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At least 55 records · Page 3
All sourcesNASA NTRSDOE OSTI
DOE OSTI2023

Redox and mineral controls on Fe and Ti isotopic fractionations during calc-alkaline magmatic differentiation

Titanium and Fe isotopic compositions of lavas from a calc-alkaline differentiation suite and corresponding mineral separates from the Rindjani Volcano, Indonesia show that Fe and Ti isotopic fractionations between minerals and melts are lower than those recorded in other suites at all stages of differentiation. Here, the limited isotopic fractionation for Ti is likely due to low-Ti magnetite and clinopyroxene being the dominant carriers of Ti in Rindjani lavas, as these minerals are thought to have limited equilibrium Ti isotopic fractionation relative to silicate magmas. Other magmatic differentiation suites controlled by removal of Ti-rich magnetite and characterized by a lesser role of clinopyroxene have larger Ti isotopic fractionations. This effect is an indirect consequence of the elevated Fe 3+ /Fe 2+ ratio of calc-alkaline magmas such as Rindjani, which promotes Fe 3+ incorporation into magnetite at the expense of Fe 2+ -Ti 4+ pairs, such that increased oxygen fugacity will subdue Ti isotopic fractionation in global magmatic series. Similarly, we find negligible Fe isotopic fractionation in Rindjani bulk rocks and mineral separates, unlike previous studies. This is also likely due to the oxidized nature of the Rindjani differentiation suite, which leads to similar Fe 3+ /Fe 2+ ratios in melt and minerals and decreases overall mineral-melt Fe fractionation factors. Paired Ti and Fe isotopic analyses may therefore represent a powerful tool to assess oxygen fugacity during differentiation, independent from Fe 3+ determinations of erupted samples.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2025

High-resolution tunnelling spectroscopy of fractional quantum Hall states

Strong interactions between electrons in two-dimensional systems in the presence of a high magnetic field give rise to fractional quantum Hall states that host quasiparticles with a fractional charge and fractional exchange statistics. Here, in this work, we demonstrate high-resolution scanning tunnelling microscopy and spectroscopy of fractional quantum Hall states in ultra-clean Bernal-stacked bilayer graphene devices. Spectroscopy measurements show sharp excitations that have been predicted to emerge when electrons fractionalize into bound states of quasiparticles. We found energy gaps for candidate non-abelian fractional states that are larger by a factor of five than those in other related systems, for example, semiconductor heterostructures, and this suggests that bilayer graphene is an ideal platform for manipulating these quasiparticles and for creating topological quantum bits. We also found previously unobserved fractional states in our very clean graphene samples.

quantum Hall↗
DOE OSTI2024

Effect of the volume fraction gradient on the phase interaction force model for disperse two-phase flows

In this work, the effects of the particle volume fraction gradient on fluid-particle interactions are studied. The phase interaction force is decomposed into three terms. For the first term, namely the symmetrized force density, we present theoretical reasoning and numerical evidence to assume that it is independent of the particle volume fraction gradient. The second term is the particle volume fraction gradient times a newly introduced diffusion stress. The third term is the divergence of the particle-fluid-particle (PFP) stress. If this assumption of independence of the particle volume fraction gradient for the first term can be verified, to the first order of the ratio of the mean distance between particles to the macroscopic lengthscale, all three terms can be studied and modeled in flows with uniform particle distributions. Models thus obtained are applicable to statistically inhomogeneous flows, with the second and third terms accounting for statistical inhomogeneity. To verify this assumption, numerical simulations of flows passing fixed arrays of particles are performed. Both uniform and nonuniform particle volume fractions are studied and compared for disperse multiphase flows with the particle Reynolds numbers ranging from 1 to 100, and particle volume fraction ranging from 1% to 26% in statistically steady states. It is found that the symmetrized force (first) term can be well approximated by the drag force obtained from studies of uniform flows. The diffusion stress is positive along the flow direction and negative in the directions perpendicular to the flow. In the case of moving particles, this stress could potentially cause particle aggregation in the flow direction and dispersion in the directions perpendicular to the flow. Finally, the diffusion stress is only important when there is a volume fraction gradient, while the PFP stress can be important in inhomogeneous flows with either nonuniform particle concentrations or nonuniform average relative velocities between the phases.

