Engineering Papers⌕ Search

SEARCH · Engineering Papers

Results for “proton science”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 55 records · Page 3
All sourcesNASA NTRSDOE OSTI
DOE OSTI2021

Demonstration of TNSA proton radiography on the National Ignition Facility Advanced Radiographic Capability (NIF-ARC) Laser

We report that proton radiography using short-pulse laser drivers is an important tool in high-energy density (HED) science for dynamically diagnosing key characteristics in plasma interactions. Here we detail the first demonstration of target-normal sheath acceleration (TNSA)-based proton radiography the NIF-ARC laser system aided by the use of compound parabolic concentrators (CPCs). The multi-kJ energies available at the NIF-ARC laser allows for a high-brightness proton source for radiography and thus enabling a wide range of applications in HED science. In this demonstration, proton radiography of a physics package was performed and this work details the spectral properties of the TNSA proton probe as well as description of the resulting radiography quality.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
DOE OSTI2021

Exploring the structural uniformity and integrity of protonic ceramic thin film electrolyte using wet powder spraying

Thin protonic ceramic electrolyte contributes to lower ohmic resistance and enhances electrochemical performance of protonic ceramic electrochemical cells. However, manufacturing of large-scale thin electrolyte remains a challenge. Wet powder spraying is an attractive technique to deposit <10 µm thin electrolyte when advanced atomizing techniques and optimized spraying process are integrated. Here ultrasonic atomization is integrated in the wet powder spray technique to reduce the thickness of electrolyte. Moreover, a parametric study is conducted to optimize the wet powder spray process to deposit uniform and crack-free electrolyte film. It is illustrated that tuning of solid loading rates and spray passes can affect the morphology of the as-sprayed electrolyte film, enabling the structural compactness of the sintered electrolyte layer. To maintain chemical stability of the electrolyte layer during sintering, effect of sintering temperature is further investigated to produce a physically thin, structurally dense, and chemically homogeneous electrolyte layer. The protonic ceramic electrochemical cells fabricated with optimized spraying and sintering parameters demonstrate excellent performance under both fuel cell and electrolysis modes. In addition, the cells exhibit remarkable structural integrity during redox and long-term stability tests.

36 MATERIALS SCIENCE↗
DOE OSTI2022

An Unbalanced Battle in Excellence: Revealing Effect of Ni/Co Occupancy on Water Splitting and Oxygen Reduction Reactions in Triple–Conducting Oxides for Protonic Ceramic Electrochemical Cells

Porous electrodes that conduct electrons, protons, and oxygen ions with dramatically expanded catalytic active sites can replace conventional electrodes with sluggish kinetics in protonic ceramic electrochemical cells. In this work, a strategy is utilized to promote triple conduction by facilitating proton conduction in praseodymium cobaltite perovskite through engineering non-equivalent B-site Ni/Co occupancy. Surface infrared spectroscopy is used to study the dehydration behavior, which proves the existence of protons in the perovskite lattice. The proton mobility and proton stability are investigated by hydrogen/deuterium (H/D) isotope exchange and temperature-programmed desorption. It is observed that the increased nickel replacement on the B-site has a positive impact on proton defect stability, catalytic activity, and electrochemical performance. This doping strategy is demonstrated to be a promising pathway to increase catalytic activity toward the oxygen reduction and water splitting reactions. The chosen PrNi 0.7 Co 0.3 O 3–δ oxygen electrode demonstrates excellent full-cell performance with high electrolysis current density of –1.48 A cm –2 at 1.3 V and a peak fuel-cell power density of 0.95 W cm –2 at 600 °C and also enables lower-temperature operations down to 350 °C, and superior long-term durability.

08 HYDROGEN↗
DOE OSTI2023

IOTA Proton Injector Beamline Installation

The IOTA Proton Injector (IPI), currently under installation at the Fermilab Accelerator Science and Technology facility, is a beamline capable of delivering 20-mA pulses of protons at 2.5 MeV to the Integrable Optics Test Accelerator (IOTA) ring. First beam in the IPI beamline is anticipated in 2023, when it will operate alongside the existing electron injector beamline to facilitate further fundamental physics research and continued development of novel accelerator technologies in the IOTA ring. This report details the expected operational profile, known challenges, and the current state of installation.

