Engineering Papers⌕ Search

SEARCH · Engineering Papers

Results for “nonequilibrium”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 55 records · Page 3
All sourcesNASA NTRSDOE OSTI
NASA NTRS1973

Chemical nonequilibrium effects on the inviscid flow in the windward plane of symmetry of two simplified shuttle configurations

A theoretical study was made to delineate the effects of thermochemical nonequilibrium in the inviscid flow field of a representative space shuttle orbiter configuration. The study was based on experimental pressure data which was used as an input to a stream tube computer program. The pressure data from two configurations are tabulated. Calculations were restricted to the windward plane of symmetry and the calculations covered an altitude range from 200,000 to 250,000 feet at velocities of 16,000 to 24,000 feet per second respectively. Angles of attack of 20 and 40 degrees were included. The calculations show that the nonequilibrium effects are confined largely to the entropy layer expect at the highest altitude, where significant nonequilibrium effects are observed in the entire inviscid flow field.

Lordi, J. A.↗
NASA NTRS1973

Nonequilibrium chemistry boundary layer integral matrix procedure

The development of an analytic procedure for the calculation of nonequilibrium boundary layer flows over surfaces of arbitrary catalycities is described. An existing equilibrium boundary layer integral matrix code was extended to include nonequilibrium chemistry while retaining all of the general boundary condition features built into the original code. For particular application to the pitch-plane of shuttle type vehicles, an approximate procedure was developed to estimate the nonequilibrium and nonisentropic state at the edge of the boundary layer.

Tong, H.↗
NASA NTRS1975

Estimates of nonequilibrium radiation for Venus entry

The present investigation is an analysis of the radiation from the chemical nonequilibrium region in the shock layer about a vehicle during Venus entry. The radiation and the flow were assumed to be uncoupled. An inviscid, nonequilibrium flowfield was calculated and an effective electronic temperature was determined for the predominant radiating species. Species concentrations and electronic temperature were then input into a radiation transport code to calculate heating rates. The present results confirm earlier investigations which indicate that the radiation should be calculated using electronic temperatures for the radiating species. These temperatures are not related in a simple way to the local translational temperature. For the described mission, the nonequilibrium radiative heating rate is approximately twice the corresponding equilibrium value at peak heating.

Grose, W. L.↗
NASA NTRS1975

Computation of nonequilibrium three-dimensional inviscid flow over blunt-nosed bodies flying at supersonic speeds

A computer code based on the method of characteristics is described and applied to the study of two- and three-dimensional chemical nonequilibrium flow over sharp and blunt-nosed bodies. Nonequilibrium flow over a wedge is used to show the approach to equilibrium flow, and to demonstrate the nature of the reaction zone behind the bow shock wave. The structure and development of a blunt-body entropy layer in nonequilibrium flow is examined for a blunt cone at zero incidence. Three-dimensional computations for the space shuttle body at 30 deg angle of attack are presented. A nondimensional scaling parameter, the Damkoehler number, which is the ratio of flow time to chemical reaction time, is calculated and its significance discussed.

Rakich, J. V.↗
NASA NTRS1978

Effects of precursor heating on chemical and radiative nonequilibrium viscous flow around a Jovian entry body

The influence of precursor heating on viscous chemical nonequilibrium radiating flow around a Jovian entry body is investigated. Results obtained for a 45 deg hyperboloid blunt body entering the Jupiter's nominal atmosphere at zero angle of attack indicate that the nonequilibrium radiative heating rate is significantly higher than the corresponding equilibrium heating. The precursors heating, in general, increases the radiative and convective heating to the body and this increase is slightly higher for the nonequilibrium conditions.

Tiwari, S. N.↗
NASA NTRS1978

Effects of precursor heating on chemical and radiation nonequilibrium viscous flow around a Jovian entry body

The influence of precursor heating on viscous chemical nonequilibrium radiating flow around a Jovian entry body is investigated. Results obtained for a 45-degree hyperboloid blunt body entering Jupiter's nominal atmosphere at zero angle of attack indicate that the nonequilibrium radiative heating rate is significantly higher than the corresponding equilibrium heating. The precursor heating, in general, increases the radiative and convective heating to the body, and this increase is slightly higher for the nonequilibrium conditions.

Tiwari, S. N.↗
NASA NTRS1983

Chemical nonequilibrium effects on flowfields for aeroassist orbital transfer vehicles

Acceptable altitude and velocity ranges for the perigee of aeroassist orbital transfer vehicles (AOTV) have been determined for various values of ballistic coefficient and lift-to-drag ratio. The chemical nonequilibrium effect on the flowfield of a simple but representatively high-drag, blunt configuration was investigated for these perigee conditions, ranging from 73 to 90 km in altitude and 8 to 9.3 km/s in velocity. The analysis was performed using a two-dimensional viscous-shock-layer code which had previously demonstrated good success in predicting nonequilibrium heating on the Space Shuttle. The results indicate lower ratio of nonequilibrium/equilibrium heating for the present AOTV perigee conditions than for the Shuttle flight conditions, due to higher velocity. The trend for the degree of nonequilibrium with the effect of varying wall catalycity and configuration was determined over the altitude range. Some implications to future design consideration are stated.