42 ENGINEERING↗
DOE OSTI2021

A Bimodal Diagnostic Cloud Fraction Parameterization. Part II: Evaluation and Resolution Sensitivity

A wide range of approaches exists to account for subgrid cloud variability in regional simulations of the atmosphere. This paper addresses the following questions: 1) Is there still benefit in representing subgrid variability of cloud in convection-permitting simulations? 2) What is the sensitivity to the cloud fraction parameterization complexity? 3) Are current cloud fraction parameterizations scale-aware across convection-permitting resolutions? These questions are addressed for regional simulations of a 6-week observation campaign in the U.S. southern Great Plains. Particular attention is given to a new diagnostic cloud fraction scheme with a bimodal subgrid saturation-departure PDF, described in Part I. The model evaluation is performed using ground-based remote sensing synergies, satellite-based retrievals, and surface observations. It is shown that not using a cloud fraction parameterization results in underestimated cloud frequency and water content, even for stratocumulus. The use of a cloud fraction parameterization does not guarantee improved cloud property simulations, however. Diagnostic and prognostic cloud schemes with a symmetric subgrid saturation-departure PDF underestimate cloud fraction and cloud optical thickness, and hence overestimate surface shortwave radiation. These schemes require empirical bias-correction techniques to improve the cloud cover. The new cloud fraction parameterization, introduced in Part I, improves cloud cover, liquid water content, cloud-base height, optical thickness, and surface radiation compared to schemes reliant on a symmetric PDF. Furthermore, cloud parameterizations using turbulence-based, rather than prescribed constant subgrid variances, are shown to be more scale-aware across convection-permitting resolutions.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2023

Simulation of Mechanical Fractionation of Chopped Whole-Plant Corn (WPC) Using Discrete Element Method (DEM)

Fractionating whole-plant corn (WPC) in a single-pass harvesting system requires studies on the WPC-to-equipment interaction for improved property control, as well as mechanical and air-driven separation processes compared to the traditional multi-pass grain and stover harvesting system. The discrete element method (DEM) technique has the potential to simulate WPC mechanical fractionation and support simulation-based design of WPC separation processes. In this study, methods to develop DEM particle models of WPC (kernel, cob, stalk, and husk) and their material properties for simulating mass fractionation using the ASABE standard mechanical shaker were proposed. Measurement was done on the axial dimensions (major, intermediate, and minor) and mass of each WPC type (mean sample size is 56), sampled from single-pass harvesting. Applying gaussian multivariate regression and bootstrapping re-sampling techniques, a DEM particle approximate to each WPC was developed. Sensitivity analysis of the DEM Young‘s modulus, Poisson‘s ratio, and interaction parameters of coefficient of restitution, coefficient of rolling friction, and coefficient of static friction on mass fraction was performed after 156 ASABE sieve-shaking DEM simulation runs, generated using Latin Hypercube Design (LHD) design of experiment (DOE) from 19 DEM material parameters. DEM simulation using Hertz-Mindlin with flexible bond contact laws and DOE optimized material properties successfully reproduced the mass fractions retained in ASABE sieves at 9.8% mean relative error and a coefficient of determination of R2 = 0.87. Here, the DEM methodology developed for mechanical WPC mass fractionation could be deployed to perform virtual design of feedstock handling equipment and performance analysis of mechanical fraction systems.