43 PARTICLE ACCELERATORS↗
DOE OSTI2025

COG11.3 Abstract

COG is a high-resolution code for the Monte Carlo simulation of coupled particle transport in arbitrary3-D geometry. COG will transport neutrons, protons, deuterons, alpha particles with energies up to hundreds of GeV, and photons with energy ranges limited by the available cross section sets and physics models. Electrons can be transported via the EGS5 electron transport kernel, electrons can also be transported. The COG code is a significant upgrade from earlier Monte Carlo transport codes and has been written specifically to makes it more versatile, accurate, and easy to use. COG has provisions for calculating deep penetration (shielding) problems, criticality problems, and neutron activation problems.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗
DOE OSTI2022

Mitigating cerium migration for perfluorosulfonic acid membranes using organic ligands

Improving the electrochemical stability of proton exchange membranes is a pressing priority for heavy-duty fuel cell vehicles. The lifetime of the most widely used perfluorosulfonic acid membranes is limited by reactive free radicals generated inside the system. Cerium has been found to reduce the chemical degradation of the membranes. However, cerium migration during fuel cell operation limits the chemical durability enhancement effect expected from the radical scavenging activity of cerium. Here we investigate a wide range of organic immobilizers for cerium, measuring their suitability concerning cerium retention, radical scavenging activity, and fuel cell performance. Further, we report that partially fluorinated phosphonic acids enhance cerium retention up to 45 times and reduce fluoride emission rate by 38% compared to the commercial Nafion™ XL membrane pre-impregnated with cerium. The energetics of cerium-phosphonic acid complex systems by density functional theory calculations rationalizes effective cerium immobilization.

25 ENERGY STORAGE↗
DOE OSTI2020

Characterization and pulse-shape discrimination of a multi-stacked structure of ZnS: Ag/PMMA for fast-neutron detection in high-flux environments

The Micro-Layered Fast Neutron Detector (MLFD) is a proton-recoil scintillator that incorporates the basic concept of a Hornyak button detector with an improved design using a layered structure of ZnS:Ag and PMMA (polymethyl methacrylate). The MLFD was predicted to have low sensitivity to gamma rays, hence pulse shape discrimination was performed to determine the gamma-ray contribution. Presented in this paper are the pulse-shape discrimination characteristics of the MLFD. Additionally, the charge integration technique was employed to discriminate between the neutrons and gamma rays using a fast digitzer. The MLFD was found to exhibit excellent neutron/gamma-ray discrimination, with the highest Figure-of-Merit (FoM) being 4.56. With PSD, the neutron signal is distinct from gamma-ray, Ĉerenkov and electronic noise signals. This clear separation was achieved due to the large differences in decay times of the neutron and gamma-ray-induced pulses in the ZnS:Ag phosphor. The MLFD can be employed in high gamma-ray exposure fields, up to at least 1287.7 mR/hr, without appreciable degradation in PSD performance.

47 OTHER INSTRUMENTATION↗
DOE OSTI2026

Enhanced Electrocatalytic and Cathode‐Electrolyte Interfacial Properties With a Pr‐Based Simple Perovskite/Ruddlesden‐Popper Nanocomposite Cathode in Protonic Ceramic Fuel Cells

