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At least 55 records · Page 3

Dirtier Air from a Weaker Monsoon

The level of air pollution in China has much increased in the past decades, causing serious health problems. Among the main pollutants are aerosols, also known as particulate matter: tiny, invisible particles that are suspended in the air. These particles contribute substantially to premature mortality associated with cardiopulmonary diseases and lung cancer1. The increase of the aerosol level in China has been commonly attributed to the fast rise in pollutant emissions from the rapid economic development in the region. However, writing in Geophysical Research Letters, Jianlei Zhu and colleagues2 tell a different side of the story: using a chemical transport model and observation data, they show that the decadal scale weakening of the East Asian summer monsoon has also contributed to the increase of aerosol concentrations in China. The life cycle of atmospheric aerosols starts with its emission or formation in the atmosphere. Some aerosol components such as dust, soot and sea salt are emitted directly as particles to the atmosphere, but others are formed there by way of photochemical reactions. For example, sulphate and nitrate aerosols are produced from their respective precursor gases, sulphur dioxide and nitrogen oxides. Aerosol particles can be transported away from their source locations by winds or vertical motion of the air. Eventually, they are removed from the atmosphere by means of dry deposition and wet scavenging by precipitation. Measurements generally show that aerosol concentrations over Asia are lowest during the summer monsoon season3, because intense rainfall efficiently removes them from the air. The East Asian summer monsoon extends over subtropics and mid-latitudes. Its rainfall tends to concentrate in rain belts that stretch out for many thousands of kilometres and affect China, Korea, Japan and the surrounding area. Observations suggest that the East Asian summer monsoon circulation and precipitation have been in decline since the 1970s4. In particular, a weaker East Asian summer monsoon is characterized by weaker southerly or southwesterly winds, a deficit in rainfall over northern China and larger rainfalls in southern China. By contrast, when the East Asian summer monsoon is strong, the southerly winds and strong rainfalls extend to northern China. The decadal scale decline in the strength of the East Asian summer monsoon since the 1970s would imply an increase in aerosol concentrations in northern China, north of 28deg N, and a decrease in southern China if emissions were kept the same. One obvious reason for this direction of aerosol change is that the reduction of monsoon rainfall in northern China would cause less wet scavenging of aerosols by precipitation. Zhu et al.2 investigated this relationship between aerosol concentrations and the strength of the East Asian summer monsoon and showed that the two parameters have strong negative correlations: the summer aerosol concentrations near the surface over eastern China.

Chin, Mian↗

Mars brine formation experiment

Evaporites, particularly carbonates, nitrates, and sulfates, may be major sinks of volatiles scavenged from the martian atmosphere. Mars is thought to have once had a denser, warmer atmosphere that permitted the presence of liquid surface water. The conversion of atmospheric CO2 into carbonate is hypothesized to have degraded the martian climate to its present state of a generally subfreezing, desiccated desert. The rate for such a conversion under martian conditions is poorly known, so the time scale of climate degradation by this process cannot be easily evaluated. If some models are correct, carbonate formation may have been fast at geological time scales. The experiments of Booth and Kieffer also imply fast (10(exp 6) - 10(exp 7) yr) removal of the missing CO2 inventory, estimated to be 1 - 5 bar, by means of carbonate formation. The timing of formation of many of the fluvial features observed on Mars is, in large part, dependent on when and how fast the atmosphere changed. A knowledge of the rate at which carbonates and nitrates formed is also essential for assessing the probability that life, or its chemical precursors, could have developed on Mars. No previous experiments have quantitatively evaluated the rate of solution for a suite of mobile anions and cations from unaltered minerals and atmospheric gases into liquid water under Mars-like conditions. Such experiments are the focus of this task.

