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At least 55 records · Page 3

Results from the Gas Chromatograph Mass Spectrometer (GCMS) Experiment on the Cassini-Huygens Probe

The GCMS was part of the instrument complement on the Cassini-Huygens Probe to measure in situ the chemical composition of the atmosphere during the probe descent and coupled with the Aerosol Collector Pyrolyser (ACP) experiment by serving as detector for the pyrolization products to determine the composition of the aerosol particles. The GCMS employed a quadrupole mass filter with a secondary electron multiplier detection system and a gas sampling system providing continuous direct atmospheric composition measurements and batch sampling through three gas chromatographic (GC) columns, a chemical scrubber and a hydrocarbon enrichment cell. The GCMS gas inlet was heated to prevent condensation, and to evaporate volatiles from the surface after impact. The GCMS collected data from an altitude of 146 km to ground impact. The Probe and the GCMS survived impact and collected data for 1 hour and 9 minutes on the surface. Mass spectra were collected during descent and on the ground over a range of m/z from 2 to 141. The major constituents of the lower atmosphere were confirmed to be NP and CH4. The methane mole fraction was uniform in the stratosphere. It increased below the tropopause, at about 32 km altitude, monotonically toward the surface, reaching a plateau at about 8 km at a level near saturation. After surface impact a steep increase of the methane signal was observed, suggesting evaporation of surface condensed methane due to heating by the GCMS sample inlet heater. The measured mole fraction of Ar-40 is 4.3 x 10(exp-5) and of Ar-36 is 2.8 x 10(exp -7). The other primordial noble gases were below mole fraction. The isotope ratios of C-12/C-13 determined from methane measurements are 82.3 and of N-14/N-15 determined from molecular nitrogen are 183. The D/H isotope ratio determined from the H2 and HD measurements is 2.3 x l0(exp -4). Carbon dioxide, ethane, acetylene and cyanogen were detected evaporating from the surface in addition to methane.

Niemann, Hasso B.↗

The Resource Prospector Neutron Spectrometer System: RP's Bloodhound

The primary goal of the Resource Prospector Neutron Spectrometer System (NSS) is to locate and characterize hydrogen-bearing volatile deposits, especially subsurface ice, that may exist at the lunar poles. A key objective is to detect water-equivalent hydrogen concentrations of 0.5 wt% or greater while on a moving rover. A second objective is to determine approximate burial depth of enhanced hydrogen-bearing materials up to 1 meter below otherwise dry regolith. The instrument will be carried aboard a landed mobility system at the lunar poles. The instrument operates by measuring the changes in the leakage flux of low energy neutrons out of the regolith. These neutrons are produced by galactic cosmic rays, which are so energetic that they shatter the nuclei in surface materials. The neutrons interact with other nuclei and lose energy, becoming thermalized in the process. Hydrogen is most efficient at thermalizing neutrons owing to protons' similar mass - statistically, neutrons lose half their energy per collision with protons. With hydrogen in the soil, leakage fluxes of neutrons in the 0.5 eV to 500 keV energy range are reduced. A concentration of only1-2 wt% water-equivalent hydrogen results in a decrease in epithermal leakage flux of a factor of two. The leakage flux of thermal neutrons, from 0 to 0.5 eV in energy, can either increase or decrease depending on the hydrogen abundance and stratigraphy. As with the highly successful Lunar Prospector Neutron Spectrometer, the RP NSS detects both thermal and epithermal neutrons by using two helium-3 gas proportional counters, one covered by cadmium and the other uncovered. The former detects only epithermal neutrons with energies above approximately 0.5 eV, the latter detects both thermal (less than 0.5 eV) and epithermal energies (greater than 0.5 eV). When a neutron enters the detector tube and interacts with a helium-3 nucleus, the resulting reaction produces an energetic proton and triton that ionize the gas. The resulting electrons are accelerated toward a high-voltage anode and cascade, amplifying the net charge, which is collected at the anode. The number of electrons produced is proportional to the energy that the triton and proton deposit in the gas. A charge sensitive pre-amplifier converts the total charge to a step voltage output. A shaper amplifier then shapes this step into a uni-polar waveform with peaking time appropriate for the detection depending on the event rate. The integrated shaped waveform, representing the deposited triton/proton energy, is then measured. A histogram, or pulse height analysis, is performed to record the main capture peak and wall effect pulses. A threshold for detection is also required to limit the low amplitude counting rate such as noise floor. The system electronics consists of 2 modules - the Sensor Module (SM) front-end and the Data Processing Module (DPM) back-end circuits. SM is designed as a light-weight and low power front-end housing the two helium-3 proportional counter detectors, preamp and HVPS. It is mounted external to the rover body to detect the thermalized neutron flux with a minimum of host background. The DPM is located inside the rover; it digitizes the SM signals, performs pulse height analysis and accumulates the count rate for each spectral channel. The DPM controls high voltage and thresholding, and sends the science data to the host craft via an RS422 serial asynchronous protocol. The payload host provides all thermal management and control for the SM and DPM.

