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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 55 records · Page 3
All sourcesNASA NTRSDOE OSTI
DOE OSTI2023

Magnon orbital angular momentum of ferromagnetic honeycomb and zigzag lattice models

By expanding the gauge 𝜆 𝑛 ⁡(𝐤) for magnon band 𝑛 in harmonics of momentum 𝐤=(𝑘,𝜙), we demonstrate that the only observable component of the magnon orbital angular momentum 𝑂 𝑛 ⁡(𝐤) is its angular average over all angles 𝜙, denoted by 𝐹 𝑛 ⁡(𝑘). Although 𝐹 𝑛 ⁡(𝑘) vanishes for antiferromagnetic honeycomb and zigzag (0<𝐽 1 <𝐽 2 ) lattices, it is nonzero for the ferromagnetic (FM) versions of those lattices in the presence of Dzyaloshinskii-Moriya interactions. For a FM zigzag model with equal exchange interactions 𝐽 1⁢𝑥 and 𝐽 1⁢𝑦 along the 𝑥 and 𝑦 axes, the magnon bands are degenerate along the boundaries of the Brillouin zone with 𝑘 𝑥 −𝑘 𝑦 =±𝜋/𝑎 and the Chern numbers 𝐶 𝑛 are not well defined. However, a revised model with 𝐽 1⁢𝑦 ≠𝐽 1⁢𝑥 lifts those degeneracies and produces well-defined Chern numbers of 𝐶𝑛=±1 for the two magnon bands. When 𝐽 1⁢𝑦 =𝐽 1⁢𝑥 , the thermal conductivity 𝜅 𝑥⁢𝑦⁡ (𝑇) of the FM zigzag lattice is largest for 𝐽2/𝐽1>6 but is still about four times smaller than that of the FM honeycomb lattice at high temperatures. Due to the removal of band degeneracies, 𝜅𝑥⁢𝑦⁡(𝑇) is slightly enhanced when 𝐽 1⁢𝑦 ≠𝐽 1⁢𝑥 .

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
NASA NTRS1994

Use of radon and cosmogenic radionuclides as indicators of exchange between troposphere and stratosphere

This research grant covered participation in the operational phase of NASA's Stratosphere-Troposphere Exchange Project (STEP), a multi-agency airborne science program conducted aboard NASA U-2 and ER-2 high altitude research aircraft. The primary goals of STEP were to investigate the mechanisms of irreversible movement of mass, trace gases, and aerosols from the troposphere into the stratosphere, and to explain the observed dryness of the stratosphere. Three flight experiments were conducted to address these questions: two extratropical experiments, in 1984 and 1986, and a tropical experiment, in 1987. The cosmogenic radionuclides Be-7 and P-32, produced in the stratosphere by cosmic rays, and Rn-222 (radon), emitted from continental soils, were well-suited as tracers of intra-stratospheric air mass movements, and to follow episodes of troposphere to stratosphere exchange. Measurements of Be-7 and P-32 were made in all three STEP experiments. Measurements of radon were made in the tropical experiment only. The equipment worked well, and produced a valuable data set in support of the STEP objectives, as indicated by the 'quick-look' results outlined.

