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At least 55 records · Page 3

Characterization Results for the September 2023 Tank Farm 3H Evaporator Overhead Sample

On an annual basis, Savannah River Mission Completion (SRMC) provides 2H and 3H evaporator overhead samples to Savannah River National Lab (SRNL) to be analyzed per Section 5.2 of the Effluent Treatment Project (ETP) Waste Compliance Plan (WCP) and the Waste Acceptance Criteria (WAC). This report presents the average characterization results for the September 2023 3H evaporator overhead sample. The sample was clear and colorless with no visible solids. The results provide measurements for cesium-137 ( 137 Cs), strontium-90 ( 90 Sr), and iodine-129 ( 129 I) with the radionuclide concentration limits specified by the WAC. These analyses were performed in duplicate, and all three measured radionuclide concentrations were within ETP WAC limits. A summary of the analytical results for this 3H evaporator overhead sample includes the following: The measured cesium-137 activity in the 3H evaporator overhead sample averaged 5.70E+01 dpm/mL, which is below the ETP WAC limit of 1.30E+03 dpm/mL. As seen through historical results, Cs-137 continues to present a decreasing activity since 2020. The strontium-90 activity in the 3H evaporator overhead sample averaged <2.16E00 dpm/mL, which is below the ETP WAC limit of 1.76E+02 dpm/mL. The iodine-129 activity in the 3H evaporator overhead sample averaged <9.08E-02 dpm/mL, which is below the ETP WAC limit of 1.00E+00 dpm/mL

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Characterization Results for the October 2024 Tank Farm 3H Evaporator Overhead Sample

On an annual basis, Savannah River Mission Completion (SRMC) provides 2H and 3H evaporator overhead samples to Savannah River National Lab (SRNL) to be analyzed per Section 5.2 of the Effluent Treatment Project (ETP) Waste Compliance Plan (WCP) and the Waste Acceptance Criteria (WAC). This report presents characterization results for the October 2024 3H evaporator overhead sample. The sample was clear and colorless with no visible solids. The results provide measurements for cesium-137 (137Cs), strontium-90 (90Sr), and iodine-129 (129I) with the radionuclide concentration limits specified by the WAC. These analyses were performed in duplicate, and a summary of the analytical results for this 3H evaporator overhead sample includes the following: The measured cesium-137 activity in the 3H evaporator overhead sample averaged 6.72E+01 dpm/mL, (3.90E+00 %RSD), which is below the ETP WAC limit of 1.30E+03 dpm/mL. The strontium-90 activity in the 3H evaporator overhead sample averaged <2.72E+00 dpm/mL, which is below the ETP WAC limit of 1.76E+02 dpm/mL. The iodine-129 activity in the 3H evaporator overhead sample averaged <1.63E-01 dpm/mL, which is below the ETP WAC limit of 1.00E+00 dpm/mL.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Characterization Results for the August 2025 Tank Farm 2H Evaporator Overhead Sample

On an annual basis, Savannah River Mission Completion (SRMC) provides 2H and 3H evaporator overhead samples to Savannah River National Lab (SRNL) to be analyzed per Section 5.2 of the Effluent Treatment Project (ETP) Waste Compliance Plan (WCP) and the Waste Acceptance Criteria (WAC). This report presents the average characterization results for the August 2025 2H evaporator overhead sample. The sample was clear and colorless with no visible solids. The results provide measurements for cesium-137 ( 137 Cs), strontium-90 ( 90 Sr), and iodine-129 ( 129 I) with the radionuclide concentration limits specified by the WAC. These analyses were performed in duplicate, and all three measured radionuclide concentrations were within ETP WAC limits. A summary of the analytical results for this 2H evaporator overhead sample includes the following: The measured cesium-137 activity in the 2H evaporator overhead sample averaged 3.02E+02 dpm/mL, which is below the ETP WAC limit of 1.30E+03 dpm/mL. The strontium-90 activity in the 2H evaporator overhead sample averaged 3.33E+00 dpm/mL, which is below the ETP WAC limit of 1.76E+02 dpm/mL. The iodine-129 activity in the 2H evaporator overhead sample averaged 1.20E-01 dpm/mL, which is below the ETP WAC limit of 1.00E+00 dpm/mL. Although the measurements for Cs-137 and Sr-90 are lower compared to previous years, the results remain within a similar range to past measurements and are well below the WAC limits. Iodine-129 indicates detectable results compared to previous years, which can be attributed to recent salt batch processing trending close to the WAC limit for saltstone production. However, these results are still below the ETP WAC limit.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Minimizing Cr-Evaporation from Balance of Plant Components by Utilizing Cost-Effective Alumina-Forming Austenitic Steels