hydrogen-bearing volatile deposits↗

Results obtained with position sensitive multiwire proportional chambers with helium, carbon, and oxygen nuclei

Spatial resolution performance results obtained at the Lawrence Radiation Laboratory Bevatron with prototype multiwire proportional chamber spatial detectors with integral delay line readout are presented. The effects due to incident nuclei charge, chamber operating parameters, chamber design, electronics, gas mixtures, and magnetic field presence have been investigated and are discussed.

Emming, J. G.↗

The quiet-time spectra of cosmic-ray electrons of energies between 10 and 200 MeV observed on OGO-5.

Measurement of spectra of cosmic-ray electrons of energies between 10 and 200 MeV over a one-year period starting 1968 March. The measurement was made with a detector system on board the OGO-5 satellite. The instrument consists of a solid-state dE/dx detector, a total-energy CsI detector, a gas Cerenkov threshold detector, and two scintillation guard counters. Time periods during which no solar-flare events were recorded were selected for the study. It was found that during these quiet periods there were numerous intensity variations of the electron flux. These variations, which are seen only below 25 MeV, do not show marked correlation with any solar or interplanetary-medium parameters. The flux of the electrons of energies above 25 MeV, on the other hand, showed a gradual decrease over the one-year period, paralleling the neutron monitor intensity. The parameter describing this long-term modulation is almost independent of the rigidity of the electrons in the reported energy range. The physical implication of the finding is discussed.

L'Heureux, J.↗

Synthesis and evaluation of polymers for use in early warning fire alarm devices

Conjugated polyacetylene polymers and one condensation polyene, all containing a high degree of conjugated unsaturation, were synthesized. These polymers were characterized by chemical analysis and by thermogravimetric analysis, as well as for their film-forming capability and gas/polymer interactions. It was found that those that had a high degree of conjugated unsaturation and had resonance - stabilizing groups were very thermally stable to 200 C, e.g., poly(dicyanoacetylene), poly(ethynylferrocene) and poly(phenylacetylene); while those with labile moieties, such as poly(p-formamidophenylacetylene), among others, suffered some degradation when heated in air. When subjected to gas/polymer interaction effects, the greatest change in electrical conductance was observed when ammonia was used as the gas and poly(p-nitrophenylacetylene) was the detector. Other polymers showed similar behavior. For example, poly(ethynylcarborane), considered to be an electron acceptor also showed a change in electrical conductance when exposed to ammonia, while poly(ethynylpyridine) and poly(ethylidenepyridazine) responded to carbon monoxide. However, for "fire gases" (gases from smoldering cotton), poly(ethynylferrocene) was the most responsive. Thus, the concept of polymers with different electronegativities forming charge-transfer complexes with different gases was found to be operable.

