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NASA NTRS1993

Post-translational control of collagen fibrillogenesis in mineralizing cultures of chick osteoblasts

Cultured osteoblasts from chick embryo calvaria were used as a model system to investigate the post-translational extracellular mechanisms controlling the macroassembly of collagen fibrils. The results of these studies demonstrated that cultured osteoblasts secreted a collagenous extracellular matrix that assembled and mineralized in a defined temporal and spatial sequence. The assembly of collagen occurred in a polarized fashion, such that successive orthogonal arrays of fibrils formed between successive cell layers proceeding from the culture surface toward the media. Mineralization followed in the same manner, being observed first in the deepest and oldest fibril layers. Collagen fibrillogenesis, the kinetics of cross-link formation, and collagen stability in the extracellular matrix of the cultures were examined over a 30 day culture period. Between days 8 and 12 in culture, collagen fibril diameters increased from < 30 nm to an average of 30-45 nm. Thereafter, diameters ranged in size from 20 to 200 nm. Quantitation of the collagen cross-linking residues, hydroxylysyl pyridinoline (HP) and lysyl pyridinoline (LP), showed that these mature cross-links increased from undetectable levels to concentrations found in normal chick bone. Analysis of the kinetics of their formation by pulse-chase labeling the cultures with [3H]lysine showed a doubling time of approximately 5 days. The relationships between cross-link formation, fibrillogenesis, and collagen stability were examined in cultures treated with beta-aminopropionitrile (beta-APN), a potent inhibitor of lysyl oxidase and cross-link formation. In beta-APN-treated cultures, total collagen synthesis was increased twofold, with no change in mRNA levels for type I collagen, whereas the amount of collagen accumulated in the cell layer was decreased by 50% and mineral deposition was reduced. The rate of collagen retention in the matrix was assessed by pulse-chase analysis of [3H]proline over a 16 day period in control and beta-APN-treated cultures. In control cultures, about 20% of the labeled collagen was lost from the cell layers over a 16 day period compared with > 80% in the presence of beta-APN. The beta-APN-treated cultures also showed a wider diversity of fibril diameters with a median in the > 45-60 nm range. In summary, these data suggest that cross-linking and assembly of collagen fibrils secreted by osteoblasts in vitro occur in a fashion similar to that found in vivo. The rate of cross-link formation is relatively constant and may be correlated with increasing collagen mass.(ABSTRACT TRUNCATED AT 400 WORDS).

NASA Discipline Musculoskeletal↗

NASA NTRS1988

The cratering record in the inner solar system: Implications for earth

Internal and external processes have reworked the Earth's surface throughout its history. In particular, the effect of meteorite impacts on the early history of the earth is lost due to fluvial, aeolian, volcanic and plate tectonic action. The cratering record on other inner solar system bodies often provides the only clue to the relative cratering rates and intensities that the earth has experienced throughout its history. Of the five major bodies within the inner solar system, Mercury, Mars, and the Moon retain scars of an early episode of high impact rates. The heavily cratered regions on Mercury, Mars, and the Moon show crater size-frequency distribution curves similar in shape and crater density, whereas the lightly cratered plains on the Moon and Mars show distribution curves which, although similar to each other, are statistically different in shape and density from the more heavily cratered units. The similarities among crater size-frequency distribution curves for the Moon, Mercury, and Mars suggest that the entire inner solar system was subjected to the two populations of impacting objects but Earth and Venus have lost their record of heavy bombardment impactors. Thus, based on the cratering record on the Moon, Mercury, and Mars, it can be inferred that the Earth experienced a period of high crater rates and basin formation prior to about 3.8 BY ago. Recent studies have linked mass extinctions to large terrestrial impacts, so life forms were unable to establish themselves until impact rates decreased substantially and terrestrial conditions became more benign. The possible periodicity of mass extinctions has led to the theory of fluctuating impact rates due to comet showers in the post heavy bombardment period. The active erosional environment on the Earth complicates attempts to verify these showers by erasing geological evidence of older impact craters. The estimated size of the impactor purportedly responsible for the Cretaceous-Tertiary mass extinctions is 10 km in diameter. Thus impactors greater than or equal to the size postulated for K-T impactor are rare within the inner solar system since the end of heavy bombardment.