A solid oxide fuel cell (SOFC) is a clean and efficient energy conversion device. The development of intermediate-temperature SOFCs has made it preferable to use metallic interconnects (MICs) to greatly reduce the cost and significantly increase the efficiency compared to ceramic interconnect materials. However, gaseous chromium species will evaporate from the chromium-containing layer formed on the surface of commonly used MICs and balance of plant (BoP) components. Volatile chromium species have been shown to form solid deposits which poison the cathodes of SOFCs, causing drastic cell performance degradation and thereby limiting commercialization. In order to alleviate the Cr poisoning and achieve long-term high performance of SOFC stacks, various Al2O3-forming austenitic (AFA) stainless steels applied at different temperatures are evaluated in this project. Based on our Phase I results (500 h operation), it is shown that on the AFAs, an alumina-based protective layer forms under high temperature that is invulnerable to water vapor effects and suppresses the diffusion of chromium and manganese which can prevent the generation of spinels on the alloy surface. Therefore, 310S, OC4 and OC5 at 800 °C and 625, OC11 and OC11LZ at 900 °C are selected to be tested in the Phase II long-term operation. From the results, we find that besides the lower Cr evaporation rates and better oxidation resistance of AFAs than benchmark alloys after short-term (500 h) operation, AFAs also possess the sturdy and compact alumina layer after a long-term operation (5000 h). A protective oxide layer is of great importance for the long-term high-temperature operation of structural materials. The high-temperature oxidation behavior of AFAs and commercial 310S and 625 alloys in Air + 10% H 2 O at 800 °C and 900 °C is systematically investigated. Severe breakaway oxidation and minor spallation are observed for the 310S and 625 after the long-term operation, while the AFAs show high oxidation resistance. It is found that the formation of a continuous alumina layer could greatly prevent the volatilization of chromium vapors. In addition, the corresponding evolving models are discussed. Chromium evaporation from BoP components in high-temperature environment could severely deteriorate the electrochemical performance of SOFC. Several methods were applied to evaluate the Cr evaporation rates of BoP after 500 h exposure at 800 °C to 900 °C in air with 10% H 2 O. An optimal method was designed to exclude the effect of silicon (Si) deposits from quartz tube and sodium (Na) deposits from the sodium carbonate on the oxidation process and the chemical interaction between Cr gaseous species and alumina tube which could provide further quantitative correlation of the evaporated Cr species quantities and degradation rates of SOFC. Based on the great performance of AFAs after long-term operation, AFAs are assembled with Anode-supported cells (ASC) to investigate the the Cr deposition of anode-supported cell under a constant current density of 0.5 A cm -2 at 800 °C with AFA alloys compared with commercial alloys. In addition, the anodic and cathodic processes are deconvoluted by distribution of relaxation times (DRT) method which are comprehensively discussed. It is found out that the voltage exhibited a slight decrease of 5.09 % and 1.54 % in the presence of OC11 and OC11LZA alloy, respectively. However, a considerable decrease of 22.14 % and 12.06 % was determined in the presence of 310S and 625 alloy, respectively. AFAs possessing the low-cost, low Cr evaporation rates and the high oxidation resistance will make it of great potential to replace the existing BoP components.

