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At least 55 records · Page 3

Scientific results from the materials processing in space program

Scientific experiments conducted in a low-gravity environment make it possible to study effects, such as surface tension-driven flows, which are often masked by buoyancy-driven flows. A summary is provided of several early experiments which demonstrate that unwanted convective flows can be effectively suppressed in experiments conducted in orbiting spacecraft. Possible applications of low-G processing are discussed, taking into account Bridgman growth of solid solution alloy-type semiconductors, Bridgman growth of eutectic systems, and float-zone crystal growth. The control of macrosegregation and phase separation in castings is considered, giving attention also to containerless melting and solidification. A description of experiment facilities and opportunities is provided.

Naumann, R.↗

Effect of reduction of strategic Columbium addition in 718 Alloy on the structure and properties

A series of alloys was developed having a base composition similar to Inconel 718, with reduced Cb levels of 3.00 and 1.10 wt% Cb. Substitutions of 3.0% W, 3.0W + 0.9V or Mo increased from 3.0% to 5.8% were made for the Cb in these alloys. Two additional alloys, one containing 3.49% Cb and 1.10% Ti and another containing 3.89% Cb and 1.29% Ti were also studied. Tensile properties at rooom and elevated temperatures, stress-rupture tests, and an analysis of extracted phases were carried out for each of the alloys. Additions of solid solution elements to a reduced Cb alloy had no significant effect on the properties of the alloys under either process condition. The solution and age alloys with substitutions of 1.27% i at 3.89% Cb had tensile properties similar top hose of the original alloy and stress-rupture properties superior to the original alloy. The improved stress-rupture properties were the result of significant precipitation of Ni3Ti-gamma prime in the alloy, which is more stable than gamma' at the elevated temperatures. At lower temperatures, the new alloy benefits from gamma' strengthening. With more precise control and proper processing, the reduced Cb direct-age alloy could substitute for Alloy 718 in high strength applications.

Ziegler, K. R.↗

Effect of Residual Accelerations on the Crystal Growth of II-VI Semiconductors in Low Earth Orbit

The paper compares and summarizes the effects of residual acceleration during crystal growth on the compositional variation of two II-VI solid solution binary alloys (Hg(0.8)Cd(0.2)Te and Hg(0.84)Zn(0.16)Te). The crystals were grown by directional solidification on the second United States Microgravity Payload (USMP-2) and the first United States Microgravity Laboratory (USML-1) missions, respectively. For both alloys, changes in the direction and magnitude of the quasisteady acceleration vector (approximately 0.4- 1 mu g) caused large changes in the radial compositional distribution that demonstrates the importance of residual accelerations, even in the submicrogravity range, for large density gradients in the melt and slow solidification rates. The observed compositional variations will be correlated to changes in the radial flow velocities ahead of the solidification interface.

Gillies, D. C.↗

Development of a Thin Gauge Metallic Seal for Gas Turbine Engine Applications to 1700 F

The goal of doubling thrust-to-weight ratio for gas turbine engines has placed significant demands on engine component materials. Operating temperatures for static seals in the transition duct and turbine sections for instance, may well reach 2000 F within the next ten years. At these temperatures conventional age-hardenable superalloys lose their high strength via overaging and eventual dissolution of the gamma precipitate, and are well above their oxidation stability limit. Conventional solid-solution-strengthened alloys offer metallurgical stability, but suffer from rapid oxidation and little useful load bearing strength. Ceramic materials can theoretically be used at these temperatures, but manufacturing processes are in the developmental stages.

England, Raymond O.↗

Effect of long-time, elevated-temperature exposures to vacuum and lithium on the properties of a tantalum alloy, T-111

The effect of long-term, elevated-temperature vacuum and lithium exposures on the mechanical properties of T-111 (Ta-8W-2Hf) is determined. Exposure conditions were for 1000 hours at 980 or 1315 C, 5000 hours at 1315 C, and a duplex temperature exposure of 1000 hours at 980 C plus 4000 hours at 1040 C. The exposures resulted in reduced tensile and creep strengths of the T-111 in the 900 to 1100 C temperature range where a dynamic strain-age-strengthening mechanism is operative in this alloy. This strength reduction was attributed to the depletion of oxygen from solid solution in this alloy.

