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Infrared optical properties of Mars soil analog materials: Palagonites

The globally distributed bright soils on Mars represent products of chemical alteration of primary igneous materials. As such, understanding the chemistry and mineralogy of these soils provides clues about the nature of the parent materials and the type, duration, and extent of the chemical weathering environments on Mars. Such clues are key in developing an understanding of the interior and surficial processes that have operated throughout Mars' history to yield the surface as it is currently observed. The generally homogeneous nature of these soils is illustrated by a variety of observational data. These data include (1) direct determination of elemental abundances by the X-ray fluorescence instruments on both Viking Landers, (2) Earth-based telescopic observations, and (3) space-based observations. Based on their spectral properties in the visible and near-infrared, terrestrial palagonitic soils have been suggested as analogs for the bright regions on Mars. Palagonites represent the weathering products of basaltic glass and as such are composed of a variety of minerals/materials. In order to gain an understanding regarding the chemical, mineralogical, and spectral properties of a broad suite of palagonites, several samples were collected from the eastern and central regions of the island of Hawaii.

Roush, Ted L.↗

Measurements of Silicosis Factors in Lunar and Martian Simulants

Simulants are geologically complex materials that are developed to represent the physical and/or compositional characteristics of a planetary surface (e.g., a naturally occurring soil or regolith). There are dozens of commercially available simulants that have been developed over the years; each simulant exhibits unique physical, chemical, and mineralogical characteristics. Simulants are derived from either natural or synthetic sources (i.e., “feedstocks”) of glass, minerals, and rocks. These feedstock components are processed by crushing, pulverizing, melting, etc., and then combined in the appropriate proportions to represent a particular site, surface, or region (e.g., Lunar Highlands Regolith). The process of creating simulants therefore requires the mechanical breakdown and reincorporation of feedstock components which may contain crystalline silica minerals such as quartz, cristobalite, and tridymite. Certain crystalline silica particles of the respirable fraction (<10 μm in diameter) are of great concern; chronic and acute exposure to these respirable crystalline silica (RCS) can lead to permanent damage and scarring of lung tissue, incurable lung diseases (i.e., silicosis), lung cancer, COPD (chronic obstructive pulmonary disease), and kidney disease. Planetary simulants are used extensively as test materials in the in scientific and engineering communities (e.g., testing of dust mitigation technologies, in-situ resource utilization, rover mobility, hardware, soft goods etc.). As such, this assessment was developed to serve as a guide for simulant users, local Safety and Occupational Health professionals, and Industrial Hygienists to evaluate the risk of silicosis across a wide variety of Lunar and Martian simulants. The goal of these works is to ensure that those working with simulant can do so safely and with an informed understanding of potential health risks.

Lunar↗

Measurements of Silicosis Factors in Lunar and Martian Simulants

Simulants are geologically complex materials that are developed to represent the physical and/or compositional characteristics of a planetary surface (e.g., a naturally occurring soil or regolith). There are dozens of commercially available simulants that have been developed over the years; each simulant exhibits unique physical, chemical, and mineralogical characteristics. Simulants are derived from either natural or synthetic sources (i.e., “feedstocks”) of glass, minerals, and rocks. These feedstock components are processed by crushing, pulverizing, melting, etc., and then combined in the appropriate proportions to represent a particular site, surface, or region (e.g., Lunar Highlands Regolith). The process of creating simulants therefore requires the mechanical breakdown and reincorporation of feedstock components which may contain crystalline silica minerals such as quartz, cristobalite, and tridymite. Certain crystalline silica particles of the respirable fraction (<10 μm in diameter) are of great concern; chronic and acute exposure to these respirable crystalline silica (RCS) can lead to permanent damage and scarring of lung tissue, incurable lung diseases (i.e., silicosis), lung cancer, COPD (chronic obstructive pulmonary disease), and kidney disease. Planetary simulants are used extensively as test materials in the in scientific and engineering communities (e.g., testing of dust mitigation technologies, in-situ resource utilization, rover mobility, hardware, soft goods etc.). As such, this assessment was developed to serve as a guide for simulant users, local Safety and Occupational Health professionals, and Industrial Hygienists to evaluate the risk of silicosis across a wide variety of Lunar and Martian simulants. The goal of these works is to ensure that those working with simulant can do so safely and with an informed understanding of potential health risks.

