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At least 55 records · Page 3

Anomalous snow accumulation over the southeast region of the Greenland ice sheet during 2002-2003 snow season

Our objective is to determine seasonal snow accumulation in the percolation zone of the Greenland ice sheet on the daily-weekly basis over the large scale. Our approach utilizes data from the Greenland Climate Network (GC-Net) and from the SeaWinds Scatterometer on the QuikSCAT satellite (QSCAT) to measure snow accumulation (SA) in the percolation zone of the Greenland ice sheet. GC-Net measurements provide crucial in-situ data to facilitate the interpretation of QSCAT backscatter signature for the development of an algorithm to map SA.

Greenland

Constraining the Composition of the Subcontinental Lithospheric Mantle Beneath the East African Rift: FTIR Analysis of Water in Spinel Peridotite Mantle Xenoliths

The East African Rift System was initiated by the impingement of the Afar mantle plume on the base of the non-cratonic continental lithosphere (assembled during the Pan-African Orogeny), producing over 300,000 kmof continental flood basalts approx.30 Ma ago. The contribution of the subcontinental lithospheric mantle (SCLM) to this voluminous period of volcanism is implied based on basaltic geochemical and isotopic data. However, the role of percolating melts on the SCLM composition is less clear. Metasomatism is capable of hybridizing or overprinting the geochemical signature of the SCLM. In addition, models suggest that adding fluids to lithospheric mantle affects its stability. We investigated the nature of the SCLM using Fourier transform infrared spectrometry (FTIR) to measure water content in mantle xenoliths entrained in young (1 Ma) basaltic lavas from the Ethiopian volcanic province. The mantle xenoliths consist dominantly of spinel lherzolites and are composed of nominally anhydrous minerals, which can contain trace water as H in mineral defects. Eleven mantle xenoliths come from the Injibara-Gojam region and two from the Mega-Sidamo region. Water abundances of olivines in six samples are 1-5ppm H2O while the rest are below the limit of detection (<0.5 ppm H2O); orthopyroxene and clinopyroxene contain 80-238 and 111-340 ppm wt H2O, respectively. Two xenoliths have higher water contents - a websterite (470 ppm) and dunite (229 ppm), consistent with involvement of ascending melts. The low water content of the upper SCLM beneath Ethiopia is as dry as the oceanic mantle except for small domains represented by percolating melts. Consequently, rifting of the East African lithosphere may not have been facilitated by a hydrated upper mantle.

Erickson, Stephanie Gwen

Observations of Pronounced Greenland Ice Sheet Firn Warming and Implications for Runoff Production

Field measurements of shallow borehole temperatures in firn across the northern Greenland ice sheet are collected during May 2013. Sites first measured in 19521955 are revisited, showing long-term trends in firn temperature. Results indicate a pattern of substantial firn warming (up to +5.7C) at midlevel elevations (1400-2500 m) and little temperature change at high elevations (2500 m). We find that latent heat transport into the firn due to meltwater percolation drives the observed warming. Modeling shows that heat is stored at depth for several years, and energy delivered from consecutive melt events accumulates in the firn. The observed warming is likely not yet in equilibrium with recent melt production rates but captures the progression of sites in the percolation facies toward net runoff production.