Shinn, J. L.↗
NASA NTRS1983

The hydrodynamics of magnetic nonequilibrium

Because the dynamical nonequilibrium of closely packed twisted flux tubes is essentially the problem of two-dimensional MHD turbulence, the extensive literature on two-dimensional turbulence represents the hydrodynamics of magnetic nonequilibrium. Many features of the turbulence can conversely be understood as a consequence of the dynamical nonequilibrium. Attention is presently given to the dynamics of the strong fluid jets, issuing from reconnection points, that are exhibited by numerical simulations of two-dimensional turbulence. Simple examples are given which show that the uniformity of jet width observed is a consequence of the form of the pressure of the magnetic fields between which the jets are confined. The general hydrodynamics of a layer of fluid confined by steady pressures is reducible to a quadrature, so that a variety of effects may be considered, including gravitation. The dissipation of the solar corona is discussed.

Parker, E. N.↗
NASA NTRS1984

Calculation of nonequilibrium radiation in the flight regimes of aeroassisted orbital transfer vehicles

A computer code has been developed that calculates radiative properties of nonequilibrium air in the low-density regimes expected during the flight of aeroassisted, orbital transfer vehicles. From the given nonequilibrium thermodynamic state variables, the code calculates number densities of internal states and the accompanying emission and absorption characteristics. In addition, the code calculates the number density of the hypothetical gas in radiative equilibrium that produces the same radiation emission as the given nonequilibrium gas. Sample results are shown to demonstrate how the code predicts the nonlinear variation of radiation with density at low densities.

Park, C.↗
NASA NTRS1989

On the computation of shock shapes in nonequilibrium hypersonic flows

Several models using different descriptions of high temperature air are used to compute the bow shock shapes on experimental model configurations. The test conditions result in nonequilibrium chemical reaction and thermal excitation of the gas which has a first-order effect on the shock shapes. The computed results are compared to experiment and demonstrate that the model using seven chemical species and six temperatures predicts the experimental shock shapes very well. The other gas models, including perfect gas, equilibrium gas and one-temperature chemical nonequilibrium models are less accurate. The results illustrate the necessity of including both thermal and chemical nonequilibrium in the description of the gas. The use of these experimental data makes it possible to verify aspects of current and future chemically reacting flow algorithms.

Candler, Graham↗
NASA NTRS1989

Rotational and vibrational nonequilibrium effects in rarefied, hypersonic flow

Results are reported for an investigation into the methods by which energy transfer is calculated in the Direct Simulation Monte Carlo method. Description is made of a recently developed energy exchange model that deals with the translational and rotational modes. A new model for simulating the transfer of energy between the translational and vibrational modes is also explained. This model allows the vibrational relaxation time to follow the temperature dependence predicted by the Landau-Teller theory at moderate temperatures. For temperatures in excess of about 8000K the vibrational model is extended to include an empirical result for the relaxation time. The effect of introducing these temperature dependent collision numbers into the DSMC technique is assessed by making calculations representative of the stagnation streamline of a hypersonic space vehicle. Both thermal and chemical nonequilibrium effects are included while the flow conditions have been chosen such that ionization and radiation may be neglected. The introduction of these new models is found to significantly affect the degree of thermal nonequilibrium observed in the flowfield. Larger, and more widely ranging, differences in the results obtained with the different energy exchange probabilities are found when a significant amount of internal energy is included in the calculation of chemical nonequilibrium.

Boyd, Iain D.↗
NASA NTRS1990

Model gases for the detailed study of microscopic chemical nonequilibrium in diatomic gas flows

It is shown that chlorine (Cl2) and iodine (I2) are suitable model diatomic gases to use in theoretical studies of chemical nonequilibrium that account for rotational and vibrational as well as electronic processes in a gas. Because of the low temperature at which significant dissociation can be achieved in iodine, it is a particularly attractive candidate for the study of relatively low temperature chemically reacting flows, permitting detailed knowledge of the nonequilibrium populations of translational, rotational, vibrational and electronic energy levels. A preliminary investigation indicates that a useful iodine flow facility can be constructed and that diagnostic techniques are available to validate in detail prediction techniques for nonequilibrium flows.

Kunc, Joseph A.↗
NASA NTRS1990

Computation of thermochemical nonequilibrium flows around a simple and a double ellipse

The nonequilibrium viscous reactive flows over a simple and a double ellipse at a 30 degree angle of attack were computed. The geometry and the free stream conditions are given by INRIA/GAMNI/SMAI workshop test cases 6.2-2 and 6.2-4. The governing Navier-Stokes equations coupled with thermochemical nonequilibrium processes are solved numerically using a fully coupled, implicit, finite volume technique with a dynamically adaptive grid. The nonequilibrium gas model and the numerical method used in the calculations are briefly described.