Lunar↗

Optical effects of space weathering on lunar soils and the role of the finest fraction

Lunar soils represent a cumulative product of space weathering and as such they exhibit distinct optical alteration. In comparison to the optical properties of similar rock powders, lunar soils are darker, have weaker diagnostic absorption bands, and exhibit a characteristic red continuum slope between 0.3 and 4.5 microns. Well-developed (mature) lunar soils have a mean grain size of about 60 microns and may contain more than 50 percent agglutinates (complex, glass-welded aggregates) which were previously believed to be the principal carriers of optical alteration resulting from space weathering. A detailed analysis of the spectral reflectance properties of the bulk soil, size separates, and agglutinate separates of several Apollo and Luna soils has been undertaken to evaluate the validity of the agglutinate paradigm for optical effects of space weathering. The data and results are summarized here which indicate that the finest fraction of natural lunar soils, rather than larger complex agglutinates, carries the principal effects of optical alteration. Bidirectional reflectance spectra were obtained using the small sample configuration of the RELAB facility, which accommodates 5-30 mg of material. Spectra are displayed with the labels for individual samples listed in order of brightness.

Pieters, C. M.↗

Interannual Variability in Soil Trace Gas (CO2, N2O, NO) Fluxes and Analysis of Controllers

Interannual variability in flux rates of biogenic trace gases must be quantified in order to understand the differences between short-term trends and actual long-term change in biosphere-atmosphere interactions. We simulated interannual patterns (1983-1988) of global trace gas fluxes from soils using the NASA Ames model version of CASA (Carnegie-Ames-Stanford Approach) in a transient simulation mode. This ecosystem model has been recalibrated for simulations driven by satellite vegetation index data from the NOAA Advanced Very High Resolution Radiometer (AVHRR) over the mid-1980s. The predicted interannual pattern of soil heterotropic CO2 emissions indicates that relatively large increases in global carbon flux from soils occurred about three years following the strong El Nino Southern Oscillation (ENSO) event of 1983. Results for the years 1986 and 1987 showed an annual increment of +1 Pg (1015 g) C-CO2 emitted from soils, which tended to dampen the estimated global increase in net ecosystem production with about a two year lag period relative to plant carbon fixation. Zonal discrimination of model results implies that 80-90 percent of the yearly positive increments in soil CO2 emission during 1986-87 were attributable to soil organic matter decomposition in the low-latitudes (between 30 N and 30 S). Soils of the northern middle-latitude zone (between 30 N and 60 N) accounted for the residual of these annual increments. Total annual emissions of nitrogen trace gases (N2O and NO) from soils were estimated to vary from 2-4 percent over the time period modeled, a level of variability which is consistent with predicted interannual fluctuations in global soil CO2 fluxes. Interannual variability of precipitation in tropical and subtropical zones (30 N to 20 S appeared to drive the dynamic inverse relationship between higher annual emissions of NO versus emissions of N2O. Global mean emission rates from natural (heterotrophic) soil sources over the period modeled (1983-1988) were estimated at 57.1 Pg C-CO2yr-1, 9.8Tg (1012 g) N-NO yr-1, and 9.7 Tg N-N2O yr-1. Chemical fertilizer contributions to global soil N gas fluxes were estimated at between 1.3 to 7.3 Tg N-NO yr-1, and 1.2 to 4.0 Tg N-N2O yr-1.

Potter, C.↗

L-phase variants of Agromyces ramosus

Earlier results suggested that Agromyces ramosus possibly might exist naturally in soil as a cell-wall-defective form. The purpose of the present study was to test this hypothesis by determining whether the laboratory-adapted strains of A. ramosus could be artificially induced into the L-phase and, if so, to examine some parameters affecting induction and the stability of the L-forms. The hypothesis was also tested by attempting to revert the laboratory L-phase strains by subjecting them to the technique originally used for isolation of the bacterial form from soil. It is shown that A. ramosus is easily induced into the L-phase by growing it on an agar media containing low levels of penicillin or glycine. The L-forms are found to be stable after initial contact with the inducing agent and to be unable to be reverted to the bacterial form. However, this lack of reversion does not completely negate the hypothesis that L-forms might occur in nature, because it is possible that L-forms existing in the natural state are less stable than those found in the laboratory where there is little selective pressure toward reversion.

Horwitz, A. H.↗

Survival and reversion of a stable L form in soil

The stable L form of Agromyces ramosus reverted to a bacterial form when incubated in sterilized soil. The cellular and colonial morphology of this bacterial form resembled that of the original parent bacterial form. The two forms differed, however, in that the revertant maintained its bacterial form when transferred onto a low-salt (NaCl) medium but was virtually completely induced into the L-form state on a high-salt medium. The original parent bacterial form was not sensitive to salt. The possibility is discussed that an L-form - bacterial-form cycle for this bacterium might occur naturally in soil. This cycle would be mediated by fluctuations in local salt concentrations in the soil.