Barlow, N. G.↗

NASA NTRS2019

Analytical Techniques for Assessing Gateway and Other Spacecraft Antenna Line-of-Sight

NASA’s Artemis program is committed to landing the next man and the first woman on the Moon by 2024. A critical piece of infrastructure for the mission, the Gateway will inaugurate a sustainable crewed presence beyond low-Earth orbit in cis-lunar space and serve as a staging point for a lunar landing system. The Near Rectilinear Halo Orbit of the Gateway offers numerous operational benefits in terms of its Earth access via the Orion Multipurpose Crew Vehicle, the degree of lunar visibility and surface access it provides, and favorable conditions for station-keeping. To minimize burns during station-keeping and conserve propellant, the Gateway will continually align itself to a solar pressure equilibrium attitude with the Sun; this is convenient for solar array orientation and power generation, but causes difficulties in terms of communication line-of-sight with the Earth, Moon, and visiting vehicles, which appear to be continually rotating about the Gateway’s local frame. A fixed antenna on the Gateway is continually subject to a moving target and can find itself obstructed by the Gateway’s own geometry frequently if not placed carefully. To understand the performance of either Earth-pointing or Moon-pointing antenna placements for a given Gateway geometry, a transient solar system simulation of the Gateway is used to step through orbital ephemeris data and determine the periods in which line-of-sight to a chosen target is achieved and lost. Antenna placements can be tested in the simulation and optimized to increase the average line-of-sight exposure to the target, while also minimizing the maximum duration cut-out in line-of-sight communication experienced; long durations without a successful communication link could pose threats to operations, safety, and mission success. It may be necessary to deviate from the Gateway’s solar pressure equilibrium attitude for short periods of time in order to continue a successful line-of-sight link to a chosen target. Communication coverage spheres can offer insight into what these necessary attitude adjustments may be and are generated by using a 3D mesh of the Gateway and an implementation of the Möller-Trumbore intersection algorithm. This paper outlines the analytical techniques used to perform such antenna placements on the Gateway, offering examples of how line-of-sight strength can be enhanced with an understanding of the Gateway geometry and attitude constraints. These techniques have had direct impact on the writing of communication requirements for NASA and international partner-owned Gateway elements.

Kennedy, William J.↗

NASA NTRS2019

Analytical Techniques for Assessing Gateway and Other Spacecraft Antenna Line-of-Sight

Kennedy, William J.↗

NASA NTRSDate not supplied

2020 International Astronautical Congress Conference Presentation - ANALYTICAL TECHNIQUES FOR ASSESSING GATEWAY AND OTHER SPACECRAFT ANTENNA LINE-OF-SIGHT FOR THE ARTEMIS PROGRAM

NASA’s Artemis program is committed to landing the next man and the first woman on the Moon by 2024. The Gateway, a critical piece of infrastructure for the long-term Artemis mission profiles, will inaugurate a sustainable crewed presence beyond low-Earth orbit in cis-lunar space and serve as a staging point for a lunar landing system. The Near Rectilinear Halo Orbit of the Gateway offers numerous operational benefits in terms of its Earth access via the Orion Multipurpose Crew Vehicle, its degree of Earth and lunar visibility, the versatile surface access it provides, and favorable conditions for station-keeping. To minimize burns during station-keeping and conserve propellant, the Gateway will continually align itself to a solar pressure equilibrium attitude with the Sun; this is convenient for solar array orientation and power generation, but causes difficulties in terms of communication line-of-sight with the Earth, Moon, and visiting vehicles, which appear to be continually rotating about the Gateway’s local frame. A fixed antenna on the Gateway is continually subject to a moving target and can find itself obstructed by the Gateway’s own geometry frequently if not placed carefully. To understand the performance of either Earth-pointing or Moon-pointing antenna placements for a given Gateway geometry, a transient solar system simulation of the Gateway is used to step through orbital ephemeris data and determine the periods in which line-of-sight to a chosen target is achieved and lost. Antenna placements can be tested in the simulation and optimized to increase the average line-of-sight exposure to the target, while also minimizing the maximum duration drop-out in line-of-sight communication experienced; long durations without a successful communication link could pose threats to operations, safety, and mission success. It may be necessary to deviate from the Gateway’s solar pressure equilibrium attitude for short periods of time in order to continue a successful line-of-sight link to a chosen target. Communication coverage spheres can offer insight into what these necessary attitude adjustments may be and are generated by using a 3D mesh of the Gateway and an implementation of the Möller-Trumbore intersection algorithm. This paper outlines the analytical techniques used to perform such antenna placements on the Gateway, offering examples of how line-of-sight strength can be enhanced with an understanding of the Gateway geometry and attitude constraints. These techniques have had direct impact on the writing of communication requirements for NASA and international partner-owned Gateway elements.