ice sheet

Understanding Thermal Transport in Polymer –Silver Nanowire Composites

Understanding thermal transport across filler-polymer interfaces and filler-filler contacts within polymer composites is of great importance for better thermal design of the composites that are widely used in high-performance heat exchangers, energy storage devices, and flexible electronics. Over the past several decades, considerable progress has been made in improving the thermal conductivity of polymer composites, but several key questions concerning the influence of interfacial thermal resistance, or Kapitza resistance, still remain. Firstly, the thermal properties of these composites are highly dependent on thermal transport through the filler network and its contacts. For metallic nanofillers, the thermal conductivity is often estimated using the Wiedemann-Franz law based on electrical conductivity; however, it remains a question whether the Wiedemann-Franz law still holds at nanoscale contacts. Through investigation of silver nanowires of varying sizes, we were able to demonstrate that the Lorenz number for silver nanowire increases with decreasing nanowire diameter. Examination of the corresponding electrical and thermal conductivities indicate that these changes are due to that the relative contribution of phonons becomes more significant as a result of elastic stiffening. Furthermore, we show that for silver nanowires, the contact thermal resistance is ~8 times lower than that of multi-walled carbon nanotube (MWCNT) of similar diameters. Additionally, through systematic studies of electrospun polymer-silver nanowire composite nanofibers, we investigated the impact of interface morphology on the thermal conductivity enhancement of the composite system and probed the value of the Kapitza resistance for individual polymer-filler interfaces. For polymer nanofibers containing continuous, single silver nanowires, the thermal conductivity increases linearly with increasing volume fraction of silver, which is consistent with the prediction of percolation theory for samples above the percolation limit. By comparing this linear trend to the measured thermal conductivities of composite nanofibers with more complex structures, we were able to determine the resistance associated with any additional polymer-filler boundaries. In doing so we find that the thermal boundary resistance for polyvinylpyrrolidone (PVP)–silver interfaces is significantly lower than that of comparable polymer-MWCNT composite systems.Together our studies provide new insights into thermal transport in polymer nanocomposites and should help facilitate the design of high performance polymeric thermal interface material.

Thermal transport

Understanding Thermal Transport in Polymer - Silver Nanowire Composites

Understanding thermal transport across filler-polymer interfaces and filler-filler contacts within polymer composites is of great importance for better thermal design of the composites that are widely used in high-performance heat exchangers, energy storage devices, and flexible electronics. Over the past several decades, considerable progress has been made in improving the thermal conductivity of polymer composites, but several key questions concerning the influence of interfacial thermal resistance, or Kapitza resistance, still remain. Firstly, the thermal properties of these composites are highly dependent on thermal transport through the filler network and its contacts. For metallic nanofillers, the thermal conductivity is often estimated using the Wiedemann-Franz law based on electrical conductivity; however, it remains a question whether the Wiedemann-Franz law still holds at nanoscale contacts. Through investigation of silver nanowires of varying sizes, we were able to demonstrate that the Lorenz number for silver nanowire increases with decreasing nanowire diameter. Examination of the corresponding electrical and thermal conductivities indicate that these changes are due to that the relative contribution of phonons becomes more significant as a result of elastic stiffening. Furthermore, we show that for silver nanowires, the contact thermal resistance is ~8 times lower than that of multi-walled carbon nanotube (MWCNT) of similar diameters. Additionally, through systematic studies of electrospun polymer-silver nanowire composite nanofibers, we investigated the impact of interface morphology on the thermal conductivity enhancement of the composite system and probed the value of the Kapitza resistance for individual polymer-filler interfaces. For polymer nanofibers containing continuous, single silver nanowires, the thermal conductivity increases linearly with increasing volume fraction of silver, which is consistent with the prediction of percolation theory for samples above the percolation limit. By comparing this linear trend to the measured thermal conductivities of composite nanofibers with more complex structures, we were able to determine the resistance associated with any additional polymer-filler boundaries. In doing so we find that the thermal boundary resistance for polyvinylpyrrolidone (PVP)–silver interfaces is significantly lower than that of comparable polymer-MWCNT composite systems. Together our studies provide new insights into thermal transport in polymer nanocomposites and should help facilitate the design of high performance polymeric thermal interface material.

Matthew L. Fitzgerald

Constraining Alteration Processes Along the Siccar Point Unconformity in Gale Crater: Results from the Sample Analysis at Mars Instrument

A driving factor for sending the Mars Science Laboratory, Curiosity rover to Gale Crater was the orbital detection of clay minerals in the Glen Torridon (GT) region suggesting a past aqueous environment was habitable and could contain organic evidence of past microbiology. The objective of the Curiosity’s Sample Analysis at Mars (SAM)instrument was to detect organic evidence of past microbiology and volatile bearing mineralogy that would inform if past geochemical conditions would have supported microbiology in the GT region. The Siccar Point unconformity occurs between the underlying GT mudstone and the overlying Stimsons and stone of the Green heugh Pediment has evidence of enhanced alteration in the mudstone just below the contact suggestive of aqueous processes favorable for microbial activity. The origin of the altered material includes subaerial weathering, alteration from fluids moving along unconformity, upward fluid percolation from the mudstone or downward fluid percolation from the Pediment 1,2,3,4,5The objectives of this work were to 1) Utilize the S AM-EGA results to characterize the geochemistry and mineralogy above and below the Siccar Point unconformity through analysis of drilled samples in the3 GT mudstones and an overlying pediment sandstone. and 2) Utilize SAM-EGA results to constrain alteration scenario(s) below the unconformity.