Moore, Jeffrey M.↗

From Earth to Space: Application of Biological Treatment for the Removal of Ammonia from Water

Managing ammonia is often a challenge in both drinking water and wastewater treatment facilities. Ammonia is unregulated in drinking water, but its presence may result in numerous water quality issues in the distribution system such as loss of residual disinfectant, nitrification, and corrosion. Ammonia concentrations need to be managed in wastewater effluent to sustain the health of receiving water bodies. Biological treatment involves the microbiological oxidation of ammonia to nitrate through a two‐step process. While nitrification is common in the environment, and nitrifying bacteria can grow rapidly on filtration media, appropriate conditions, such as the presence of dissolved oxygen and required nutrients, need to be established. This presentation will highlight results from two ongoing research programs - one at NASA's Johnson Space Center, and the other at a drinking water facility in California. Both programs are designed to demonstrate nitrification through biological treatment. The objective of NASA's research is to be able to recycle wastewater to potable water for spaceflight mission. To this end, a biological water processor (BWP) has been integrated with a forward osmosis secondary treatment system (FOST). Bacteria mineralize organic carbon to carbon dioxide as well as ammonia‐nitrogen present in the wastewater to nitrogen gas, through a combination of nitrification and denitrification. The effluent from the BWP system is low in organic contaminants, but high in total dissolved solids. The FOST system, integrated downstream of the BWP, removes dissolved solids through a combination of concentration‐driven forward osmosis and pressure driven reverse osmosis. The integrated system testing planned for this year is expected to produce water that requires only a polishing step to meet potable water requirements for spaceflight. The pilot study in California is being conducted on Golden State Water Company's Yukon wellsthat have hydrogen sulfide odor, color, total organic carbon, bromide, iron and manganese in addition to ammonia. A treatment evaluation, conducted in 2011, recommended the testing of biological oxidation filtration for the removal of ammonia and production of biologically stable water. A 8‐month pilot testing program was conducted to develop and optimize key design and operational variables. Steadystate operational data was collected to demonstrate long‐term performance and inform California Department of Public Health permitting of the full‐scale process. As ammonia continues to present challenges to water and wastewater systems, innovative strategies such as biological treatment can be applied to successfully manage it. This presentation will discuss application of cutting‐age research being conducted by NASA that will bridge existing information gaps, and benefit municipal utilities.

Ghosh, Amlan↗

From Earth to Space: Application of Biological Treatment for the Removal of Ammonia from Water

Managing ammonia is often a challenge in both drinking water and wastewater treatment facilities. Ammonia is unregulated in drinking water, but its presence may result in numerous water quality issues in the distribution system such as loss of residual disinfectant, nitrification, and corrosion. Ammonia concentrations need to be managed in wastewater effluent to sustain the health of receiving water bodies. Biological treatment involves the microbiological oxidation of ammonia to nitrate through a two‐step process. While nitrification is common in the environment, and nitrifying bacteria can grow rapidly on filtration media, appropriate conditions, such as the presence of dissolved oxygen and required nutrients, need to be established. This presentation will highlight results from two ongoing research programs - one at NASA's Johnson Space Center, and the other at a drinking water facility in California. Both programs are designed to demonstrate nitrification through biological treatment. The objective of NASA's research is to be able to recycle wastewater to potable water for spaceflight missions. To this end, a biological water processor (BWP) has been integrated with a forward osmosis secondary treatment system (FOST). Bacteria mineralize organic carbon to carbon dioxide as well as ammonia‐nitrogen present in the wastewater to nitrogen gas, through a combination of nitrification and denitrification. The effluent from the BWP system is low in organic contaminants, but high in total dissolved solids. The FOST system, integrated downstream of the BWP, removes dissolved solids through a combination of concentration‐driven forward osmosis and pressure driven reverse osmosis. The integrated system testing planned for this year is expected to produce water that requires only a polishing step to meet potable water requirements for spaceflight. The pilot study in California is being conducted on Golden State Water Company's Yukon wells that have hydrogen sulfide odor, color, total organic carbon, bromide, iron and manganese in addition to ammonia. A treatment evaluation, conducted in 2011, recommended the testing of biological oxidation filtration for the removal of ammonia and production of biologically stable water. An 8‐month pilot testing program was conducted to develop and optimize key design and operational variables. Steadystate operational data was collected to demonstrate long‐term performance and inform California Department of Public Health permitting of the full‐scale process. As ammonia continues to present challenges to water and wastewater systems, innovative strategies such as biological treatment can be applied to successfully manage it. This presentation will discuss application of cutting‐age research being conducted by NASA that will bridge existing information gaps, and benefit municipal utilities.