Gateway↗

NASA NTRS2001

Thermal and Chemical Characterization of Non-metallic Materials Using Coupled Thermogravimetric Analysis and Infrared Spectroscopy

Thermogravimetric analysis (TGA) is widely employed in the thermal characterization of non-metallic materials, yielding valuable information on decomposition characteristics of a sample over a wide temperature range. However, a potential wealth of chemical information is lost during the process, with the evolving gases generated during thermal decomposition escaping through the exhaust line. Fourier Transform-Infrared spectroscopy (FT-IR) is a powerful analytical technique for determining many chemical constituents while in any material state, in this application, the gas phase. By linking these two techniques, evolving gases generated during the TGA process are directed into an appropriately equipped infrared spectrometer for chemical speciation. Consequently, both thermal decomposition and chemical characterization of a material may be obtained in a single sample run. In practice, a heated transfer line is employed to connect the two instruments while a purge gas stream directs the evolving gases into the FT-IR, The purge gas can be either high purity air or an inert gas such as nitrogen to allow oxidative and pyrolytic processes to be examined, respectively. The FT-IR data is collected real-time, allowing continuous monitoring of chemical compositional changes over the course of thermal decomposition. Using this coupled technique, an array of diverse materials has been examined, including composites, plastics, rubber, fiberglass epoxy resins, polycarbonates, silicones, lubricants and fluorocarbon materials. The benefit of combining these two methodologies is of particular importance in the aerospace community, where newly developing materials have little available data with which to refer. By providing both thermal and chemical data simultaneously, a more definitive and comprehensive characterization of the material is possible. Additionally, this procedure has been found to be a viable screening technique for certain materials, with the generated data useful in the selection of other appropriate analytical procedures for further material characterization.

Huff, Timothy L.↗

NASA NTRS2002

Thermal and Chemical Characterization of Non-Metallic Materials Using Coupled Thermogravimetric Analysis and Infrared Spectroscopy

Thermogravimetric analysis (TGA) is widely employed in the thermal characterization of non-metallic materials, yielding valuable information on decomposition characteristics of a sample over a wide temperature range. However, a potential wealth of chemical information is lost during the process, with the evolving gases generated during thermal decomposition escaping through the exhaust line. Fourier Transform-Infrared spectroscopy (FT-IR) is a powerful analytical technique for determining many chemical constituents while in any material state, in this application, the gas phase. By linking these two techniques, evolving gases generated during the TGA process are directed into an appropriately equipped infrared spectrometer for chemical speciation. Consequently, both thermal decomposition and chemical characterization of a material may be obtained in a single sample run. In practice, a heated transfer line is employed to connect the two instruments while a purge gas stream directs the evolving gases into the FT-IR. The purge gas can be either high purity air or an inert gas such as nitrogen to allow oxidative and pyrolytic processes to be examined, respectively. The FT-IR data is collected realtime, allowing continuous monitoring of chemical compositional changes over the course of thermal decomposition. Using this coupled technique, an array of diverse materials has been examined, including composites, plastics, rubber, fiberglass epoxy resins, polycarbonates, silicones, lubricants and fluorocarbon materials. The benefit of combining these two methodologies is of particular importance in the aerospace community, where newly developing materials have little available data with which to refer. By providing both thermal and chemical data simultaneously, a more definitive and comprehensive characterization of the material is possible. Additionally, this procedure has been found to be a viable screening technique for certain materials, with the generated data useful in the selection of other appropriate analytical procedures for further material characterization.