36 MATERIALS SCIENCE↗

Water vapor transport through bioenergy grass residues and its effects on soil water evaporation

Miscanthus is a productive perennial grass that is suitable as a bioenergy crop in “marginal” lands (e.g., eroded soils) with low water holding capacity. However, little is known about the impact of miscanthus residues on vapor transport and soil water budgets. Laboratory experiments were conducted to measure the vapor conductance through miscanthus residues and its effect on soil water evaporation. The ranges for the length, width, and thickness of residue elements were 0.5–9.0, 0.1–0.5, and 0.1–0.5 cm, respectively. Average residue areal, bulk, and skeletal densities were 0.88 kg m –2 , 24 kg m –3 , and 1006 kg m –3 , respectively, giving a porosity of 0.98 m 3 m –3 . A power function described the decrease in conductance with increasing residue load. The corresponding conductance for a residue load of 0.88 kg m –2 was 1.6 mm s –1 . During the first days of a 60-day drying experiment, cumulative evaporation showed logarithmic decay with increasing residue load. Conversely, cumulative evaporation during the last days of the study showed little difference between treatments. Measurements indicated that there is a “critical” residue load (~1.0 kg m –2 ) beyond which evaporation no longer decreases appreciably when the soil is under the stage 1 evaporation regime. Results suggest that soil water conservation in marginal lands may be accomplished by maintaining moderate amounts of bioenergy grass residue covering the soil. Determining “critical” loads for different residue types is a knowledge gap that merits further research.

54 ENVIRONMENTAL SCIENCES↗

Modeling of crystallization fouling on a horizontal-tube falling-film evaporator for thermal desalination

Scale formation within horizontal-tube falling-film evaporators is an important issue for thermal desalination, because of the deterioration of heat transfer performance and added maintenance costs. Predicting the fouling process is crucial for desalination plant design, operation, and maintenance. In this paper, a model is developed to predict the crystallization fouling process during seawater falling-film flow over a horizontal tube bundle. The scaling is estimated based on deposition theory, with couple heat transfer including the in-tube steam condensation, conduction through the tube wall and the scale layer, and falling-film evaporation. The spatial and temporal variations of temperature, heat transfer coefficient, and scale thickness are predicted, and the effects of variations in process parameters of steam, feed seawater, and tube properties on the scale thickness, evaporation rate, and heat transfer coefficient for falling-film evaporation are analyzed. Comparisons to existing experimental data show the scaling layer thickness falls in the general range of reported measurements, with a slight overestimation due to neglecting the delay of scaling onset under real conditions. The scale layer thickness increases dramatically as the in-tube steam pressure is increased or the seawater flow rate is decreased. In general, the scaling layer becomes thicker on the lower tubes in the tube bundle, due to the heat and mass transfer of the falling film. The effect of tube material on scaling appears mainly dependent on thermal conductivity; thus, using polymer rather than a stainless steel tube decreases scaling and evaporation rate 96% and 88%, respectively. Finally, this work has potential to guide thermal desalination plant design, material selection, and operating parameter optimization.

42 ENGINEERING↗

Universal correlation for falling film evaporation on a horizontal plain tube

Falling film evaporators are widely used in many industrial sectors, such as desalination, refrigeration & air-conditioning, and chemical processes. The heat transfer correlations suitable for wider operating conditions and various refrigerants are useful for designing falling film evaporators. Although many researchers developed the correlation for their own experimental data, there is a limited universal correlation for falling film evaporators. In addition, the dry-out effects were not considered in the available universal correlations. Here, therefore, this study proposes a new correlation for falling film evaporation on a single horizontal plain tube, which includes nucleate boiling, film evaporation, and dry-out effects. The proposed correlation covers a wider range of operating conditions (Heat flux is of 2.5–168kWm -2 , and film Reynolds number is up to 3500), various refrigerants (R134a, R245fa, R1234ze(E), R123, R32, R410A, R290, and R600a), and the large number of experimental data (1101 data in total). The proposed correlation is validated against the available standard correlation with regard to mean absolute deviation (MAD) and R 2 values. The MAD of the new correlation is about 10%, respectively, which is the lowest among other correlations. Similarly, the R 2 showed a value of 0.92, which is the highest compared to the existing correlations. A simplified correlation is also proposed.