Gokcen, Tahir↗
NASA NTRS1991

Nonequilibrium Phase Chemistry in High Temperature Structure Alloys

Titanium and nickel aluminides of nonequilibrium microstructures and in thin gauge thickness were identified, characterized and produced for potential high temperature applications. A high rate sputter deposition technique for rapid surveillance of the microstructures and nonequilibrium phase is demonstrated. Alloys with specific compositions were synthesized with extended solid solutions, stable dispersoids, and specific phase boundaries associated with different heat treatments. Phase stability and mechanical behavior of these nonequilibrium alloys were investigated and compared.

Wang, R.↗
NASA NTRS1991

Aeroacoustic and aerodynamic applications of the theory of nonequilibrium thermodynamics

Recent developments in the field of nonequilibrium thermodynamics associated with viscous flows are examined and related to developments to the understanding of specific phenomena in aerodynamics and aeroacoustics. A key element of the nonequilibrium theory is the principle of minimum entropy production rate for steady dissipative processes near equilibrium, and variational calculus is used to apply this principle to several examples of viscous flow. A review of nonequilibrium thermodynamics and its role in fluid motion are presented. Several formulations are presented of the local entropy production rate and the local energy dissipation rate, two quantities that are of central importance to the theory. These expressions and the principle of minimum entropy production rate for steady viscous flows are used to identify parallel-wall channel flow and irrotational flow as having minimally dissipative velocity distributions. Features of irrotational, steady, viscous flow near an airfoil, such as the effect of trailing-edge radius on circulation, are also found to be compatible with the minimum principle. Finally, the minimum principle is used to interpret the stability of infinitesimal and finite amplitude disturbances in an initially laminar, parallel shear flow, with results that are consistent with experiment and linearized hydrodynamic stability theory. These results suggest that a thermodynamic approach may be useful in unifying the understanding of many diverse phenomena in aerodynamics and aeroacoustics.

Horne, W. Clifton↗
NASA NTRS1989

Nonequilibrium hypersonic aerothermodynamics

Nonequilibrium phenomena in hypersonic flows are examined on the basis of theoretical models and selected experimental data, in an introduction intended for second-year graduate students of aerospace engineering. Chapters are devoted to the physical nature of gas atoms and molecules, transitions of internal states, the formulation of the master equation of aerothermodynamics, the conservation equations, chemical reactions in CFD, the behavior of air flows in nonequilibrium, experimental aspects of nonequilibrium flow, a review of experimental results, and gas-solid interaction. Diagrams, graphs, and tables of numerical data are provided.

Park, Chul↗
NASA NTRS1991

A numerical study of shock wave/boundary layer interaction in nonequilibrium chemically reacting air - The effects of catalytic walls

This paper presents a numerical study that investigate the effects of nonequilibrium chemistry, and in particular, wall catalycity on the separated flow region generated by an oblique shock wave impinging upon a flat plate boundary layer. To obtain a solution to this problem, the full two dimensional Navier-Stokes equations were solved using MacCormack's predictor-corrector time dependent technique on a rectangular grid. Nonequilibrium chemistry was included by utilizing the 5 species, 17 reaction modified Dunn-Kang chemical kinetics model. Separate results were obtained for: calorically perfect, chemically reacting - noncatalytic wall, and chemically reacting - fully catalytic wall cases, for a given set of flow conditions. A direct comparison of all three cases revealed a slight decrease in the peak heat transfer for the noncatalytic wall case, as compared to the calorically perfect case. On the other hand, the fully catalytic wall case had a tremendous increase in the peak surface heat transfer. It is concluded that, for the particular conditons treated here (nearly frozen flow in the free stream), the effects of the nonequilibrium chemically reacting flow on the shock-wave/boundary-layer interaction depend critically on the catalycity of the wall, having virtually no effect for the case of a noncatalytic wall, and exerting a tremendous effect for a fully catalytic wall.

Grumet, Adam A.↗
NASA NTRS1991

Stagnation point nonequilibrium radiative heating and the influence of energy exchange models

A nonequilibrium radiative heating prediction method has been used to evaluate several energy exchange models used in nonequilibrium computational fluid dynamics methods. The radiative heating measurements from the FIRE II flight experiment supply an experimental benchmark against which different formulations for these exchange models can be judged. The models which predict the lowest radiative heating are found to give the best agreement with the flight data. Examination of the spectral distribution of radiation indicates that despite close agreement of the total radiation, many of the models examined predict excessive molecular radiation. It is suggested that a study of the nonequilibrium chemical kinetics may lead to a correction for this problem.

Hartung, Lin C.↗