Huff, Timothy L.↗

NASA NTRS2013

Forest Cover Associated with Improved Child Health and Nutrition: Evidence from the Malawi Demographic and Health Survey and Satellite Data

Healthy forests provide human communities with a host of important ecosystem services, including the provision of food, clean water, fuel, and natural medicines. Yet globally, about 13 million hectares of forests are lost every year, with the biggest losses in Africa and South America. As biodiversity loss and ecosystem degradation due to deforestation continue at unprecedented rates, with concomitant loss of ecosystem services, impacts on human health remain poorly understood. Here, we use data from the 2010 Malawi Demographic and Health Survey, linked with satellite remote sensing data on forest cover, to explore and better understand this relationship. Our analysis finds that forest cover is associated with improved health and nutrition outcomes among children in Malawi. Children living in areas with net forest cover loss between 2000 and 2010 were 19% less likely to have a diverse diet and 29% less likely to consume vitamin A-rich foods than children living in areas with no net change in forest cover. Conversely, children living in communities with higher percentages of forest cover were more likely to consume vitamin A-rich foods and less likely to experience diarrhea. Net gain in forest cover over the 10-year period was associated with a 34% decrease in the odds of children experiencing diarrhea (P5.002). Given that our analysis relied on observational data and that there were potential unknown factors for which we could not account, these preliminary findings demonstrate only associations, not causal relationships, between forest cover and child health and nutrition outcomes. However, the findings raise concerns about the potential short- and long-term impacts of ongoing deforestation and ecosystem degradation on community health in Malawi, and they suggest that preventing forest loss and maintaining the ecosystems services of forests are important factors in improving human health and nutrition outcomes.

malawi↗

NASA NTRS2019

Method for Tracking and Communicating Aggregate Risk Through the Use of Model-Based Systems Engineering (MBSE) Tools

Large, complex projects can identify a significant number and variety of risks, throughout the project life cycle. These risks are analyzed, mitigated, closed or accepted as independent uncertainties. Once closed or accepted, it is easy for projects to lose awareness of their impact. In reality, each of these risks contributes some amount to the overall risk posture of the project. The ability to track and effectively communicate this aggregate risk has represented a challenge to project management. There have been previous attempts to create a schema to communicate the aggregate effect of risks, without notable success. Most of these attempts have centered on some additive metric derived from the scoring of likelihood and consequence values. This, in and of itself, is a logical approach, but all too often the scores were then aggregated to a level where all context was lost. One weakness has been a lack of attempt to create linkages or logical groups of the risks upon which useful aggregation could then occur. The overall move to model-based (systems) engineering (MBSE) has opened up a vast frontier of opportunities to better integrate all project data. MBSE provides an underlying layer that links data items to each other. Objectives link to requirements, which then link to functions, functions to physical architecture items, and so on, as far down as projects want to model. While it started with a focus on modeling requirements based on things like use cases, efforts are now underway to integrate safety and mission assurance (S&MA) information and analyses, such as risks. This effort, called Model Based Mission Assurance (MBMA), is yielding models that are more useful and are a more accurate representations of the systems. MBSE models, with this ability to link related items, provide a new means of tracking and communicating aggregate risks. In the proposed method, risks are added into the models as distinct items, having attributes that communicate a scoring derived from the likelihood and consequence values as charted on the standard NASA 5x5 risk matrix. Like earlier efforts, each box in the 5x5 has an associated scoring, which may include both a current score and potential post-mitigation/control score. The risk items are then linked to elements of the model, such as system objectives/goals, requirements, functions, or physical architecture items, with "Risk to" relationships. These risks will then be communicated by use of reports generated from the model, detailing all risks and/or hazards linked to model elements. These reports can include aggregate impacts, including a current scoring and potential future state scoring based on the planned mitigations and/or controls. These reports will show all risks, open, accepted, and closed, linked to project objectives or requirements. When run as part of an upcoming risk acceptance discussion, these reports will serve to remind the team of all previous risks that relate to the effected portion of the system. When included as part of periodic program or project reviews, risk reviews, and safety reviews, this method can improve the overall understanding of the system's true risk posture. This proposed method takes full advantage of the advances that modern modeling techniques provide, with a minimal investment of additional time. Utilizing the model environment also enables a near constant access to current state of aggregate risks.

