAW Start-Up

In Performance Assessment (PA) of the Hanford Integrated Disposal Facility (IDF), 129 I is a significant contributor to the risk. The 2017 IDF PA accounted for 0.22% of the total 129 I inventory in Hanford tank waste as residing in the solidified liquid waste from the Effluent Treatment Facility (ETF). However, recent estimates suggest that higher percentages of the iodine processed at the Hanford Waste Treatment and Immobilization Plant (WTP) may be present in the liquid waste routed to the Liquid Effluent Retention Facility (LERF) for eventual treatment at the ETF. In addition, a recent integrated melter test performed at the Vitreous State Laboratory (VSL) at The Catholic University of America (CUA) showed the possibility that a significant fraction (>50%) of the total iodine in the melter feed could be present in the aqueous waste stream destined for the ETF. This stream represents a combination of the Effluent Management Facility (EMF) evaporator overhead condensate and the liquid waste from the WTP off-gas caustic scrubber. Higher levels of 129 I in this stream could affect the LERF and ETF Hazard Categorizations as well as the acceptability of the solidified ETF liquid secondary waste brine for disposal at the IDF. Accordingly, there is a need to investigate and develop potential methods and processes to mitigate this risk. Washington River Protection Solutions, LLC (WRPS) tasked Atkins and VSL to perform development and testing work to evaluate potential methods for removal of iodine species from the waste stream routed to the LERF. In particular, the testing investigated the use of an Atkins-SpinIonic™ Rotating Bed Reactor (RBR) system as a potential alternative to conventional column-based ion exchange or absorption processes. The present report provides results obtained from testing with an RBR system for the removal of iodine from simulants of the projected WTP waste stream that discharges to the LERF.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