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At least 55 records · Page 3

In Situ Dating Experiments of Igneous Rocks Using the KArLE Instrument: A Case Study for Approximately 380 Ma Basaltic Rocks

We report new K-Ar isochron data for two approximately 380 Ma basaltic rocks, using an updated version of the Potassium-Argon Laser Experiment (KArLE). These basalts have K contents comparable to lunar KREEP basalts or igneous lithologies found by Mars rovers, whereas previous proof-of-concept studies focused primarily on more K-rich rocks. We continue to measure these analogue samples to show the advancing capability of in situ K-Ar geochronology. KArLE is applicable to other bodies including the Moon or asteroids.

Cho, Yuichiro↗

Dating Igneous Rocks Using the Potassium–Argon Laser Experiment (KArLE) Instrument: A Case Study for ~380 Ma Basaltic Rocks

We report new K–Ar isochron data for two ~380 Ma basaltic rocks, using an updated version of the Potassium–Argon Laser Experiment (KArLE), which is being developed for future in situ dating of planetary materials. These basalts have K contents comparable with those of lunar KREEP basalts or igneous lithologies found by Mars rovers, whereas previous proof‐of‐concept studies focused primarily on more K‐rich rocks. We aim to measure these analogous samples to show the advancing capability of in situ K–Ar geochronology. Combining laser‐induced breakdown spectroscopy (LIBS), mass spectrometry (MS), and microscopic analyses, we measured the abundance of K and 40Ar from 23 spots on the basalt samples. We then constructed K–Ar isochron plots from these rocks. The breadboard instrument consists of flight‐equivalent devices including a 30‐mJ Nd:YAG laser and a quadrupole mass spectrometer. Despite much lower K abundances than in previous studies, the isochron slopes yielded 380 ± 44 Ma and 398 ± 50 Ma for 380.7‐Ma and 373.5‐Ma rocks, respectively, indicating that accuracy better than 25 Ma (<7%) is achievable with our instrument. The isochron intercepts both yielded trapped 40Ar approximately 1 × 10−6 cm3 STP/g. Our experimental results demonstrate that accurate and precise measurements are possible using the KArLE approach on basaltic rocks, which are ubiquitous on planetary surfaces, and are useful in addressing a wide range of questions in planetary science.

Yuichiro Cho↗

Dating Igneous Rocks Using the Potassium-Argon Laser Experiment (KArLE) Instrument: A Case Study for ~380 Ma Basaltic Rocks

We report new K-Ar isochron data for two approximately 380 million-years-old basaltic rocks, using an updated version of the Potassium-Argon Laser Experiment (KArLE), which is being developed for future in situ dating of planetary materials. These basalts have K contents comparable with those of lunar KREEP basalts or igneous lithologies found by Mars rovers, whereas previous proof-of-concept studies focused primarily on more K-rich rocks. We aim to measure these analogous samples to show the advancing capability of in situ K-Ar geochronology.

Cho, Yuichiro↗

Venus - Chemical weathering of igneous rocks and buffering of atmospheric composition

Data from the Pioneer Venus radar mapper, combined with measurements of wind velocity and atmospheric composition, suggest that surface erosion on Venus varies with altitude. Calcium- and magnesium-rich weathering products are produced at high altitudes by gas-solid reactions with igneous minerals, then removed into the hotter lowlands by surface winds. These fine-grained weathering products may then rereact with the lower atmosphere and buffer the composition of the observed gases carbon dioxide, water vapor, sulfur dioxide, and hydrogen fluoride in some regions of the surface. This process is a plausible mechanism for the establishment in the lowlands of a calcium-rich mineral assemblage, which had previously been found necessary for the buffering of these species.