Pickering, Karen↗

Natural hydrocarbons, urbanization, and urban ozone

The combined effects of emission control and urbanization, with its concomitant intensification of the urban heat island, on urban ozone concentrations are studied. The effect of temperature on ozone is considered, and attention is given to the temperature effect on ozone photochemistry. Model calculations suggest that ozone concentration enhancements are caused by the effect of temperature on the atmospheric chemistry of peroxyacetyl nitrate, as well as the temperature dependence of natural and anthropogenic hydrocarbon emissions. It is pointed out that, because of the sensitivity of urban ozone to local climatic conditions and the ability of trees to moderate summertime temperatures, the inadvertent removal of trees from urbanization can have an adverse effect on urban ozone concentration, while a temperature increase in the urban heat island caused by urbanization can essentially cancel out the ozone-reducing benefits obtained from a 50-percent reduction in anthropogenic hydrocarbon emissions.

Cardelino, C. A.↗

Single-Wall Carbon Nanotube Production by the Arc Process: A Parametric Study

Single wall carbon nanotubes are produced using the arc discharge process. Graphite anodes are filled with a mixture of nickel and yttrium metallic powders, then vaporized by creating a high current arc. By varying the current, gap distance, and ambient pressure it is shown that the best yield of single wall carbon nanotubes is obtained within a narrow range of conditions. The relative yield and purity of the product are indicated semi-quantitatively from scanning electric microscopy (SEM) and thermogravimetric analysis (TGA). Two types of anodes have been investigated. The first is hollow and filled with a powder mixture of graphite, nickel and yttrium. The second is filled with a paste made of a mixture of metal nitrates, graphite powder and carbon adhesive, then reduced in an argon atmosphere at high temperature. Product purity and yield will be compared for the two types of anodes. The graphite in the anodes may have hydrogen attached in the pores. To remove this impurity anodes have been baked up to 1400 - 1500 C. The effect of baking the anodes on impurities in the product will be given.

Scott, Carl D.↗

Tropospheric Trace Gas Interactions with Aerosols

Tropospheric aerosols are of considerable environmental importance. They modify the radiative budget of Earth by scattering and absorbing radiation, and by providing nuclei for cloud formation. Additionally, they provide surfaces for heterogeneous and multiphase reactions that affect tropospheric chemistry. For example, Dentener and Crutzen (1993) showed that reactions of N2O5 and NO3 with sulfate aerosols may significantly alter the tropospheric concentrations of NO(x), O3, and OH by converting NOx to HNO3 which is rapidly removed by precipitation. Zhang et al. (1994) assumed these same reactions would occur on dust aerosols and showed that dust outbreaks may reduce NO(x) levels by up to 50%. Dentener et al. (1996) studied the possible effect of reactions on dust on sulfate, nitrate, and O3 concentration. Heterogeneous and multiphase reactions on aerosols may also perturb the sulfur cycle the chlorine cycle and the bromine cycle. Because these reactions can release free chlorine and free bromine they might lead to the destruction of ozone in the marine boundary layer that may be important to include in models of tropospheric chemistry. The goal of our proposed work is to examine the role of heterogeneous and multiphase reactions in the tropospheric cycles of reactive nitrogen and sulfur.

Penner, Joyce E.↗

Effects of simulated microgravity on arterial nitric oxide synthase and nitrate and nitrite content

The aim of the present work was to investigate the alterations in nitric oxide synthase (NOS) expression and nitrate and nitrite (NOx) content of different arteries from simulated microgravity rats. Male Wistar rats were randomly assigned to either a control group or simulated microgravity group. For simulating microgravity, animals were subjected to hindlimb unweighting (HU) for 20 days. Different arterial tissues were removed for determination of NOS expression and NOx. Western blotting was used to measure endothelial NOS (eNOS) and inducible NOS (iNOS) protein content. Total concentrations of NOx, stable metabolites of nitric oxide, were determined by the chemiluminescence method. Compared with controls, isolated vessels from simulated microgravity rats showed a significant increase in both eNOS and iNOS expression in carotid arteries and thoracic aorta and a significant decrease in eNOS and iNOS expression of mesenteric arteries. The eNOS and iNOS content of cerebral arteries, as well as that of femoral arteries, showed no differences between the two groups. Concerning NOx, vessels from HU rats showed an increase in cerebral arteries, a decrease in mesenteric arteries, and no change in carotid artery, femoral artery and thoracic aorta. These data indicated that there were differential alterations in NOS expression and NOx of different arteries after hindlimb unweighting. We suggest that these changes might represent both localized adaptations to differential body fluid redistribution and other factors independent of hemodynamic shifts during simulated microgravity.

