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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 55 records · Page 3

Machine Learning for Daily Forecasts of Arctic Sea Ice Motion: An Attribution Assessment of Model Predictive Skill

Physics-based simulations of Arctic sea ice are highly complex, involving transport between different phases, length scales, and time scales. Resultantly, numerical simulations of sea ice dynamics have a high computational cost and model uncertainty. We employ data-driven machine learning (ML) to make predictions of sea ice motion. The ML models are built to predict present-day sea ice velocity given present-day wind velocity and previous-day sea ice concentration and velocity. Models are trained using reanalysis winds and satellite-derived sea ice properties. We compare the predictions of three different models: persistence (PS), linear regression (LR), and a convolutional neural network (CNN). We quantify the spatiotemporal variability of the correlation between observations and the statistical model predictions. Additionally, we analyze model performance in comparison to variability in properties related to ice motion (wind velocity, ice velocity, ice concentration, distance from coast, bathymetric depth) to understand the processes related to decreases in model performance. Results indicate that a CNN makes skillful predictions of daily sea ice velocity with a correlation up to 0.81 between predicted and observed sea ice velocity, while the LR and PS implementations exhibit correlations of 0.78 and 0.69, respectively. The correlation varies spatially and seasonally: lower values occur in shallow coastal regions and during times of minimum sea ice extent. LR parameter analysis indicates that wind velocity plays the largest role in predicting sea ice velocity on 1-day time scales, particularly in the central Arctic. Regions where wind velocity has the largest LR parameter are regions where the CNN has higher predictive skill than the LR.

54 ENVIRONMENTAL SCIENCES↗

Understanding Subsurface Fracture Evolution Dynamics Using Time‐Lapse Full Waveform Inversion of Continuous Active‐Source Seismic Monitoring Data

Abstract Predicting the behavior, geometry, and flow properties of subsurface fractures remains a challenging problem. Seismic models that can characterize fractures usually suffer from low spatiotemporal resolution. Here, we develop a correlative double‐difference time‐lapse full waveform inversion of continuous active source seismic monitoring data for determining high‐spatiotemporal‐resolution time‐lapse V p models of in‐situ fracture evolution at a shallow contamination site in Wyoming, USA. Assisted by rock physics modeling, we find that (a) rapidly increasing pore pressure initializes and grows the fracture, increasing the porosity slightly (from ∼13.7% to ∼14.6%) in the tight clay formation, thus decreasing V p (∼50 m/s); (b) the fluid injection continues decreasing V p , likely through the introduction of gas bubbles in the injectate; and (c) final V p reductions reach over ∼150 m/s due to a posited ∼4.5% gas saturation. Our results demonstrate that high‐resolution V p changes are indicative of mechanical and fluid changes within the fracture zone during hydrofracturing.

58 GEOSCIENCES↗

The Sensitivity of WRF Daily Summertime Simulations over West Africa to Alternative Parameterizations. Part 1: African Wave Circulation

The performance of the NCAR Weather Research and Forecasting Model (WRF) as a West African regional-atmospheric model is evaluated. The study tests the sensitivity of WRF-simulated vorticity maxima associated with African easterly waves to 64 combinations of alternative parameterizations in a series of simulations in September. In all, 104 simulations of 12-day duration during 11 consecutive years are examined. The 64 combinations combine WRF parameterizations of cumulus convection, radiation transfer, surface hydrology, and PBL physics. Simulated daily and mean circulation results are validated against NASA's Modern-Era Retrospective Analysis for Research and Applications (MERRA) and NCEP/Department of Energy Global Reanalysis 2. Precipitation is considered in a second part of this two-part paper. A wide range of 700-hPa vorticity validation scores demonstrates the influence of alternative parameterizations. The best WRF performers achieve correlations against reanalysis of 0.40-0.60 and realistic amplitudes of spatiotemporal variability for the 2006 focus year while a parallel-benchmark simulation by the NASA Regional Model-3 (RM3) achieves higher correlations, but less realistic spatiotemporal variability. The largest favorable impact on WRF-vorticity validation is achieved by selecting the Grell-Devenyi cumulus convection scheme, resulting in higher correlations against reanalysis than simulations using the Kain-Fritch convection. Other parameterizations have less-obvious impact, although WRF configurations incorporating one surface model and PBL scheme consistently performed poorly. A comparison of reanalysis circulation against two NASA radiosonde stations confirms that both reanalyses represent observations well enough to validate the WRF results. Validation statistics for optimized WRF configurations simulating the parallel period during 10 additional years are less favorable than for 2006.