09 BIOMASS FUELS↗
DOE OSTI2022

Soil and soil fraction radiocarbon, C and N from the Enriched Background Isotope Study, Oak Ridge National Laboratory, Tennessee, USA

A large accidental 14CO2 release at the Oak Ridge Reservation in Tennessee, USA provided a strong label pulse into adjacent, well-studied oak forests, resulting in highly elevated Δ14C values in leaf litter (~1000‰) and roots (~260–450‰). A four-year manipulative study was conducted to provide insight into mechanisms underlying soil Organic matter dynamics, specifically to determine the relative contribution of litter versus roots to the bulk mineral soil C pool, as well as to free light, occluded light and heavy fractions. The heavy fraction was further split into fractions with densities of 1.7–2.4 g cm-3 and >2.4 g cm-3 to test the homogeneity of the mineral-associated fraction of C. Substantial concentrations of label were detected in all soil fractions within a year of the 14CO2 release, indicating rapid incorporation of newly fixed photosynthates in all fractions of soil organic C, regardless of differences in stability inferred by previous work. This rapid incorporation of label occurred only in treatments where roots were labeled, indicating that roots are the major source of inputs to mineral soil C stocks at these sites. Separation of the heavy fraction into subfractions of intermediate (1.7–2.4 g cm -3) and high (>2.4 g cm-3) density indicated that both subfractions incorporated label at similar rates, despite significant differences in degree of microbial processing.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2024

Reference Gastrointestinal Absorption Fractions for Radionuclides Ingested in Soil

Oak Ridge National Laboratory is conducting a project for the Environmental Protection Agency (EPA) Office of Superfund Remediation and Technology Innovation involving derivation of cancer risk coefficients for ingestion of radionuclides in soil. EPA provides guidance on quantifying gastrointestinal (GI) absorption of a chemical in a given medium for use in risk evaluations including assessments for Superfund sites. Essentially, a medium-specific GI absorption fraction may be applied if and only if there is sound information to support that value. Otherwise, the applied GI absorption fraction should be the best estimate of fractional absorption of the chemical when ingested in highly soluble form. Based on our review of the literature on GI absorption of elements in soil, we have concluded that for many elements there is convincing evidence of substantially reduced absorption in ingested soil compared with ingestion in readily dissolved form. This report summarizes the reviewed information and proposes a comprehensive set of GI absorption fractions for ingestion of elements in soil. For most elements, the proposed GI absorption fractions are lower than the default absorption fractions recommended by the International Commission on Radiological Protection for radionuclides ingested in highly soluble form, even though considerable conservatism has been incorporated into the proposed soil-specific GI absorption fractions.

59 BASIC BIOLOGICAL SCIENCES↗
DOE OSTI2022

Rare Earth Element (REE) and Critical Mineral Fractions of Central Appalachian Coal-Related Strata Determined by 7-Step Sequential Extraction

Rare earth elements (REEs) and critical minerals (CMs) are used in many modern industries, including the automotive sector, generation and storage, clean energy, and defense. The demand for REEs is increasing, and the REE supply chain is unpredictable. The US has driven to assess non-conventional sources of REE (such as coal underclay) to identify domestic resources to stabilize this uncertainty in supply. Knowledge of the minerology, distribution, and modes of occurrence of REEs is integral to the assessment of non-conventional sources. Additionally, extraction techniques can be optimized and targeted when REE distribution in different solid fractions from source material is understood. In this study, four bituminous coal-related samples associated with the Lower and Middle Kittanning coal seams in the Appalachian Basin (US) underwent a seven-step sequential extraction procedure, primarily targeting the water-soluble, exchangeable, acid soluble, mildly reducible, moderately reducible, strongly reducible, and oxidizable fractions. The REE and other elements of interest from each extraction step were analyzed, and the percentages of element extracted from raw solids were calculated. REEs extracted from the total seven steps were reported as the extractable fraction, whereas the fractions in the residual solids were reported as the non-extractable fraction. Less than 6% of REE were extracted from three samples. Twenty-one percent of REE was extracted from the fourth sample, mainly from the steps targeting oxidizable and exchangeable phases. Co-extraction of critical metals (Co, Ni, Cu, and Zn) occurred during the oxidizable, exchangeable, acid soluble, and water-soluble steps for the four samples. In the extracted fractions, the four samples all exhibited a middle and heavy REE enrichment relative to light REE. The mobility of major cation (e.g., Ca, Fe, and P) and REE is associated with exchangeable, oxidizable, and acid soluble fractions. Non-extractable REE is likely held in refractory apatitic phases, and/or primary REE-phosphates (e.g., monazite and xenotime).

