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At least 55 records · Page 3

A Model for Formation of Dust, Soil and Rock Coatings on Mars: Physical and Chemical Processes on the Martian Surface

This model is one of many possible scenarios to explain the generation of the current surface material on Mars using chemical, magnetic and spectroscopic data From Mars and geologic analogs from terrestrial sites. One basic premise of this model is that the dust/soil units are not derived exclusively from local rocks, but are rather a product of global, and possibly remote, weathering processes. Another assumption in this model is that there are physical and chemical interactions of the atmospheric dust particles and that these two processes create distinctly different results on the surface. Physical processes distribute dust particles on rocks and drift units, forming physically-aggregated layers; these are reversible processes. Chemical reactions of the dust/soil particles create alteration rinds on rock surfaces and cohesive, crusted surface units between rocks, both of which are relatively permanent materials. According to this model the dominant components of the dust/soil particles are derived from alteration of volcanic ash and tephra, and contain primarily nanophase and poorly crystalline ferric oxides/oxyhydroxide phases as well as silicates. These phases are the alteration products that formed in a low moisture environment. These dust/soil particles also contain a smaller amount of material that was exposed to more water and contains crystalline ferric oxides/oxyhydroxides, sulfates and clay silicates. These components could have formed through hydrothermal alteration at steam vents or fumeroles, thermal fluids, or through evaporite deposits. Wet/dry cycling experiments are presented here on mixtures containing poorly crystalline and crystalline ferric oxides/oxyhydroxides, sulfates and silicates that range in size from nanophase to 1-2 pm diameter particles. Cemented products of these soil mixtures are formed in these experiments and variation in the surface texture was observed for samples containing smectites, non-hydrated silicates or sulfates. Reflectance spectra were measured of the initial particulate mixtures, the cemented products and ground versions of the cemented material. The spectral contrast in the visible/near-infrared and mid-infrared regions is significantly reduced for the cemented material compared to the initial soil, and somewhat reduced for the ground, cemented soil compared to the initial soil. The results of this study suggest that diurnal and seasonal cycling on Mars will have a profound effect on the texture and spectral properties of the dust/soil particles on the surface. The model developed in this study provides an explanation for the generation of cemented or crusted soil units and rock coatings on Mars and may explain albedo variations on the surface observed near large rocks or crater rims.

Bishop, Janice

Energy Barriers for H 2 Uptake and Release by Defects in Boron Nitride

Density functional theory simulations (DFT) have been used in combination with the climbing image nudged elastic band method (CI-NEB) to determine the energy barriers required to dissociate H 2 at four types of h-BN defects and evaluate the potential for reacted H species to hop to adjacent available sites. The defects were selected based on previous work in which ab initio thermodynamics was used to identify specific defects with optimal thermodynamics for reversible H 2 storage, that is, the defects would dissociate molecular H 2 while not binding H species too strongly so that hydrogen release is favorable. The four defects investigated are the N and B monovacancies, which only offer either B or N defective sites respectively, as well as larger cluster vacancy defects named 3V(1B2N) and hexagonal 6V(3B3N), which present a mixture of B and N defect sites available for H binding. While homogeneous H 2 dissociation by B and N monovacancies have energy barriers larger than 0.4 eV, we found that mixed BN terminated defects have energy barrier lower than 0.4 eV for H 2 dissociation. In particular, H 2 dissociation by the hexagonal 6V(3B3N) defect, exclusively made of Frustrated Lewis Pairs (FLPs), is almost barrierless. The energy barrier for subsequent H hopping to available adjacent B or N sites of the defect were also calculated. It was found that the hopping of H species generally involves high energy barriers ranging from 0.26 eV to 2.57 eV. In conclusion, this work completes previous thermodynamic theoretical investigations and provides a more comprehensive picture of H 2 reaction with defective h-BN for potential H 2 storage and recovery.