Kritz, Mark A.↗
NASA NTRS2006

Novel Concept for LSS Based on Advanced Microalgal Biotechnologies

One of the key issues for successful human space exploration is biomedical life support in hostile space and planetary environments that otherwise cannot sustain life. Bioregenerative life support systems (LSS) are one of the options for atmospheric regeneration. To date, no bioregenerative LSS has shown capability for 100% air regeneration. Nor have these LSS been robust enough to simultaneously provide a regenerable complete food source. In contrast to microalgae, traditional plant approaches, e.g. wheat and lettuce, are lacking essential amino acids, vitamins, and micronutrients. Moreover, the rate of photosynthesis by microalgae significantly exceeds that of high plants. Nevertheless, the employment of microalgae in LSS technology was restricted, until recently, due to high water demands. Also the per person requirement of a 40L volume of microalgae in a photobioreactor, to provide daily O2 production, made an algae-based approach less attractive. By employing a vertically stacked membrane bioreactor, coupled with a solar tracker and photon-delivery system, a lightweight air revitalization system for space based applications, with minimal water requirements, can be developed. Our preliminary estimations suggest that a membrane bioreactor, 8m3 in volume, comprised of 80m2 (twenty 2m x 2m membranes, each spaced 10 cm apart), and a total of 70L of water could produce 2.7 kg of dried microalgal biomass that would supply the energy and essential amino acid requirements, as well as producing sufficient O2 for the daily needs of a 15 member crew. Research on the biochemical content of edible blue-green alga Spirulina (Arthrospira) platensis shows a wide spectrum of stable Spirulina mutants with an enhanced content of amino acids, -carotene, and phycobilliprotein c-phycocyanin. Feeding animals suffering from radiation-induced lesions, c-phycocyanin, extracted from strain 27G, led to a correction in the decrement of dehydrogenase activity and energy-rich phosphate levels, as well as improved antioxidant defense and pyruvate levels, compared to untreated animals. Experimental anemia in rats was corrected by feeding Spirulina platensis strains 198B and 27G, (with an enhanced content of methionine, phycobiliproteins and carotenoids). Spirulina was recently shown by Ananyev et al, 2005, to be an oxygenic organism with the highest level of photosystem II activity (O2 production). We propose therefore to develop a design for membrane-based photoreactors for Lunar and Mars exploration habitat LSS, for the cultivation of genetically modified strains of Spirulina to scrub CO2 and supply astronauts with O2, protein, vitamins, and immunostimulators.

Brown, I.↗
DOE OSTI2022

Experimental Investigation of Barium Sources and Fluid–Rock Interaction in Unconventional Marcellus Shale Wells Using Ba Isotopes

Produced waters from unconventional Marcellus Shale gas wells have anomalously high barium (Ba) concentrations and yield some of the isotopically heaviest Ba measured to date. Experiments were conducted to constrain the source of Ba in these fluids and the controls on barite (BaSO 4 ) precipitation and dissolution in oil and gas wells. Experiments simulating the acidizing stage evaluated the solubility of pure barite and drilling mud in 2 M HCl at 80 °C for periods of 2, 6, and 48 h and resulted in <0.01% barite dissolution with no appreciable change in δ 138 Ba ( 138 Ba/ 134 Ba normalized to NIST standard 3104a). Static autoclave experiments conducted at 66 °C and 20.7 MPa with combinations of ground Marcellus Shale solids and/or barite-bearing drilling mud with synthetic low-Ba fracturing fluid resulted in decreased Ba concentrations in the fluid, with the largest decrease in the shale-only run. Fluid δ 138 Ba values increased by about 0.5‰ as Ba concentrations decreased, consistent with closed-system Rayleigh fractionation. Flow-through experiments in Marcellus Shale core conducted for 28 days resulted in effluent Ba concentrations an order of magnitude lower than the influent, while sulfate concentrations increased over time. Effluent δ 138 Ba values increased over the first 12 days and plateaued at about 1‰ higher than the influent. Modeling suggests a combination of the release of labile shale Ba and barite precipitation. This work indicates that the processes of Ba release from fluid–shale interactions and barite precipitation in fractures and the well bore, while capable of producing high δ 138 Ba fluids, are unlikely to generate fluids with high-Ba concentrations and δ 138 Ba values like those in Marcellus-produced waters. As a result, we find that the release of sulfate from shale pyrite oxidation rapidly catalyzes barite precipitation and that dissolution of drilling mud barite or natural barite in the shale is unlikely to be the major source of Ba in Marcellus-produced waters.

54 ENVIRONMENTAL SCIENCES↗
NASA NTRS1971

Analytical basis for planetary quarantine.

The attempt is made to investigate quarantine constraints, and alternatives for meeting them, in sufficient detail for identifying those courses of action which compromise neither the quarantine nor the space mission objectives. Mathematical models pertinent to this goal are formulated at three distinct levels. The first level of mission constraint models pertains to the quarantine goals considered necessary by the international scientific community. The principal emphasis of modeling at this level is to quantify international considerations and to produce well-defined mission constraints. Such constraints must be translated into explicit implementation requirements by the operational agency of the launching nation. This produces the second level of implementation system modeling. However, because of the multitude of factors entering into the implementation models, it is convenient to consider these factors at the third level of implementation parameter models. These models are intentionally limited to the inclusion of only those factors which can be quantified realistically, either now or in the near future.