58 GEOSCIENCES↗
DOE OSTI2026

Radial Profiles of the Binary Fraction in Elliptical Galaxies

The radial profile of the binary fraction may vary with environment and is of significant importance for studying the formation mechanisms of binary stars and their dynamical evolution within globular clusters and galaxies. However, existing studies remain limited to the Milky Way and its neighboring galaxies. Leveraging the method proposed by Zhang et al. for estimating the variation in the binary fraction from integrated spectral features, we analyze a sample of 513 elliptical galaxies drawn from the Mapping Nearby Galaxies at Apache Point Observatory survey to measure their radial binary fraction profiles. Our results show that after accounting for the effect induced by radial variations in the stellar population (SP), the median SP-subtracted binary fraction, $r^{\textrm{med}}_{\textrm{b,sub}}$, becomes approximately flat. For nearly all elliptical galaxies in our sample, the variation in the binary fraction relative to the galaxy center at 1R e is less than 5%. No clear correlation is found between the ​​​​​gradient of the binary fraction and the gradients of the SP properties. Moreover, we also compare differences between ultraviolet (UV) upturn and non-UV upturn galaxies. The overall binary fraction profiles and the SP properties of the non-UV upturn galaxies in our sample are comparable to those of the UV upturn galaxies. This similarity may arise from the presence of residual star formation in the non-UV upturn systems.

Li, Xiejin [Chinese Academy of Sciences; Universit↗
DOE OSTI2023

Technical Lignin Fractionation: A Powerful Tool for Lignin Structure Homogenization and Its Application

Extracted lignin as a by-product of pulping and bio-refining processes is the main available bio-phenolic polymer. The structural complexity, polydispersity, and black color of lignin are the main limiting factors for its application. Preparation of lignin with lower structural complexity and polydispersity through lignin fractionation is one of the primary solutions to engineer lignin into a value-added material. Sequential lignin fractionation was developed based on pH reduction from alkaline to acidic using mineral acids and was recently optimized using carbon dioxide as a pH controller. The partial solubility of lignin in organic solvents is another promising method for lignin fractionation. Organic solvents with different polarity and solubility factors are able to fractionate lignin, yielding a more homogeneous chemical structure. As a modification of the lignin fractionation process, the use of solvents, water/organic solvent mixtures, such as alcohols, and acetic acid from room to high temperature has been proposed as a greener method for lignin fractionation. Using membrane technology is another promising method and current results indicate its good potential for lignin recovery and fractionation.

Sadeghifar, Hasan↗
DOE OSTI2020

Chromium isotope fractionation during reduction of Chromium(VI) by Iron(II/III)-bearing clay minerals

Chromium stable isotope ratios are used to trace the reduction of Cr(VI) to Cr(III) in both ancient and modern systems. However, quantitative interpretation of Cr isotopic signatures has been stymied by the large variability in isotopic fractionation factors for Cr(VI) reduction by different reductants. Here we determine Cr isotope fractionation factors during Cr(VI) reduction by Fe(II/III)-bearing clay minerals, which are abundant in subsurface environments. Several variables were tested: pH, total Fe content of the clay, and the fraction of reduced Fe within the clay (Fe(II)/Fe(total)). The latter controls the standard reduction potential of the clay. Our results demonstrate that neither pH nor total Fe content of the clay have major effects on isotopic fractionation. In contrast, as the effective standard reduction potential of the clay and thus the standard free energy of Cr(VI) reduction become more negative, Cr isotope fractionation factors decrease in magnitude from - 4.9 to -1.3‰ according to a linear free energy relationship. This linear free energy relationship can be predicted from Marcus electron transfer theory and allows first-order predictions of Cr isotope fractionation factors to be made from the standard reduction potential or Fe(II)/Fe(total) of a clay, potentially improving our ability to model Cr isotope signatures in geochemical systems. Chromium is the first isotope system to show such a linear free energy relationship over a diverse range of reductants, including both aqueous and solid-phase reductants, and may provide a model for determining other redox-driven kinetic isotope effects in environmentally important isotope systems.