Sassi, Michel J. [Pacific Northwest National Labor

NASA Space Launch System Prepares for Key Hotfire Test Before Vehicle Integration

NASA this year is working toward the final major integrated hardware and avionics test for its Space Launch System (SLS), the agency’s new super heavy-lift vehicle to send large, strategic payloads to the Moon, Mars and beyond. As the backbone of the Artemis human lunar exploration program, Artemis I SLS operations will then shift to the launch site and integration for the inaugural mission. For this final major test of the first vehicle NASA has built exclusively for deep space exploration since the Saturn V, a NASA/Boeing/Aerojet Rocketdyne team will conduct the final core stage “green run” test at NASA's Stennis Space Center with a dramatic firing of all four core stage engines. This test will validate the operation of the stage structures, main propulsion system, engines, avionics, and software. Following data review, stage inspection, and refurbishment, the stage will be barged to NASA’s Kennedy Space Center to continue integration of the Artemis I launch vehicle. Already underway is assembly of the mission’s five-segment solid rocket boosters. The mission’s upper stage and spacecraft adapters also are staged at the launch site ready for integration. Even as the Artemis I SLS proceeds toward launch later this year, the Artemis II and Artemis III vehicles are coming together, with core stages, engines, boosters, upper stage, and payload accommodations in various stages of manufacturing and/or processing. Planning is also underway for additional core stages and a new, more powerful upper stage that will increase lunar payload mass. SLS is the anchor transportation leg of a plan for sustained human exploration of the Moon, including the first human landing later in the decade. This paper will discuss SLS progress to date and expected 2021 milestones.

Bruce R. Askins

The Role of Cu Species in the Regeneration of a Coked Cu/BEA Zeolite Catalyst

Active site occlusion by carbon species, often referred to as coke, is a common deactivation mechanism for heterogeneous catalysts. While it is known that transition metals can lower the temperature required for oxidative coke removal, the roles of ionic species and metal nanoparticles in coke removal are not well understood. This work aims to differentiate how ionic and nanoparticle Cu sites catalyze oxidative regeneration of a coked beta (BEA) zeolite catalyst. This was accomplished by synthesizing catalysts containing exclusively CuOx nanoparticles (NPs) or Cu2+ ions supported on BEA, physically mixing Cu/BEA with a coked BEA catalyst, and monitoring coke removal using in situ spectroscopy. Our results point to an improved combustion activity for CuOx NPs relative to Cu2+ ions, especially in the combustion of graphitic-type coke species. This improved understanding of coke combustion in transition metal containing catalysts informs strategies to improve catalyst regeneration, thereby increasing operational lifetimes.

BIOMASS FUELS,INORGANIC, ORGANIC, PHYSICAL, AND AN

A role for cysteine 3635 of RYR1 in redox modulation and calmodulin binding

Oxidation of the skeletal muscle Ca(2+) release channel (RYR1) increases its activity, produces intersubunit disulfide bonds, and blocks its interaction with calmodulin. Conversely, bound calmodulin protects RYR1 from the effects of oxidants (Zhang, J.-Z., Wu, Y., Williams, B. Y., Rodney, G., Mandel, F., Strasburg, G. M., and Hamilton, S. L. (1999) Am. J. Physiol. 276, Cell Physiol. C46-C53). In addition, calmodulin protects RYR1 from trypsin cleavage at amino acids 3630 and 3637 (Moore, C. P., Rodney, G., Zhang, J.-Z., Santacruz-Toloza, L., Strasburg, G. M., and Hamilton, S. L. (1999) Biochemistry 38, 8532-8537). The sequence between these two tryptic sites is AVVACFR. Alkylation of RYR1 with N-ethylmaleimide (NEM) blocks both (35)S-apocalmodulin binding and oxidation-induced intersubunit cross-linking. In the current work, we demonstrate that both cysteines needed for the oxidation-induced intersubunit cross-link are protected from alkylation with N-ethylmaleimide by bound calmodulin. We also show, using N-terminal amino acid sequencing together with analysis of the distribution of [(3)H]NEM labeling with each sequencing cycle, that cysteine 3635 of RYR1 is rapidly labeled by NEM and that this labeling is blocked by bound calmodulin. We propose that cysteine 3635 is located at an intersubunit contact site that is close to or within a calmodulin binding site. These findings suggest that calmodulin and oxidation modulate RYR1 activity by regulating intersubunit interactions in a mutually exclusive manner and that these interactions involve cysteine 3635.