Buzzard, R. J.↗

Correlation of creep rate with microstructural changes during high temperature creep

The techniques of electron microscopy were used to examine the microstructural changes which occur during primary creep for two important types of engineering alloys: (1) alloys strengthened by solid-solution additions, and (2) dispersion-strengthened alloys. The metals chosen for study are unalloyed titanium, Ti-6Al-4V, and the cobalt-base alloy, Haynes 188. Results to date on NGR 47-004-108 show that development of prior dislocation substructure in Haynes 188 by 10% prestrain and annealing for one hour at 1800 F increases the time to reach 0.5% creep strain at 1600 F by more than an order of magnitude for creep stresses from 3 to 20 ksi. For creep at 1800 F, similar results were obtaind for stresses above 7 ksi, but the prior substructure decreases creep resistance below 7 ksi. This effect appears to be related to instability of grain structure at 1800 F in prestrained material.

Young, C. T.↗

Braze alloy holds bonding strength over wide temperature range

Copper-based quaternary alloys of the solid solution type is used for vacuum furnace brazing of large stainless steel components at a maximum temperature of 1975 deg F. The alloy has high bonding strength and good ductility over a temperature range extending from the cryogenic region to approximately 800 deg F.

Source record↗

Influence of creep damage on the low cycle thermal-mechanical fatigue behavior of two tantalum base alloys

Low cycle fatigue tests have been performed on the tantalum base alloys T-111 and ASTAR 811C with synchronized, independently programmed temperature and strain cycling. The thermal-mechanical cycles applied fell into three basic categories: these were isothermal cycling, in-phase thermal cycling, and out-of-phase thermal cycling. In-phase cycling was defined as tensile deformation associated with high temperature and compressive deformation with low temperature, while out-of-phase thermal cycling was defined as the reverse case. The in-phase thermal cycling had a pronounced detrimental influence on the fatigue life of both alloys, with the life reduction being greater in the solid solution strengthened T-111 alloy than in the carbide strengthened ASTAR 811C alloy. The out-of-phase tests also showed pronounced effects on the fatigue life of both alloys, although not as dramatic.

Sheffler, K. D.↗

Solid state processing for high temperature alloys and composites

A variety of solid state powder processing methods have been examined for their potential to produce high temperature materials. These techniques included solid state diffusion, mechanical alloying, reaction milling, and exothermic reactions. While both mechanical alloying and exothermic reactions are capable of producing high temperature composites in addition to yielding solid solution and precipitation hardened alloys, reaction milling can only be used to make composite materials. Although at present this method has only been applied to make carbide strengthened Al, recent work indicates that reaction milling is capable of yielding high strength NiAl-AlN composites.

Whittenberger, J. Daniel↗

Nondestructive determination of mechanical properties

The sensitivity of the velocity of ultrasonic waves to the elasticity of the materials (acousto-elastic constant - AEC) as controlled by the microstructure of the materials was examined experimentally. Rolled-plate specimens of five different Al alloys were subjected to tensile tests while being monitored for the velocity change of a 10 MHz longitudinal wave as a function of the applied tensile stress. The acoustic propagation velocity was measured perpendicularly to the stress. Determinations were made of the yield strength and the hardnesses of the specimens. Samples of the plate materials examined microscopically to characterize the solid phases. The AECs varied linearly with the percentage of solid solution phase of the alloys. The trend for strain-hardened samples was, however, opposite from that in the precipitation-hardened alloys. The results underscore the necessity of considering the microstructural dependencies of the AECs when using ultrasonic NDE methods, and also opened the potential of determining some mechanical properties with NDE techniques.

Schneider, E.↗

Growth of Solid Solution Single Crystals

The objective of the study is to establish the effects of processing semiconducting, solid solution, single crystals in a microgravity environment on the metallurgical, compositional, electrical, and optical characteristics of the crystals. The alloy system being investigated is the solid solution semiconductor Hg(1-x)Cd(x)Te, with x-values appropriate for infrared detector applications in the 8 to 14 mm wavelength region. Both melt and Te-solvent growth are being performed. The study consists of an extensive ground-based experimental and theoretical research effort followed by flight experimentation where appropriate. The ground-based portion of the investigation also includes the evaluation of the relative effectiveness of stabilizing techniques, such as applied magnetic fields, for suppressing convective flow during the melt growth of the crystals.

Lehoczky, Sandor L.↗

Computer simulation of the motion of a straight dislocation line in concentrated solid solutions. II

An investigation was undertaken to determine if the size and modulus interaction of a solute atom with a screw dislocation and the modulus interaction with an edge dislocation contributed to strengthening, in addition to the size interaction with an edge dislocation. The results indicate that the size interaction between solute atom and an edge dislocation accounts for most of the solid solution strengthening in f.c.c. alloys. The contribution to the yield stress from the modulus interaction with an edge dislocation is less than 15%. The interaction between a solute atom and a screw dislocation is much less than that between a solute atom and an edge dislocation.

Kuo, C. T. K.↗