Schalkowsky, S.↗
NASA NTRS2001

Team Expo: A State-of-the-Art JSC Advanced Design Team

In concert with the NASA-wide Intelligent Synthesis Environment Program, the Exploration Office at the Johnson Space Center has assembled an Advanced Design Team. The purpose of this team is two-fold. The first is to identify, use, and develop software applications, tools, and design processes that streamline and enhance a collaborative engineering environment. The second is to use this collaborative engineering environment to produce conceptual, system-level-of-detail designs in a relatively short turnaround time, using a standing team of systems and integration experts. This includes running rapid trade studies on varying mission architectures, as well as producing vehicle and/or subsystem designs. The standing core team is made up of experts from all of the relevant engineering divisions (e.g. Power, Thermal, Structures, etc.) as well as representatives from Risk and Safety, Mission Operations, and Crew Life Sciences among others. The Team works together during 2- hour sessions in the same specially enhanced room to ensure real-time integration/identification of cross-disciplinary issues and solutions. All subsystem designs are collectively reviewed and approved during these same sessions. In addition there is an Information sub-team that captures and formats all data and makes it accessible for use by the following day. The result is Team Expo: an Advanced Design Team that is leading the change from a philosophy of "over the fence" design to one of collaborative engineering that pushes the envelope to achieve the next-generation analysis and design environment.

Tripathi, Abhishek↗
DOE OSTI2024

Utah FORGE: Well 16A(78)-32 and 16B(78)-32 Stimulation Production Logging Tests

These are production logging tests (PLT) results from Halliburton collected during the nine hour circulation test performed at Utah FORGE on April 27th, 2024. The circulation test involved injecting into well 16A(78)-32 and producing out of well 16B(78)-32) and was carried out after the fracturing of both of those wells. Data attached here includes raw and processed PLT logs from both wells, as well as technical reports summarizing the data collection and results.

15 GEOTHERMAL ENERGY↗
NASA NTRS1994

Tensile Creep and Stress-rupture Behavior of Polymer Derived Sic Fibers

Tensile creep and stress-rupture studies were conducted on polymer derived Nicalon, Hi-Nicalon, and SiC/BN-coated Nicalon SiC fibers. Test conditions were temperatures from 1200 to 1400 C, stresses from 100 to 1600 MPa, stress application times up to 200 hours, and air, argon, and vacuum test environments. For all fibers, creep occurred predominantly in the primary stage. Hi-Nicalon had much higher 0.2 and 1 percent creep strengths than as-produced as well as-coated Nicalon fibers. The stress-rupture strength of Hi-Nicalon up to 100 hours was also higher than that of the coated and as-produced Nicalon fibers. SiC/BN coating on Nicalon increased only the short-term low-temperature rupture strength. Limited testing in argon and vacuum suggests that for all fiber types, creep and rupture resistances are reduced in comparison to the results in air. Possible mechanisms for the observed behavior are discussed.

Yun, H. M.↗
DOE OSTI2022

Reaction–drift–diffusion models from master equations: application to material defects

We present a general method to produce well-conditioned continuum reaction–drift–diffusion equations directly from master equations on a discrete, periodic state space. We assume the underlying data to be kinetic Monte Carlo models (i.e. continuous-time Markov chains) produced from atomic sampling of point defects in locally periodic environments, such as perfect lattices, ordered surface structures or dislocation cores, possibly under the influence of a slowly varying external field. Our approach also applies to any discrete, periodic Markov chain. Here, the analysis identifies a previously omitted non-equilibrium drift term, present even in the absence of external forces, which can compete in magnitude with the reaction rates, thus being essential to correctly capture the kinetics. To remove fast modes which hinder time integration, we use a generalized Bloch relation to efficiently calculate the eigenspectrum of the master equation. A well conditioned continuum equation then emerges by searching for spectral gaps in the long wavelength limit, using an established kinetic clustering algorithm to define a proper reduced, Markovian state space.

