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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 55 records · Page 3
All sourcesNASA NTRSDOE OSTI
DOE OSTI2022

Opportunities and data requirements for data-driven prognostics and health management in liquid hydrogen storage systems

During the past decade, Prognostics and Health Management (PHM) has become an important set of tools in various areas of industry and academic reliability engineering. PHM consists of a variety of mathematical and computational methods used to support data-driven decision-making to increase the safety, availability, and reliability of complex engineering systems. In particular, PHM can provide crucial insight into reliability and safety design improvements for developing technologies where historical performance and failure data are limited. This is the case of hydrogen fueling and storage technologies. This work presents a high-level approach for designing data-driven PHM applications for bulk liquid hydrogen (LH 2 ) storage systems for hydrogen fueling stations. This paper addresses core aspects of the design, development, and implementation of data-driven PHM applications that can improve the reliability assessment of hydrogen components. The analysis focuses on the relationship between data availability and diagnostic/prognostic capabilities; potential challenges; and integration schemes for current risk mitigation measures. We identify potential condition-monitoring data sources for key components in an LH 2 storage system, including storage tanks, piping, and pumps. Further, we determine that the short-term goals for the implementation of data-driven models in PHM frameworks in hydrogen systems should focus on developing adequate data collection and analysis strategies, as well as exploring the effect on reliability, safety, and regulations for hydrogen systems.

08 HYDROGEN↗
DOE OSTI2018

Hydrogen: What's Different Now

This is an exciting time for hydrogen fuel-cell electric vehicles (FCEVs). They seem to be on the verge of a major market breakthrough. However, those of us who have been working in the hydrogen and FC industry for a while are familiar with the boom and bust cycle of FCEV hype-it feels like we have been here before. The first FC automobile was designed as far back as the 1960s. NASA was using FCs to power its spacecraft, and, in 1966, General Motors (GM) used this space-age technology in the prototype GM Electrovan. The Electrovan used the body and chassis of GM's Handivan, their production utility van at the time. The FC and hydrogen components for this vehicle filled nearly the entire available space of the van. At this point, FCs were clearly too expensive and impractical for production vehicles.

08 HYDROGEN↗
DOE OSTI2020

Characteristic of cryogenic hydrogen flames from high-aspect ratio nozzles

Unintentional leaks at hydrogen fueling stations have the potential to form hydrogen jet flames, which pose a risk to people and infrastructure. The heat flux from these jet flames are often used to develop separation distances between hydrogen components and buildings, lot-lines, etc. The heat flux and visible flame length is well understood for releases from round nozzles, but real unintended leaks would be expected to be from higher aspect-ratio cracks. Here, we measured the visible flame length and heat-flux characteristics of cryogenic hydrogen flames from high-aspect ratio nozzles. Heat flux measurements from 5 radiometers were used to assess the single-point vs the multi-point methods for interpretation of heat flux sensor data, finding the axial distance of the sensor for a single-point heat flux measurement to be important. We compare the flame length and heat flux data to flames of both cryogenic and compressed hydrogen from round nozzles. The aspect ratio of the release does not affect the flame length or heat flux significantly, for a given mass flow under the range of conditions studied. The engineering correlations presented in this work enable the prediction of flame length and heat flux which can be used to assess risk at hydrogen fueling stations with liquid hydrogen and develop science-based separation distances for these stations.

08 HYDROGEN↗
DOE OSTI2025

Global Gyrokinetic Simulations of Isotope Effects under Ambipolar Electric Fields and Advances Toward Whole-Volume Modeling

We review global gyrokinetic simulation studies on plasma transport in the Large Helical Device using XGC-S. XGC-S is an extended version of X-point Gyrokinetic Code for stellarators and has been progressively verified throughout the code development process. Verification tests of neoclassical transport successfully demonstrate the generation of an ambipolar electric field due to ripple-trapped particles. We perform quasi-linear analyses of the ion temperature gradient mode under the influence of the ambipolar electric field. The results reveal that the ambipolar electric field and the heavy hydrogen component in mixed isotope plasmas can lead to the favorable isotope effect observed in recent deuterium experiments. We also present recent efforts in code development toward whole-volume simulations, including the helical divertor region. A mesh generation scheme based on field-line tracing and the construction of curved surfaces perpendicular to the magnetic field would be promising for global field calculations in the whole-volume simulations.