Byrd, N. R.↗

NASA Tech Briefs, March 2012

The topics include: 1) Spectral Profiler Probe for In Situ Snow Grain Size and Composition Stratigraphy; 2) Portable Fourier Transform Spectroscopy for Analysis of Surface Contamination and Quality Control; 3) In Situ Geochemical Analysis and Age Dating of Rocks Using Laser Ablation-Miniature Mass Spectrometer; 4) Physics Mining of Multi-Source Data Sets; 5) Photogrammetry Tool for Forensic Analysis; 6) Connect Global Positioning System RF Module; 7) Simple Cell Balance Circuit; 8) Miniature EVA Software Defined Radio; 9) Remotely Accessible Testbed for Software Defined Radio Development; 10) System-of-Systems Technology-Portfolio-Analysis Tool; 11) VESGEN Software for Mapping and Quantification of Vascular Regulators; 12) Constructing a Database From Multiple 2D Images for Camera Pose Estimation and Robot Localization; 13) Adaption of G-TAG Software for Validating Touch and Go Asteroid Sample Return Design Methodology; 14) 3D Visualization for Phoenix Mars Lander Science Operations; 15) RxGen General Optical Model Prescription Generator; 16) Carbon Nanotube Bonding Strength Enhancement Using Metal Wicking Process; 17) Multi-Layer Far-Infrared Component Technology; 18) Germanium Lift-Off Masks for Thin Metal Film Patterning; 19) Sealing Materials for Use in Vacuum at High Temperatures; 20) Radiation Shielding System Using a Composite of Carbon Nanotubes Loaded With Electropolymers; 21) Nano Sponges for Drug Delivery and Medicinal Applications; 22) Molecular Technique to Understand Deep Microbial Diversity; 23) Methods and Compositions Based on Culturing Microorganisms in Low Sedimental Fluid Shear Conditions; 24) Secure Peer-to-Peer Networks for Scientific Information Sharing; 25) Multiplexer/Demultiplexer Loading Tool (MDMLT); 26) High-Rate Data-Capture for an Airborne Lidar System; 27) Wavefront Sensing Analysis of Grazing Incidence Optical Systems; 28) Foam-on-Tile Damage Model; 29) Instrument Package Manipulation Through the Generation and Use of an Attenuated-Fluent Gas Fold; 30) Multicolor Detectors for Ultrasensitive Long-Wave Imaging Cameras; 31) Lunar Reconnaissance Orbiter (LRO) Command and Data Handling Flight Electronics Subsystem; and 32) Electro-Optic Segment-Segment Sensors for Radio and Optical Telescopes.

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Spartan - Space at low-cost

Mission profiles and objectives of the Spartan Shuttle payload are described. Spartan was designed to provide extended observations normally carried out for only a few minutes using sounding rockets. The payload will be placed in co-orbit with the Orbiter by the RMS arm and controlled by a ground-based researcher or by an on-board program. Spartan features minimal battery power, batteries, and control systems and no redundancy. Thermal control is added because the flights last 100-1000 times as long as those on sounding rockets. Data are recorded by an on-board tape recorder and operations are controlled by an on-board microprocessor. Spartan 1 will carry a star-pointer and X-ray detectors for high energy astrophysics experiments. Spartan 2 will gather solar physics data in the form of temperatures of hydrogen gas and ions and electrons. Particle densities will also be monitored and a 43 cm solar telescope will produce UV and white light solar coronagraphs. UV spectroscopy of stars, clouds and galaxies will be performed by the Spartan 3 payload.

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Cold cathode gage experiment (lunar-atmosphere detector)

A preliminary evaluation of the cold cathode gage experiment which was included in the ALSEP to determine the amount of gas present on the lunar surface is reported. The instrument, electronic circuitry, and deployment are described. The preliminary results are summarized and include temperature history, and variations in gas concentration detected after deployment.

Johnson, F. S.↗

Instrument to measure energy and charge of low energy interplanetary particles

An experiment to measure the charge composition and energy spectra of ultra low energy charged particles in interplanetary space has been developed and launched on the IMP 8 (Explorer 50) satellite on Oct. 26, 1973. The instrument consists of two separate sensors sharing common electronics. One of these sensors uses a thin window gas proportional counter to measure the rate of energy loss and a totally depleted silicon surface barrier detector to measure total energy of incoming particles. The energy range for two dimensional analysis extends from 300 KeV to 2.5 MeV for protons and 60 KeV/nucleon to 25 MeV/nucleon for iron with excellent resolution of individual chemical elements. The other sensor combines electrostatic deflection with total energy measurements in silicon surface barrier detectors to give the ionic charge and kinetic energy of the particle.