36 MATERIALS SCIENCE↗
DOE OSTI2022

Gain roll-off in cadmium selenide colloidal quantum wells under intense optical excitation

Colloidal quantum wells, or nanoplatelets, show among the lowest thresholds for amplified spontaneous emission and lasing among solution-cast materials and among the highest modal gains of any known materials. Using solution measurements of colloidal quantum wells, this work shows that under photoexcitation, optical gain increases with pump fluence before rolling off due to broad photoinduced absorption at energies lower than the band gap. Despite the common occurrence of gain induced by an electron–hole plasma found in bulk materials and epitaxial quantum wells, under no measurement conditions was the excitonic absorption of the colloidal quantum wells extinguished and gain arising from a plasma observed. Instead, like gain, excitonic absorption reaches a minimum intensity near a photoinduced carrier sheet density of 2 × 10 13 cm –2 above which the absorption peak begins to recover. To understand the origins of these saturation and reversal effects, measurements were performed with different excitation energies, which deposit differing amounts of excess energy above the band gap. Across many samples, it was consistently observed that less energetic excitation results in stronger excitonic bleaching and gain for a given carrier density. Transient and static optical measurements at elevated temperatures, as well as transient X-ray diffraction of the samples, suggest that the origin of gain saturation and reversal is a heating and disordering of the colloidal quantum wells which produces sub-gap photoinduced absorption.

36 MATERIALS SCIENCE↗
DOE OSTI2024

Bayesian batch optimization for molybdenum versus tungsten inertial confinement fusion double shell target design

Access to reliable, clean energy sources is a major concern for national security. Much research is focused on the “grand challenge” of producing energy via controlled fusion reactions in a laboratory setting. For fusion experiments, specifically inertial confinement fusion (ICF), to produce sufficient energy, the fusion reactions in the ICF fuel need to become self-sustaining and burn deuterium-tritium (DT) fuel efficiently. The recent record-breaking NIF ignition shot was able to achieve this goal as well as produce more energy than used to drive the experiment. This achievement brings self-sustaining fusion-based power systems closer than ever before, capable of providing humans with access to secure, renewable energy. In order to further progress toward the actualization of such power systems, more ICF experiments need to be conducted at large laser facilities such as the United States's National Ignition Facility (NIF) or France's Laser Mega-Joule. The high cost per shot and limited number of shots that are possible per year make it prohibitive to perform large numbers of experiments. As such, experimental design relies heavily on complex predictive physics simulations for high-fidelity “preshot” analysis. These multidimensional, multi-physics, high-fidelity simulations have to account for a variety of input parameters as well as modeling the extreme conditions (pressures and densities) present at ignition. Such simulations (especially in 3D) can become computationally prohibitive to turn around for each ICF experiment. In this work, we explore using Bayesian optimization with Gaussian processes (GPs) to find optimal designs for ICF double shell targets, while keeping computational costs to manageable levels. These double shell targets have an inner shell that grades from beryllium on the outer surface to the higher Z material molybdenum, as opposed to the nominally used tungsten, on the inside in order to trade off between the high performance associated with high density inner shells and capsule stability. We describe our results for “capsule-only” xRAGE simulations to study the physics between different capsule designs, inner shell materials, and potential for future experiments.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
DOE OSTI2022

Cosmological constraints on light but massive relics

Many scenarios of physics beyond the standard model predict new light, weakly coupled degrees of freedom, populated in the early universe and remaining as cosmic relics today. Due to their high abundances, these relics can significantly affect the evolution of the universe. For instance, massless relics produce a shift ΔN eff to the cosmic expectation of the effective number of active neutrinos. Massive relics, on the other hand, additionally become part of the cosmological dark matter in the later universe, though their light nature allows them to freely stream out of potential wells. This produces novel signatures in the large-scale structure (LSS) of the universe, suppressing matter fluctuations at small scales. Here, we present the first general search for such light (but massive) relics (LiMRs) with cosmic microwave background (CMB) and LSS data, scanning the 2D parameter space of their masses m X and temperatures $T^{(0)}_{X}$ today. In the conservative minimum-temperature ($T^{(0)}_{X}$ = 0.91 K) scenario, we rule out Weyl (and higher-spin) fermions -- such as the gravitino -- with m X ≥ 2.26 eV at 95% C.L., and set analogous limits of m X ≤ 11.2,1.06,1.56 eV for scalar, vector, and Dirac-fermion relics. This is the first search for LiMRs with joint CMB, weak-lensing, and full-shape galaxy data; we demonstrate that weak-lensing data is critical for breaking parameter degeneracies, while full-shape information presents a significant boost in constraining power relative to analyses with only baryon acoustic oscillation parameters. Under the combined strength of these datasets, our constraints are the tightest and most comprehensive to date.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2025