variability↗

Spatiotemporal Thermal Coupling in VO 2 Device Arrays

Correlated oxides such as VO 2 exhibit an electrically driven insulator–metal transition (IMT) that underlies their promise for neuromorphic and memory devices. Yet the IMT is not a uniform bulk process but a spatiotemporal phenomenon in which local heating nucleates filaments, contracts or dissolves them with the electric field, and couples to the environment. In this work, we directly image the VO 2 IMT dynamics by mid-wave infrared, thermography synchronized with electrical transport, resolving device temperature with micrometer spatial and microsecond temporal resolution. At the single-device level, we capture the full cycle of filament nucleation, contraction, and relaxation during current/voltage-driven resistive switching. At the array level, we show that heat propagates across etched gaps with an effective length scale of ∼131 µm, enabling cooperative behaviors among electrically isolated devices. Short-range distanced devices exhibit mutual filament attraction and sequential dissolution, while long-range distanced devices differentiate into distinct roles: drivers that initiate switching, cooperative responders that undergo assisted self-oscillations, and passive reporters that record the thermal field. Furthermore, these results reframe thermal crosstalk, long regarded as parasitic, as an intrinsic coupling channel and design principle for organizing collective switching behaviors, with direct implications for emergent circuit functionality in neuromorphic and unconventional computing architectures.

coupling↗

Thermodynamic phase transitions of nematic order in magnetic helices

A nematic phase lacks translation order but has orientational order. Nematic phases have been discovered in a variety of systems, including liquid crystals, correlated materials, and superconductors. Here, we report on a magnetic nematic phase, where the basis components are composed of magnetic helices. We directly probed the order parameters associated with the magnetic helices using resonant soft x-ray scattering and find two distinct nematic phases with complex spatiotemporal signatures. Using x-ray correlation spectroscopy, we find that near the phase boundary between the two nematic phases, fluctuations coexist on multiple disparate timescales. Our micromagnetic simulations and density functional theory calculations show that the fluctuations occur concomitantly with a reorientation of the magnetic helices, indicating spontaneous symmetry breaking and the emergence of additional degrees of freedom. Our results provide a framework for characterizing exotic phases that can be extended to a broad class of physical systems.

36 MATERIALS SCIENCE↗

Learning to Correct Climate Projection Biases

The fidelity of climate projections is often undermined by biases in climate models due to their simplification or misrepresentation of unresolved climate processes. While various bias correction methods have been developed to post-process model outputs to match observations, existing approaches usually focus on limited, low-order statistics, or break either the spatiotemporal consistency of the target variable, or its dependency upon model resolved dynamics. We develop a Regularized Adversarial Domain Adaptation (RADA) methodology to overcome these deficiencies, and enhance efficient identification and correction of climate model biases. Instead of pre-assuming the spatiotemporal characteristics of model biases, we apply discriminative neural networks to distinguish historical climate simulation samples and observation samples. The evidences based on which the discriminative neural networks make distinctions are applied to train the domain adaptation neural networks to bias correct climate simulations. We regularize the domain adaptation neural networks using cycle-consistent statistical and dynamical constraints. An application to daily precipitation projection over the contiguous United States shows that our methodology can correct all the considered moments of daily precipitation at approximately $1^\circ$ resolution, ensures spatiotemporal consistency and inter-field correlations, and can discriminate between different dynamical conditions. Our methodology offers a powerful tool for disentangling model parameterization biases from their interactions with the chaotic evolution of climate dynamics, opening a novel avenue toward big-data enhanced climate predictions.

58 GEOSCIENCES↗

Revealing meso-structure dynamics in additive manufacturing of energy storage via operando coherent X-ray scattering

3D printing is an emerging technology for the fabrication of energy storage devices, offering advantages over traditional manufacturing methods. However, optimization and design of such devices requires an understanding of the meso-structure formation during the 3D printing process. This study utilizes operando coherent X-ray scattering, X-ray Photon Correlation Spectroscopy (XPCS), to study the spatiotemporally-resolved far-from-equilibrium dynamics during direct ink writing 3D printing. Here, Lithium Titanate (LTO) based ink is prepared and rheologically tested for its shear-thinning properties. Two-time intensity-intensity functions are calculated to be used in subsequent quantitative analysis, which allows for an overall characterization of the dynamics, description of an initial fast decorrelation and identification of sudden rearrangements of subdomains of the sample. The results show the dynamics to be anisotropic, spatiotemporally heterogenous and marked by distinct rearrangement events, all of which impact the electrochemical performance of energy storage devices. The studied 3D printing ink is used to fabricate electrodes which are then electrochemically tested, showing good performance in cycling and retaining structural integrity. This work furthers the understanding of the far-from-equilibrium material dynamics during 3D printing, giving quantitative characterization of this process, and highlights aspects of structure formation relevant to the electrochemical performance of the resultant energy storage device.