Non-NASA Center↗

Cyclic variations in nitrogen uptake rate of soybean plants: effects of external nitrate concentration

Net uptake of NO3- by non-nodulated soybean plants [Glycine max (L.) Merr. cv. Ransom] growing in flowing hydroponic cultures containing 0.5, 1.0 and 10.0 mol m-3 NO3- was measured daily during a 24-d period of vegetative development to determine if amplitude of maximum and minimum rates of net NO3- uptake are responsive to external concentrations of NO3-. Removal of NO3- from the replenished solutions during each 24-h period was determined by ion chromatography. Neither dry matter accumulation nor the periodicity of oscillations in net uptake rate was altered by the external NO3- concentrations. The maxima of the oscillations in net uptake rate, however, increased nearly 3-fold in response to external NO3- concentrations. The maxima and minima, respectively, changed from 4.0 and 0.6 mmol NO3- per gram root dry weight per day at an external solution level of 0.5 mol m-3 NO3- to 15.2 and -2.7 mmol NO3- per gram root dry weight per day at an external solution level of 10.0 mol m-3 NO3-. The negative values for minimum net uptake rate from 10.0 mol m-3 NO3- solutions show that net efflux was occurring and indicate that the magnitude of the efflux component of net uptake was responsive to external concentration of NO3-.

Non-NASA Center↗

Increase in nitrate uptake by soybean plants during interruption of the dark period with low intensity light

Diurnal patterns of net NO3- uptake by nonnodulated soybean [Glycine max (L.) Merr. cv. Ransom] plants growing in flowing hydroponic culture at 26 and 16 degrees C root temperatures were measured at hourly intervals during alternate days of a 12-day growth period. Ion chromatography was used to determine removal of NO3- from the culture solution. Day and night periods of 9 and 15 h were used during growth. The night period included two 6-h dark periods and an intervening 3-h period of night interruption by incandescent lamps to effect a long-day photoperiod and repress floral initiation. At both root temperatures, the average specific rates of NO3- uptake were twice as great during the night interruption period as during the day period; they were greater during the day period than during the dark periods; and they were greater during the dark period immediately following the day period than during the later dark period that followed the night interruption. While these average patterns were repetitious among days, measured rates of uptake varied hourly and included intervals of net efflux scattered through the day period and more frequently through the 2 dark periods. Root temperature did not affect the average daily specific rates of uptake or the qualitative relationships among day, dark and night interruption periods of the diurnal cycle.

Non-NASA Center↗

Exploring the limits of crop productivity: A model to evaluate progress

The goal was to determine the limits of crop productivity when all environmental constraints were removed. Researchers define productivity as food output per unit of input. Researchers evaluated cultivars of wheat with reduced leaf size and number to decrease the leaf area index at high plant densities. These cultivars may also have an improved harvest index. Hydroponic studies indicate that 1 mM nitrate in solution is adequate to support maximum growth in these systems, provided iron nutrition is adequate. Wheat does not accumulate nitrate in leaves even when the solution nitrate concentration is 15 mM. Long-term photosynthetic efficiency (g mol (exp -1) of photons) and harvest index were not altered by photoperiod (16, 20, or 24 hours). Wheat does not need, nor benefit from, a diurnal dark period.

Bugbee, Bruce↗

Ozone and Water Vapor Measurements by Raman Lidar in the Planetary Boundary Layer: Error Sources and Field Measurements

Why do we need time series of ozone and water vapor profiles at low altitude? The degradation of air quality is a very serious environmental problem that affects urban and industrial areas worldwide. Air pollution injures human health and ecosystems, diminishes crop yield, and spoils patrimony and materials. The phenomena involved in air pollution are very complex. Once emitted into the atmosphere, (primary) pollutants are transported, dispersed, transformed by gas/solid phase change and chemical reaction, and finally removed by dry and wet deposition. Most challenging is the fact that the health and environmental impacts of secondary pollutants (formed in the atmosphere) are frequently more severe than those of their precursors (primary pollutants). This is the case of ozone and other photochemical pollutants, such as peroxyacetil nitrate (PAN) and secondary particles, produced in the atmosphere by the photo-oxidation volatile organic compounds (VOC) catalyzed by nitrogen oxides (NO(sub x)). Photochemical air pollution is a complex science because of the non-linearity of its response to changes in primary emission.