42 ENGINEERING↗

Formation of a Secondary Phase in Thermally Evaporated MAPbI 3 and Its Effects on Solar Cell Performance

Thermal evaporation is a promising deposition technique to scale up perovskite solar cells (PSCs) to large areas, but the lack of understanding of the mechanisms that lead to high-quality evaporated methylammonium lead triiodide (MAPbI 3 ) films gives rise to devices with efficiencies lower than those obtained by spin coating. Here this work investigates the crystalline properties of MAPbI 3 deposited by the thermal coevaporation of PbI 2 and MAI, where the MAI evaporation rate is controlled by setting different temperatures for the MAI source and the PbI 2 deposition rate is controlled with a quartz crystal microbalance (QCM). Using grazing incident wide-angle X-ray scattering (GIWAXS) and X-ray diffraction (XRD), we identify the formation of a secondary orthorhombic phase (with a Pnma space group) that appears at MAI source temperatures below 155 °C. With synchrotron-based X-ray fluorescence (XRF) microscopy, we show that the changes in crystalline phases are not necessarily due to changes in stoichiometry. The films show a stochiometric composition when the MAI source is heated between 140 to 155 °C, and the samples become slightly MAI rich at 165 °C. Increasing the MAI temperature beyond 165 °C introduces an excess of MAI in the film, which promotes the formation of films with low crystallinity that contain low-dimensional perovskites. When they are incorporated in solar cells, the films deposited at 165 °C result in the champion power conversion efficiency, although the presence of a small amount of low-dimensional perovskite may lead to a lower open-circuit voltage. We hypothesize that the formation of secondary phases in evaporated films limits the performance of PSCs and that their formation can be suppressed by controlling the MAI source temperature, bringing the film toward a phase-pure tetragonal structure. Control of the phases during perovskite evaporation is therefore crucial to obtain high-performance solar cells.

36 MATERIALS SCIENCE↗

Implementation and Performance Evaluation of a Community-Scale Adobe Evaporative Cooling Chamber for Vegetable Preservation

The construction of evaporative coolers in remote areas can increase the longevity of vegetables, improving food security and the local economy of small farmers in remote, impoverished communities without access to electricity. This work presents a 1:1 scale prototype of an 8 m 3 (2.1 × 2.1 × 2.3 m) stabilized adobe evaporative cooler, with a design based on the appropriate technology framework, and it was built as a chamber using double adobe walls, filled with wet sand, to induce evaporative cooling. Furthermore, the paper presents the prototype’s performance evaluation. The tests were carried out in the dry and wet states, with different volumes of water. The results show good performance compared with other prototypes, although the optimum watering volume could not be determined because of the high climate variance (outside temperature and humidity) that prevented the repetition of the experiments in identical operating conditions. Stabilized adobe proved to be a good choice for use in the cooler, even when subject to moisture accumulation, indicating an estimated long lifetime for the cooler. The data obtained about the efficiency of evaporative cooling show that the cooler, as expected, has its best performance on the hottest and driest days, reducing the internal temperature (up to 13.24 °C) and managing to keep the internal humidity. The cost, efficiency, durability, and replicability make the proposed evaporative cooler a feasible solution for food preservation.

42 ENGINEERING↗

Thermally Evaporated Naphthalene Diimides as Electron Transport Layers for Perovskite Solar Cells

Thermally evaporated organic electron transport layers (ETLs) have the potential to enable high-performance and scalable perovskite solar cells (PSCs). Among these, naphthalene diimide (NDI)-based ETLs are a promising family of materials that exhibit the optoelectronic properties, ambient stability and versatility required of high-performance ETLs. Here, we synthesized five NDI derivatives with varying functional groups and identified the two most promising candidates for evaluating the impact of molecular structure on processability via thermal evaporation. While phosphonic acid functionalization was shown to introduce thermal instability, leading to chemical changes during evaporation, NDI-bis N-phenyl-bromide (NDI-(PhBr) 2 ) emerged as a promising ETL candidate. NDI-(PhBr) 2 demonstrated excellent compatibility with the thermal evaporation process and enabled PSCs with power conversion efficiencies (PCEs) of 15.6%, surpassing all previously reported PSCs containing thermally evaporated NDI ETLs. Furthermore, NDI-(PhBr) 2 exhibited excellent operational stability, retaining 75% of the initial PCE after 150 h of operation under continuous illumination at 65 °C. These results highlight the potential of NDI-based ETLs for advancing the scalability and performance of PSCs.