36 MATERIALS SCIENCE↗

Grain Growth and Coarsening Dynamics in a Compositionally Asymmetric Block Copolymer Revealed by X-ray Photon Correlation Spectroscopy

The dynamics of nanostructured soft materials crucially impact their associated macroscopic material properties, yet they are often difficult to measure due to spatiotemporal limitations of conventional instrumentation. Herein, we use X-ray photon correlation spectroscopy (XPCS) to directly observe particle-scale dynamics during grain growth and coarsening in a BCC- forming diblock polymer melt, with specific attention to the distribution of structural relaxation times associated with the interplanar (110) distance. Following sample quenching from the disordered state, these dynamical phenomena surprisingly exhibit little dependence on time and thermal quench depth. We posit that these relaxations stem from collective particle motions during grain rotation. We also observe unusual internally-referenced heterodyne correlations, which enable measurements of speed distributions within the sample. In this work, these speeds are significantly slower and appear at much longer annealing times than those previously reported during grain nucleation and growth in microphase separated block polymer melts. Drawing on analogies between polycrystalline hard and soft materials, we ascribe these speed distributions to misorientation-dependent grain boundary migration during ordered domain coarsening and anomalously fast, cooperative string-like particle motion along the grain boundaries. Thus, these coherent X-ray measurements provide new opportunities to interrogate grain boundary structure and dynamics in polycrystalline soft materials.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Mesoscopic two-point collective dynamics of glass-forming liquids

The collective density–density and hydrostatic pressure–pressure correlations of glass-forming liquids are spatiotemporally mapped out using molecular dynamics simulations. It is shown that the sharp rise of structural relaxation time below the Arrhenius temperature coincides with the emergence of slow, nonhydrodynamic collective dynamics on mesoscopic scales. The observed long-range, nonhydrodynamic mode is independent of wave numbers and closely coupled to the local structural dynamics. Below the Arrhenius temperature, it dominates the slow collective dynamics on length scales immediately beyond the first structural peak in contrast to the well-known behavior at high temperatures. Furthermore, these results highlight a key connection between the qualitative change in mesoscopic two-point collective dynamics and the dynamic crossover phenomenon.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Towards a Satellite Formaldehyde – in situ Hybrid Estimate for Organic Aerosol Abundance

Organic aerosol (OA) is one of the main components of the global particulate burden and intimately links natural and anthropogenic emissions with air quality and climate. It is challenging to accurately represent OA in global models. Direct quantification of global OA abundance is not possible with current remote sensing technology; however, it may be possible to exploit correlations of OA with remotely observable quantities to infer OA spatiotemporal distributions. In particular, formaldehyde (HCHO) and OA share common sources via both primary emissions and secondary production from oxidation of volatile organic compounds (VOCs). Here, we examine OA–HCHO correlations using data from summertime airborne campaigns investigating biogenic (NASA SEAC4RS and DC3), biomass burning (NASA SEAC4RS), and anthropogenic conditions (NOAA CalNex and NASA KORUS-AQ). In situ OA correlates well with HCHO (r=0.59–0.97), and the slope and intercept of this relationship depend on the chemical regime. For biogenic and anthropogenic regions, the OA–HCHO slopes are higher in low NOx conditions, because HCHO yields are lower and aerosol yields are likely higher. The OA–HCHO slope of wildfires is over 9 times higher than that for biogenic and anthropogenic sources. The OA–HCHO slope is higher for highly polluted anthropogenic sources (e.g., KORUS-AQ) than less polluted (e.g., CalNex) anthropogenic sources. Near-surface OAs over the continental US are estimated by combining the observed in situ relationships with HCHO column retrievals from NASA's Ozone Monitoring Instrument (OMI). HCHO vertical profiles used in OA estimates are from climatology a priori profiles in the OMI HCHO retrieval or output of specific period from a newer version of GEOS-Chem. Our OA estimates compare well with US EPA IMPROVE data obtained over summer months (e.g., slope =0.60–0.62, r=0.56 for August 2013), with correlation performance comparable to intensively validated GEOS-Chem (e.g., slope =0.57, r=0.56) with IMPROVE OA and superior to the satellite-derived total aerosol extinction (r=0.41) with IMPROVE OA. This indicates that OA estimates are not very sensitive to these HCHO vertical profiles and that a priori profiles from OMI HCHO retrieval have a similar performance to that of the newer model version in estimating OA. Improving the detection limit of satellite HCHO and expanding in situ airborne HCHO and OA coverage in future missions will improve the quality and spatiotemporal coverage of our OA estimates, potentially enabling constraints on global OA distribution.