Basic Plasma Phenomena and Gas Discharges↗
DOE OSTI2019

Generation and acceleration of electron bunches from a plasma photocathode

Plasma waves generated in the wake of intense, relativistic laser or particle beams can accelerate electron bunches to gigaelectronvolt energies in centimetre-scale distances. This allows the realization of compact accelerators with emerging applications ranging from modern light sources such as the free-electron laser to energy frontier lepton colliders. In a plasma wakefield accelerator, such multi-gigavolt-per-metre wakefields can accelerate witness electron bunches that are either externally injected or captured from the background plasma. Here in this work, we demonstrate optically triggered injection and acceleration of electron bunches, generated in a multi-component hydrogen and helium plasma employing a spatially aligned and synchronized laser pulse. This ‘plasma photocathode’ decouples injection from wake excitation by liberating tunnel-ionized helium electrons directly inside the plasma cavity, where these cold electrons are then rapidly boosted to relativistic velocities. The injection regime can be accessed via optical density down-ramp injection and is an important step towards the generation of electron beams with unprecedented low transverse emittance, high current and 6D-brightness. This experimental path opens numerous prospects for transformative plasma wakefield accelerator applications based on ultrahigh-brightness beams.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗
DOE OSTI2021

Hydrogen Storage Tests Phase 2: Advanced Cryocompressed Hydrogen Delivery and Onboard Storage (CRADA No. TC02207 Final Report)

Thin-lined, high fiber fraction vessels have been designed, built and tested for producing cryogenic pressurized hydrogen storage with weight (9+% hydrogen weight fraction) and volume ( 50+ grams of hydrogen per liter of system volume) onboard storage performance. Long-term vessel durability was tested and partially demonstrated to 456 cycles. Other accomplishments included cycle testing a vessel provided by BMW 1000 times to demonstrate durability; and building and testing a facility for efficient testing of vessels and hydrogen components.

42 ENGINEERING↗
DOE OSTI2026

Assessment of Vibration and Shock Loading Environments on Steels Used in Railroad Applications Considering Hydrogen Embrittlement

Studies that examine the combined effects of hydrogen and rail loading environments in the context of hydrogen embrittlement of steels have not been performed. Large-scale hydrogen storage requires either gaseous hydrogen stored in pressure vessels and tubing or liquid hydrogen in cryogenic, insulated tanks. Since the focus of this study is on steels, we examine the influence of hydrogen on stainless steel used for high pressure tubing and cryogenic tanks and Cr-Mo steel liners used in gaseous pressure vessels. Literature studies show that despite hydrogen degradation, these steels can be used effectively and safely if the stresses are managed. The shock and vibration environment on railcars present unique environments where stresses and loading rates can be high. A literature review was conducted to understand the accelerations experienced in rail by examining instrumented railcars of nuclear fuel casks. Hydrogen studies were examined that focused on steel pressure hardware with an emphasis on fatigue, fast loading rates, and low temperatures. A simplified fatigue assessment was performed to examine design cycles for three different hydrogen components: stainless steel tubing, stainless steel cryogenic tanks, and gaseous pressure vessels. The assessments were idealized and used bounding cases of accelerations in both normal rail conditions and coupling events. In normal shock and vibration environments when accelerations were less than 2 g, infinite design life was calculated. In extreme shock or coupling environments, finite design life was calculated which was shown to be dependent on unsupported lengths of pressure components. It was shown that adjusting the unsupported length can reduce the bending stress thereby increasing design life.

36 MATERIALS SCIENCE↗
DOE OSTI2016

THE INTERMEDIATE LUMINOSITY OPTICAL TRANSIENT SN 2010DA: THE PROGENITOR, ERUPTION, AND AFTERMATH OF A PECULIAR SUPERGIANT HIGH-MASS X-RAY BINARY