Tums, E.↗

Detectors for high energy cosmic rays on Spacelab

Two instruments designed to determine the spectra of the individual cosmic-ray components at very high energies are described. One of these (CRNE) uses a combination of gas Cerenkov counters and transition radiation detectors for the cosmic-ray nuclei lithium to nickel; the other (TRIC) is optimized for the light cosmic rays (electrons, protons, helium) and uses a transition-radiation/ionization-calorimeter combination. The CRNE instrument, constructed at the University of Chicago, was delivered to NASA for a first Shuttle flight on Spacelab-2 in summer 1985. Some of the technical and programmatic requirements encountered during the hardware construction and integration are discussed, and the expected scientific return and the prospects of using such instrumentation on the Space Station are considered.

Lheureux, J.↗

Operation of a microchannel plate counting system in a mass spectrometer

A multiplier detector system has been developed as part of a mass spectrometer in an ion counting mode. During its operation ions striking a microchannel plate release pulses of electrons which are accelerated to a phosphor layer. The resulting flash of light is carried by a fiber-optic bundle to a photodiode array. The detector simultaneously counts ions throughout a mass spectrum covering more than 30 amu. It extends the mass spectrometer's operation toward low count rates for trace gas analysis. Each mass peak can be independently measured at count rates between 0.1 and 1000 counts/s. Higher rates on a few peaks do not blind the entire detector. The detector's capabilities have been demonstrated by measuring Kr and Xe isotopes in air at natural abundances. The mass spectrometer, detector, and readout electronics are sufficiently compact to permit use in a balloon-borne experiment.

Murphy, D. M.↗

Miniature Tunable Laser Spectrometer for Detection of a Trace Gas

An open-path laser spectrometer (OPLS) for measuring a concentration of a trace gas, the OPLS including an open-path multi-pass analysis region including a first mirror, a second mirror at a distance and orientation from the first mirror, and a support structure for locating the mirrors, a laser coupled to the analysis region and configured to emit light of a wavelength range and to enable a plurality of reflections of the emitted light between the mirrors, a detector coupled to the analysis region and configured to detect a portion of the emitted light impinging on the detector and to generate a corresponding signal, and an electronic system coupled to the laser and the detector, and configured to adjust the wavelength range of the emitted light from the laser based on the generated signal, and to measure the concentration of the trace gas based on the generated signal.

Christensen, Lance E.↗

Cosmic ray experimental observations

The current experimental situation in cosmic ray studies is discussed, with special emphasis on the development of new detector systems. Topics covered are the techniques for particle identification, energy measurements, gas Cerenkov counters, magnet spectrometers, ionization spectrometers, track detectors, nuclear emulsions, multiparameter analysis using arrays of detectors, the Goddard ionization spectrometer, charge spectra, relative abundances, isotope composition, antinuclei in cosmic rays, electrons, the measurement of cosmic ray arrival directions, and the prehistory of cosmic rays.

Balasubrahmanyan, V. K.↗

Electron beam fluorescence system to measure gas density in impulse facilities

Very rapid measurements, ranging from a few microsecond to milliseconds in duration, characterize studies made in shock regions or behind them. A system to measure gas density under such conditions in a 15.24-cm (6-in.) expansion tube is described. The basic elements are an electron beam of moderate energy and high current capability, an optical detector, and the associated electronics and data readout equipment. A heated-cathode electron gun, capable of pulsed operation and delivering up to 200 milliamperes current, provides the source of electrons. Optics include a simple collector lens, aperture, collimator lens, filters, and a photomultiplier tube. The photomultiplier output signal was recorded by means of photographed oscilloscope traces for pulsed beam operation.