anthropogenic emissions↗

Assessment of Tropospheric Concentrations of NO2 from the TROPOMI/Sentinel-5 Precursor for the Estimation of Long-Term Exposure to Surface NO2 over South Korea

Since April 2018, the TROPOspheric Monitoring Instrument (TROPOMI) has provided data on tropospheric NO2 column concentrations (CTROPOMI) with unprecedented spatial resolution. This study aims to assess the capability of TROPOMI to acquire high spatial resolution data regarding surface NO2 mixing ratios. In general, the instrument effectively detected major and moderate sources of NO2 over South Korea with a clear weekday–weekend distinction. We compared the CTROPOMI with surface NO2 mixing ratio measurements from an extensive ground-based network over South Korea operated by the Korean Ministry of Environment (SKME; more than 570 sites), for 2019. Spatiotemporally collocated CTROPOMI and SKME showed a moderate correlation (correlation coefficient, r = 0.67), whereas their annual mean values at each site showed a higher correlation (r = 0.84). The CTROPOMI and SKME were well correlated around the Seoul metropolitan area, where significant amounts of NO2 prevailed throughout the year, whereas they showed lower correlation at rural sites. We converted the tropospheric NO2 from TROPOMI to the surface mixing ratio (STROPOMI) using the EAC4 (ECMWF Atmospheric Composition Reanalysis 4) profile shape, for quantitative comparison with the SKME. The estimated STROPOMI generally underestimated the in-situ value obtained, SKME (slope = 0.64), as reported in previous studies.

TROPOMI↗

Spatiotemporal spread of perturbations in power-law models at low temperatures: Exact results for classical out-of-time-order correlators

Here, we present exact results for the classical version of the out-of-time-order commutator (OTOC) for a family of power-law models consisting of N particles in one dimension and confined by an external harmonic potential. These particles are interacting via power-law interaction of the form ∝ $Σ_{i,j=(i≠j)}^{N}$ |x i -x j | -k for every k>1 where x i is the position of the i th particle. We present numerical results for the OTOC for finite N at low temperatures and short enough times so that the system is well approximated by the linearized dynamics around the many-body ground state. In the large-N limit, we compute the ground-state dispersion relation in the absence of external harmonic potential exactly and use it to arrive at analytical results for OTOC. We find excellent agreement between our analytical results and the numerics. We further obtain analytical results in the limit where only linear and leading nonlinear (in momentum) terms in the dispersion relation are included. The resulting OTOC is in agreement with numerics in the vicinity of the edge of the “light cone.” We find remarkably distinct features in OTOC below and above k=3 in terms of going from non-Airy behavior (1 < k < 3) to an Airy universality class (k>3). We present certain additional rich features for the case k=2 that stem from the underlying integrability of the Calogero-Moser model. We present a field theory approach that also assists in understanding certain aspects of OTOC such as the sound speed. Our findings are a step forward towards a more general understanding of the spatiotemporal spread of perturbations in long-range interacting systems.

1-dimensional systems↗

Spatiotemporal characterization of the field-induced insulator-to-metal transition

Watching a metal filament grow Resistive switching is a process in which the electrical resistance of a sample changes abruptly in response to a voltage pulse, often by orders of magnitude. This process is at the heart of many neuromorphic computing approaches but visualizing it in both space and time is tricky. del Valle et al . monitored the resistive switching in three different vanadium oxide compounds by measuring time- and space-resolved optical reflectivity (see the Perspective by Hilgenkamp and Gao). A characteristic conducting filament was quickly nucleated on the inhomogeneities in the sample and then propagated due to Joule heating. —JS

Science & Technology - Other Topics↗

Spatiotemporal quenches for efficient critical ground state preparation in the two-dimensional transverse field Ising model

Quantum simulators have the potential to shed light on the study of quantum many-body systems and materials, offering unique insights into various quantum phenomena. Although adiabatic evolution has been conventionally employed for state preparation, it faces challenges when the system evolves too quickly or the coherence time is limited. In such cases, shortcuts to adiabaticity, such as spatiotemporal quenches, provide a promising alternative. This paper numerically investigates the application of spatiotemporal quenches in the two-dimensional transverse field Ising model with ferromagnetic interactions, focusing on the emergence of the ground state and its correlation properties at criticality when the gap vanishes. We demonstrate the effectiveness of these quenches in rapidly preparing ground states in critical systems. Our simulations reveal the existence of an optimal quench front velocity at the emergent speed of light, leading to minimal excitation energy density and correlation lengths of the order of finite system sizes we can simulate. These findings emphasize the potential of spatiotemporal quenches for efficient ground state preparation in quantum systems, with implications for the exploration of strongly correlated phases and programmable quantum computing.