38 RADIATION CHEMISTRY, RADIOCHEMISTRY, AND NUCLEA↗
DOE OSTI2021

Examination of probability distribution of mixture fraction in LES/FDF modelling of a turbulent partially premixed jet flame

An accurate prediction of the probability density function (PDF) of the mixture fraction is crucial to the prediction of combustion since mixing plays an important role in turbulent non-premixed and partially premixed flames. This work provides an assessment of the large-eddy simulation (LES)/filtered density function (FDF) method for the prediction of the PDF of the mixture fraction. The advantage of the LES/FDF method is that it provides the full predictions of the statistical distribution of scalars including the mixture fraction. The predictive accuracy of the method for the PDF is yet to be fully validated. Assessing the prediction of the PDF of the mixture fraction, a conserved scalar, is an important starting point. The Sydney/Sandia inhomogeneous inlet jet flame is used as a test case. A quick comparison shows that the LES/FDF predicted PDF shapes of the mixture fraction deviate significantly from the commonly presumed Beta-PDF as well as from the experimental data in the flame. Here, to examine the source of the discrepancy, we clarify the different PDF definitions used in the comparison among the predictions, measurements, and the presumed shape PDFs. The discrepancy observed from the comparison is largely reconciled by clarifying the difference between the PDFs that are examined. The PDF of the resolved mixture fraction is shown to be close to the Beta-PDF in both the measurements and predictions, while the PDF directly deduced from the LES/FDF particles deviates significantly from the Beta-PDF. A multimodal PDF analysis and a pseudo convergence analysis are conducted to provide plausible evidence to support the predicted multimodal PDF shapes. The sub-filter scale FDF is shown to be close to the Beta-PDF too through the construction of a synthesized PDF, which supports the common presumed Beta-PDF assumption used in the presumed PDF methods when combined with LES.

42 ENGINEERING↗
DOE OSTI2026

Effects of 9.5 years warming on SOC concentration and composition in bulk soil and density fractions

Original data of whole-soil warming experiment after 9.5 years at Blodgett Forest Research Station. The Blodgett Forest is a mixed coniferous temperate forest with Mediterranean climate. The annual air temperature is 12.5℃ and the annual precipitation is 1774 mm yr-1- The soil is mesic ultic Alfisol of granitic origin, equivalent to Dystric Cambisol according to The World Reference Base for Soil Resources (WRB) system. The soil is warmed down to 1 m at + 4℃ by vertically installed heating cables. At the time of soil sampling on 1 May 2023, the whole-soil warming experiment had been running for approximately 9.5 years, from January 2014 to May 2023. The dataset includes: - Bulk_EA: C, N content, δ13C, and CN ratio of bulk soil; - Density_fractionation: organic carbon concentration, δ13C, and C/N ratio of free light fraction (fLF), occluded ligh fraction (oLF), and heavy fraction (HF); - PCA_DRIFT_AUC: original data of area under the curve (AUC) values of eight carbon bond types integrated on diffuse reflectance infrared fourier transform spectroscopy for each soil sample and soil fraction, which are consequently used for principal component analysis (PCA); - DRIFTS_stability_index: the calculation of aliphatic C–H (3000–2800 cm-1) to aromatic C=C (1670–1600 cm-1) ratios for each bulk soil sample and soil fraction. All data are provided in CSV format and can be viewed using Microsoft Excel.