36 MATERIALS SCIENCE↗

Strong Local Evaporative Cooling Over Land Due to Atmospheric Aerosols

Abstract Aerosols can enhance terrestrial productivity through increased absorption of solar radiation by the shaded portion of the plant canopy—the diffuse radiation fertilization effect. Although this process can, in principle, alter surface evaporation due to the coupling between plant water loss and carbon uptake, with the potential to change the surface temperature, aerosol‐climate interactions have been traditionally viewed in light of the radiative effects within the atmosphere. Here, we develop a modeling framework that combines global atmosphere and land model simulations with a conceptual diagnostic tool to investigate these interactions from a surface energy budget perspective. Aerosols increase the terrestrial evaporative fraction, or the portion of net incoming energy consumed by evaporation, by over 4% globally and as much as ∼40% regionally. The main mechanism for this is the increase in energy allocation from sensible to latent heat due to global dimming (reduction in global shortwave radiation) and slightly augmented by diffuse radiation fertilization. In regions with moderately dense vegetation (leaf area index >2), the local surface cooling response to aerosols is dominated by this evaporative pathway, not the reduction in incident radiation. Diffuse radiation fertilization alone has a stronger impact on gross primary productivity (+2.18 Pg C y −1 or +1.8%) than on land evaporation (+0.18 W m −2 or +0.48%) and surface temperature (−0.01 K). Our results suggest that it is important for land surface models to distinguish between quantity (change in total magnitude) and quality (change in diffuse fraction) of radiative forcing for properly simulating surface climate.

Chakraborty, TC↗

Spatial pattern of lake evaporation increases under global warming linked to regional hydroclimate change

Abstract Lakes are critical natural resources that are vulnerable to climate change. In a warmer climate, lake evaporation is projected to increase globally, but with substantial variation between regions. Here, based on ensemble projections of climate and lake models and an attribution method, we show that future lake evaporation increase is strongly modulated by regional hydroclimate change. Specifically, a drying hydroclimate will amplify evaporation increase by enlarging surface vapor pressure deficit and reducing cloud shortwave reflection. Future lake evaporation increase is amplified in tropical America, the Mediterranean and Southeast China with drier future hydroclimates, and dampened in high latitudes and the Tibetan Plateau with wetter future hydroclimates. Such spatially coupled changes in lake evaporation and hydroclimate have important implications on regional lake water balance and volume change, which can aggravate water scarcity and flood risks.

54 ENVIRONMENTAL SCIENCES↗

A purely kinetic description of the evaporation of water droplets

The process of water evaporation, although deeply studied, does not enjoy a kinetic description that captures known physics and can be integrated with other detailed processes such as drying of catalytic membranes embedded in vapor-fed devices and chemical reactions in aerosol whose volumes are changing dynamically. In this work, we present a simple, three-step kinetic model for water evaporation that is based on theory and validated by using well-established thermodynamic models of droplet size as a function of time, temperature, and relative humidity as well as data from time-resolved measurements of evaporating droplet size. Additionally, the kinetic mechanism for evaporation is a combination of two limiting processes occurring in the highly dynamic liquid-vapor interfacial region: direct first order desorption of a single water molecule and desorption resulting from a local fluctuation, described using third order kinetics. The model reproduces data over a range of relative humidities and temperatures only if the interface that separates bulk water from gas phase water has a finite width, consistent with previous experimental and theoretical studies. The influence of droplet cooling during rapid evaporation on the kinetics is discussed; discrepancies between the various models point to the need for additional experimental data to identify their origin.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Direct numerical simulation of turbulent dispersion of evaporative aerosol clouds produced by an intense expiratory event

Airborne particles are a major route for transmission of COVID-19 and many other infectious diseases. When a person talks, sings, coughs, or sneezes, nasal and throat secretions are spewed into the air. After a short initial fragmentation stage, the expelled material is mostly composed of spherical particles of different sizes. While the dynamics of the largest droplets are dominated by gravitational effects, the smaller aerosol particles, mostly transported by means of hydrodynamic drag, form clouds that can remain afloat for long times. In subsaturated air environments, the dependence of pathogen-laden particle dispersion on their size is complicated due to evaporation of the aqueous fraction. Particle dynamics can significantly change when ambient conditions favor rapid evaporation rates that result in a transition from buoyancyto-drag dominated dispersion regimes. To investigate the effect of particle size and evaporation on pathogen-laden cloud evolution, a direct numerical simulation of a mild cough was coupled with an evaporative Lagrangian particle advection model. The results suggest that while the dispersion of cough particles in the tails of the size distribution are unlikely to be disrupted by evaporative effects, preferential aerosol diameters (30-40 μm) may exhibit significant increases in the residence time and horizontal range under typical ambient conditions. Using estimations of the viral concentration in the spewed fluid and the number of ejected particles in a typical respiratory event, we obtained a map of viral load per volume of air at the end of the cough and the number of virus copies per inhalation in the emitter vicinity.