2-dimensional systems↗

Going With the Flow: Using a Particle Dispersion Model to Reveal Links Between Ocean Ecosystems and Marine Aerosols

Marine biogenic particle contributions to atmospheric aerosol concentrations are not well understood though they are important for determining cloud optical and cloud nucleating properties. Here we examine the relationship between marine aerosol measurements with satellite and model fields of ocean biology and meteorological variables during the North Atlantic Aerosols and Marine Ecosystems Study (NAAMES). NAAMES consisted of four field campaigns between November 2015 and April 2018 that aligned with the four major phases of the annual phytoplankton bloom cycle. The FLEXPART Lagrangian particle dispersion model is used to connect these variables spatiotemporally to ship-based aerosol. We find that correlations between some aerosol measurements with satellite measured and modelled variables increase with increasing trajectory length. This indicates biological and meteorological processes over the air mass history are influential to measured particle properties. For example, results show organic aerosol mass is driven by biogenic volatile organic compound (VOC) emissions from photosynthesis by phytoplankton stocks during advection into the region. In contrast, primary marine aerosol (PMA) concentrations showed better correlations to variables weighted with shorter air mass residence times, which reflects their localized origin as primary emissions. Evidence also suggest variability in PMA concentrations likely play an important role in VOC emission removal. The removal of VOCs lessen their impact on particle number and mass concentrations. The sensitivity of marine aerosols to the main ecosystem-atmosphere drivers and its dependence on air mass history are to be further discussed.

Kevin J Sanchez↗

Bioenergy Cropping Reduces the Spatiotemporal Scaling of Soil Bacterial Biodiversity

Widespread bioenergy cropping can transform landscapes, strongly affecting biodiversity. However, the impact of bioenergy cropping on the spatiotemporal scaling of soil biodiversity remains virtually unknown, despite its profound implications for the functioning of the ecological community. Here, we investigated how bioenergy cropping influenced the spatiotemporal scaling of soil bacterial biodiversity in marginal soils (sandy loam and clay loam soils) in Oklahoma, USA. We detected strong, significant species-time-area relationships (STARs) and phylogenetic-time-area relationships (PTARs) in bacterial communities and their lineages, suggesting that STARs and PTARs exist in microbial ecology within the studied system. Also, spatiotemporal scaling rates (the slopes of STAR and PTAR models) varied substantially among bacterial lineages and were positively correlated with their 16S rRNA gene copy numbers, a genomic trait indicative of microbial growth potentials. Strikingly, bioenergy cropping significantly reduced spatiotemporal scaling rates by 6.8%-14.1%, with a more pronounced reduction observed in sandy loam soils, where those rates were significantly lower than in clay loam soils. The heterogeneity of soil phosphorus and carbon resulted in variations in bacterial spatiotemporal scaling rates. Collectively, our findings suggest that bioenergy cropping may alleviate rapid shifts in soil biodiversity across space and time, thereby stabilizing soil biodiversity and supporting its role as part of sustainable land management and climate mitigation strategies.

bacterial diversity↗

Spatiotemporal Variations of Evapotranspiration in Amazonia Using the Wavelet Phase Difference Analysis

The relationships and seasonal-to-annual variations among evapotranspiration (ET), precipitation (P), terrestrial water storage anomalies (TWSA), radiation (downward shortwave radiation, DSR), and phenology (leaf area index, LAI) are complex across the Amazon basin. Here, to analyze how ET is controlled by these influencing factors, we used wavelet phase difference (WPD) to investigate the effects of P, TWSA, DSR, and LAI on ET at different spatiotemporal scales. The Amazon-scale averaged ET has strong correlations with these factors at the annual and multi-year periodicities. The patterns of WPDs have south-north and west-east divides due to the significant variation in climatic conditions. The results demonstrate that ET is mainly affected by water and energy availability while vegetation regulates both processes. The deep soil moisture/groundwater can provide strong subsidies to ET during the meteorological dry season in the water-limited area of Amazon. The WPD can well reflect the responses of ET to the variations of P, TWSA, DSR, and LAI, and the process of vegetation sustaining ET in the dry years in the water-limited area of the Amazon.

54 ENVIRONMENTAL SCIENCES↗