B Sutter

Balancing Manufacturability with Performance: Achieving Extrudable, High Thermal Conductivity, and Dielectrically Robust Thermoplastic Composites

Improved thermal management solutions for electrical insulation systems are a priority for increasing efficiency. Although polymeric electrical insulation is ubiquitous, it generally exhibits low thermal conductivities (κ ; 0.1 – 0.3 W/mK). High κ electrical insulation systems are desirable for several reasons including improved heat wicking. Polymer-ceramic composites offer a viable path towards increasing κ of electrical insulation systems. However, processing-induced anisotropic particle orientation can result in prohibitively high concentrations of high κ particles being required to achieve impactful improvements. This work evaluates the effectiveness of a double percolation approach and its impacts on extruded polymer composite insulation κ using polyimide (PI), polyphenylsulfone (PPSU), and hexagonal boron nitride (hBN). Thermoplastic composite blends of PI/PPSU exhibited a 15% improvement in composite κ at comparable loading levels of hBN relative to mono-polymer material systems. On the other hand, PI/PPSU/hBN composites exhibited lower dielectric strengths than either neat polymer/hBN composite. A trade-off between maximizing material κ and resultant processing and dielectric performances may exist when using a double percolation approach for thermoplastic composites.

Witold K. Fuchs

Enzyme activity in terrestrial soil in relation to exploration of the Martian surface

An exploration was made of enzyme activities in soil, including abundance, persistence and localization of these activities. An attempt was made to develop procedures for the detection and assaying of enzymes in soils suitable for presumptive tests for life in planetary soils. A suitable extraction procedure for soil enzymes was developed and measurements were made of activities in extracts in order to study how urease is complexed in soil organic matter. Mathematical models were developed, based on enzyme action and microbial growth in soil, for rates of oxidation of nitrogen as nitrogen compounds are moved downward in soil by water flow. These biogeochemical models should be applicable to any percolating system, with suitable modification for special features, such as oxygen concetrations, and types of hydrodynamic flow.

Ardakani, M. S.

Application of LANDSAT system for improving methodology for inventory and classification of wetlands

The author has identified the following significant results. Thematic maps were produced for surface water in stratum 46. The presence of large amounts of surface water, particularly during the May period, is readily apparent in the photoreduced thematic maps. Sheet water comprises much of the water detected in the May scene. Spring sheet water tends to be ephemeral and occurs as a result of an ice seal which exists within the underlying soil, temporarily preventing the percolation of water. The abundance of water in the May scene is also a result of unusually heavy precipitation which occurred during the spring and the previous fall. A qualitative analysis of the July map indicates surface water is less abundant than during the previous May; however, surface water present in the July 1975 LANDSAT scene was unusually abundant compared to other midsummer LANDSAT scenes obtained since 1972. This condition was particularly apparent for the drift plain.

Gilmer, D. S.

An integrated approach to the remote sensing of floating ice

Review article on remote sensing applications to glaciology. Ice parameters sensed include: ice cover vs open water, ice thickness, distribution and morphology of ice formations, vertical resolution of ice thickness, ice salinity (percolation and drainage of brine; flushing of ice body with fresh water), first-year ice and multiyear ice, ice growth rate and surface heat flux, divergence of ice packs, snow cover masking ice, behavior of ice shelves, icebergs, lake ice and river ice; time changes. Sensing techniques discussed include: satellite photographic surveys, thermal IR, passive and active microwave studies, microwave radiometry, microwave scatterometry, side-looking radar, and synthetic aperture radar. Remote sensing of large aquatic mammals and operational ice forecasting are also discussed.

Campbell, W. J.

The excess fission xenon problem in lunar samples

This paper presents noble-gas (neon, krypton, and xenon) data obtained in stepwise heating of five lunar breccias: 14063, 14082, 15205, 15405, and 15445. These data are discussed in terms of spallation gas content, cosmic-ray exposure ages, and content of fission xenon. None of these samples is rich in solar-wind gases, and none contains more fission xenon than would be expected for in situ fission of U-238 and Pu-244. The essential features of the excess-fission-xenon phenomenon seen in several Apollo 14 samples are reviewed, as are models which might account for this phenomenon and criteria by which these models may be evaluated. The lack of excess fission xenon in 14063 and 14082 eliminates models relying on microscale xenon redistribution. A model is proposed in which the excess fission xenon originates in local material and percolates through and is adsorbed on regolith material.