60 APPLIED LIFE SCIENCES↗

Volatile propellant droplet evaporation measurements in metered dose inhaler sprays

Many aerosol products rely on the rapid vaporization of volatile propellants to produce a fine spray. In the simplest case, these are binary mixtures of propellant and a delivered product which undergo a flash-evaporation process leaving only the less volatile product in the resultant droplet. In more complex applications, such as pressurized metered-dose inhalers, the non-propellant component may contain dissolved or suspended drug which precipitates or dries to form a matured particle. The size and morphology of the particles depend strongly on the time-history of the droplet as the propellant evaporates. However, measuring the dynamic evaporation processes that occur in dense sprays containing millions of droplets is challenging. In this paper, we demonstrate a novel application of Ultra Small Angle X-ray Scattering to measure the bulk composition of volatile HFC134a–ethanol sprays and compare the obtained results with simple evaporation models in a dry nitrogen environment. The data reveal that diffusion-limiting processes inside the droplet are equally important as external convection and mixing-limited factors in determining evaporative timescales.

42 ENGINEERING↗

Efficiency Limits of Evaporative Fabric Drying Methods

Cloth drying is a major consumer of energy, and most drying is conducted by evaporative methods. The evaporative drying energy efficiency limit is commonly assumed to be 100%: one unit of latent heat removed per unit of energy expended. However, this ignores the “free drying” available from unsaturated ambient air and the possible role of heat pumping. We demonstrate that efficiency limits for evaporative drying are fundamentally related to both drying rate and ambient psychrometric conditions. A relationship among efficiency, drying rate, and ambient conditions is quantified for several evaporative drying technologies, and a comparison among evaporative technologies is provided. In addition, a comparison is provided between efficiency limits and state of the art device performance. This research will help guide future research in the most promising directions.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

Factors influencing quantum evaporation of helium from polar semiconductors from first principles

While there is much indirect evidence for the existence of dark matter (DM), to date it has evaded detection. Current efforts focus on DM masses over ~GeV—to push the sensitivity of DM searches to lower masses, new DM targets and detection schemes are needed. In this work, we focus on the latter—a novel detection scheme recently proposed to detect 10–100 meV phonons in polar target materials. Previous work showed that well-motivated models of DM can interact with polar semiconductors to produce an athermal population of phonons. This new sensing scheme proposes that these phonons then facilitate quantum evaporation of 3 He from a van der Waals film deposited on the target material. However, a fundamental understanding of the underlying process is still unclear, with several uncertainties related to the precise rate of evaporation and how it can be controlled. In this work, we use ab initio density functional theory calculations to compare the adsorption energies of helium atoms on a polar target material, sodium iodide, to understand the underlying evaporation physics. We explore the role of surface termination, monolayer coverage, and elemental species on the rate of He evaporation from the target material. Using this, we discuss the optimal target features for He-evaporation experiments and their range of tunability through chemical and physical modifications such as applied field and surface termination.

36 MATERIALS SCIENCE↗

Psychrometric Analysis for New NuMI Evaporator Weather Station

Tritium (H-3) is a weakly radioactive isotope of hydrogen and is a byproduct of accelerator operations at Fermi National Accelerator Laboratory (Fermilab). The Neutrinos at the Main Injector (NuMI) target produced tritiated condensate exhausted via the MI-65 building evaporators. Re-condensation of tritium evaporate was observed on the MI-65 rooftop, on nearby buildings, and on the surrounding grounds due to inefficiency of the existing evaporator system. A new evaporator system is being designed to eliminate re-condensation, and psychrometric data (temperature, humidity and dew point) plays a vital role in determining the location of a weather station to control the new evaporator system.

Alvarado-Anderson, Chase↗