Antimicrobial activity of peptoids against Metallo-β-lactamase-producing Klebsiella pneumoniae, Acinetobacter baumannii, Pseudomonas aeruginosa , and other WHO priority pathogens, including Candida auris

Abstract Aims The World Health Organization has identified ESKAPE bacteria and Candida auris as priority pathogens, emphasizing an urgent need for novel antimicrobials to combat them. This study aimed to explore the therapeutic potential of antimicrobial peptidomimetics, specifically peptoids with sequence-specific N-substituted glycines, against ESKAPEE pathogens, including metallo-β-lactamase (MBL) producers, as well as C. auris strains. Methods and results This study evaluated activity of the peptoids against the multidrug-resistant priority pathogens. The peptoid TM8 (with an N-decyl alkyl chain) demonstrated a geometric mean minimum inhibitory concentration (MIC) of 7.8 μg ml−1 against MBL-producing bacteria, and 5.5 μg ml−1 against C. auris. TM8 showed synergy with ciprofloxacin, enhancing its effectiveness 4-fold against NDM-1-producing Klebsiella pneumoniae. No antagonism was seen when TM8 was used with either conventional antibiotics or antifungals. Peptoids that had therapeutic indices below 3 were generally more hydrophobic, due to either alkyl chains or bromine. Scanning electron microscopy and live-dead staining assay on peptoid-treated C. auris confirmed morphological changes and killing activity, respectively. Furthermore, the peptoid could effectively inhibit biofilm formation by C. auris. Conclusion Peptoids demonstrated antibacterial activity against ESKAPEE, particularly against MBL-producing Gram-negative bacteria. Additionally, they exhibited antifungal and anti-biofilm activities against C. auris strains.

Biotechnology & Applied Microbiology↗
DOE OSTI2022

Metallic Technetium Sequestration in Nickel Core/Shell Microstructure during Fe(OH)2 Transformation with Ni doping

This study investigates the impacts of Ni doping on technetium-99 (Tc) sequestration in aqueous solutions through transformation of Fe(OH)2(s) to iron spinel (magnetite) under alkaline conditions. Extensive solid characterization was performed for the mineral phases produced, as well as the Tc/Ni speciation and distribution within these phases. X-ray diffraction results show that iron spinel was the dominant mineral product without detectable Ni incorporation. The doped Ni ions mainly precipitated as fine Fe/Ni oxide/hydroxide particles, including strongly reduced nanometer?sized spheroidal Ni-rich and metallic Ni phases. High-resolution analytical scanning transmission electron microscopy using energy dispersive X-ray spectroscopy and electron energy loss spectroscopy on the produced solid samples (focused ion beam-prepared specimens) revealed three Tc distribution domains dominated by nanocrystals and, especially, a Tc-rich metallic phase. Instances of metallic Tc were specifically found in spheroidal, Ni-rich and metallic nanoparticles exhibiting a core/shell microstructure that suggests strong reduction and sequential precipitation of Ni-Tc-Ni. Mass balance analysis showed nearly 100% Tc removal from the 4.8 × 10-4 M Tc solutions. The finding of the metallic Tc encapsulation indicates that Tc sequestration through Ni-doped Fe(OH)2(s)?to?iron spinel transformation process likely provides an alternative treatment pathway for Tc removal and could be combined into further waste treatment approaches.