The sluggish kinetics and poor stability of the oxygen reduction reaction (ORR) remain the primary bottleneck for achieving high performance in protonic ceramic fuel cells (PCFCs) at intermediate temperatures (400–650°C). In this work, a Pr-based nanocomposite cathode comprised of simple perovskite phase (PrNi 0.7 Co 0.3 O 3-δ ) and Ruddlesden-Popper phase (Co-doped Pr 4 Ni 3 O 10+δ ) is developed. Although PrNi 0.7 Co 0.3 O 3-δ solely stands as a good cathode with facile proton transfer, combining the superior catalytic activity against oxygen on the Ruddlesden-Popper phase boosts the ORR performance further. The designed nanocomposite cathode outperforms the simple perovskite cathode, attributed to enhanced oxygen absorption and surface diffusion with the Ruddlesden-Popper phase. A precursor-based cathode deposition technique is also developed to achieve cathode grain sizes of ∼100 nm. A single cell with the nanocomposite cathode delivers a peak power density of 1.38 W cm −2 at 650°C, among the highest in reported PCFCs with Pr-based cathodes, with a small degradation rate of 0.145 mV h −1 during 250 h stability test. Further investigation of cathode-electrolyte interface revealed interfacial PrO 2 phase formation, promoted by abundant Pr 6 O 11 in the nanocomposite precursor powder, thereby improving both ohmic resistance and stability. These findings highlight the effectiveness of the nanocomposite cathode and underscore its advantages on interfacial properties.

08 - HYDROGEN↗
DOE OSTI2024

Constructing Highly Porous Low Iridium Anode Catalysts Via Dealloying for Proton Exchange Membrane Water Electrolyzers

Iridium (Ir) is the most active and durable anode catalyst for the oxygen evolution reaction (OER) for proton exchange membrane water electrolyzers (PEMWEs). However, their large-scale applications are hindered by high costs and scarcity of Ir. Lowering Ir loadings below 1.0 mgcm -2 causes significantly reduced PEMWE performance and durability. Therefore, developing efficient low Ir-based catalysts is critical to widely commercializing PEMWEs. Herein, an approach is presented for designing porous Ir metal aerogel (MA) catalysts via chemically dealloying IrCu alloys. In this study, the unique hierarchical pore structures and multiple channels of the Ir MA catalyst significantly increase electrochemical surface area (ECSA) and enhance OER activity compared to conventional Ir black catalysts, providing an effective solution to design low-Ir catalysts with improved Ir utilization and enhanced stability. An optimized membrane electrode assembly (MEA) with an Ir loading of 0.5 mg Ir cm -2 generated 2.0 A cm -2 at 1.79 V, higher than the Ir black at a loading of 2.0 mg Ir cm -2 (1.63 A cm -2 ). The low-Ir MEA demonstrated an acceptable decay rate of ≈40 µV h -1 during durability tests at 0.5 (>1200 h) and 2.0 A cm -2 (400 h), outperforming the commercial Ir-based MEA (175 µV h -1 at 2.0 mg Ir cm -2 ).

36 MATERIALS SCIENCE↗
DOE OSTI2020

Single-Crystal Polycationic Polymers Obtained by Single-Crystal-to-Single-Crystal Photopolymerization

The efficient preparation of single-crystalline ionic polymers and fundamental understanding of their structure–property relationships at the molecular level remains a challenge in chemistry and materials science. Herein, we observe the single-crystal structure of a highly ordered polycationic polymer (polyelectrolyte) and its proton conductivity. The polyelectrolyte single crystals can be prepared on a gram-scale in quantitative yield, by taking advantage of an ultraviolet/sunlight-induced topochemical polymerization, from a tricationic monomer—a self-complementary building block possessing a preorganized conformation. A single-crystal-to-single-crystal photopolymerization was revealed unambiguously by in situ single-crystal X-ray diffraction analysis, which was also employed to follow the progression of molecular structure from the monomer, to a partially polymerized intermediate, and, finally, to the polymer itself. Collinear polymer chains are held together tightly by multiple Coulombic interactions involving counterions to form two-dimensional lamellar sheets (1 nm in height) with sub-nanometer pores (5 Å). The polymer is extremely stable under 254 nm light irradiation and high temperature (above 500 K). The extraordinary mechanical strength and environmental stability—in combination with its impressive proton conductivity (~3 × 10 –4 S cm –1 )—endow the polymer with potential applications as a robust proton-conducting material. By marrying supramolecular chemistry with macromolecular science, the outcome represents a major step toward the controlled synthesis of single-crystalline polyelectrolyte materials with perfect tacticity.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2022