Nozette, S.↗

Pristine Igneous Rocks and the Early Differentiation of Planetary Materials

Our studies are highly interdisciplinary, but are focused on the processes and products of early planetary and asteroidal differentiation, especially the genesis of the ancient lunar crust. Most of the accessible lunar crust consists of materials hybridized by impact-mixing. Rare pristine (unmixed) samples reflect the original genetic diversity of the early crust. We studied the relative importance of internally generated melt (including the putative magma ocean) versus large impact melts in early lunar magmatism, through both sample analysis and physical modeling. Other topics under investigation included: lunar and SNC (martian?) meteorites; igneous meteorites in general; impact breccias, especially metal-rich Apollo samples and polymict eucrites; effects of regolith/megaregolith insulation on thermal evolution and geochronology; and planetary bulk compositions and origins. We investigated the theoretical petrology of impact melts, especially those formed in large masses, such as the unejected parts of the melts of the largest lunar and terrestrial impact basins. We developed constraints on several key effects that variations in melting/displacement ratio (a strong function of both crater size and planetary g) have on impact melt petrology. Modeling results indicate that the impact melt-derived rock in the sampled, megaregolith part of the Moon is probably material that was ejected from deeper average levels than the non-impact-melted material (fragmental breccias and unbrecciated pristine rocks). In the largest lunar impacts, most of the impact melt is of mantle origin and avoids ejection from the crater, while most of the crust, and virtually all of the impact-melted crust, in the area of the crater is ejected. We investigated numerous extraordinary meteorites and Apollo rocks, emphasizing pristine rocks, siderophile and volatile trace elements, and the identification of primary partial melts, as opposed to partial cumulates. Apollo 15 sample 15434,28 is an extraodinarily large glass spherule, nearly if not entirely free of meteoritic contamination, and provides insight into the diversity of mare basalts in the Hadley-Apennine region. Apollo 14 sample 14434 is in many respects a new rock type, intermediate between nonmare gabbronorites and mare basalts. We helped to both plan and implement a consortium to study the Yamato-793605 SNC/martian meteorite.

Warren, Paul H.↗

Pristine Igneous Rocks and the Early Differentiation of Planetary Materials

Our studies are highly interdisciplinary, but are focused on the processes and products of early planetary and asteroidal differentiation, especially the genesis of the ancient lunar crust. The compositional diversity that we explore is the residue of process diversity, which has strong relevance for comparative planetology. Most of the accessible lunar crust consists of materials hybridized by impact-mixing. Our lunar research concentrates on the rare pristine (unmixed) samples that reflect the original genetic diversity of the early crust. Among HED basalts (eucrites and clasts in howardites), we distinguish as pristine the small minority that escaped the pervasive thermal metamorphism of the parent asteroid's crust. We have found a correlation between metamorphically pristine HED basalts and the similarly small minority of compositionally evolved "Stannern trend" samples, which are enriched in incompatible elements and titanium compared to main group eucrites, and yet have relatively high mg ratios. Other topics under investigation included: lunar and SNC (martian?) meteorites; igneous meteorites in general; impact breccias, especially metal-rich Apollo samples and polymict eucrites; siderophile compositions of the lunar and martian mantles; and planetary bulk compositions and origins.

Warren, Paul H.↗

Some textures in Apollo 12 lunar igneous rocks and in terrestrial analogs.

The interpretation of immature crystallization and some lunar textures characterized by it are the principal objectives of this investigation. A comparative and selective approach is adopted, and particular reference is made to the form and textural relations of olivine in 12009 and of pyroxenes and plagioclase in 12021, and to terrestrial analogs. The optic orientation of the olivines in 12009 is determined, and their skeletal crystallization is illustrated and evaluated. Microprobe and optical data are associated in a textural analysis of an analog from the upper contact of a minor intrusion in Skye. The optic orientation of pyroxene enclosed in plagioclase cores is determined, and the results are plotted stereographically. The need for greater precision in the use of textural terms is stressed, and a new term - intrafasciculate - is introduced for textures in which pyroxene has crystallized within hollow, skeletal plagioclase. Apollo 12 pyroxene-phyric basalts are texturally reviewed, and the crystallization of the phenocrysts is discussed, emphasis being placed on size-independence of skeletal growth.