Horwitz, A. H.↗

Carbon cycle: Terrestrial interactions

The effect of living biota, soil organic matter, soil carbonates, natural or steady state exchange, rivers, fossil fuels, and plant respiration on the carbon cycle are discussed.

Schlesinger, W. H.↗

The physical characteristics of satellite surfaces

Both exogenic and endogenic effects have been proposed to explain the major observed characteristics of satellite surfaces. The current view is that the basic properties of most surfaces result from the intrinsic composition of a body and its geologic history. Exogenic effects have, however, played a role in modifying the appearance of nearly all surfaces. The most important exogenic effect is impact cratering, one manifestation of which is the production of micrometeoroid gardened regoliths on airless bodies. On large, silicate bodies the micrometeoroid bombardment can produce an optically mature, dark agglutinate-rich soil; the nature of regoliths on predominantly icy satellites remains uncertain. Direct accumulation of infalling material does not appear to play a major role in modifying most surfaces. Solar wind radiation effects have not altered greatly the optical properties of solar system objects; magnetospheric charged particles may have modified the optical properties of some outer planet satellites (e.g., sulfur ion bombardment in the case of some of the satellites of Jupiter). Other effects, such as aeolian and liquid/solid chemical weathering, may be important on satellites with atmospheres like Titan and Triton.

Veverka, J.↗

Diagnosing the Sensitivity of Local Land-Atmosphere Coupling via the Soil Moisture-Boundary Layer Interaction

The inherent coupled nature of earth s energy and water cycles places significant importance on the proper representation and diagnosis of land atmosphere (LA) interactions in hydrometeorological prediction models. However, the precise nature of the soil moisture precipitation relationship at the local scale is largely determined by a series of nonlinear processes and feedbacks that are difficult to quantify. To quantify the strength of the local LA coupling (LoCo), this process chain must be considered both in full and as individual components through their relationships and sensitivities. To address this, recent modeling and diagnostic studies have been extended to 1) quantify the processes governing LoCo utilizing the thermodynamic properties of mixing diagrams, and 2) diagnose the sensitivity of coupled systems, including clouds and moist processes, to perturbations in soil moisture. This work employs NASA s Land Information System (LIS) coupled to the Weather Research and Forecasting (WRF) mesoscale model and simulations performed over the U.S. Southern Great Plains. The behavior of different planetary boundary layers (PBL) and land surface scheme couplings in LIS WRF are examined in the context of the evolution of thermodynamic quantities that link the surface soil moisture condition to the PBL regime, clouds, and precipitation. Specifically, the tendency toward saturation in the PBL is quantified by the lifting condensation level (LCL) deficit and addressed as a function of time and space. The sensitivity of the LCL deficit to the soil moisture condition is indicative of the strength of LoCo, where both positive and negative feedbacks can be identified. Overall, this methodology can be applied to any model or observations and is a crucial step toward improved evaluation and quantification of LoCo within models, particularly given the advent of next-generation satellite measurements of PBL and land surface properties along with advances in data assimilation schemes.

Santanello, Joseph A., Jr.↗

Comparison of Morphologies of Apollo 17 Dust Particles with Lunar Simulant, JSC-1

Lunar dust (< 20 microns) makes up approx.20 wt.% of the lunar soil. Because of the abrasive and adhering nature of lunar soil, a detailed knowledge of the morphology (size, shape and abundance) of lunar dust is important for dust mitigation on the Moon. This represents a critical step towards the establishment of long-term human presence on the Moon (Taylor et al. 2005). Machinery design for in-situ resource utilization (ISRU) on the Moon also requires detailed information on dust morphology and general physical/chemical characteristics. Here, we report a morphological study of Apollo 17 dust sample 70051 and compare it to lunar soil stimulant, JSC-1. W e have obtained SEM images of dust grains from sample 70051 soil (Fig. 1). The dust grains imaged are composed of fragments of minerals, rocks, agglutinates and glass. Most particles consist largely of agglutinitic impact glass with their typical vesicular textures (fine bubbles). All grains show sub-angular to angular shapes, commonly with sharp edges, common for crushed glass fragments. There are mainly four textures: (1) ropey-textured pieces (typical for agglutinates), (2) angular shards, (3) blocky bits, and (4) Swiss-cheese grains. This last type with its high concentration of submicron bubbles, occurs on all scales. Submicron cracks are also present in most grains. Dust-sized grains of lunar soil simulant, JSC-1, were also studied. JSC-1 is a basaltic tuff with relatively high glass content (approx.50%; McKay et al. 1994). It was initially chosen in the early 90s to approximate the geotechnical properties of the average lunar soil (Klosky et al. 1996). JSC-1 dust grains also show angular blocky and shard textures (Fig. 2), similar to those of lunar dust. However, the JSC-1 grains lack the Swiss-cheese textured particles, as well as submicron cracks and bubbles in most grains.