model based mission assurance↗

NASA NTRS1992

On-orbit deployment anamolies: What can be done?

Modern communications satellites rely heavily upon deployable appendage (i.e., solar arrays, communications antennas, etc.) to perform vital functions that enable the spacecraft to effectively conduct mission objectives. Communications and telemetry antennas provide the radio-frequency link between the spacecraft and the earth ground station, permitting data to be transmitted and received from the satellite. Solar arrays serve as the principle source of electrical energy to the satellite, and re-charge internal batteries during operation. However, since satellites cannot carry back-up systems, if a solar array fails to deploy, the mission is lost. The subject of on-orbit anomalies related to the deployment of spacecraft appendage, and possible causes of such failures are examined. Topics discussed include mechanical launch loading, on-orbit thermal and solar concerns, reliability of spacecraft pyrotechnics, and practical limitations of ground-based deployment testing. Of particular significance, the article features an in-depth look at the lessons learned from the successful recovery of the Telesat Canada Anik-E2 satellite in 1991.

Freeman, Michael↗

NASA NTRS2010

ICER-3D Hyperspectral Image Compression Software

Software has been developed to implement the ICER-3D algorithm. ICER-3D effects progressive, three-dimensional (3D), wavelet-based compression of hyperspectral images. If a compressed data stream is truncated, the progressive nature of the algorithm enables reconstruction of hyperspectral data at fidelity commensurate with the given data volume. The ICER-3D software is capable of providing either lossless or lossy compression, and incorporates an error-containment scheme to limit the effects of data loss during transmission. The compression algorithm, which was derived from the ICER image compression algorithm, includes wavelet-transform, context-modeling, and entropy coding subalgorithms. The 3D wavelet decomposition structure used by ICER-3D exploits correlations in all three dimensions of sets of hyperspectral image data, while facilitating elimination of spectral ringing artifacts, using a technique summarized in "Improving 3D Wavelet-Based Compression of Spectral Images" (NPO-41381), NASA Tech Briefs, Vol. 33, No. 3 (March 2009), page 7a. Correlation is further exploited by a context-modeling subalgorithm, which exploits spectral dependencies in the wavelet-transformed hyperspectral data, using an algorithm that is summarized in "Context Modeler for Wavelet Compression of Hyperspectral Images" (NPO-43239), which follows this article. An important feature of ICER-3D is a scheme for limiting the adverse effects of loss of data during transmission. In this scheme, as in the similar scheme used by ICER, the spatial-frequency domain is partitioned into rectangular error-containment regions. In ICER-3D, the partitions extend through all the wavelength bands. The data in each partition are compressed independently of those in the other partitions, so that loss or corruption of data from any partition does not affect the other partitions. Furthermore, because compression is progressive within each partition, when data are lost, any data from that partition received prior to the loss can be used to reconstruct that partition at lower fidelity. By virtue of the compression improvement it achieves relative to previous means of onboard data compression, this software enables (1) increased return of hyperspectral scientific data in the presence of limits on the rates of transmission of data from spacecraft to Earth via radio communication links and/or (2) reduction in spacecraft radio-communication power and/or cost through reduction in the amounts of data required to be downlinked and stored onboard prior to downlink. The software is also suitable for compressing hyperspectral images for ground storage or archival purposes.