Climate change↗
DOE OSTI2023

Techno-Economic Case Study: Low-Temperature Conversion Performance Based on Isolated Anatomical Fractions of Corn Stover

This report summarizes analysis conducted to support a case study under the Feedstock-Conversion Interface Consortium (FCIC) focused on techno-economic analysis (TEA) modeling to quantify the yield and cost ramifications for processing isolated anatomical fractions of corn stover through a low-temperature conversion (biochemical pathway) biorefinery. It is hypothesized that different individual anatomical fractions of corn stover vary in composition and recalcitrance, such that processing each fraction on its own e.g. through dedicated campaigns may enable economic benefits relative to processing the whole stover material. To investigate this concept, we worked with FCIC researchers to obtain data on compositional analysis, as well as processing conditions and yields, for conversion of whole corn stover plus three individual anatomical fractions (cobs, husks, and stalks) across key steps of the biorefinery conversion process within FCIC research scope, namely pretreatment and enzymatic hydrolysis. After running the data through the TEA models, fractionated cobs and husks achieved higher fuel yields and lower minimum fuel selling prices than whole corn stover, but stalks fared worse than whole stover on both metrics. The most direct takeaway from this assessment is that a biorefinery would stand to benefit economically from maximizing the use of cob and husk fractions while avoiding or minimizing the use of stalks, though recognizing practical constraints with this approach in maintaining an equivalent processing capacity (fixed at 2,000 dry metric tonne per day in all cases).

09 BIOMASS FUELS↗
DOE OSTI2021

Potassium isotopic fractionation in a humid and an arid soil–plant system in Hawai‘i

Plants play a critical role in the cycling of potassium (K) and the fractionation of its isotopes. However, little is known about K stable isotopic compositions in natural soil–plant systems and possible fractionation during intra-plant transport and root-soil uptake of K. Herein this study focuses on K isotopic fractionation within a humid and an arid soil–plant system sampled on the windward and leeward sides of Kohala Mountain, Hawai‘i. We determined the K isotopic compositions of < 2-mm bulk soil, soil saturation extraction, and selected plant tissues by multi-collector inductively coupled plasma mass spectrometry and X-ray absorption spectroscopy. We studied soils and individual tissue samples such as roots, stems, barks, shoots (a sum of stems and fresh leaves), leaves (fresh and dead), seeds, and flowers of trees and grasses. The results demonstrated that: (i) tissue δ 41 K values ranged from –1.06 ± 0.06 to 1.15 ± 0.09‰; (ii) within the same plant, stems (barks), dead leaves, and reproductive tissues (flowers and seeds) were isotopically lighter compared to fresh leaves, and to a lesser extent, roots; (iii) δ 41 K values of the humid soil (-0.54 ± 0.07 to –0.49 ± 0.06‰) were lower than those of the arid soil (-0.24 ± 0.07 to –0.14 ± 0.06‰); and (iv) soil bioavailable pool δ 41 K (saturation extracts) ranged from –0.63 ± 0.08 to 0.34 ± 0.08‰ and 0.48 ± 0.08 to 0.54 ± 0.10‰ in the humid and arid soils, respectively. From synchrotron-based analysis of K atoms, we identified two major K-bearing phases co-existing as ionic K + and K-pectate association of different fractions. Based on K isotopic and synchrotron data, we conclude that two dominant processes are responsible for plant-mediated K isotopic fractionation, including (1) K redistribution during intra-plant circulation and (2) uptake at the root-soil interface. For intra-plant circulation of K, there is a high affinity of isotopically lighter K to organic complexes as K-pectate, and K-pectate is particularly enriched in roots and fresh leaves. For K uptake at root-soil interface, isotopically lighter K is preferentially taken by roots from soil bioavailable pools following a low-affinity (passive) transport path. Soil K budget in two sites reflects strong source mixing effects with limited plant imprints. This work provides exploratory data on the biogeochemical fractionation of K isotopes in the soil–plant system.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2025

Upconversion of non-recycled MSW paper fractions into biochar via slow pyrolysis and life cycle analysis: Pathways to net negative GHG emission