Wang, Guohui↗
NASA NTRS2004

Measured Fluid Flow in an Active H2O-CO2 Geothermal Well as an Analog to Fluid Flow in Fractures on Mars: Preliminary Report

Water in the Earth's crust generally contains dissolved gases such as CO2. Models for both 'Blue Mars' (H2O-driven processes) and 'White Mars' (CO2-driven processes) predict liquid H2O with dissolved CO2 at depth. The fate of dissolved CO2 as this mixture rises toward the surface has not been quantitatively explored. Our approach is a variation on NASA's 'Follow the Water' as we 'Follow the Fluid' from depth to the surface in hydrothermal areas on Earth and extrapolate our results to Mars. This is a preliminary report on a field study of fluid flow in a producing geothermal well. For proprietary reasons, the name and location of this well cannot be revealed, so we have named it 'Earth1' for this study.

Kieffer, Susan W.↗
NASA NTRSDate not supplied

Quantitative Characterization of Lunar Regolith Simulants for Direct Comparison to Apollo Soil Samples

Introduction: Sustained characterization efforts of lunar regolith simulant properties are not only integral for verification of commercially-produced material designed for a wide array of testing applications but are also necessary in establishing a comprehensive comparison to a lunar reference source. As a resource for the lunar science and engineering communities, the Simulant Development Lab (SDL) within the Astromaterials Research & Exploration Science (ARES) division at the Johnson Space Center (JSC) is actively pursuing closure of existing knowledge gaps in fundamental simulant attributes, including chemistry, mineralogy, particle size distribution, particle geometry, bulk and relative density, magnetic susceptibility, and shear strength (i.e., cohesion and angle of internal friction), as well as producing Figures of Merit for comparison of lunar simulants to Apollo regolith samples.

R. Kovtun↗
NASA NTRS2000

Impact Crater in Coastal Patagonia

Impact craters are geological structures attributed to the impact of a meteoroid on the Earth's (or other planet's) surface (Koeberl and Sharpton. 1999). The inner planets of the solar system as well as other bodies such as our moon show extensive meteoroid impacts (Gallant 1964, French 1998). Because of its size and gravity, we may assume that the Earth has been heavily bombarded but weathering and erosion have erased or masked most of these features. In the 1920's, a meteor crater (Mark 1987) was identified in Arizona and to this first finding the identification of a large number of impact structures on Earth followed (Hodge 1994). Shock metamorphic effects are associated with meteorite impact craters. Due to extremely high pressures, shatter cones are produced as well as planar features in quartz and feldspar grains, diaplectic glass and high-pressure mineral phases such as stishovite (French 1998).

D'Antoni, Hector L↗
DOE OSTI2022

High Performance Circuit Pastes for Solid Oxide Fuel Cell Applications: Final Technical Report

Using a combination of in-plane electrical conductivity measurements, electrical contact resistance measurements, tensile fracture tests, double shear lap fracture tests, rapid thermal cycling adhesion tests, in situ wetting angle measurements, 3D X-ray tomography, reduction-oxidation (RedOx) cycling, scanning electron microscopy (SEM), energy dispersive x-ray spectroscopy (EDAX), Density Functional Theory (DFT) modeling, Molecular Dynamics (MD) modeling, and Phase Field modeling, this project determined that a new brazing technique developed by the PIs (specifically the use of nickel particles to direct the wetting and spreading of molten silver) could be used to produce well-adhered, >97% dense, electrically-conductive circuits, current collectors, and/or electrical contacts on a variety of ceramic and ceramic-coated substrates (specifically lanthanum strontium manganite, yttria stabilized zirconia, sapphire, Cr2O3-passivated stainless steel, and Al2O3-passivated stainless steel). Compared to other silver-based alternatives, Ag:Ni led to less manufacturing defects and was more tolerant of the extreme environments (isothermal high-temperature aging) and occasional abuse (rapid thermal cycling and RedOx cycling) encountered during Solid Oxide Fuel Cell and/or Solid Oxide Electrolysis Cell operation. Further, in some situations (such as when to produce Ag:Ni electrical contacts to Al2O3-protected stainless steel) the Ni particles also improved operation by acting as chemical getters that removed electrically-insulating, surface-segregating substrate impurities (i.e. by lowering the contact resistance with the underlying substrate).

36 MATERIALS SCIENCE↗