Drozd, R. J.

A numerical treatment of melt/solid segregation - Size of the eucrite parent body and stability of the terrestrial low-velocity zone

Crystal sinking to form cumulates and melt percolation toward segregation in magma pools can be treated with modifications of Stokes' and Darcy's laws, respectively. The velocity of crystals and melt depends, among other things, on the force of gravity (g) driving the separations and the cooling time of the environment. The increase of g promotes more efficient differentiation, whereas the increase of cooling rate limits the extent to which crystals and liquid can separate. The rate at which separation occurs is strongly dependent on the proportion of liquid that is present. The observation of cumulates and segregated melts among the eucrite meteorites is used as a basis for calculating the g (and planet size) required to perform these differentiations. The eucrite parent body was probably at least 10-100 km in radius. The earth's low velocity zone (LVZ) is shown to be unstable with respect to draining itself of excess melt if the melt forms an interconnecting network. A geologically persistent LVZ with a homogeneous distribution of melt can be maintained with melt fractions only on the order of 0.1% or less.

Walker, D.

Nonlinear and linear bottom interaction effects in shallow water

The paper examines wave-energy dissipation rates in shallow water calculated from measured wave spectra at different distances from the shore. Different linear and nonlinear transfer and dissipation mechanisms are discussed. The various data sets are interpreted in terms of prevailing mechanisms at the respective sites. The incorporation of different processes in a predictive shallow-water model is outlined. The analysis suggests that bottom motion is primarily responsible for wave-energy dissipation in the Delta Region of the Gulf of Mexico, that friction is mainly responsible for wave-energy dissipation in Marineland, Panama City and Melkbosstrand, and that percolation is probably the dominant mechanism in the JONSWAP area of the North Sea.

Shemdin, O.

Ejecta emplacement of the Martian impact crater Bamburg

The paper examines the ejecta emplacement of the Martian impact crater Bamburg. During ejecta emplacement, secondary crater formation preceeded the deposition of mobile surface flows, which are overrun by more viscous flows characterized by longitudinal grooves and transverse ridges. Many areas of flat terrain on the ejecta deposits may indicate that the sediment-laden melt water percolated out of the volatile-rich ejecta and the crater rim. The number of secondary craters associated with Bamburg is less than one third the value for lunar and Mercurian craters of equivalent size; this is attributed to preferential destruction of ejecta blocks sufficiently large to form secondary craters or to the subsequent burial of such craters.

Mouginis-Mark, P. J.

Effects of granular convection in the response of C I 5380 A to solar luminosity variations

The response of the weak solar photospheric neutral carbon line at 5380.3 A to percolations of photospheric granulation and the five-minute solar oscillations is investigated in order to calibrate the sensitivity of the line to temporal variations in solar luminosity. Line strength variations and simultaneous continuum variations in two granular regions were observed at 30 sec intervals using a 25-cm coude spectrograph. The response of line equivalent width to continuum intensity variations is found to be essentially uniform at time scales ranging from 5 min to 2 hr independently of whether the variations arise from granular convection or velocity field oscillations. The extent to which line strength varies with luminosity (sensitivity) is observed to be significantly smaller than estimates based on models of the perturbed Harvard-Smithsonian Reference Atmosphere of Gingerich et al. (1970), and it is proposed that the structure of the solar granulation is a major factor determining local luminosity variations and line sensitivity.

Lindsey, C. A.

Mechanisms of wave transformation in finite-depth water

Mechanisms of wave transformation in finite-depth water are investigated. The linear mechanisms examined are percolation, bottom motion, shoaling, and refraction. The nonlinear mechanisms examined are wave-wave interaction and bottom friction. New exact computations of the nonlinear transfer for finite-depth waves are presented for some directional wave spectra. These mechanisms are found to explain satisfactorily wave decay observations obtained at several sites with different bottom sediment properties. The decay rates at these sites are found to be dominated by different mechanisms which are determined by the bottom conditions. As an example, detailed calculations are presented for data obtained at the Jonswap site.

Shemdin, O. H.