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Use of Machine Learning and Principal Component Analysis to Retrieve Nitrogen Dioxide (NO 2 ) With Hyperspectral Imagers and Reduce Noise in Spectral Fitting

Nitrogen dioxide (NO 2 ) is an important trace-gas pollutant and climate agent whose presence also leads to spectral interference in ocean color retrievals. NO 2 column densities have been retrieved with satellite UV–Vis spectrometers such as the Ozone Monitoring Instrument (OMI) and the Tropospheric Monitoring Instrument (TROPOMI) that typically have spectral resolutions of the order of 0.5 nm or better and spatial footprints as small as 3.6 km × 5.6 km. These NO 2 observations are used to estimate emissions, monitor pollution trends, and study effects on human health. Here, we investigate whether it is possible to retrieve NO 2 amounts with lower-spectral-resolution hyperspectral imagers such as the Ocean Color Instrument (OCI) that will fly on the Plankton, Aerosol, Cloud, ocean Ecosystem (PACE) satellite set for launch in early 2024. OCI will have a spectral resolution of 5 nm and a spatial resolution of ∼ 1 km with global coverage in 1–2 d. At this spectral resolution, small-scale spectral structure from NO 2 absorption is still present. We use real spectra from the OMI to simulate OCI spectra that are in turn used to estimate NO 2 slant column densities (SCDs) with an artificial neural network (NN) trained on target OMI retrievals. While we obtain good results with no noise added to the OCI simulated spectra, we find that the expected instrumental noise substantially degrades the OCI NO 2 retrievals. Nevertheless, the NO 2 information from OCI may be of value for ocean color retrievals. OCI retrievals can also be temporally averaged over timescales of the order of months to reduce noise and provide higher-spatial-resolution maps that may be useful for downscaling lower-spatial-resolution data provided by instruments such as OMI and TROPOMI; this downscaling could potentially enable higher-resolution emissions estimates and be useful for other applications. In addition, we show that NNs that use coefficients of leading modes of a principal component analysis of radiance spectra as inputs appear to enable noise reduction in NO 2 retrievals. Once trained, NNs can also substantially speed up NO 2 spectral fitting algorithms as applied to OMI, TROPOMI, and similar instruments that are flying or will soon fly in geostationary orbit.

NO2

A Technique Using Principal Component Analysis to Compare Seasonal Cycles of Earth Radiation from CERES and Model Computations

A method for quantitatively comparing the seasonal cycles of two global data sets is presented. The seasonal cycles of absorbed solar radiation (ASR) and outgoing longwave radiation (OLR) have been computed from an eight-year data set from the Clouds and Earth's Radiant Energy System (CERES) scanning radiometers and from a model data set produced by the NASA Goddard Space Flight Center Global Modeling and Assimilation Office. To compare the seasonal cycles from these two data sets, principal component (PC) analysis is used, where the PCs express the time variations and the corresponding empirical orthogonal functions (EOFs) describe the geographic variations. Ocean has a long thermal response time compared to land, so land and ocean are separated for the analysis. The root-mean square values for the seasonal cycles of ASR and OLR are extremely close for the two data sets. The first three PCs are quite close, showing that the time responses and magnitudes over the globe are very similar. The agreement between the two sets of PCs is quantified by computing the matrix of inner products of the two sets. For ASR over land, the first PCs of CERES and the model agree to better than 99.9%. The EOF maps are similar for most of the globe, but differ in a few places, and the agreement of the EOF maps is likewise quantified. Maps of differences between the annual cycles show regions of agreement and disagreement.

Smith, G. Louis

A closed-loop principal component analysis of a tetrahedral truss

A tetrahedral truss, representative of a fairly broad class of large space structures, is considered. A method, measuring the dynamical importance of each elastic mode when the structure is under feedback control, is presented. The main conclusion is that the closed-loop importance of each vibration mode depends on the robustness requirements. Also, there appears to be a conflict between precise control of a given node of the structure and stability margin, these two requirements leading to contradictory classifications of the modes by order of importance.

Jonckheere, E. A.

Passive microwave remote sensing of thin sea ice using principal component analysis

The possibility of developing a satellite-based sea-ice-concentration algorithm which solves for the presence of thinner ice is explored on the basis of time sequences of surface-based measurements of passive MW emission from growing saline ice reported by Wensnahan et al. (1993). It is shown that two classes of thinner ice can be distinguished from mixtures of open water, first-year ice, and multiyear ice. Newly formed ice appears to be optically thick at 37 and 90 GHz and has a relatively dry surface. The thin ice spectrum occurs when the ice is greater than 4 cm thick and appears to result from the accumulation of brine at the ice surface. Thin ice has a relatively stable spectrum characterized by high brightness temperatures, a near-zero spectral gradient at vertical polarization, and a large difference between vertical and horizontal polarizations. It is concluded that thin ice can be detected using satellite data.