Lazzarotto, Benoit↗

A simulation analysis of the fate of phytoplankton within the mid-Atlantic bight

A time-dependent, three-dimensional simulation model of wind-induced changes of the circulation field, of light and nutrient regulation of photosynthesis, of vertical mixing as well as algal sinking, and of herbivore grazing stress, is used to analyze the seasonal production, consumption, and transport of the spring bloom within the mid-Atlantic Bight. The particular case (c) of a 58-day period in February-April 1979, simulated primary production, based on both nitrate and recycled nitrogen, with a mean of 0.62 g C sq m/day over the whole model domain, and an export at the shelf-break off Long Island of 2.60 g ch1 sq m/day within the lower third of the water column. About 57% of the carbon fixation was removed by herbivores, with 21% lost as export, either downshelf or offshore to slope waters, after the first 58 days of the spring bloom. Extension of the model for another 22 days of case (c) increased the mean export to 27%, while variation of the model's parameters in 8 other cases led to a range in export from 8% to 38% of the average primary production. Spatial and temporal variations of the simulated albal biomass, left behind in the shelf water column, reproduced chlorophyll fields sensed by satellite, shipboard, and in situ instruments.

Walsh, J. J.↗

Annular denuders for use in global climate and stratospheric measurements of acidic gases and particles

Measurements of acidic and basic gases that coexist with fine particle (less than 2.5 micron) may be useful for determining the impact of these species on global climate changes and determining species that influence stratospheric ozone levels. Annular denuders are well suited for this purpose. A new concentric annular denuder system, consisting of a three channel denuder, a Teflon coated cyclone preseparator, and a multistage filter pack was developed, evaluated, and shown to provide reliable atmospheric measurements of SO2, HNO2, HNO3, NH3, SO4(=), NH4(+), NO3(-), and H(+). For example, the precision of the annular denuder for the ambient measurements of HNO3 and nitrates at concentrations between 0.1 to 3 microgram/cu m was + or - 12 and 16 pct., respectively. The 120 x 25 mm three channel denuder is encased in a stainless steel sheath and has annular spaces that are 1 mm wide. This design was shown to have nearly identical capacity for removal of SO2 as conventional 210 x 25 mm single channel denuder configurations. The cyclone preseparator was designed and tested to have a D sub 50 cutoff diameter of 2.5 micron and minimal retention of HNO3.

Stevens, Robert K.↗

Infrared spectrum of Io, 2.8-5.2 microns

The reflectance spectrum of Io is presented from 2.8 to 5.2 microns demonstrating the full extent of the broad and deep spectral absorption between 3.5 and 4.8 microns. Laboratory spectra of nitrates and carbonates diluted with sulfur do not satisfactorily reproduce the Io spectrum, but new information based on recently discovered volcanic activity on the satellite lead to consideration of other classes of compounds reported by Fanale et al. (1979). It is concluded that the variability of the supply of condensible SO2 gas to the surface of Io, its removal by sublimination, and the temporal variations in the strength of the SO2 band may provide an index of volcanic activity on Io that can be monitored from the earth.

Cruikshank, D. P.↗

Directional and Spectral Irradiance in Ocean Models: Effects on Simulated Global Phytoplankton, Nutrients, and Primary Production

The importance of including directional and spectral light in simulations of ocean radiative transfer was investigated using a coupled biogeochemical-circulation-radiative model of the global oceans. The effort focused on phytoplankton abundances, nutrient concentrations and vertically-integrated net primary production. The importance was approached by sequentially removing directional (i.e., direct vs. diffuse) and spectral irradiance and comparing results of the above variables to a fully directionally and spectrally-resolved model. In each case the total irradiance was kept constant; it was only the pathways and spectral nature that were changed. Assuming all irradiance was diffuse had negligible effect on global ocean primary production. Global nitrate and total chlorophyll concentrations declined by about 20% each. The largest changes occurred in the tropics and sub-tropics rather than the high latitudes, where most of the irradiance is already diffuse. Disregarding spectral irradiance had effects that depended upon the choice of attenuation wavelength. The wavelength closest to the spectrally-resolved model, 500 nm, produced lower nitrate (19%) and chlorophyll (8%) and higher primary production (2%) than the spectral model. Phytoplankton relative abundances were very sensitive to the choice of non-spectral wavelength transmittance. The combined effects of neglecting both directional and spectral irradiance exacerbated the differences, despite using attenuation at 500 nm. Global nitrate decreased 33% and chlorophyll decreased 24%. Changes in phytoplankton community structure were considerable, representing a change from chlorophytes to cyanobacteria and coccolithophores. This suggested a shift in community function, from light-limitation to nutrient limitation: lower demands for nutrients from cyanobacteria and coccolithophores favored them over the more nutrient-demanding chlorophytes. Although diatoms have the highest nutrient demands in the model, their relative abundances were generally unaffected because they only prosper in nutrient-rich regions, such as the high latitudes and upwelling regions, which showed the fewest effects from the changes in radiative simulations. The results showed that including directional and spectral irradiance when simulating the ocean light field can be important for ocean biology, but the magnitude varies with variables and regions. The quantitative results are intended to assist ocean modelers when considering improved irradiance representations relative to other processes or variables associated with the issues of interest.