Shielding Analyses for SNS Accelerator Power Upgrade

The Proton Power Upgrade (PPU) project [1] at Spallation Neutron Source (SNS) is aiming at increasing the neutron beam intensities at the First Target Station (FTS) and advancing accelerator capability to additionally power a future Second Target Station (STS) [2]. PPU will involve upgrading the SNS accelerator complex to double the currently available proton beam power from 1.4 to 2.8 MW, by increasing the proton beam energy from 1 GeV to 1.3 GeV and by increasing the proton beam current.PPU will enable new science capabilities enhancing the experiment throughput of the 19 existing FTS instruments, which are heavily oversubscribed. STS will include 22 additional neutron scattering instruments. Numerous neutronics analyses are performed to support PPU evaluating the FTS systems for higher beam power and for system upgrades. Part of the PPU scope is an extension of the Ring to Target Beam Transport (RTBT) line, a stub out of the accelerator tunnel for the future Ring to STS Transport (RTST) line[3]. As the RTST tunnel will not be built within the PPU project, the stub will be shielded by a plug, which is planned to be made from regular concrete.In order to provide radiation protection safety, analyses are required to design adequate plug thickness for the stub. The thickness of the stub is driven by the criterion that the area downstream of the plug is “unrestricted access area”, demanding the dose rate downstream the stub be below 0.25 mrem/h at 30 cm from the surface at normal operation and below 20 Rem/hr for accident cases. Additionally, analyses verifying the amount of soil for shielding the accelerator tunnel to the above stated requirements are performed.

Popova, Irina I.↗
DOE OSTI2024

Status of the IOTA proton injector

The IOTA Proton Injector (IPI), currently under installation at the Fermilab Accelerator Science and Technology facility (FAST), is a machine capable of delivering 20\,mA pulses of protons at 2.5\,MeV to the Integrable Optics Test Accelerator (IOTA) ring. First beam in the IPI beamline is anticipated in the first half of~2024, when it will operate alongside the existing electron injector beamline to facilitate further beam physics research and continued development of novel accelerator technologies at the IOTA ring. This report details the expected operational profile, known challenges, and the current state of installation.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗
NASA NTRS2002

Model predictions and visualization of the particle flux on the surface of Mars

Model calculations of the particle flux on the surface of Mars due to the Galactic Cosmic Rays (GCR) can provide guidance on radiobiological research and shielding design studies in support of Mars exploration science objectives. Particle flux calculations for protons, helium ions, and heavy ions are reported for solar minimum and solar maximum conditions. These flux calculations include a description of the altitude variations on the Martian surface using the data obtained by the Mars Global Surveyor (MGS) mission with its Mars Orbiter Laser Altimeter (MOLA) instrument. These particle flux calculations are then used to estimate the average particle hits per cell at various organ depths of a human body in a conceptual shelter vehicle. The estimated particle hits by protons for an average location at skin depth on the Martian surface are about 10 to 100 particle-hits/cell/year and the particle hits by heavy ions are estimated to be 0.001 to 0.01 particle-hits/cell/year.

NASA Center JSC↗
NASA NTRS1995

Deuterium Exchange in the Systems of H2O+/H2O and H3O+/H2O

Using tandem mass spectrometry various water ion interactions were observed. These reactions consisted of a series of charge transfer, proton transfer, and isotopic exchange steps. The experimental data sets consist of variations of ion abundances over a neutral pressure range. An expected sequence of isotopic exchange reactions is given along with differential equation solutions & reaction rate data.

Spectroscopy Deuterium Proton Ion Atmospheric Scie↗
DOE OSTI2023

Status of the IOTA Proton Injector

The IOTA Proton Injector (IPI), currently under installation at the Fermilab Accelerator Science and Technology facility (FAST), is a machine capable of delivering 20 mA pulses of protons at 2.5 MeV to the Integrable Optics Test Accelerator (IOTA) ring. First beam in the IPI beamline is anticipated in the first half of 2024, when it will operate alongside the existing electron injector beamline to facilitate further beam physics research and continued development of novel accelerator technologies at the IOTA ring. This report details the expected operational profile, known challenges, and the current state of installation.