Wensnahan, Mark

Principal Component Analysis for Biosignature Detection in Extraterrestrial Samples

Analysis of extraterrestrial samples for organic signatures of past or present life presents several problems. Chief among these is distinguishing bonafide extraterrestrial organic material from terrestrial contamination, either carried on a spacecraft or present in the terrestrial environment to which the sample is exposed. A related problem is separating biologically derived molecules from those produced by abiotic syntheses in the interstellar medium, on meteorite parent bodies, or in planetary atmospheres and oceans.

McDonald, G. D.

Real time on-chip sequential adaptive principal component analysis for data feature extraction and image compression

In this paper, we present a new, simple, and optimized hardware architecture sequential learning technique for adaptive Principle Component Analysis (PCA) which will help optimize the hardware implementation in VLSI and to overcome the difficulties of the traditional gradient descent in learning convergence and hardware implementation.

PCA feature extraction image compression real time

Principal Components Analysis of Reflectance Spectra Returned by the Mars Exploration Rover Opportunity

The Mars Exploration Rover Opportunity has spent over six years exploring the Martian surface near its landing site at Meridiani Planum. Meridiani bedrock observed by the rover is largely characterized by sulfate-rich sandstones and hematite spherules, recording evidence of ancient aqueous environments [1]. The region is a deflationary surface, allowing hematite spherules, fragments of bedrock, and "cobbles" of foreign origin to collect loosely on the surface. These cobbles may be meteorites (e.g., Barberton, Heat Shield Rock, Santa Catarina) [2], or rock fragments of exotic composition derived from adjacent terranes or from the subsurface and delivered to Meridiani Planum as impact ejecta [3]. The cobbles provide a way to better understand Martian meteorites and the lithologic diversity of Meridiani Planum by examining the various rock types located there. In the summer of 2007, a global dust storm on Mars effectively disabled Opportunity's Miniature Thermal Emission Spectrometer (Mini-TES), which served as the Athena Science Team s primary tool for remotely identifying rocks of interest on a tactical timescale for efficient rover planning. While efforts are ongoing to recover use of the Mini-TES, the team is currently limited to identifying rocks of interest by visual inspection of images returned from Opportunity's Panoramic Camera (Pancam). This study builds off of previous efforts to characterize cobbles at Meridiani Planum using a database of reflectance spectra extracted from Pancam 13-Filter (13F) images [3]. We analyzed the variability of rock spectra in this database and identified physical characteristics of Martian rocks that could potentially account for the observed variance. By understanding such trends, we may be able to distinguish between rock types at Meridiani Planum and regain the capability to remotely identify locally unique rocks.

Mercer, C. M.

Principal Components Analysis of Reflectance Spectra from the Mars Exploration Rover Opportunity

In the summer of 2007 a global dust storm on Mars effectively disabled Opportunity's Miniature Thermal Emission Spectrometer (Mini-TES), the primary instrument used by the Athena Science Team to identify locally unique rocks on the Martian surface. The science team needs another way to distinguish interesting rocks from their surroundings on a tactical timescale. This study was designed to develop the ability to identify locally unique rocks on the Martian surface remotely using the Mars Exploration Rovers' Panoramica Camera (PanCam) instrument. Meridiani bedrock observed by Opportunity is largely characterized by sulfate-rich sandstones and hematite spherules. Additionally, loose fragments of bedrock and "cobbles" of foreign origin collet on the surface, some of which are interpreted as meteorites.

Mercer, C. M.

Using Principal Component Analysis (PCA) to Speed up Radiative Transfer (RT) Computations

Multiple scattering RT calculations time-consuming. Need a speed improvement of about 1000 (for OCO)! Solution: Make use of redundancies in spectra. Correlated-k (Lacis and Wang, Lacis and Oinas, Goody et al, Fu and Liou) Problem: Assume that spectral variation of atmospheric optical properties spatially correlated at all points along optical path. High accuracy (HI) and 2-stream (2S) calculations have high correlation. Single scattering (SS) computations highly scenario-dependent, but not time consuming. Perform SS and 2S calculations at every wavelength. Perform small number of HI computations. Need to compute correction factor B at every wavelength.

data sets

Discerning the Impact of Powder Feedstock Variability on Structure, Property, and Performance of Selective Laser Melted Alloy 718: A Principal Component Analysis (PCA) of Feedstock Variability

Extensive mechanical, chemical and microstructural analyses were conducted on additively manufactured Alloy 718 to characterize powders from multiple vendors to determine the effects of variations observed in the powders had on the consolidated material. With over 190 variables examined, it was necessary to reduce the number of variables and identify the variables and classes of variables that had the greatest effect. Principle Component Analysis (PCA) was used to reduce the number of variable to effectively 12 while identifying several classes of variables as most important.

Ellis, David