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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 55 records · Page 3

Nanohybrid of Cu2O-Ti3C2Tx as a Silver-Free MXene Sorbent for Iodine Gas Capture from Nuclear Waste

The capture of volatile radioiodine from nuclear fuel reprocessing off-gas streams remains a critical challenge due to the high volatility, long half-life of 129I, and biological uptake of iodide from the environment. Although silver-based sorbents provide strong iodine chemisorption, their high cost and regulatory classification as mixed radioactive-hazardous waste motivate the development of alternative materials. Here, we report a silver-free Cu2O-Ti3C2Tx MXene hybrid for iodine gas capture at 150 °C. Structural and compositional analyses confirm the formation of Cu2O nanoparticles on Ti3C2Tx nanosheets and their subsequent conversion to thermodynamically stable CuI upon static iodine gas exposure, achieving an iodine mass loading of up to 1115 mg/g. These results demonstrate the potential of Cu2O-Ti3C2Tx MXene as a copper-based alternative to silver sorbents for elevated-temperature iodine gas capture.

iodine gas capture↗

Free-free absorption of infrared radiation in collisions of electrons with neutral rare-gas atoms

A relationship between the inverse bremsstrahlung absorption cross section and the electron neutral momentum transfer cross section has been utilized to determine the infrared free-free continuum absorption coefficient for the negative ions of helium, neon, argon, krypton, and xenon. The values of the momentum transfer cross section for this calculation have been obtained from experimental measurements. Analytical expressions for the absorption coefficient have also been developed. From the results of this calculation, it is possible to determine the absorption coefficient per unit electron density per neutral atom for temperatures in the range from 2500 to 25,000 K. The results are compared with those from tabulations of previous calculations and those computed from theoretical values of the phase shifts for the elastic scattering of electrons by neutral atoms.

Stallcop, J. R.↗

Non-context-free grammars generating context-free languages

If G is a grammar such that in each non-context-free rule of G, the right side contains a string of terminals longer than any terminal string appearing between two nonterminals in the left side, then the language generated by G is context free. Six previous results follow as corollaries of this theorem.

Baker, B. S.↗

Theoretical models of free-free microwave emission from solar magnetic loops

The free-free microwave emission is calculated from a series of model magnetic loops. The loops are surrounded by a cooler external plasma, as required by recent simultaneous X ray and microwave observations, and a narrow transition zone separating the loops from the external plasma. To be consistent with the observational results, upper limits on the density and temperature scale lengths in the transition zone are found to be 360 km and 250 km, respectively. The models which best produce agreement with X ray and microwave observations also yielded emission measure curves which agree well with observational emission measure curves for solar active regions.

Brosius, Jeffrey W.↗