Liu, Yang↗

In-situ release of solar wind gases from lunar soil

A concept is described which has the potential to perform the in situ heating of the lunar regolith in order to release the solar wind gases. The poor thermal conductivity of the lunar soil is increased approximately 100-fold by the introduction of an artificial hydrogen atmosphere at 1 atm pressure enclosed in an inflatable structure. The leakage rate of H2 through the soil is minimal because of the close-packed nature of the soil and the design and operation of the facility.

Wittenberg, Layton J.↗

The Use of AIS Data for Identifying and Mapping Calcareous Soils in Western Nebraska

The identification of calcareous soils, through unique spectral responses of the vegetation to the chemical nature of calcareous soils, can improve the accuracy of delineating the boundaries of soil mapping units over conventional field techniques. The objective of this experiment is to evaluate the use of the Airborne Imaging Spectrometer (AIS) in the identification and delineation of calcareous soils in the western Sandhills of Nebraska. Based upon statistical differences found in separating the spectral curves below 1.3 microns, calcareous and non-calcareous soils may be identified by differences in species of vegetation. Additional work is needed to identify biogeochemical differences between the two soils.

Samson, S. A.↗

Calculations of the spectral nature of the microwave emission from soils

The brightness temperatures for a set of soil profiles observed at USDA facilities in Arizona and Georgia were calculated at the wavelengths of 2.8, 6, 11, 21, and 49 cm using a coherent radiative transfer model. The soil moisture sampling depth is found to be a function of wavelength and is in the range 0.06 to 0.1 of a wavelength. The thermal sampling depth also depends on wavelength and is approximately equal to one wavelength at dry soil condition and 0.1 - 0.5 wavelengths at wet soil conditions. Calculated values of emissivity show strong diurnal variations when the soils are wet, while there is little diurnal change when the soil is dry. The soil moistures within the four depth intervals of 0-2, 0-5, 0-9, and 0-15 cm were parameterized as function of the calculated emissivity and brightness temperature. Best-fit parameters and correlation coefficients are presented for five wavelengths. Interrelationships among the effective temperature, surface temperature, and emissivity are displayed.

Mo, T.↗

Noble gases in Luna 24 core soils

Isotopic abundances of the noble gases have been determined in grain size separates of six soils from different depths in the Luna 24 core. Concentrations of cosmogenic Ne-21 in these soils show a complex pattern as a function of soil depth, and are inconsistent with a single stage, in situ production in a static regolith or with a simple model of slow accumulation of previously unirradiated soils followed by a static period. All soils have apparently had a complex pre-irradiation history. Some soils show significant differences in the concentration of cosmogenic Ne-21 between different grain sizes, which is consistent with suggestions that they formed as a mixture of soils with different maturities. The exact subsurface depth relationships of the soils are not known, and several possibilities are discussed. Because of this factor and the complex nature of the soils, the cosmogenic Ne data do not define the depositional-irradiational history of the core. Luna 24 core soils may have been deposited any time during the past 300 million years.

Bogard, D. D.↗

Origins of Marslike spectral and magnetic properties of a Hawaiian palagonitic soil

Results are presented on spectral, Moessbauer, static magnetic, petrographic, and compositional data for a Hawaiian palagonitic soil from Mauna Kea (HWMK1). It was found that reflectivity spectra of size separates smaller than 20 microns resemble spectra for Martian bright regions, while spectra of larger size separates show characteristics in common with spectra for Martian dark regions. Data on the HWMK1 soil are consistent with the partitioning of iron among the following minerals: olivine, titanomagnetite, hematite, and a superparamagnetic colored ferric oxide. These mineralogies are heterogeneously distributed within the soil with respect to both particle type and soil-particle diameter. The strongly magnetic titanomagnetite is associated with black particles and is responsible for the magnetic nature of the soil, while the colored weakly magnetic superparamagnetic ferric oxide and minor hematite are associated with orange particles.

Morris, Richard V.↗

Release of microorganisms from soil with respect to transmission electron microscopy viewing and plate counts

A study was conducted to obtain information concerning the fate of soil microorganisms during the procedures normally used in separating them from the soil in connection with various types of investigations. A silty clay loam (pH 6.0, moisture content 25%, organic content 3.5%) was used in the study. The results of the study indicate that many of the microbial cells naturally residing in soil remain attached to or, for some other reason, are not separated from the soil debris despite the use of various combinations of blending, sonication, and chemical dispersing agents. The method B used by Balkwill et al. (1975) provides a reasonable electron microscopy evaluation of the soil microflora.

Balkwill, D. L.↗