Non-NASA Center

Trace element evidence for a laterally inhomogeneous moon

A number of trace element interrelationships support the concept of a laterally inhomogeneous moon based originally on Clr/P2O5 ratios. The correspondence between Clr/P2O3 and Rb/Sr ratios in basalts are of special interest since the isotropic evolution of the latter pair of elements relates to the earliest history of the moon. This implies the times when the Clr/P2O5 relationships were established. The early magma ocean is conjectured to have been made up of non-intermixing seas resulting either from large convection cells or large body accretion. These mutually exclusive regions could be lunar geological provinces. It is proposed that the diversity of basalts from the Apollo 17 site is related to the lateral inhomogeneity of the moon. Ca/Na ratios in basalts show a trend which parallels that of Ru/Os and in a corresponding fashion may serve as a depth indicator.

Jovanovic, S.

Actuator placement for active sound and vibration control of cylinders

Active structural acoustic control is a method in which the control inputs (used to reduce interior noise) are applied directly to a vibrating structural acoustic system. The control concept modeled in this work is the application of in-plane force inputs to piezoceramic patches bonded to the wall of a vibrating cylinder. The cylinder is excited by an exterior noise source -- an acoustic monopole -- located near the outside of the cylinder wall. The goal is to determine the force inputs and sites for the piezoelectric actuators so that (1) the interior noise is effectively damped; (2) the level of vibration of the cylinder shell is not increased; and (3) the power requirements needed to drive the actuators are not excessive. We studied external monopole excitations at two frequencies. A cylinder resonance of 100 Hz, where the interior acoustic field is driven in multiple, off-resonance cylinder cavity modes, and a cylinder resonance of 200 Hz are characterized by both near and off-resonance cylinder vibration modes which couple effectively with a single, dominant, low-order acoustic cavity mode at resonance. Previous work has focused almost exclusively on meeting objective (1) and solving a complex least-squares problem to arrive at an optimal force vector for a given set of actuator sites. In addition, it has been noted that when the cavity mode couples with cylinder vibration modes (our 200 Hz case) control spillover may occur in higher order cylinder shell vibrational modes. How to determine the best set of actuator sites to meet objectives (1)-(3) is the main contribution of our research effort. The selection of the best set of actuator sites from a set of potential sites is done via two metaheuristics -- simulated annealing and tabu search. Each of these metaheuristics partitions the set of potential actuator sites into two disjoint sets: those that are selected to control the noise (on) and those that are not (off). Next, each metaheuristic attempts to improve this initial solution by calculating the change in the objective value when one selected actuator site is turned off and one actuator site that previously was not selected is turned on. All such pairwise exchanges are performed and the exchange that improves the objective the most is made. Eventually the search is unable to improve the objective value and a local optimum (with respect to pairwise exchanges) is reached. Both simulated annealing and tabu search provide mechanisms to escape local optima and allow the search to continue until (hopefully) a global optimum is found. Our experiments with the 100 Hz and 200 Hz cases confirm that both metaheuristics are able to uncover better solutions than those selected based upon engineering judgement alone. In addition, the high quality solutions generated by these metaheuristics, when minimizing interior noise, do not further excite the cylinder shell. Thus, we are able to meet objective (2) without imposing an additional constraint or forming a multiobjective performance measure. An additional observation is that in many cases the amplitude and phase values for several chosen actuator sites were nearly identical. This natural grouping means that fewer control channels are needed and the resulting control system is simpler. Currently no power requirements have been set, so objective (3) cannot be addressed. A set of experiments is planned with a laboratory test article (a cylinder). For these experiments the transfer matrices will be generated experimentally. It is hoped that the predicted performance of the best actuator sites found by our metaheuristics will correlate well with the measured performance.

Kincaid, Rex K.

Microwave microscope studies of trapped vortex dynamics in superconductors

Trapped vortices in superconductors introduce residual resistance in superconducting radio-frequency (SRF) cavities and disrupt the operation of superconducting quantum and digital electronic circuits. Understanding the detailed dynamics of trapped vortices under oscillating magnetic fields is essential for advancing these technologies. We have developed a near-field magnetic microwave microscope to study the dynamics of a limited number of trapped vortices under the probe when stimulated by a localized rf magnetic field. By measuring the local second-harmonic response (𝑃 2⁢f ) at subfemto-Watt levels, we isolate signals exclusively arising from trapped vortices, excluding contributions from surface defects and Meissner screening currents. Toy models of niobium superconductor hosting vortex pinning sites are introduced and studied with time-dependent Ginzburg-Landau (TDGL) simulations of probe/sample interaction to better understand the measured second-harmonic response. The simulation results demonstrate that the second-harmonic response of trapped vortex motion under a localized rf magnetic field shares key features with the experimental data. Here, this measurement technique provides access to vortex dynamics at the micrometer scale, such as depinning events and spatially resolved pinning properties, as demonstrated in measurements on a niobium film with an antidot flux pinning array.