Xie, Hua↗

NASA NTRS2020

Pervasive ice sheet mass loss reflects competing ocean and atmosphere processes

Quantifying changes in Earth’s ice sheets and identifying the climate drivers are central to improving sea level projections. We provide unified estimates of grounded and floating ice mass change from 2003 to 2019 using NASA’s Ice, Cloud and land Elevation Satellite (ICESat) and ICESat-2 satellite laser altimetry. Our data reveal patterns likely linked to competing climate processes: Ice loss from coastal Greenland (increased surface melt), Antarctic ice shelves (increased ocean melting), and Greenland and Antarctic outlet glaciers (dynamic response to ocean melting) was partially compensated by mass gains over ice sheet interiors (increased snow accumulation). Losses outpaced gains, with grounded-ice loss from Greenland (200 billion tonnes per year) and Antarctica (118 billion tonnes per year) contributing 14 millimeters to sea level. Mass lost from West Antarctica’s ice shelves accounted for more than 30% of that region’s total.

Ben Smith↗

NASA NTRS1995

Noncausal telemetry data recovery techniques

Cost efficiency is becoming a major driver in future space missions. Because of the constraints on total cost, including design, implementation, and operation, future spacecraft are limited in terms of their size power and complexity. Consequently, it is expected that future missions will operate on marginal space-to-ground communication links that, in turn, can pose an additional risk on the successful scientific data return of these missions. For low data-rate and low downlink-margin missions, the buffering of the telemetry signal for further signal processing to improve data return is a possible strategy; it has been adopted for the Galileo S-band mission. This article describes techniques used for postprocessing of buffered telemetry signal segments (called gaps) to recover data lost during acquisition and resynchronization. Two methods, one for a closed-loop and the other one for an open-loop configuration, are discussed in this article. Both of them can be used in either forward or backward processing of signal segments, depending on where a gap is specifically situated in a pass.

Tsou, H.↗

NASA NTRS1995

Connective tissue integrity is lost in vitamin B-6-deficient chicks

The objective of the present investigation was to characterize further the connective tissue disorder produced by pyridoxine (vitamin B-6) deficiency, as previously evidenced by electron microscopy. Following the second post-natal week, fast growing male chicks were deprived of pyridoxine for a 1-mo period. Six weeks post-natally, blood concentrations in the experimental deficiency group had declined to deficiency levels as registered by low concentrations of pyridoxal phosphate (coenzyme form) in erythrocytes, but did not reach levels associated with neurological symptoms. Light microscopic study showed abnormalities in the extracellular matrix of the connective tissues. Collagen cross-links and the aldehyde contents were not significantly lower in cartilage and tendon collagens of vitamin B-6-deficient animals than in age-matched controls; also, their proteoglycan degrading protease and collagenase activities measured in articular cartilages were not greater. Thus, proteolysis was an unlikely alternative mechanism to account for the loss of connective tissue integrity. These results point to the need for further investigation into adhesive properties of collagen associated proteoglycans or other proteins in vitamin B-6-deficient connective tissue.

Non-NASA Center↗

NASA NTRS1996

Characterization of Microgravity Effects on Bone Structure and Strength Using Fractal Analysis

Protecting humans against extreme environmental conditions requires a thorough understanding of the pathophysiological changes resulting from the exposure to those extreme conditions. Knowledge of the degree of medical risk associated with the exposure is of paramount importance in the design of effective prophylactic and therapeutic measures for space exploration. Major health hazards due o musculoskeletal systems include the signs and symptoms of hypercalciuria, lengthy recovery of lost bone tissue after flight, the possibility of irreversible trabecular bone loss, the possible effect of calcification in the soft tissues, and the possible increase in fracture potential. In this research, we characterize the trabecular structure with the aid of fractal analysis. Our research to relate local trabecular structural information to microgravity conditions is an important initial step in understanding the effect of microgravity and countermeasures on bone condition and strength. The proposed research is also closely linked with Osteoporosis and will benefit the general population.