Phytoplankton↗

Measurement report: Closure Analysis of Aerosol–cloud Composition in Tropical Maritime Warm Convection

Cloud droplet chemical composition is a key observable property that can aid understanding of how aerosols and clouds interact. As part of the Clouds, Aerosols and Monsoon Processes – Philippines Experiment (CAMP2Ex), three case studies were analyzed involving collocated airborne sampling of relevant clear and cloudy air masses associated with maritime warm convection. Two of the cases represented a polluted marine background, with signatures of transported East Asian regional pollution, aged over water for several days, while the third case comprised a major smoke transport event from Kalimantan fires. Sea salt was a dominant component of cloud droplet composition, in spite of fine particulate enhancement from regional anthropogenic sources. Furthermore, the proportion of sea salt was enhanced relative to sulfate in rainwater and may indicate both a propensity for sea salt to aid warm rain production and an increased collection efficiency of large sea salt particles by rain in subsaturated environments. Amongst cases, as precipitation became more significant, so too did the variability in the sea salt to (non-sea salt) sulfate ratio. Across cases, nitrate and ammonium were fractionally greater in cloud water than fine-mode aerosol particles; however, a strong covariability in cloud water nitrate and sea salt was suggestive of prior uptake of nitrate on large salt particles. A mass-based closure analysis of non-sea salt sulfate compared the cloud water air-equivalent mass concentration to the concentration of aerosol particles serving as cloud condensation nuclei for droplet activation. While sulfate found in cloud was generally constrained by the sub-cloud aerosol concentration, there was significant intra-cloud variability that was attributed to entrainment – causing evaporation of sulfate-containing droplets –and losses due to precipitation. In addition, precipitation tended to promote mesoscale variability in the sub-cloud aerosol through a combination of removal, convective downdrafts, and dynamically driven convergence. Physical mechanisms exerted such strong control over the cloud water compositional budget that it was not possible to isolate any signature of chemical production/loss using in-cloud observations. The cloud-free environment surrounding the non-precipitating smoke case indicated sulfate enhancement compared to convective mixing quantified by a stable gas tracer; however, this was not observed in the cloud water (either through use of ratios or the mass closure), perhaps implying that the warm convective cloud timescale was too short for chemical production to be a leading-order budgetary term and because precursors had already been predominantly exhausted. Closure of other species was truncated by incomplete characterization of coarse aerosol (e.g., it was found that only 10 %–50% of sea salt mass found in cloud was captured during clear-air sampling) and unmeasured gasphase abundances affecting closure of semi-volatile aerosol species (e.g., ammonium, nitrate and organic) and soluble volatile organic compound contributions to total organic carbon in cloud water.

Ewan Crosbie↗

Flash photolysis resonance fluorescence investigation of the reaction of Cl/2P/ atoms with ClONO2

Rate constants for the removal of Cl(2P) atoms by homogeneous gas phase reaction with ClONO2 were measured using the flash photolysis resonance fluorescence technique at 224, 250, and 273 K. The values obtained have been used to derive the above Arrhenius equation. The uncertainties expressed are 95% confidence limits obtained using the statistical standard deviation of the individual rate constants plus a 15% additional estimated uncertainty attributed to difficulties in chlorine nitrate concentration measurements. The results indicate that destruction of chlorine nitrate by reaction with chlorine atoms is perhaps the least important of the atmospheric reactive channels, and is at least three orders of magnitude slower than calculated photodissociation rates at all stratospheric altitudes.

Kurylo, M. J.↗