43 PARTICLE ACCELERATORS

Exploring Aristarchus Plateau as a Potential Lunar Base Site

As part the exploration strategy, NASA has been studying the feasibility of a low cost human return to the Moon. The currently planned mission has a dual focus on the advancement of lunar science and the use of in situ resources. Thus far, our space exploration plans have relied almost exclusively on equipment and supplies transported from Earth. This may be appropriate for operations in Earth orbit, or for short duration stays on the lunar surface. However, the ability to "live off the land," will prove vital for long term habitation of the Moon and planets. This study takes a close look at the Aristarchus Plateau, one of the primary candidate sites for human lunar exploration. Based on this synthesis study, we recommend two sites on the Aristarchus Plateau that will maximize science return and provide a convincing demonstration of the use of in situ resources and which may be a viable future lunar base site.

Coombs, Cassandra R.

Scalable Hierarchical Network Management System for Displaying Network Information in Three Dimensions

A network management system has SNMP agents distributed at one or more sites, an input output module at each site, and a server module located at a selected site for communicating with input output modules, each of which is configured for both SNMP and HNMP communications. The server module is configured exclusively for HNMP communications, and it communicates with each input output module according to the HNMP. Non-iconified, informationally complete views are provided of network elements to aid in network management.

George, Jude

Major facilitator family transporters specifically enhance caffeyl alcohol uptake during C‐lignin biosynthesis

The mode of transport of lignin monomers to the sites of polymerization in the apoplast remains controversial. C-Lignin is a recently discovered form of lignin found in some seed coats that is composed exclusively of units derived from caffeyl alcohol. RNA-seq and proteome analyses identified a number of transporters co-expressed with C-lignin deposition in the seed coat of Cleome hassleriana. Cloning and influx/efflux analysis assays in yeast identified two low-affinity transporters, ChPLT3 and ChSUC1, that were active with caffeyl alcohol but not with the classical monolignols p-coumaryl, coniferyl, and sinapyl alcohols, consistent with molecular modeling and docking studies. Expression of ChPLT3 in Arabidopsis seedlings enhanced root growth in the presence of caffeyl alcohol, and expression of ChPLT3 and ChSUC1 correlated with lignin C-unit content in hairy roots of Medicago truncatula. We present a model, consistent with phylogenetic and evolutionary considerations, whereby passive caffeyl alcohol transport may be supplemented by hitchhiking on secondary active transporters to ensure the synthesis of C-lignin, and inhibition of synthesis of G-lignin, in the apoplast.

59 BASIC BIOLOGICAL SCIENCES

Supported Organochromium Ethylene Oligomerization Enabled by Surface Lithiation

Here, in this work, supported organochromium ethylene polymerization catalysts have been tuned to mediate ethylene oligomerization via surface lithiation, which provides a generalizable protocol to control stereoelectronics and redox states of surface organometallic active sites. The homoleptic chromium(IV) alkyl complex Cr(CH 2 SiMe 3 ) 4 was grafted on high-surface-area anatase titania (TiO 2 ) nanoparticles as well as on silica to produce Cr/TiO 2 and Cr/SiO 2 , respectively. Treatment of these materials with excess n-butyllithium led to the reduced chromium complexes Cr/Li x TiO 2 and Cr/Li/SiO 2 , each of which still retains one hydrocarbyl ligand on chromium. A set of heterogeneous complexes were studied by electron paramagnetic resonance and X-ray absorption spectroscopy, which indicate a reduction in the oxidation state of the major chromium species to Cr II upon lithiation. Cr/Li x TiO 2 converts ethylene to hexenes with a high selectivity (>80%), which was persistent over 10 days at 80 °C, achieving >950 turnovers. The exclusive formation of C 4 and C 6 olefins, preferring the trimerization product, without a statistical (Flory–Schulz) distribution is characteristic of the oxidative cyclization oligomerization mechanism rather than the traditional Cossee–Arlman mechanism, whereas Cr/Li/SiO 2 produced a mixture of trimerization and polymerization products, suggesting site heterogeneity in the silica-based material. On the other hand, the unreduced chromium(IV) materials as well as low lithium-containing Cr/Li x TiO 2 (x < 0.16) exclusively produced ultrahigh molecular weight polyethylene, determined by differential scanning calorimetry and gel permeation chromatography analysis, likely formed via a linear-insertion mechanism, with a crossover from the polymerization to oligomerization regime observed at ~16% Li intercalation.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH

Detection of Vegetation Trends in Highly Variable Environments After Grazing Exclusion in Mongolia

Aims: Environmental variability (e.g. in precipitation) has a large effect on vegetation dynamics, and this often makes it difficult to assess the recovery of vegetation after a disturbance. In this study, we assessed vegetation recovery trends in response to grazing exclusion while considering for the annual environmental variability. Location: Two regions with highly variable precipitation: a steppe near Mandalgobi, in Mongolia's Central Gobi province, and a desert steppe near Bulgan, in Mongolia's South Gobi province. Methods: Changes in vegetation were observed along grazing gradients at the above two sites, and vegetation thresholds were identified. We established reference plots in pre-threshold areas along the grazing gradients. We removed the impact of livestock grazing at various locations along the grazing gradients by establishing exclosures, and investigated vegetation from 2005 to 2013. We developed a smoothed hierarchical model within a Bayesian framework, and examined the effect of grazing exclusion on vegetation, focusing especially on the extent of grass cover recovery. In addition, we compared soil nutrient conditions in the reference plots and inside and outside each exclosure along the grazing gradients. Results: Temporal trends in the cover of perennial grass in each plot inside and outside of the exclosures largely coincided, irrespective of grazing intensity, and exclosure had no effect (Bulgan) or a negative effect (Mandalgobi) on vegetation recovery. Soil nutrient content was not significantly affected by exclosure at a given distance from the grazing source, but decreased significantly with decreasing grazing intensity. Thus, recovery of the land from a post-threshold state may not be apparent even after 9 yr of grazing exclusion in environments with highly variable precipitation. Conclusion: The effect of exclosure duration on perennial grass cover was limited, even after controlling for environmental variability. Once a vegetation threshold has been crossed, merely removing livestock from the landscape may not be sufficient for that area to recover.

Bayesian statistics;Drought;Environmental variabil

Climate Change from the Mars Exploration Rover Landing Sites: From Wet in the Noachian to Dry and Desiccating Since the Hesperian

Mars Exploration Rover Opportunity discovered sedimentary dirty evaporites in Meridiani Planum that were deposited in salt-water playas or sabkhas in the Noachian, roughly coeval with a variety of geomorphic indicators (valley networks, degraded craters and highly eroded terrain) of a possible early warmer and wetter environment. In contrast, the cratered plains of Gusev that Spirit has traversed (exclusive of the Columbia Hills) have been dominated by impact and eolian processes and a gradation history that argues for a dry and desiccating environment since the Late Hesperian. This paper reviews the surficial geology and gradation history of the plains in Gusev crater as observed along the traverse by Spirit that supports this climate change from the two landing sites on Mars.

Golombek, M. P.

When can we detect lianas from space? Toward a mechanistic understanding of liana‐infested forest optics