Hoppe, J. C.↗

Proportional counter for X-ray analysis of lunar and planetary surfaces

A position sensitive proportional scintillation detector was developed and evaluated for use in applications involving X-ray imaging as well as spectroscopy. Topics covered include limitations of the proportional scintillation counter for use in space; purification of the xenon gas in the detector, and the operation of the detector system. Results show that the light signal in a proportional scintillation detector remains well localized. With modest electric fields in xenon, the primary electrons from a photoelectric absorption of an X-ray can be brought a distance of a few millimeters to a higher field region without spreading more than a millimeter or so. Therefore, it is possible to make a proportional scintillation detector with good position sensitivity that could be used to calibrate out the difference in light collection over its sensitive volume.

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Gas ionization solar spectral monitor (GISSMO)

We are currently developing an instrument free from optical components to measure the full-disk solar spectrum in the extreme ultraviolet regime covering wavelengths from 75-500 A. The instrument, which will be launched aboard a NASA Black Brant sounding rocket in September 1992, consists of a windowless noble gas ionization cell followed by a toroidal electrostatic analyzer to spatially disperse photoelectrons as a function of their energies. A microchannel plate based position sensitive detector will be used to detect individual electrons, indirectly returning the solar EUV spectrum.

Vickers, James S.↗

Search for life on Mars: Evaluation of techniques

An important question for exobiology is, did life evolve on Mars? To answer this question, experiments must be conducted on the martian surface. Given current mission constraints on mass, power, and volume, these experiments can only be performed using proposed analytical techniques such as: electron microscopy, X-ray fluorescence, X-ray diffraction, a-proton backscatter, g-ray spectrometry, differential thermal analysis, differential scanning calorimetry, pyrolysis gas chromatography, mass spectrometry, and specific element detectors. Using prepared test samples consisting of 1% organic matter (bovine serum albumin) in palagonite and a mixture of palagonite, clays, iron oxides, and evaporites, it was determined that a combination of X-ray diffraction and differential thermal analysis coupled with gas chromatography provides the best insight into the chemistry, mineralogy, and geological history of the samples.

Schwartz, D. E.↗

Miniature Focusing Time-of-Flight Mass Spectrometer

An improved miniature time-of-flight mass spectrometer has been developed in a continuing effort to minimize the sizes, weights, power demands, and costs of mass spectrometers for such diverse applications as measurement of concentrations of pollutants in the atmosphere, detecting poisonous gases in mines, and analyzing exhaust gases of automobiles. Advantageous characteristics of this mass spectrometer include the following: It is simple and rugged. Relative to prior mass spectrometers, it is inexpensive to build. There is no need for precise alignment of its components. Its mass range is practically unlimited Relative to prior mass spectrometers, it offers high sensitivity (ability to measure relative concentrations as small as parts per billion). Its resolution is one dalton (one atomic mass unit). An entire mass spectrum is recorded in a single pulse. (In a conventional mass spectrometer, a spectrum is recorded mass by mass.) The data-acquisition process takes only seconds. It is a lightweight, low-power, portable instrument. Although time-of-flight mass spectrometers (TOF-MSs) have been miniaturized previously, their performances have not been completely satisfactory. An inherent adverse effect of miniaturization of a TOF-MS is a loss of resolution caused by reduction of the length of its flight tube. In the present improved TOF-MS, the adverse effect of shortening the flight tube is counteracted by (1) using charged-particle optics to constrain ion trajectories to the flight-tube axis while (2) reducing ion velocities to increase ion flight times. In the present improved TOF-MS, a stream of gas is generated by use of a hypodermic needle. The stream of gas is crossed by an energy-selected, pulsed beam of electrons (see Figure 1). The ions generated by impingement of the electrons on the gas atoms are then focused by three cylindrical electrostatic lenses, which constitute a segmented flight tube. After traveling along the flight tube, the ions enter a charged-particle detector. The output of the detector is fed to a counting circuit to obtain data on the counting rate as a function of time. Inasmuch as time of flight is directly proportional to the ion mass, a plot of the counting rate versus time of flight is equivalent to a mass spectrum (see Figure 2).

Kanik, Isik↗