This study presents an integrated and sustainable approach to valorizing non-recycled municipal solid waste (MSW), a heterogeneous and underutilized waste stream destined for landfilling, by converting it into valuable biochar resources. Specifically, we investigated the upcycling of nonrecycled paper waste based on compositional analysis into four major fractions: high cellulose, high lignin, high contamination, and high ash content papers. These fractions were then homogenized and subjected to slow pyrolysis. The high cellulose fraction (36.1 %) was the most abundant, and contained 66.7 % cellulose, while the high lignin fraction showed the highest lignin (12.1 %) and carbon content (44 %), resulting in highest energy value of 17.4 MJ kg −1 . Biochar yields ranged from 25.6 % to 35.6 %, with the high ash fraction producing the highest yield and alkalinity (pH ≈ 11.2) due to its higher mineral content. Elemental analysis revealed enhanced carbon content up to 76.9 % and reduced oxygen and hydrogen, confirming effective carbonization. The high lignin-derived biochar showed the highest aromatic carbon content (82.8 %) and greater structural stability, while contaminated and ash-rich fractions exhibited dense, low-porosity surfaces due to the presence of contaminants and minerals. Spectroscopic analysis revealed degradation of carbohydrates, disappearance of cellulose peaks and formation of aromatic and mineral derived phases. The scaled life cycle process yielded a global warming potential (GWP) of 119.3 kg CO 2 -eq per ton of dry paper waste, offset by soil carbon sequestration of − 556.41 kg CO 2 -eq, resulting in a net impact of − 427.36 kg CO 2 -eq. This represents a net carbon removal exceeding by ~186 % the emissions associated with landfilling paper waste with electricity generation.

09 BIOMASS FUELS↗
DOE OSTI2021

Radially resolved active charge exchange measurements of the hydrogenic isotope fraction on DIII-D

Radially resolved hydrogenic isotope fraction measurement capabilities have been developed for DIII-D using the main-ion charge exchange recombination (MICER) spectroscopy system in preparation for mixed hydrogen and deuterium experiments. Constraints on the hydrogenic ion temperatures and velocities based on measurements of the impurity ion properties are required to accurately fit the spectrum. Corrections for cross sectional distortions, spatial smearing due to the halo, and a neoclassical offset between the impurity and hydrogenic toroidal rotation are applied to the constraints prior to fitting the MICER spectrum. Extensive atomic physics calculations have been performed using the FIDASIM code, which has recently been improved to allow simulations using mixtures of hydrogenic species. Overall, these results demonstrate that for the same plasma parameters, the Dα emission is 20%–30% brighter than Hα due to differences in rate coefficients associated with the different ion thermal velocities for the same temperature and therefore must be taken into consideration when calculating absolute densities. However, despite these differences, the absolute error when estimating the hydrogen isotope fraction [n H /(n H + n D )] by using the Hα radiance fraction [L Hα /(L Hα + L Dα )] is typically less than 5% due to the way the fraction is formed, making the radiance fraction a reasonably accurate estimate of the isotope fraction for most cases.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
DOE OSTI2022

Correlation between the relative blob fraction and plasma parameters in NSTX

Here, we present a simple analysis of the fraction of blobs observed in the scrape-off layer of NSTX and calculates the correlation between this blob fraction and various plasma parameters. The measurements were made using the gas puff imaging (GPI) diagnostic on a database of 103 shots from 2010 with neutral beam power P NBI = 0–6 MW. The blob fraction ranged from f b = 0.1% to 4.8%, where f b is defined as the fraction of time the GPI signal was larger than three times its average value within 0–7.5 cm outside the separatrix. The blob fraction generally decreased with increasing neutral beam injection power and was lower on average in H-mode plasmas than Ohmic and L-mode plasmas. The blob fraction had its highest correlation with the measured poloidal turbulence velocity and its radial gradient just inside the separatrix. This is in part consistent with a model in which the blob generation rate increases with the poloidal velocity shear.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