Abstract Lianas, woody vines acting as structural parasites of trees, have profound effects on the composition and structure of tropical forests, impacting tree growth, mortality, and forest succession. Remote sensing could offer a powerful tool for quantifying the scale of liana infestation, provided the availability of robust detection methods. We analyze the consistency and global geographic specificity of spectral signals—reflectance across wavelengths—from liana‐infested tree crowns and forest stands, examining the underlying mechanisms of these signals. We compiled a uniquely comprehensive database, including leaf reflectance spectra from 5424 leaves, fine‐scale airborne reflectance data from 999 liana‐infested canopies, and coarse‐scale satellite reflectance data covering 775 ha of liana‐infested forest stands. To unravel the mechanisms of the liana spectral signal, we applied mechanistic radiative transfer models across scales, establishing a synthesis of the relative importance of different mechanisms, which we corroborate with field data on liana leaf chemistry and canopy structure. We find a consistent liana spectral signal at canopy and stand scales across globally distributed sites. This signature mainly arises at the canopy level due to direct effects of more horizontal leaf angles, resulting in a larger projected leaf area, and indirect effects from increased light scattering in the near and short‐wave infrared regions, linked to lianas' less costly leaf construction compared with trees on average. The existence of a consistent global spectral signal for lianas suggests that large‐scale quantification of liana infestation is feasible. However, because the traits responsible for the liana canopy‐reflectance signal are not exclusive to lianas, accurate large‐scale detection requires rigorously validated remote sensing methods. Our models highlight challenges in automated detection, such as potential misidentification due to leaf phenology, tree life history, topography, and climate, especially where the scale of liana infestation is less than a single remote sensing pixel. The observed cross‐site patterns also prompt ecological questions about lianas' adaptive similarities in optical traits across environments, indicating possible convergent evolution due to shared constraints on leaf biochemical and structural traits.

Environmental Sciences & Ecology

Northern Hemisphere Gullies on Mars: Analysis of Spacecraft Data and Implications for Formation Mechanisms

The origin of geologically recent gullies on Mars has remained controversial since the discovery of these features by Malin and Edgett in 2000. Numerous models have been proposed which invoke various physical processes as well as various agents of erosion to explain the origin of the Martian gullies. Hypotheses to explain the formation of the gullies invoke shallow liquid water aquifers, deep liquid water aquifers, melting ground ice, snowmelt, dry landslides, and carbon dioxide aquifers. We test the validity of such gully formation mechanisms by analyzing data from the Mars Global Surveyor and Mars Odyssey spacecrafts to uncover trends in the dimensional and physical properties of the gullies and their surrounding terrain. A similar study has previously been completed for gullies located in the southern hemisphere of Mars. The work presented here focuses exclusively on gullies in the northern hemisphere based on the identification of 136 Mars Orbiter Camera (MOC) images containing clear evidence of gully landforms, distributed in the northern mid and high latitudes. These sites have been analyzed in combination with Mars Orbiter Laser Altimeter (MOLA), Thermal Emission Spectrometer (TES), and Gamma Ray Spectrometer (GRS) data to provide quantitative measurements of numerous gully characteristics. Parameters measured include apparent source depth and distribution, vertical and horizontal dimensions, slopes, compass orientations, near-surface ice content, and factors controlling present-day climatic conditions.

Heldmann, J. L.

Dynamics of hydride anion and acetyloxyl radical production by electron attachment to acetic acid

Here, we investigate the dynamics and site-selectivity in the dissociation of transient anions formed upon attachment of low energy electrons to acetic acid by anion fragment momentum imaging experiments. The resonances at 6.7 and 7.7 eV are confirmed to dissociate exclusively by the O–H bond, while a third resonance at 9.1 eV dissociates primarily by both C–H break and O–H break. A fourth resonance near 10 eV is found to dissociate by O–H break. For each resonance, the measured kinetic energy release indicates two-body dissociation produces a neutral radical in the ground electronic state, for all four resonances. The measured angular distributions are consistent with all four resonances having A' symmetry.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH

Space Station Freedom assembly and operation at a 51.6 degree inclination orbit

This study examines the implications of assembling and operating Space Station Freedom at a 51.6 degree inclination orbit utilizing an enhanced lift Space Shuttle. Freedom assembly is currently baselined at a 220 nautical mile high, 28.5 degree inclination orbit. Some of the reasons for increasing the orbital inclination are (1) increased ground coverage for Earth observations, (2) greater accessibility from Russian and other international launch sites, and (3) increased number of Assured Crew Return Vehicle (ACRV) landing sites. Previous studies have looked at assembling Freedom at a higher inclination using both medium and heavy lift expendable launch vehicles (such as Shuttle-C and Energia). The study assumes that the shuttle is used exclusively for delivering the station to orbit and that it can gain additional payload capability from design changes such as a lighter external tank that somewhat offsets the performance decrease that occurs when the shuttle is launched to a 51.6 degree inclination orbit.

Troutman, Patrick A.