We present optical spectroscopy, ultraviolet-to-infrared imaging, and X-ray observations of the intermediate luminosity optical transient (ILOT) SN 2010da in NGC 300 ( d = 1.86 Mpc) spanning from −6 to +6 years relative to the time of outburst in 2010. Based on the light-curve and multi-epoch spectral energy distributions of SN 2010da, we conclude that the progenitor of SN 2010da is a ≈10–12 M {sub ⊙} yellow supergiant possibly transitioning into a blue-loop phase. During outburst, SN 2010da had a peak absolute magnitude of M {sub bol} ≲ −10.4 mag, dimmer than other ILOTs and supernova impostors. We detect multi-component hydrogen Balmer, Paschen, and Ca ii emission lines in our high-resolution spectra, which indicate a dusty and complex circumstellar environment. Since the 2010 eruption, the star has brightened by a factor of ≈5 and remains highly variable in the optical. Furthermore, we detect SN 2010da in archival Swift and Chandra observations as an ultraluminous X-ray source ( L {sub X} ≈ 6 × 10{sup 39} erg s{sup −1}). We additionally attribute He ii 4686 Å and coronal Fe emission lines in addition to a steady X-ray luminosity of ≈10{sup 37} erg s{sup −1} to the presence of a compact companion.

79 ASTRONOMY AND ASTROPHYSICS↗
NASA NTRS1978

Spectral line profiles in a planetary corona - A collisional model

An attempt is made to report on an extension of the theory of spectral line profiles for a planetary corona to include the effects of H-H(+) resonant charge exchange in which satellite particles are omitted. A computational procedure is outlined, three classes of particle orbits are distinguished (ballistic, satellite, escaping), and several complications are considered. A collisional profile is obtained, and appropriate collisionless and collisional curves are compared. It is concluded that good profiles could disclose the presence of a nonthermal hydrogen component. Effects of omitting satellite particles are briefly discussed.

Prisco, R. A.↗
NASA NTRS1994

Study of cosmic-ray H and He isotopes at 23 AU

We have measured the spectra of H and He isotopes during the 1987 solar minimum with the cosmic-ray detector system (CRS) on the Voyager 2 spacecraft. By carrying out the measurement near solar minimum and at large heliospheric distances, the effects of solar modulations were reduced. In particular, the adiabatic energy losses were smaller, and these results from 23 AU over the solar minimum period of cycle 21 represent observations at energies not accessible from previous measurements near 1 AU. The modulated spectra with the diffusion coefficient constant k(sub 0) = 3.15 x 10(exp 22) sq cm/s (which corresponds to a solar modulation parameter of 360 MV at 23 AU and 500 MV at 1 AU) agree well with both our data at 23 AU and the previous solar minimum measurements at 1 AU. The measured H-1 and H-2 spectra are both consistent with the calculated spectra, using standard Galactic and heliospheric propagation models without invoking an anomalous hydrogen component. With the fixed modulation parameter of 360 MV, the mean pathlengths, source spectra, and cross sections were varied to study the effects of different input parameters on the spectra and relative abundances. At this stage of our work, we have not found any strong evidence from the low-energy H-2 and He-3 data that H-1 and He-4 should have a different propagation history, or different types of source spectra from the heavier cosmic-ray nuclei.

Seo, E. S.↗
NASA NTRS2003

Guide for Hydrogen Hazards Analysis on Components and Systems

The physical and combustion properties of hydrogen give rise to hazards that must be considered when designing and operating a hydrogen system. One of the major concerns in the use of hydrogen is that of fire or detonation because of hydrogen's wide flammability range, low ignition energy, and flame speed. Other concerns include the contact and interaction of hydrogen with materials, such as the hydrogen embrittlement of materials and the formation of hydrogen hydrides. The low temperature of liquid and slush hydrogen bring other concerns related to material compatibility and pressure control; this is especially important when dissimilar, adjoining materials are involved. The potential hazards arising from these properties and design features necessitate a proper hydrogen hazards analysis before introducing a material, component, or system into hydrogen service. The objective of this guide is to describe the NASA Johnson Space Center White Sands Test Facility hydrogen hazards analysis method that should be performed before hydrogen is used in components and/or systems. The method is consistent with standard practices for analyzing hazards. It is recommended that this analysis be made before implementing a hydrogen component qualification procedure. A hydrogen hazards analysis is a useful tool for hydrogen-system designers, system and safety engineers, and facility managers. A hydrogen hazards analysis can identify problem areas before hydrogen is introduced into a system-preventing damage to hardware, delay or loss of mission or objective, and possible injury or loss of life.