43 PARTICLE ACCELERATORS↗
DOE OSTI2022

Synthesis and Photonic Sintering of Proton Conducting Lanthanide Nickelates

Lanthanide nickelate perovskites are known proton conductors at intermediate temperatures (350-600°C). They are attractive targets for proton conducting fuel cells and electrolyzers due to their operational temperature range and their stability in the presence of CO 2 . These materials have the formula LNiO 3 , with the lanthanide L = La, Ce, Pr, Nd, or Sm. Sintering is challenging due to phase transformations that occur at lower temperatures than those required for sintering. In this project, a series of lanthanide nickelate perovskites was synthesized via both a precursor solid solution method and the glycine nitrate process. Powders derived from the precursor solid solution method for LaNiO 3 and NdNiO 3 were sintered at Utility Global Inc. at various temperatures utilizing fast photonic sintering. LaNiO 3 was successfully sintered while maintaining the perovskite phase. NdNiO 3 underwent a phase transformation at all the conditions tested. The stability of the perovskite phase decreases moving right across the lanthanides in the periodic table, while the expected proton conductivity increases. These results will inform further investigations into lanthanide nickelate perovskites toward the goal of producing a free-standing, sintered, proton-conducting membrane.

36 MATERIALS SCIENCE↗
DOE OSTI2020

Proton irradiation damage and annealing effects in ON Semiconductor J-series silicon photomultipliers

Silicon photomultipliers (SiPMs) have become popular light conversion devices in recent years due to their low bias voltage and sensitivity to wavelengths emitted from common scintillating materials. These properties make them particularly attractive for resource-constrained missions such as space-based detector applications. However, the space radiation environment is known to be particularly harsh on semiconductor devices, where high particle fluences can degrade performance over time. The radiation hardness of a particular SiPM, manufactured by ON Semiconductor (formally SensL), has yet to be studied with high energy protons, which are native to the space radiation environment. As such, to study these effects we have irradiated groups of two SiPMs to four different fluences of 800 MeV protons delivered by the accelerator at the Los Alamos Neutron Science Center. Fluences of 1.68 × 10 9 , 1.73 × 10 10 , 6.91 × 10 10 , and 1.73 × 10 11 protons cm –2 , and their corresponding estimated doses of 0.15, 1.55, 6.19, and 15.5 kRad, were chosen based on estimates of the potential exposure a SiPM might receive during an interplanetary space mission lasting 10 years. We report the effects these doses have on dark current and the self-annealing time.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗
DOE OSTI2021

Cryo-EM structures of Escherichia coli cytochrome bo 3 reveal bound phospholipids and ubiquinone-8 in a dynamic substrate binding site

Two independent structures of the proton-pumping, respiratory cytochrome bo3 ubiquinol oxidase (cyt bo 3 ) have been determined by cryogenic electron microscopy (cryo-EM) in styrene–maleic acid (SMA) copolymer nanodiscs and in membrane scaffold protein (MSP) nanodiscs to 2.55- and 2.19-Å resolution, respectively. The structures include the metal redox centers (heme b, heme o 3 , and Cu B ), the redox-active cross-linked histidine–tyrosine cofactor, and the internal water molecules in the proton-conducting D channel. Each structure also contains one equivalent of ubiquinone-8 (UQ8) in the substrate binding site as well as several phospholipid molecules. The isoprene side chain of UQ8 is clamped within a hydrophobic groove in subunit I by transmembrane helix TM0, which is only present in quinol oxidases and not in the closely related cytochrome c oxidases. Both structures show carbonyl O1 of the UQ8 headgroup hydrogen bonded to D75I and R71 I . In both structures, residue H98 I occupies two conformations. In conformation 1, H98 I forms a hydrogen bond with carbonyl O4 of the UQ8 headgroup, but in conformation 2, the imidazole side chain of H98 I has flipped to form a hydrogen bond with E14 I at the N-terminal end of TM0. We propose that H98 I dynamics facilitate proton transfer from ubiquinol to the periplasmic aqueous phase during oxidation of the substrate. Computational studies show that TM0 creates a channel, allowing access of water to the ubiquinol headgroup and to H98 I .

bioenergetics↗