Acharya, Raj S.↗

NASA NTRS1995

High Modulus and High T(sub g) Thermally Stable Polymers from p-Ethynyl-Terminated Rigid-Rod Monomers

Novel p-ethynyl-substituted rigid rod monomers were studied by pressure Differential Scanning Calorimetry (DSC), ThermoGravimetric Analysis (TGA), IsothermoGravimetric Analysis (IGA), and TGA-IR. These monomers, 4,4'-bis(((4-ethynylphenyl)carbonyl)oxy)biphenyl, designated 1, 1,5-bis-(((4-ethynylphenyl)carbonyl)oxy)naphthalene, designated 2, and bis(4-ethynylphenyl)pyromellitimide, designated 3, were polymerized in the solid state. Thermal polymerization in N2 or air produced highly cross-linked resins with polymerization exotherms centered between 212 and 276 C. The (delta)H's of polymerization of these resins in air were found to be double those in N2. When monomers 1 and 2 were heated in air from 23 to 750 C at 10 C/min, the main decomposition product was carbon dioxide, evolving at a maximum rate between 500 and 600 C; water was also detected as a decomposition product. Void-free neat resin moldings, designated lp to 3p, were made by compression molding the monomers and then heating them. The resulting polymers were highly cross-linked, and their glass transition temperatures (T(sub g)) were much higher than their polymerization temperatures. Using ThermoMechanical Analysis (TMA), we found that polymers lp to 3p had T(sub g)'s of 422, 329, and 380 C, respectively. The thermal and thermooxidative stabilities improved when lp to 3p were postcured in N2 (the postcured polymers were designated 1pp to 3pp). The Linear Thermal Expansions (LTE) for lp and 3p were 1% between 23 and 420 C. Using rheological analysis, we could not clearly detect the T(sub g)'s of lp to 3p because their moduli dropped only slightly between 23 and 490 C and the changes in tan beta were very low. Because of high cross-link density, their moduli changed little as the resins went from a glassy to a rubbery state. Their shear storage moduli in air ranged from 0.82 (3p, 3pp) to 1.6 GPa (lpp) at 23 C, from 0.16 (2p) to 0.7GPa(lpp) at 380 C, and from 0.18(lpp)to 0.6GPa(2p) at 490 C. Finally, these novel-p-ethynyl polymers exhibited an excellent combination of high T(sub g), low LTE, and high thermooxidative stability. Most notably, 3pp lost only 3% of its initial weight when it was aged for 500 h at 288 C in air.

Melissaris, Anastasios P.↗

NASA NTRS1988

The loss and reestablishment of the wind in 66 Ophiuchi in 1985

The paper addresses the mass loss in the Be star 66 Oph during the first six months of 1985, when the star temporarily lost its wind. Particular attention is given to IUE observations obtained just before the wind faded, during the hiatus in mass loss, and in the period of reestablishment. During the espisode considered, the wind faded in less than three weeks, but reestablished itself within two months. While the peak intensity of the H-alpha emission feature has been steadily increasing since the mid-1970s, a marked decrease in strength in June 1985 indicates that the wind and Balmer emitting regions are linked.

Peters, Geraldine J.↗

NASA NTRS1992

An ion mass spectrometer for measuring isotopic adundances and loss rates of O, C and H in Mars' upper atmosphere

The history of Mars' climate is clearly intimately linked to the evolution of its store of volatiles, particularly H2O, and CO2. The global CO2-H2O system is complex, with a number of production, loss, exchange, and buffering mechanisms operating between the atmosphere and the surface. For example, loss of these volatiles takes place through solar wind interaction with the upper atmosphere/ionosphere, ionospheric chemistry, and thermal escape. The atmospheric water inventory is, in turn, influenced by the exchange with polar water ice deposits and high latitude ground-ice. Atmospheric CO2, on the other hand, can be lost through adsorption in the regolith and in the formation of carbonates. Finally, oxygen is exchanged between atmospheric CO2 and H2O.

Elphic, R. C.↗