Beeson, Harold↗
NASA NTRS2006

Multiphysics Thermal-Fluid Design Analysis of a Non-Nuclear Tester for Hot-Hydrogen Materials and Component Development

The objective of this effort is to perform design analyses for a non-nuclear hot-hydrogen materials tester, as a first step towards developing efficient and accurate multiphysics, thermo-fluid computational methodology to predict environments for hypothetical solid-core, nuclear thermal engine thrust chamber design and analysis. The computational methodology is based on a multidimensional, finite-volume, turbulent, chemically reacting, thermally radiating, unstructured-grid, and pressure-based formulation. The multiphysics invoked in this study include hydrogen dissociation kinetics and thermodynamics, turbulent flow, convective, and thermal radiative heat transfers. The goals of the design analyses are to maintain maximum hot-hydrogen jet impingement energy and to minimize chamber wall heating. The results of analyses on three test fixture configurations and the rationale for final selection are presented. The interrogation of physics revealed that reactions of hydrogen dissociation and recombination are highly correlated with local temperature and are necessary for accurate prediction of the hot-hydrogen jet temperature.

Wang, Ten-See↗
DOE OSTI2026

A Quantitative Examination of Catalyst Component Impacts on Hydrogen Adsorption and Spillover

Hydrogen spillover is a widely recognized but poorly understood surface phenomenon. We coupled volumetric chemisorption with Fourier transform infrared spectroscopy, thermogravimetric analysis, and acid–base titrations to quantify the roles of metal (Pt, Au) and support chemistry (anatase, rutile, P25 titania) on spillover. We show that metal identity has little to no impact on the amount of spillover hydrogen. Spillover pressure dependence is essentially the same on Au/TiO 2 and Pt/TiO 2 , indicating H 2 adsorption is equilibrated across both the metal and support. Conversely, spillover is highly sensitive to support surface chemistry, as rutile TiO 2 stabilizes ∼5× more surface hydrogen than anatase TiO 2 . This change is due to a combination of factors, including the rutile surface’s higher proton affinity, stabilized surface electronic states, and larger surface entropy. This work highlights the utility of Au/MO x catalysts as control materials for spillover, as they enable quantitative evaluation of H 2 adsorption on active metals and spillover onto the support.

Adsorption↗
DOE OSTI2024

Assessment of Potential Failure Modes and Effects for On-Board Components for Hydrogen-Powered Locomotives

Hydrogen fuel sources offer alternatives to conventional fuels in the rail transportation industry. Hydrogen powered locomotive designs utilizing either a fuel cell or an internal combustion engine can make migration to alternative fuels possible for rail transportation. Codes and standards are still in development for rail application of hydrogen and safety risks must be assessed for hydrogen locomotive applications. This report utilizes a failure mode & effects analysis framework to help qualitatively understand possible risks from a hydrogen locomotive system. Findings illustrate how a combination of three mitigations greatly reduces the risks from a hydrogen locomotive system.

08 HYDROGEN↗
NASA NTRS1970

Mounting, support, and isolation of various components of a hydrogen maser

Polytetrafluoroethylene tubing partially collapsed during assembly protects the shields from thermal expansion stress in isothermal and magnetic canisters. Thermal insulation between the shields is made from epoxy foam cast in position and cured under high temperature. Stacked mounting array supports the maser's hexapole magnet and hydrogen atom source.

Cutler, L.↗
DOE OSTI2016

IS Process Hydrogen Production Test for Components and System Made of Industrial Structural Material - (I) - Bunsen and HI Concentration Section - 18628

Japan Atomic Energy Agency (JAEA) has been conducting research and development on a hydrogen production system as one of the heat applications of High Temperature Gas-Cooled Reactor. The iodine-sulfur (IS) process is one of the most promising thermochemical methods because of its potential for large-scale CO{sub 2} free hydrogen production. In the IS process, hydrogen is produced through three chemical reactions: Bunsen reaction, hydriodic acid (HI) decomposition and sulfuric acid (H{sub 2}SO{sub 4}) decomposition. High corrosion resistance is required of the component materials in the IS process because the high-temperature strong acids flow in this process. JAEA has fabricated a 30 NL/h - H{sub 2}-scale apparatus made of glass and Teflon which boast corrosion-resistance for the acids, and has succeeded a continuous operation for a week. However, for practical use on a larger scale, the components have to be made of industrial corrosion-resistance materials. As a next step, we have fabricated the new test-facility which can produce H{sub 2} of 100 NL/h-scale for the demonstration of the continuous operation by using the industrial materials. In advance of the continuous operation, we investigated the performance of the components in each section of the IS process. In this presentation, the test results of Bunsen and HI concentration sections will mainly be discussed. (authors)

08 HYDROGEN↗