Drever, H. I.↗

SNC meteorites - Igneous rocks from Mars

It is argued that SNC (shergottite, nakhlite, chassignite) meteorites are ejecta from Mars. The mineralogy and chemistry of these objects is discussed, including rare earth element content, potassium/uranium ratios, oxidation state, oxygen isotopes, ages and isotopic evolution, magnetism, shock and texture. The possibility of SNC's deriving from Mercury, Venus, earth, moon, or a eucrite parent body is argued against. Mercury is too volatile-poor and anhydrous, Venus's atmosphere too thick and hot and its gravitational field too large, earth's oxygen isotope content too different from that of SNC's, the moon too different isotopically and chemically, and the ages of eucrites too different. Models suggest that SNC's could have escaped from Mars's gravitational field, and their composition supports Martian origin. Statistically, they could have reached the earth within their measured shock ages. Objections to the hypothesis are also discussed.

Wood, C. A.↗

Cosmogenic helium in a terrestrial igneous rock

New helium isotopic measurements on samples from the Kula formation of Haleakala volcano of Hawaii are presented that are best explained by an in situ cosmogenic origin for a significant fraction of the He-3. Results from crushing and stepwise heating experiments, and consideration of the exposure age of the sample at the surface and the cosmic ray fluxes strongly support this hypothesis. Although crustal cosmogenic helium has been proposed previously, this represents its first unambiguous identification in a terrestrial sample.

Kurz, M. D.↗

Pb, Sr, and Nd isotopic compositions of a suite of Large Archean, igneous rocks, eastern Beartooth Mountains - Implications for crust-mantle evolution

Compositionally diverse Late Archean rocks (2.74-2.79 Ga old) from the eastern Beartooth Mountains (Montana and Wyoming) were studied and shown to have the same initial Pb, Sr, and Nd isotopic ratios. Lead and Sr initial ratios are higher and Nd initial values lower than predicted for rocks derived from model mantle sources and strongly indicate the involvement of an older crustal reservoir in the genesis of these rocks. A model involving subduction of continental detritus and contamination of the overlying mantle is suggested.

Wooden, J. L.↗

Charge Generation and Propagation in Igneous Rocks

Various electrical phenomena have been reported prior to or concurrent with earthquakes such as resistivity changes, ground potentials, electromagnetic (EM), and luminous signals. Doubts have been raised as to whether some of these phenomena are real and indeed precursory. One of the reasons for uncertainty is that, despite decades of intense work, there is still no physically coherent model. Using low- to medium-velocity impacts to measure electrical signals with microsecond time resolution, it has now been observed that when dry gabbro and diorite cores are impacted at relatively low velocities, approximately 100 m/s, highly mobile charge carriers are generated in a small volume near the impact point. They spread through the rocks, causing electric potentials exceeding +400 mV, EM, and light emission. As the charge cloud spreads, the rock becomes momentarily conductive. When a dry granite block is impacted at higher velocity, approximately 1.5 km/s, the propagation of the P and S waves is registered through the transient piezoelectric response of quartz. After the sound waves have passed, the surface of the granite block becomes positively charged, suggesting the same charge carriers as observed during the low-velocity impact experiments, expanding from within the bulk. During the next 2-3 ms the surface potential oscillates, indicating pulses of electrons injected from ground and contact electrodes. The observations are consistent with positive holes, e.g., defect electrons in the O(2-) sublattice, traveling via the O 2p-dominated valence band of the silicate minerals. Before activation, the positive holes lay dormant in the form of electrically inactive positive hole pairs (PHP), chemically equivalent to peroxy links, O3X/OO\XO3, with X=Si(4+), Al(3+), etc. PHPs are introduced into the minerals by way of hydroxyl,O3X-OH, which all nominally anhydrous minerals incorporate when crystallizing in H2O-laden environments. The fact that positive holes can be activated by low-energy impacts, and their attendant sound waves, suggests that they can also be activated by microfracturing. Depending on where in the stressed rock volume the charge carriers are activated, they will form rapidly moving or fluctuating charge clouds that may account for earthquake-related electrical signals and EM emission. Wherever such charge clouds intersect the surface, high fields are expected, causing electric discharges and earthquake lights.

Freund, Friedemann↗